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Renee R. Frontiera

Publications and source records attributed to Renee R. Frontiera.

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Measuring chiral phonons

Chiral phonons are quantized vibrations where the atomic motion in a solid breaks improper rotation symmetries. In many cases, chiral phonons possess angular momenta and are therefore selective to circularly polarized light. Both fundamental and applied research efforts on chiral phonons have been gaining increasing attention owing to their importance in a variety of fields including spintronics, spin-selective chemical reactions, thermal transport, quantum information processing and biosensing, where the bi-directional spin-lattice coupling enabled by chiral phonons can be harnessed in new ways, and potentially lead to new functionalities. Thus far, the studies of chiral phonons across diverse materials platforms have evolved largely independently within these fields, but the experimental techniques are often interrelated. In this perspective, we present a detailed description, as well as advantages and disadvantages of the current approaches for experimentally measuring chiral phonons in chiral and achiral materials. We conclude with a discussion of new methods for measuring chiral phonons. Ultimately, this work seeks to offer an experimental guide for systematically investigating the properties of chiral phonons in various materials systems and applications.

cond-mat.mtrl-sci

Quantification of Nuclear Coordinate Activation on Polaritonic Potential Energy Surfaces

Polaritonic states, which arise from strong coupling between light and matter, show great promise in modifying chemical reactivity. However, reproducible enhancement of chemical reactions with polaritons is challenging due to a lack of understanding on how to launch wavepackets along productive reactive coordinates while avoiding unproductive local minima in the multidimensional potential energy landscape. Here we employ resonance Raman intensity analysis to quantify mode-specific nuclear displacement values in pentacene thin films and pentacene exciton-polaritons. We find that coupling significantly changes the potential energy landscape, including both enhancement and suppression of nuclear displacements. We demonstrate that controlling cavity parameters enables selective steering of vibronic wavepackets. Our approach provides a quantitative methodology for screening polaritonic catalysts and opens new avenues for designing reproducible and effective cavity-controlled chemistry.

physics.chem-ph