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Ravi P. Singh

Publications and source records attributed to Ravi P. Singh.

14 recordsLinked to original sources

Stacking-tuned superconductivity and competing charge-density-wave states in NbSe$_2$

Layer stacking provides a powerful yet underexplored route for reshaping collective quantum order in van der Waals materials. Here we use high-resolution scanning tunneling microscopy and spectroscopy to show that the stacking sequence alone can qualitatively transform the charge density and superconducting orders in NbSe$_2$, while preserving the same in-plane atomic structure. Comparing the 4Ha and 2H polytypes, we find that, unlike the ubiquitous triangular incommensurate $3Q^\mathrm{I}$ order of 2H-NbSe$_2$, 4Ha-NbSe$_2$ hosts two competing CDW states with no measurable correlation with local strain: a unidirectional commensurate $1Q^\mathrm{C}$ phase and a triangular incommensurate $3Q^\mathrm{I}$ phase, with $Q^\mathrm{I}=Q^\mathrm{C}+δ$. We introduce a phase-resolved analysis that directly maps the gradient of the CDW phases and reveals vortices bound to the $1Q^\mathrm{C}$ - $3Q^\mathrm{I}$ phase boundaries. These vortices accommodate the momentum mismatch $δ$ through abrupt $2π$ phase slips, providing a mechanism by which distinct charge orders coexist. Superconductivity is also reshaped by stacking, while both polytypes exhibit multiband pairing.

cond-mat.supr-con

Moiré-induced symmetry breaking of charge order in van der Waals heterostructures

Layered materials that stack different lattice symmetries are rare in nature. Misfit layered chalcogenides, which combine square and hexagonal lattices of rocksalt monochalcogenides and transition-metal dichalcogenides, provide a platform to explore how incommensurability and explicit symmetry breaking impact collective electronic phases. Here we use low-temperature scanning tunneling microscopy/spectroscopy to probe the misfit compounds (MS)$_{1+δ}$TaS$_{2}$ with M = Pb, Sn and track how the misfit interface reshapes the electronic ground state of the embedded 1H-TaS$_{2}$ monolayers. High-resolution STM imaging and Fourier analysis reveal that the charge-density wave (CDW) is incommensurate and fragments into nanometer-sized domains. Strikingly, the CDW exhibits a pronounced and anisotropic response to the uniaxial moiré potential imposed by the misfit layer: its coherence lengths and ordering wavevectors become inequivalent, demonstrating a strong nonlinear coupling between the intrinsic CDW instability and the symmetry-breaking moiré field. First-principles-informed multiscale modeling shows that this reorganization arises from the combined effect of interlayer charge transfer and the spatially anisotropic energy landscape introduced by the misfit interface. In contrast, superconductivity is comparatively insensitive to the moiré, revealing a uniform, single full-gap consistent with s-wave pairing. Our results establish heterosymmetry stacking as a route to engineer correlated states in van der Waals materials.

cond-mat.str-el

ARPES signature of the competition between magnetic order and Kondo effect in CeCoGe3

The competition between magnetic order and Kondo effect is essential for the rich physics of heavy fermion systems. Nevertheless, how such competition is manifested in the quasiparticle bands in a real periodic lattice remains elusive in spectroscopic experiments. Here we report a high-resolution photoemission study of the antiferromagnetic Kondo lattice system CeCoGe3 with a high TN1 of 21K. Our measurements reveal a weakly dispersive 4f band at the Fermi level near the Z point, arisingfrom moderate Kondo effect. The intensity of this heavy 4f band exhibits a logarithmic increase with lowering temperature and begins to deviate from this Kondo-like behavior below 25 K, just above TN1, and eventually ceases to grow below 12 K. Our work provides direct spectroscopic evidence for the competition between magnetic order and the Kondo effect in a Kondo lattice system with local-moment antiferromagnetism, indicating a distinct scenario for the microscopic coexistence and competition of these phenomena, which might be related to the real-space modulation.

cond-mat.str-el

Spin-polarized supercurrent through the van der Waals Kondo lattice ferromagnet Fe$_3$GeTe$_2$

In the new van der Waals Kondo-lattice Fe$_3$GeTe$_2$, itinerant ferromagnetism and heavy fermionic behaviour coexist. Both the key properties of such a system namely a spin-polarized Fermi surface and a low Fermi momentum are expected to significantly alter Andreev reflection dominated transport at a contact with a superconducting electrode, and display unconventional proximity-induced superconductivity. We observed interplay between Andreev reflection and Kondo resonance at mesoscopic interfaces between superconducting Nb and Fe$_3$GeTe$_2$. Above the critical temperature ($T_c$) of Nb, the recorded differential conductance ($dI/dV$) spectra display a robust zero-bias anomaly which is described well by a characteristic Fano line shape arising from Kondo resonance. Below $T_c$, the Fano line mixes with Andreev reflection dominated $dI/dV$ leading to a dramatic, unconventional suppression of conductance at zero bias. As a consequence, an analysis of the Andreev reflection spectra within a spin-polarized model yields an anomalously large spin-polarization which is not explained by the density of states of the spin-split bands at the Fermi surface alone. The results open up the possibilities of fascinating interplay between various quantum phenomena that may potentially emerge at the mesoscopic superconducting interfaces involving Kondo lattice systems hosting spin-polarized conduction electrons.

cond-mat.str-el

Rydberg Excitons in Synthetic Cuprous Oxide (Cu$_2$O)

High-lying Rydberg states of Mott-Wannier excitons are receiving considerable interest due to the possibility of adding long-range interactions to the physics of exciton-polaritons. Here, we study Rydberg excitation in bulk synthetic cuprous oxide grown by the optical float zone technique and compare the result with natural samples. X-ray characterization confirms both materials are mostly single crystal, and mid-infrared transmission spectroscopy revealed little difference between synthetic and natural material. The synthetic samples show principal quantum numbers up to $n=10$, exhibit additional absorption lines, plus enhanced spatial broadening and spatial inhomogeneity. Room temperature and cryogenic photoluminescence measurements reveal a significant excess of copper vacancies in the synthetic material. These measurements provide a route towards achieving \mbox{high-$n$} excitons in synthetic crystals, opening a route to scalable quantum devices.

cond-mat.mtrl-sci

Magnetization reversal, giant exchange bias effect and magnetoresistance in oxygen vacancy ordered Sr$_{4}$Fe$_{3}$CoO$_{11}$

We report the structural, magnetic, exchange bias and magnetotransport effect in Sr$_{4}$Fe$_{3}$CoO$_{11}$. The material crystallizes in the orthorhombic $\textit{Cmmm}$ space group. It shows antiferromagnetic (G-type) transition (T$_{N}$ = 255 K) along with interesting temperature induced magnetization reversal (T$_{Comp.}$= 47 K measured at 100 Oe). The magnetic reversal can be elucidated considering the increased magnetocrystalline anisotropy with Co substitution. Magnetoresistance measurements shows an interesting crossover from negative to positive side at $\sim$ 100 K. The negative magnetoresistance reaches 80 $\%$ at 25 K in 7 T magnetic field. Giant exchange bias effect is observed below T$_{N}$ under field cooling condition. The origin of the negative magnetoresistance and giant exchange bias in this sample can be attributed to the magnetic frustration.

cond-mat.str-el

Probing the superconducting ground state of the rare-earth ternary boride superconductors $R$RuB$_2$ ($R$ = Lu,Y) using muon-spin rotation and relaxation

The superconductivity in the rare-earth transition metal ternary borides $R$RuB$_2$ (where $R$ = Lu and Y) has been investigated using muon-spin rotation and relaxation. Measurements made in zero-field suggest that time-reversal symmetry is preserved upon entering the superconducting state in both materials; a small difference in depolarization is observed above and below the superconducting transition in both compounds, however this has been attributed to quasistatic magnetic fluctuations. Transverse-field measurements of the flux-line lattice indicate that the superconductivity in both materials is fully gapped, with a conventional s-wave pairing symmetry and BCS-like magnitudes for the zero-temperature gap energies. The electronic properties of the charge carriers in the superconducting state have been calculated, with effective masses $m^*/ m_\mathrm{e} = $ $9.8\pm0.1$ and $15.0\pm0.1$ in the Lu and Y compounds, respectively, with superconducting carrier densities $n_\mathrm{s} = $ ($2.73\pm0.04$) $\times 10^{28}$ m$^{-3}$ and ($2.17\pm0.02$) $\times 10^{28}$ m$^{-3}$. The materials have been classified according to the Uemura scheme for superconductivity, with values for $T_\mathrm{c}/T_\mathrm{F}$ of $1/(414\pm6)$ and $1/(304\pm3)$, implying that the superconductivity may not be entirely conventional in nature.

cond-mat.supr-con

Room Temperature Magnetoresistance and Exchange Bias in "314 - type" Oxygen-Vacancy Ordered SrCo$_{0.85}$Fe$_{0.15}$O$_{2.62}$

Herein, we report the magneto-transport and exchange bias effect in a "314 - type" oxygen - vacancy ordered material with composition SrCo$_{0.85}$Fe$_{0.15}$O$_{2.62}$. This material exhibits a ferrimagnetic transition above room temperature, at 315 K. The negative magnetoresistance starts to appear from room temperature (-1.3 $\%$ at 295 K in 70 kOe) and reaches a sizable value of 58 $\%$ at 4 K in 70 kOe. Large exchange bias effect is observed below 315 K when the sample is cooled in the presence of a magnetic field. The coexistence of nearly compensated and ferrimagnetic regions in the layered structure originate magnetoresistance and exchange bias in this sample. The appearance of a sizable magnetoresistance and giant exchange bias effect, especially near room temperature indicates that "314-type" cobaltates are a promising class of material systems for the exploration of materials with potential applications as magnetic sensors or in the area of spintronics.

cond-mat.str-el

Unveiling of Bragg glass to vortex glass transition by an ac driving force in a single crystal of Yb3Rh4Sn13

We present here some striking discrepancies in the results of ac and dc magnetization measurements performed in a single crystal of low Tc superconductor, Yb3Rh4Sn13. Fingerprint of a transition from an ordered vortex lattice a la Bragg glass (BG) phase to a partially-disordered vortex glass (VG) like phase gets unearthed under the influence of an ac driving force present inevitably in the isothermal ac susceptibility measurements. In contrast to its well-known effect of improving the state of spatial order in the vortex matter, the ac drive is surprisingly found to promote disorder by assisting the BG to VG transition to occur at a lower field value in this compound. On the other hand, the isothermal dc magnetization (M-H) scans, devoid of such a driving force, do not reveal this transition; they instead yield signature of another order-disorder transition at elevated fields, viz., peak effect (PE), located substantially above the BG to VG transition observed in the isothermal ac susceptibility measurements. Further, the evolution of PE feature with increasing field as observed in isofield ac susceptibility plots indicates emergence of an ordered vortex configuration (BG) from a disordered phase above a certain field, H* (~ 4 kOe). Below H*, the vortex matter created via field-cooling (FC) is found to be better spatially ordered than that prepared in zero field-cooled (ZFC) mode. This is contrary to the usual behavior anticipated near the high-field order-disorder transition (PE) wherein a FC state is supposed to be a supercooled disordered phase and the ZFC state is comparatively better ordered.

cond-mat.supr-con

Evidence of surface superconductivity and multi-quanta vortex states in a weakly-pinned single crystal of Ca3Ir4Sn13

We report here the observation of anomalous paramagnetic signal(s) in the isofield field-cooled cool-down magnetization scans (MFCC(T)) recorded for a single crystal of a low Tc superconductor Ca3Ir4Sn13. Novel features emanating from the MFCC(T) response include an oscillatory magnetization behaviour below Tc and a rich multiplicity (non-uniqueness) in magnetization ranging from diamagnetism to paramagnetism at a given H, T value. The metastability in MFCC(T) has been ascribed to non-unique coexistence of multi-quanta vortex states and single quantum (Abrikosov) vortices. Additionally, the isothermal M(H) scans recorded across a short window of temperature just below Tc show evidence for only the multi-quanta vortex states in the domain of surface superconductivity, with no fingerprint(s) of pinned Abrikosov lattice.

cond-mat.supr-con

Dual role of an ac driving force and the underlying two distinct order-disorder transitions in the vortex phase diagram of Ca3Ir4Sn13

We present distinct demarcation of the Bragg glass (BG) to multi-domain vortex glass (VG) transition line and the eventual amorphization of the VG phase in a weakly pinned single crystal of the superconducting compound Ca3Ir4Sn13 on the basis of comprehension of the different yields about the second magnetization peak (SMP) anomaly in the dc magnetization and the corresponding anomalous feature in the ac susceptibility measurements. The shaking by a small ac magnetic field, inevitably present in the ac susceptibility measurements, is seen to result in contrasting responses in two different portions of the field-temperature (H, T) phase space of the multi-domain VG. In one of the portions, embracing the BG to VG transition across the onset of the SMP anomaly, the ac drive is surprisingly seen to assist the transformation of the well ordered BG phase to a lesser ordered VG phase. The BG phase exists as a superheated state over a small portion of the VG space and this attests to the first order nature of the BG to VG transition.

cond-mat.supr-con

Crystal growth and properties of the non-centrosymmetric superconductor, Ru7B3

We describe the crystal growth of high quality single crystals of the non-centrosymmetric superconductor, Ru7B3 by the floating zone technique, using an optical furnace equipped with xenon arc lamps. The crystals obtained are large and suitable for detailed measurements, and have been examined using x-ray Laue patterns. The superconducting properties of the crystals obtained have been investigated by magnetisation and resistivity measurements. Crystals have also been grown starting with enriched 11B isotope, making them suitable for neutron scattering experiments.

cond-mat.supr-con

Anomalous Magnetic Properties of Sr2YRuO6

Anomalous magnetic properties of the double perovskite ruthenates compound Sr2YRuO6 are reported here. Magnetization measurements as a function of temperature in low magnetic fields show clear evidence for two components of magnetic order (TM1 ~ 32K and TM2 ~ 27K) aligned opposite to each other with respect to the magnetic field direction even though only Ru5+moments can order magnetically in this compound. The second component of the magnetic order at TM2 ~ 27K results only in a magnetization reversal, and not in the negative magnetization when the magnetization is measured in the field cooled (FC) mode. Isothermal magnetization (M-H) measurements show hysteresis with maximum coercivity (Hc) and remnant magnetization (Mr) at T ~ 27 K, corroborating the presence of the two oppositely aligned magnetic moments, each with a ferromagnetic component. The two components of magnetic ordering are further confirmed by the double peak structure in the heat capacity measurements. These anomalous properties have significance to some of the earlier results obtained for the Cu-substituted superconducting Sr2YRu1-xCuxO6 compounds.

cond-mat.str-el

Observation of magnetization reversal and negative magnetization in a double perovskite compound Sr2YbRuO6

Detailed magnetic properties of the compound Sr2YbRuO6 are presented here. The compound belongs to the family of double perovskites forming a monoclinic structure. Magnetization meas-urements reveal clear evidence for two components of magnetic ordering aligned opposite to each other, leading to a magnetization reversal, compensation temperature (T* = 34 K) and neg-ative magnetization at low temperatures and low magnetic fields. Heat capacity measurements corroborate the presence of two components in the magnetic ordering and a noticeable third anomaly at low temperatures (~15 K) which cannot be attributed the Schottky effect. The calcu-lated magnetic entropy is substantially lower than that expected for the ground states of the or-dered moments of Ru5+ and Yb3+, indicating the presence of large crystal field effects and/ or in-complete magnetic ordering and/or magnetic frustrations well above the magnetic ordering. An attempt is made to explain the magnetization reversal within the frameworks of available models.

cond-mat.str-el