arXiv subjects

Rebecca Flint

Publications and source records attributed to Rebecca Flint.

At least 19 recordsLinked to original sources

arXiv2025

Hidden symmetry-breaking in a kagome Ising ferromagnet

Kagome metals can host unconventional electronic phenomena that emerge from their frustrated lattice geometry and associated band topology. Correlated electronic orders, such as charge-density waves and superconductivity, are observed to intertwine with subtle time-reversal symmetry breaking whose microscopic origin is not currently understood. Here, we provide evidence for such time-reversal symmetry breaking in the kagome metal TbV$_6$Sn$_6$ arising from staggered magnetic moments within the kagome layers. TbV$_6$Sn$_6$ consists of metallic V kagome layers separated by Tb triangular layers that host Ising ferromagnetic order. Deep in the ferromagnetic state, the Tb Ising doublet ground state should display a single, dispersionless spin-flip excitation. Instead, inelastic neutron scattering reveals two sharp excitations associated with inequivalent Tb sites, demonstrating that a symmetry-broken phase coexists with Ising ferromagnetism. No additional structural or magnetic phase transitions are detected, and first-principles calculations rule out lattice distortions as the origin of the splitting. We attribute this effect to time-reversal symmetry breaking encoded by small V moments that couple to the Tb sublattice and leave a measurable spectral fingerprint. Our results establish rare-earth local moment spectroscopy as a sensitive probe of subtle broken symmetries and highlight an unexpected interplay between kagome magnetism and rare-earth local moment magnetism.

cond-mat.str-el↗

arXiv2025

Physical properties of $R$Co$_{2}$Al$_{8}$ ($R=$ La, Ce, Pr, Nd and Sm) single crystals: An emerging structure-type for anisotropic Kondo lattice studies

Systematic investigations of rare-earth ($R$) based intermetallic materials are a leading strategy to reveal the underlying mechanisms governing a range of physical phenomena, such as the formation of a Kondo lattice and competing electronic and magnetic anisotropies. In this work, the magnetic, thermal and transport properties of $R$Co$_{2}$Al$_{8}$ ($R=$ La, Ce, Pr, Nd and Sm) single crystals are presented. LaCo$_{2}$Al$_{8}$ is characterized as a Pauli paramagnet and transport measurements, with the current along and perpendicular to the orthorhombic $c$-axis ($\rho_{c}$ and $\rho_{ab}$, respectively), reveal a clear electronic anisotropy, with $\rho_{ab }\approx(4-7)\rho_{c }$ at $300$ K. We show that CeCo$_{2}$Al$_{8}$ is a Kondo-lattice for which the Kondo coherence temperature $T_{\text{K}}^{*}$, deduced from broad maximums in $\rho_{c}$ and $\rho_{ab}$ at $\approx$ 68 and 46 K, respectively, is also anisotropic. This finding is related to a possible underlying anisotropy of the Kondo coupling in CeCo$_{2}$Al$_{8}$. The Pr- and Nd-based materials present strong easy-axis anisotropy ($c$-axis) and antiferromagnetic (AFM) orders below $T=4.84$ K and $T=8.1$ K, respectively. Metamagnetic transitions from this AFM to a spin-polarized paramagnetic phase state are investigated by isothermal magnetization measurements. The Sm-based compound is also an easy-axis AFM with a transition at $T=21.6$ K.

cond-mat.str-el↗

arXiv2025

Search for stable and low-energy Ce-Co-Cu ternary compounds using machine learning

Cerium-based intermetallics have garnered significant research attention as potential new permanent magnets. In this study, we explore the compositional and structural landscape of Ce-Co-Cu ternary compounds using a machine learning (ML)-guided framework integrated with first-principles calculations. We employ a crystal graph convolutional neural network (CGCNN), which enables efficient screening for promising candidates, significantly accelerating the materials discovery process. With this approach, we predict five stable compounds, Ce3Co3Cu, CeCoCu2, Ce12Co7Cu, Ce11Co9Cu and Ce10Co11Cu4, with formation energies below the convex hull, along with hundreds of low-energy (possibly metastable) Ce-Co-Cu ternary compounds. First-principles calculations reveal that several structures are both energetically and dynamically stable. Notably, two Co-rich low-energy compounds, Ce4Co33Cu and Ce4Co31Cu3, are predicted to have high magnetizations.

cond-mat.mtrl-sci↗

arXiv2024

Nature of quantum criticality in the Ising ferromagnet TbV$_6$Sn$_6$

TbV$_6$Sn$_6$ is a topological metal where ferromagnetic Tb ions with strong uniaxial magnetic anisotropy interact with V kagome layers. Inelastic neutron scattering (INS) measurements show that the Tb ions adopt an Ising doublet ground state. Here, we consider whether a transverse magnetic field can drive TbV$_6$Sn$_6$ toward a quantum critical point, providing a rare example of transverse-field Ising criticality in a metallic compound. High-field magnetization measurements reveal a first-order-like spin-reorientation transition at 25.6 T. Our INS-based magnetic model finds that this is caused by an avoided crossing of an excited-state singlet with the ground-state doublet. Surprisingly, our model predicts that quantum critical and tricritical points are accessible within the range of experimentally determined model parameters and may be reached by varying the direction of an applied magnetic field.

cond-mat.str-el↗

arXiv2024

Tuning magnetic interactions with nonequilibrium optical phonon populations: a theoretical study

We theoretically explore how light-driven optical phonons can be used to drive magnetic exchange interactions into interesting physical regimes by developing a general theory of spin-phonon pumping in magnetic insulators with non-equilibrium optical phonon distributions, focusing on the diabatic regime where phonon frequencies are much larger than the magnetic interactions. We present several applications of spin-phonon pumping two-dimensional nearest-neighbor Heisenberg, XYZ and Kitaev models to examine what kind of further neighbor interactions and chiral fields can be generated, and how anisotropic couplings can be enhanced, showing that experimentally accessible non-equilibrium phonon distributions can generically drive significant frustration and realize a variety of spin liquid regimes. This effect is described for both direct and superexchange mechanisms, and we derive simple geometric rules for which phonon modes are ``spin-phonon'' active and for which magnetic interactions. Spin-phonon pumping provides an intriguing possibility for preferentially pumping specific magnetic interaction terms. In addition to generating further neighbor interactions, such pumping can lead to increased magnetic anisotropy for initially weakly anisotropic models, and selectively pumping the Kitaev-Heisenberg model can suppress undesirable Heisenberg terms while enhancing Kitaev interactions.

cond-mat.str-el↗

arXiv2024

Machine learning accelerated prediction of Ce-based ternary compounds involving antagonistic pairs

The discovery of novel quantum materials within ternary phase spaces containing antagonistic pair such as Fe with Bi, Pb, In, and Ag, presents significant challenges yet holds great potential. In this work, we investigate the stabilization of these immiscible pairs through the integration of Cerium (Ce), an abundant rare-earth and cost-effective element. By employing a machine learning (ML)-guided framework, particularly crystal graph convolutional neural networks (CGCNN), combined with first-principles calculations, we efficiently explore the composition/structure space and predict 9 stable and 37 metastable Ce-Fe-X (X=Bi, Pb, In and Ag) ternary compounds. Our findings include the identification of multiple new stable and metastable phases, which are evaluated for their structural and energetic properties. These discoveries not only contribute to the advancement of quantum materials but also offer viable alternatives to critical rare earth elements, underscoring the importance of Ce-based intermetallic compounds in technological applications.

cond-mat.mtrl-sci↗

arXiv2024

Algebraic Hastatic Order in One-Dimensional Two-Channel Kondo Lattice

The two-channel Kondo lattice likely hosts a rich array of phases, including hastatic order, a channel symmetry breaking heavy Fermi liquid. We revisit its one-dimensional phase diagram using density matrix renormalization group and, in contrast to previous work find algebraic hastatic orders generically for stronger couplings. These are heavy Tomonaga-Luttinger liquids with nonanalyticities at Fermi vectors captured by hastatic density waves. We also find a predicted additional non-local order parameter due to interference between hastatic spinors, not present at large-N; and residual repulsive interactions at strong coupling suggesting non-Fermi-liquid physics in higher dimensions.

cond-mat.str-el↗

arXiv2023

Floquet engineering multi-channel Kondo physics

Floquet engineering is a powerful technique using periodic potentials, typically laser light, to drive materials into regimes inaccessible in equilibrium. Here, we show that Kondo models can be driven to multi-channel degenerate points, even when the starting model is single-channel. These emergent channels are differentiated by symmetry, and their strength and number can be controlled by changing the light polarization, frequency and amplitude. Unpolarized light, constructed by polarization averaging, is particularly useful to induce three and four channel degeneracies. Multi-channel Kondo models host a wide variety of exotic phenomena, including non-Abelian anyons in impurity models and composite pair superconductivity in lattice models. We demonstrate our findings on both a simple square lattice toy model and a more realistic spin-orbit coupled model for $J=5/2$ Ce ions in a tetragonal environment, as relevant for the Ce 115 materials, and show that the transition temperature for composite pair superconductivity can be dynamically enhanced.

cond-mat.str-el↗

arXiv2023

Unified Theory of Hastatic order and Antiferromagnetism in URu$_2$Si$_2$

The hidden order phase of URu$_2$Si$_2$ has eluded identification for over thirty-five years. A compelling proposal that explains the Ising heavy-fermion nature of the material is \emph{hastatic order}: a symmetry breaking heavy-Fermi liquid arising from a spinorial microscopic hybridization. The original hastatic proposal cannot microscopically model the pressure induced antiferromagnetic phase; and while it predicts a spinorial order parameter, it does not provide any detectable signatures of the spinorial nature. Here, we present a more realistic microscopic model of hastatic order in URu$_2$Si$_2$ based on two conducting electron bands and explore its phase diagram in detail. Our model non-trivially preserves the Ising heavy-fermion physics of the original, while allowing us to tune between the antiferromagnet and hidden order using pressure analogues and magnetic field. Our model is also consistent with recent phenomenological predictions of not one, but two vector order parameters associated with the spinorial order that provide the first microscopic predictions for detecting the spinorial nature.

cond-mat.str-el↗

arXiv2021

Polarization as a tuning parameter for Floquet engineering: magnetism in the honeycomb, square, and triangular Mott insulators

Magnetic exchange couplings can be tuned by coupling to periodic light, where the frequency and amplitude are typically varied: a process known as Floquet engineering. The polarization of the light is also important, and in this paper, we show how different polarizations, including several types of unpolarized light, can tune the exchange couplings in distinct ways. Using unpolarized light, for example, it is possible to tune the material without breaking either time-reversal or any lattice symmetries. To illustrate these effects generically, we consider single-band Hubbard models at half-filling on the honeycomb, square and triangular lattices. We derive the effective Heisenberg spin models to fourth order in perturbation theory for arbitrary fixed polarizations, and several types of unpolarized light that preserve time-reversal and lattice symmetries. Coupling these models to periodic light tunes first, second and third neighbor exchange couplings, as well as ring exchange terms on the square and triangular lattices. Circularly polarized light induces chiral fields for the honeycomb and triangular lattices, which favors non-coplanar magnetism and potential chiral spin liquids. We discuss how to maximize the enhancement of the couplings without inducing heating.

cond-mat.str-el↗

arXiv2021

Floquet engineering correlated materials with unpolarized light

Floquet engineering is a powerful tool that drives materials with periodic light. Traditionally, the light is monochromatic, with amplitude, frequency, and polarization varied. We introduce Floquet engineering via unpolarized light built from quasi-monochromatic light, and show how it can modify strongly correlated systems, while preserving the original symmetries. Different types of unpolarized light can realize different strongly correlated phases As an example, we treat insulating magnetic materials on a triangular lattice and show how unpolarized light can induce a Dirac spin liquid.

cond-mat.str-el↗

arXiv2021

Mobile Majorana zero-modes in two-channel Kondo insulators

Non-abelian anyons are highly desired for topological quantum computation purposes, with Majorana fermions providing a promising route, particularly zero modes with non-trivial mutual statistics. Yet realizing Majorana zero modes in matter is a challenge, with various proposals in chiral superconductors, nanowires, and spin liquids, but no clear experimental examples. Heavy fermion materials have long been known to host Majorana fermions at two-channel Kondo impurity sites, however, these impurities cannot be moved adiabatically and generically occur in metals, where the absence of a gap removes the topological protection. Here, we consider an ordered lattice of these two-channel Kondo impurities, which at quarter-filling form a Kondo insulator. We show that topological defects in this state will host Majorana zero modes, or possibly more complicated parafermions. These states are protected by the insulating gap and may be adiabatically braided, providing the novel possibility of realizing topological quantum computation in heavy fermion materials.

cond-mat.str-el↗

arXiv2020

Signatures of spinorial order in URu$_2$Si$_2$: Landau-Ginzburg theory of hastatic order

The hidden order in URu$_2$Si$_2$ remains a compelling mystery after more than thirty years, with the order parameter still unidentified. One intriguing proposal for the phase has been hastatic order: a symmetry breaking heavy Fermi liquid with a spinorial hybridization that breaks both single and double time-reversal symmetry. Hastatic order is the first spinorial, rather than vectorial order in materials, but previous work has not yet found direct consequences of the spinorial nature. In this paper, we revisit the hastatic proposal within Landau-Ginzburg theory. Rather than a single spinorial order parameter breaking double-time-reversal symmetry, we find two gauge invariant vectorial orders: the expected composite order with on-site moments, and a new quantity capturing symmetries broken solely by the spinorial nature. We address the effect of fluctuations and disorder on the tetragonal symmetry breaking, explaining the absence of in-plane moments in URu$_2$Si$_2$ and predicting a new transition in transverse field.

cond-mat.str-el↗

arXiv2020

Symmetric spin liquids on the stuffed honeycomb lattice

We use a projective symmetry group analysis to determine all symmetric spin liquids on the stuffed honeycomb lattice Heisenberg model. This lattice interpolates between honeycomb, triangular and dice lattices, always preserving hexagonal symmetry, and it already has one spin liquid candidate, TbInO$_3$, albeit with strong spin-orbit coupling not considered here. In addition to the stuffed honeycomb lattice itself, we gain valuable insight into potential spin liquids on the honeycomb and triangular lattices, as well as how they might be connected. For example, the sublattice pairing state proposed on the honeycomb lattice connects to the uniform spinon Fermi surface that may be relevant for the triangular lattice with ring exchange, while there are no spin liquids competitive on both the $J_1-J_2$ honeycomb and triangular lattice limits. In particular, we find three stuffed honeycomb descendants of the U(1) Dirac spin liquid widely believed to be found on the $J_1-J_2$ triangular lattice. We also discuss how spin liquids near the honeycomb limit can potentially explain the physics of LiZn$_2$Mo$_3$O$_8$.

cond-mat.str-el↗

arXiv2019

Field-induced Ferrohastatic Order in Cubic Non-Kramers Doublet Systems

Cubic Pr-based compounds with $Γ_3$ non-Kramers doublet ground states can realize a novel heavy Fermi liquid with spinorial hybridization ('hastatic' order) that breaks time reversal symmetry. Several Pr-"1-2-20" materials exhibit a suggestive heavy Fermi liquid stabilized in intermediate magnetic fields; these provide key insight into the quadrupolar Kondo lattice. We develop a simple, yet realistic microscopic model of ferrohastatic order, and elaborate its experimental signatures and behavior in field, where it is a good candidate to explain the observed heavy Fermi liquids at intermediate fields in Pr(Ir,Rh)$_2$Zn$_{20}$. In addition, we develop the Landau theory of ferrohastatic order, which allows us to understand its behavior close to the transition and explore thermodynamic signatures from magnetic susceptibility to thermal expansion.

cond-mat.str-el↗

arXiv2018

Classical phase diagram of the stuffed honeycomb lattice

We investigate the classical phase diagram of the stuffed honeycomb Heisenberg lattice, which consists of a honeycomb lattice with a superimposed triangular lattice formed by sites at the center of each hexagon. This lattice encompasses and interpolates between the honeycomb, triangular and dice lattices, preserving the hexagonal symmetry while expanding the phase space for potential spin liquids. We use a combination of iterative minimization, classical Monte Carlo and analytical techniques to determine the complete ground state phase diagram. It is quite rich, with a variety of non-coplanar and non-collinear phases not found in the previously studied limits. In particular, our analysis reveals the triangular lattice critical point to be a multicritical point with two new phases vanishing via second order transitions at the critical point. We analyze these phases within linear spin wave theory and discuss consequences for the S = 1/2 spin liquid.

cond-mat.str-el↗

arXiv2018

Cubic hastatic order in the two-channel Kondo-Heisenberg model

Materials with non-Kramers doublet ground states naturally manifest the two-channel Kondo effect, as the valence fluctuations are from a non-Kramers doublet ground state to an excited Kramers doublet. Here, the development of a heavy Fermi liquid requires a channel symmetry breaking spinorial hybridization that breaks both single and double time-reversal symmetry, and is known as hastatic order. Motivated by cubic Pr-based materials with $Γ_3$ non-Kramers ground state doublets, this paper provides a survey of cubic hastatic order using the simple two-channel Kondo-Heisenberg model. Hastatic order necessarily breaks time-reversal symmetry, but the spatial arrangement of the hybridization spinor can be either uniform (ferrohastatic) or break additional lattice symmetries (antiferrohastatic). The experimental signatures of both orders are presented in detail, and include tiny conduction electron magnetic moments. Interestingly, there can be several distinct antiferrohastatic orders with the same moment pattern that break different lattice symmetries, revealing a potential experimental route to detect the spinorial nature of the hybridization. We employ an SU(N) fermionic mean-field treatment on square and simple cubic lattices, and examine how the nature and stability of hastatic order varies as we vary the Heisenberg coupling, conduction electron density, band degeneracies, and apply both channel and spin symmetry breaking fields. We find that both ferrohastatic and several types of antiferrohastatic orders are stabilized in different regions of the mean-field phase diagram, and evolve differently in strain and magnetic fields.

cond-mat.str-el↗

arXiv2017

Emergent Ising degrees of freedom above double-stripe magnetism

Double-stripe magnetism $[\mathbf{Q}=(π/2, π/2)]$ has been proposed as the magnetic ground state for both the iron-telluride and BaTi$_2$Sb$_2$O families of superconductors. Double-stripe order is captured within a $J_1-J_2-J_3$ Heisenberg model in the regime $J_3 \gg J_2 \gg J_1$. Intriguingly, besides breaking spin-rotational symmetry, the ground state manifold has three additional Ising degrees of freedom associated with bond-ordering. Via their coupling to the lattice, they give rise to an orthorhombic distortion and to two non-uniform lattice distortions with wave-vector $(π, π)$. Because the ground state is four-fold degenerate, modulo rotations in spin space, only two of these Ising bond order parameters are independent. Here we introduce an effective field theory to treat all Ising order parameters, as well as magnetic order, and solve it within a large-$N$ limit. All three transitions, corresponding to the condensations of two Ising bond order parameters and one magnetic order parameter are simultaneous and first order in three dimensions, but lower dimensionality, or equivalently weaker interlayer coupling, and weaker magnetoelastic coupling can split the three transitions, and in some cases allows for two separate Ising phase transitions above the magnetic one.

cond-mat.supr-con↗