arXiv subjects

Renyu Hu

Publications and source records attributed to Renyu Hu.

At least 73 records · Page 4Linked to original sources

arXiv2024

JWST observations of K2-18b can be explained by a gas-rich mini-Neptune with no habitable surface

JWST recently measured the transmission spectrum of K2-18b, a habitable-zone sub-Neptune exoplanet, detecting CH$_4$ and CO$_2$ in its atmosphere. The discovery paper argued the data are best explained by a habitable "Hycean" world, consisting of a relatively thin H$_2$-dominated atmosphere overlying a liquid water ocean. Here, we use photochemical and climate models to simulate K2-18b as both a Hycean planet and a gas-rich mini-Neptune with no defined surface. We find that a lifeless Hycean world is hard to reconcile with the JWST observations because photochemistry only supports $< 1$ part-per-million CH$_4$ in such an atmosphere while the data suggest about $\sim 1\%$ of the gas is present. Sustaining %-level CH$_4$ on a Hycean K2-18b may require the presence of a methane-producing biosphere, similar to microbial life on Earth $\sim 3$ billion years ago. On the other hand, we predict that a gas-rich mini-Neptune with $100 \times$ solar metallicity should have 4% CH$_4$ and nearly 0.1% CO$_2$, which are compatible with the JWST data. The CH$_4$ and CO$_2$ are produced thermochemically in the deep atmosphere and mixed upward to the low pressures sensitive to transmission spectroscopy. The model predicts H$_2$O, NH$_3$ and CO abundances broadly consistent with the non-detections. Given the additional obstacles to maintaining a stable temperate climate on Hycean worlds due to H$_2$ escape and potential supercriticality at depth, we favor the mini-Neptune interpretation because of its relative simplicity and because it does not need a biosphere or other unknown source of methane to explain the data.

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arXiv2024

GJ 367b is a dark, hot, airless sub-Earth

We present the mid-infrared (5-12 $μ$m) phase curve of GJ 367b observed by the Mid-Infrared Instrument (MIRI) on the James Webb Space Telescope (JWST). GJ 367b is a hot (T_eq=1370 K), extremely dense (10.2 +- 1.3 g/cm^3) sub-Earth orbiting a M dwarf on a 0.32 d orbit. We measure an eclipse depth of 79 +- 4 ppm, a nightside planet-to-star flux ratio of 4 +- 8 ppm, and a relative phase amplitude of 0.97 +- 0.10 -- all fully consistent with a zero-albedo planet with no heat recirculation. Su ch a scenario is also consistent with the phase offset of 11 +- 5 degrees East to within 2.2$σ$. The emission spectrum is likewise consistent with a blackbody with no heat redistribution and a low albedo of A_B ~ 0.1, with the exception of one anomalous wavelength bin that we attribute to unexplained systematics. The emission spectrum puts few constraints on the surface composition, but rules out a CO2 atmosphere >~ 1 bar, an outgassed atmosphere >~10 mbar (under heavily reducing conditions), or an outgassed atmosphere >~0.01 mbar (under heavily oxidizing conditions). The lack of day-night heat recirculation implies that 1 bar atmospheres are ruled out for a wide range of compositions, while 0.1 bar atmospheres are consistent with the data. Taken together with the fact that most of the dayside should be molten, our JWST observations suggest the planet must have lost the vast majority of its initial inventory of volatiles.

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arXiv2024

Super-Earth LHS3844b is tidally locked

Short period exoplanets on circular orbits are thought to be tidally locked into synchronous rotation. If tidally locked, these planets must possess permanent day- and nightsides, with extreme irradiation on the dayside and none on the nightside. However, so far the tidal locking hypothesis for exoplanets is supported by little to no empirical evidence. Previous work showed that the super-Earth LHS 3844b likely has no atmosphere, which makes it ideal for constraining the planet's rotation. Here we revisit the Spitzer phase curve of LHS 3844b with a thermal model of an atmosphere-less planet and analyze the impact of non-synchronous rotation, eccentricity, tidal dissipation, and surface composition. Based on the lack of observed strong tidal heating we rule out rapid non-synchronous rotation (including a Mercury-like 3:2 spin-orbit resonance) and constrain the planet's eccentricity to less than 0.001 (more circular than Io's orbit). In addition, LHS 3844b's phase curve implies that the planet either still experiences weak tidal heating via a small-but-nonzero eccentricity (requiring an undetected orbital companion), or that its surface has been darkened by space weathering; of these two scenarios we consider space weathering more likely. Our results thus support the hypothesis that short period rocky exoplanets are tidally locked, and further show that space weathering can significantly modify the surfaces of atmosphere-less exoplanets.

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arXiv2024

Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

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arXiv2023

The Importance of the Upper Atmosphere to CO/O$_2$ Runaway on Habitable Planets Orbiting Low-Mass Stars

Efforts to spectrally characterize the atmospheric compositions of temperate terrestrial exoplanets orbiting M-dwarf stars with the James Webb Space Telescope (JWST) are now underway. Key molecular targets of such searches include O$_2$ and CO, which are potential indicators of life. Recently, it was proposed that CO$_2$ photolysis generates abundant ($\gtrsim0.1$ bar) abiotic O$_2$ and CO in the atmospheres of habitable M-dwarf planets with CO$_2$-rich atmospheres, constituting a strong false positive for O$_2$ as a biosignature and further complicating efforts to use CO as a diagnostic of surface biology. Importantly, this implied that TRAPPIST-1e and TRAPPIST-1f, now under observation with JWST, would abiotically accumulate abundant O$_2$ and CO, if habitable. Here, we use a multi-model approach to re-examine photochemical O$_2$ and CO accumulation on planets orbiting M-dwarf stars. We show that photochemical O$_2$ remains a trace gas on habitable CO$_2$-rich M-dwarf planets, with earlier predictions of abundant O$_2$ and CO due to an atmospheric model top that was too low to accurately resolve the unusually-high CO$_2$ photolysis peak on such worlds. Our work strengthens the case for O$_2$ as a biosignature gas, and affirms the importance of CO as a diagnostic of photochemical O$_2$ production. However, observationally relevant false positive potential remains, especially for O$_2$'s photochemical product O$_3$, and further work is required to confidently understand O$_2$ and O$_3$ as biosignature gases on M-dwarf planets.

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arXiv2023

Detection of Carbon Monoxide in the Atmosphere of WASP-39b Applying Standard Cross-Correlation Techniques to JWST NIRSpec G395H Data

Carbon monoxide was recently reported in the atmosphere of the hot Jupiter WASP-39b using the NIRSpec PRISM transit observation of this planet, collected as part of the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) Program. This detection, however, could not be confidently confirmed in the initial analysis of the higher resolution observations with NIRSpec G395H disperser. Here we confirm the detection of CO in the atmosphere of WASP-39b using the NIRSpec G395H data and cross-correlation techniques. We do this by searching for the CO signal in the unbinned transmission spectrum of the planet between 4.6 and 5.0 $μ$m, where the contribution of CO is expected to be higher than that of other anticipated molecules in the planet's atmosphere. Our search results in a detection of CO with a cross-correlation function (CCF) significance of $6.6 σ$ when using a template with only ${\rm ^{12}C^{16}O}$ lines. The CCF significance of the CO signal increases to $7.5 σ$ when including in the template lines from additional CO isotopologues, with the largest contribution being from ${\rm ^{13}C^{16}O}$. Our results highlight how cross-correlation techniques can be a powerful tool for unveiling the chemical composition of exoplanetary atmospheres from medium-resolution transmission spectra, including the detection of isotopologues.

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arXiv2023

Reflected spectroscopy of small exoplanets III: probing the UV band to measure biosignature gasses

Direct-imaging observations of terrestrial exoplanets will enable their atmospheric characterization and habitability assessment. Considering the Earth, the key atmospheric signatures for the biosphere is O$_2$ and the photochemical product O$_3$. However, this O$_2$-O$_3$ biosignature is not detectable in the visible wavelengths for most of the time after the emergence of oxygenic photosynthesis life (i.e., the Proterozoic Earth). Here we demonstrate spectroscopic observations in the ultraviolet wavelengths for detecting and characterizing O$_2$ and O$_3$ in Proterozoic Earth-like planets, using ExoReL$^\Re$. For an O$_2$ mixing ratio 2 to 3 orders of magnitude less than the present-day Earth, and an O$_3$ mixing ratio of $10^{-7}-10^{-6}$, we find that O$_3$ can be detected and its mixing ratio can be measured precisely (within $~1$ order of magnitude) in the ultraviolet ($0.25-0.4\ μ$m) in addition to visible-wavelength spectroscopy. With modest spectral resolution ($R=7$) and S/N ($\sim10$) in the ultraviolet, the O$_3$ detection is robust against other potential gases absorbing in the ultraviolet (e.g., H$_2$S and SO$_2$), as well as the short-wavelength cutoff between 0.2 and 0.25 $μ$m. While the O$_3$ detection does not rely on the near-infrared spectra, extending the wavelength coverage to the near-infrared ($1-1.8\ μ$m) would provide essential information to interpret the O$_3$ biosignature, including the mixing ratio of H$_2$O, the cloud pressure, as well as the determination of the dominant gas of the atmosphere. The ultraviolet and near-infrared capabilities should thus be evaluated as critical components for future missions aiming at imaging and characterizing terrestrial exoplanets, such as the Habitable Worlds Observatory.

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arXiv2023

Potential Atmospheric Compositions of TRAPPIST-1 c constrained by JWST/MIRI Observations at 15 $μ$m

The first JWST observations of TRAPPIST-1 c showed a secondary eclipse depth of 421+/-94 ppm at 15 um, which is consistent with a bare rock surface or a thin, O2-dominated, low CO2 atmosphere (Zieba et al. 2023). Here, we further explore potential atmospheres for TRAPPIST-1 c by comparing the observed secondary eclipse depth to synthetic spectra of a broader range of plausible environments. To self-consistently incorporate the impact of photochemistry and atmospheric composition on atmospheric thermal structure and predicted eclipse depth, we use a two-column climate model coupled to a photochemical model, and simulate O2-dominated, Venus-like, and steam atmospheres. We find that a broader suite of plausible atmospheric compositions are also consistent with the data. For lower pressure atmospheres (0.1 bar), our O2-CO2 atmospheres produce eclipse depths within 1$σ$ of the data, consistent with the modeling results of Zieba et al. (2023). However, for higher-pressure atmospheres, our models produce different temperature-pressure profiles and are less pessimistic, with 1-10 bar O2, 100 ppm CO2 models within 2.0-2.2$σ$ of the measured secondary eclipse depth, and up to 0.5% CO2 within 2.9$σ$. Venus-like atmospheres are still unlikely. For thin O2 atmospheres of 0.1 bar with a low abundance of CO2 ($\sim$100 ppm), up to 10% water vapor can be present and still provide an eclipse depth within 1$σ$ of the data. We compared the TRAPPIST-1 c data to modeled steam atmospheres of $\leq$ 3 bar, which are 1.7-1.8$σ$ from the data and not conclusively ruled out. More data will be required to discriminate between possible atmospheres, or to more definitively support the bare rock hypothesis.

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arXiv2023

No thick carbon dioxide atmosphere on the rocky exoplanet TRAPPIST-1 c

Seven rocky planets orbit the nearby dwarf star TRAPPIST-1, providing a unique opportunity to search for atmospheres on small planets outside the Solar System (Gillon et al., 2017). Thanks to the recent launch of JWST, possible atmospheric constituents such as carbon dioxide (CO2) are now detectable (Morley et al., 2017, Lincowski et al., 2018}. Recent JWST observations of the innermost planet TRAPPIST-1 b showed that it is most probably a bare rock without any CO2 in its atmosphere (Greene et al., 2023). Here we report the detection of thermal emission from the dayside of TRAPPIST-1 c with the Mid-Infrared Instrument (MIRI) on JWST at 15 micron. We measure a planet-to-star flux ratio of fp/fs = 421 +/- 94 parts per million (ppm) which corresponds to an inferred dayside brightness temperature of 380 +/- 31 K. This high dayside temperature disfavours a thick, CO2-rich atmosphere on the planet. The data rule out cloud-free O2/CO2 mixtures with surface pressures ranging from 10 bar (with 10 ppm CO2) to 0.1 bar (pure CO2). A Venus-analogue atmosphere with sulfuric acid clouds is also disfavoured at 2.6 sigma confidence. Thinner atmospheres or bare-rock surfaces are consistent with our measured planet-to-star flux ratio. The absence of a thick, CO2-rich atmosphere on TRAPPIST-1 c suggests a relatively volatile-poor formation history, with less than 9.5 +7.5 -2.3 Earth oceans of water. If all planets in the system formed in the same way, this would indicate a limited reservoir of volatiles for the potentially habitable planets in the system.

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arXiv2023

Narrow loophole for H2-dominated atmospheres on habitable rocky planets around M dwarfs

Habitable rocky planets around M dwarfs that have H2-dominated atmospheres, if they exist, would permit characterizing habitable exoplanets with detailed spectroscopy using JWST, owing to their extended atmospheres and small stars. However, the H2-dominated atmospheres that are consistent with habitable conditions cannot be too massive, and a moderate-size H2-dominated atmosphere will lose mass to irradiation-driven atmospheric escape on rocky planets around M dwarfs. We evaluate volcanic outgassing and serpentinization as two potential ways to supply H2 and form a steady-state H2-dominated atmosphere. For rocky planets of 1-7 Earth mass and early, mid, and late M dwarfs, the expected volcanic outgassing rates from a reduced mantle fall short of the escape rates by >~1 order of magnitude, and a generous upper limit of the serpentinization rate is still less than the escape rate by a factor of a few. Special mechanisms that may sustain the steady-state H2-dominated atmosphere include direct interaction between liquid water and mantle, heat-pipe volcanism from a reduced mantle, and hydrodynamic escape slowed down by efficient upper-atmospheric cooling. It is thus unlikely to find moderate-size, H2-dominated atmospheres on rocky planets of M dwarfs that would support habitable environments.

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arXiv2023

Detection of carbon monoxide's 4.6 micron fundamental band structure in WASP-39b's atmosphere with JWST NIRSpec G395H

Carbon monoxide (CO) is predicted to be the dominant carbon-bearing molecule in giant planet atmospheres, and, along with water, is important for discerning the oxygen and therefore carbon-to-oxygen ratio of these planets. The fundamental absorption mode of CO has a broad double-branched structure composed of many individual absorption lines from 4.3 to 5.1 $\mathrmμ$m, which can now be spectroscopically measured with JWST. Here we present a technique for detecting the rotational sub-band structure of CO at medium resolution with the NIRSpec G395H instrument. We use a single transit observation of the hot Jupiter WASP-39b from the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) program at the native resolution of the instrument ($R \,{\sim} 2700$) to resolve the CO absorption structure. We robustly detect absorption by CO, with an increase in transit depth of 264 $\pm$ 68 ppm, in agreement with the predicted CO contribution from the best-fit model at low resolution. This detection confirms our theoretical expectations that CO is the dominant carbon-bearing molecule in WASP-39b's atmosphere, and further supports the conclusions of low C/O and super-solar metallicities presented in the JTEC ERS papers for WASP-39b.

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arXiv2023

Photochemically-produced SO$_2$ in the atmosphere of WASP-39b

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent observations from the JWST Transiting Exoplanet Early Release Science Program found a spectral absorption feature at 4.05 $μ$m arising from SO$_2$ in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M$_J$) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of $\sim$1100 K. The most plausible way of generating SO$_2$ in such an atmosphere is through photochemical processes. Here we show that the SO$_2$ distribution computed by a suite of photochemical models robustly explains the 4.05 $μ$m spectral feature identified by JWST transmission observations with NIRSpec PRISM (2.7$σ$) and G395H (4.5$σ$). SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The sensitivity of the SO$_2$ feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of $\sim$10$\times$ solar. We further point out that SO$_2$ also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.

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arXiv2023

Constraints on the Size and Composition of the Ancient Martian Atmosphere from Coupled CO2-N2-Ar Isotopic Evolution Models

Present-day Mars is cold and dry, but mineralogical and morphological evidence shows that liquid-water existed on the surface of ancient Mars. In order to explain this evidence and assess ancient Mars's habitability, one must understand the size and composition of the ancient atmosphere. Here we place constraints on the ancient Martian atmosphere by modeling the coupled, self-consistent evolution of atmospheric CO2, N2, and Ar on Mars from 3.8 billion years ago (Ga) to the present. Our model traces the evolution of these species' abundances and isotopic composition caused by atmospheric escape, volcanic outgassing, and crustal interaction. Using a Markov-Chain Monte Carlo method to explore a plausible range of parameters, we find hundreds of thousands of model solutions that recreate the modern Martian atmosphere. These solutions indicate that Mars's atmosphere contained 0.3-1.5 bar CO2 and 0.1-0.5 bar N2 at 3.8 Ga. The global volume of deposited carbonates critically determines the ancient atmospheric composition. For example, a ~1 bar CO2 ancient atmosphere with 0.2-0.4 bar N2 requires ~0.9 bar CO2 deposited in carbonates primarily in open-water systems. With the joint analysis of C, N, and Ar isotopes, we refine the constraints on the relative strengths of outgassing and sputtering, leading to an indication of a reduced early mantle from which the outgassing is sourced. Our results indicate that a CO2-N2 atmosphere with a potential H2 component on ancient Mars is consistent with Mars's geochemical evolution and may explain the evidence for its past warm and wet climate.

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arXiv2022

Early Release Science of the exoplanet WASP-39b with JWST NIRCam

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $μ$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $μ$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere.

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arXiv2022

Early Release Science of the Exoplanet WASP-39b with JWST NIRSpec G395H

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $μ$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$σ$) and H$_2$O (21.5$σ$), and identify SO$_2$ as the source of absorption at 4.1 $μ$m (4.8$σ$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range.

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arXiv2022

Spectropolarimetry as a Means to Address Cloud Composition and Habitability for a Cloudy Exoplanetary Atmosphere in the Habitable Zone

In our solar system, the densely cloud-covered atmosphere of Venus stands out as an example of how polarimetry can be used to gain information on cloud composition and particle mean radius. With current interest running high on discovering and characterizing extrasolar planets in the habitable zone where water exists in the liquid state, making use of spectropolarimetric measurements of directly-imaged exoplanets could provide key information unobtainable through other means. In principle, spectropolarimetric measurements can determine if acidity causes water activities in the clouds to be too low for life. To this end, we show that a spectropolarimeter measurement over the range 400 nm - 1000 nm would need to resolve linear polarization to a precision of about 1% or better for reflected starlight from an optically thick cloud-enshrouded exoplanet. We assess the likelihood of achieving this goal by simulating measurements from a notional spectropolarimeter as part of a starshade configuration for a large space telescope (a HabEx design, but for a 6 m diameter primary mirror). Our simulations include consideration of noise from a variety of sources. We provide guidance on limits that would need to be levied on instrumental polarization to address the science issues we discuss. For photon-limited noise, integration times would need to be of order one hour for a large radius (10 Earth radii) planet to more than 100 hours for smaller exoplanets depending on the star-planet separation, planet radius, phase angle and desired uncertainty. We discuss implications for surface chemistry and habitability.

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arXiv2022

A transmission spectrum of the sub-Earth planet L98-59~b in 1.1-1.7 $μ$m

With the increasing number of planets discovered by TESS, the atmospheric characterization of small exoplanets is accelerating. L98-59 is a M-dwarf hosting a multi-planet system, and so far, four small planets have been confirmed. The innermost planet b is $\sim15\%$ smaller and $\sim60\%$ lighter than Earth, and should thus have a predominantly rocky composition. The Hubble Space Telescope observed five primary transits of L98-59b in $1.1-1.7\ μ$m, and here we report the data analysis and the resulting transmission spectrum of the planet. We measure the transit depths for each of the five transits and, by combination, we obtain a transmission spectrum with an overall precision of $\sim20$ ppm in for each of the 18 spectrophotometric channels. With this level of precision, the transmission spectrum does not show significant modulation, and is thus consistent with a planet without any atmosphere or a planet having an atmosphere and high-altitude clouds or haze. The scenarios involving an aerosol-free, H$_2$-dominated atmosphere with H$_2$O or CH$_4$ are inconsistent with the data. The transmission spectrum also disfavors, but does not rules out, an H$_2$O-dominated atmosphere without clouds. A spectral retrieval process suggests that an H$_2$-dominated atmosphere with HCN and clouds or haze may be the preferred solution, but this indication is non-conclusive. Future James Webb Space Telescope observations may find out the nature of the planet among the remaining viable scenarios.

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arXiv2022

Identification of carbon dioxide in an exoplanet atmosphere

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called "metallicity"), and thus formation processes of the primary atmospheres of hot gas giants. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2 but have not yielded definitive detections due to the lack of unambiguous spectroscopic identification. Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science Program (ERS). The data used in this study span 3.0 to 5.5 μm in wavelength and show a prominent CO2 absorption feature at 4.3 μm (26σ significance). The overall spectrum is well matched by one-dimensional, 10x solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide, and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 μm that is not reproduced by these models.

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