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Renyu Hu

Publications and source records attributed to Renyu Hu.

At least 127 records · Page 7Linked to original sources

A Case for an Atmosphere on Super-Earth 55 Cancri e

One of the primary questions when characterizing Earth-sized and super-Earth-sized exoplanets is whether they have a substantial atmosphere like Earth and Venus or a bare-rock surface like Mercury. Phase curves of the planets in thermal emission provide clues to this question, because a substantial atmosphere would transport heat more efficiently than a bare-rock surface. Analyzing phase curve photometric data around secondary eclipse has previously been used to study energy transport in the atmospheres of hot Jupiters. Here we use phase curve, Spitzer time-series photometry to study the thermal emission properties of the super-Earth exoplanet 55 Cancri e. We utilize a semi-analytical framework to fit a physical model to the infrared photometric data at 4.5 micron. The model uses parameters of planetary properties including Bond albedo, heat redistribution efficiency (i.e., ratio between radiative timescale and advective timescale of the atmosphere), and atmospheric greenhouse factor. The phase curve of 55 Cancri e is dominated by thermal emission with an eastward-shifted hot spot. We determine the heat redistribution efficiency to be ~1.47, which implies that the advective timescale is on the same order as the radiative timescale. This requirement cannot be met by the bare-rock planet scenario because heat transport by currents of molten lava would be too slow. The phase curve thus favors the scenario with a substantial atmosphere. Our constraints on the heat redistribution efficiency translate to an atmospheric pressure of ~1.4 bar. The Spitzer 4.5-micron band is thus a window into the deep atmosphere of the planet 55 Cancri e.

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Exploring Other Worlds: Science Questions for Future Direct Imaging Missions (EXOPAG SAG15 Report)

The NASA Exoplanet Exploration Program's SAG15 group has solicited, collected, and organized community input on high-level science questions that could be addressed with future direct imaging exoplanet missions and the type and quality of data answering these questions will require. Input was solicited through a variety of forums and the report draft was shared with the exoplanet community continuously during the period of the report development (Nov 2015 -- May 2017). The report benefitted from the input of over 50 exoplanet scientists and from multiple open-forum discussions at exoplanet and astrobiology meetings. The SAG15 team has identified three group of high-level questions, those that focus on the properties of planetary systems (Questions A1--A2), those that focus on the properties of individual planets (Questions B1--B4), and questions that relate to planetary processes (Questions C1--C4). The questions in categories A, B, and C require different target samples and often different observational approaches. For each questions we summarize the current body of knowledge, the available and future observational approaches that can directly or indirectly contribute to answering the question, and provide examples and general considerations for the target sample required.

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Observing Exoplanets with High Dispersion Coronagraphy. I. The scientific potential of current and next-generation large ground and space telescopes

Direct imaging of exoplanets presents a formidable technical challenge owing to the small angular separation and high contrast between exoplanets and their host stars. High Dispersion Coronagraphy (HDC) is a pathway to achieve unprecedented sensitivity to Earth-like planets in the habitable zone. Here, we present a framework to simulate HDC observations and data analyses. The goal of these simulations is to perform a detailed analysis of the trade-off between raw star light suppression and spectral resolution for various instrument configurations, target types, and science cases. We predict the performance of an HDC instrument at Keck observatory for characterizing directly imaged gas-giant planets in near infrared bands. We also simulate HDC observations of an Earth-like planet using next-generation ground-based (TMT) and spaced-base telescopes (HabEx and LUVOIR). We conclude that ground-based ELTs are more suitable for HDC observations of an Earth-like planet than future space-based missions owing to the considerable difference in collecting area. For ground-based telescopes, HDC observations can detect an Earth-like planet in the habitable zone around an M dwarf star at 10$^{-4}$ starlight suppression level. Compared to the 10$^{-7}$ planet/star contrast, HDC relaxes the starlight suppression requirement by a factor of 10$^3$. For space-based telescopes, detector noise will be a major limitation at spectral resolutions higher than 10$^4$. Considering detector noise and speckle chromatic noise, R=400 (1600) is the optimal spectral resolutions for HabEx(LUVOIR). The corresponding starlight suppression requirement to detect a planet with planet/star contrast=$6.1\times10^{-11}$ is relaxed by a factor of 10 (100) for HabEx (LUVOIR).

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Hypotheses for near-surface exchange of methane on Mars

The Curiosity rover recently detected a background of 0.7 ppb and spikes of 7 ppb of methane on Mars. This in situ measurement reorients our understanding of the Martian environment and its potential for life, as the current theories do not entail any geological source or sink of methane that varies sub-annually. In particular, the 10-fold elevation during the southern winter indicates episodic sources of methane that are yet to be discovered. Here we suggest a near-surface reservoir could explain this variability. Using the temperature and humidity measurements from the rover, we find that perchlorate salts in the regolith deliquesce to form liquid solutions, and deliquescence progresses to deeper subsurface in the season of the methane spikes. We therefore formulate the following three testable hypotheses. The first scenario is that the regolith in Gale Crater adsorbs methane when dry and releases this methane to the atmosphere upon deliquescence. The adsorption energy needs to be 36 kJ/mol to explain the magnitude of the methane spikes, higher than existing laboratory measurements. The second scenario is that microorganisms convert organic matter in the soil to methane when they are in liquid solutions. This scenario does not require regolith adsorption, but entails extant life on Mars. The third scenario is that deep subsurface aquifers produce the bursts of methane. Continued in situ measurements of methane and water, as well as laboratory studies of adsorption and deliquescence, will test these hypotheses and inform the existence of the near-surface reservoir and its exchange with the atmosphere.

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A map of the large day-night temperature gradient of a super-Earth exoplanet

Over the past decade, observations of giant exoplanets (Jupiter-size) have provided key insights into their atmospheres, but the properties of lower-mass exoplanets (sub-Neptune) remain largely unconstrained because of the challenges of observing small planets. Numerous efforts to observe the spectra of super-Earths (exoplanets with masses of one to ten times that of Earth) have so far revealed only featureless spectra. Here we report a longitudinal thermal brightness map of the nearby transiting super-Earth 55 Cancri e revealing highly asymmetric dayside thermal emission and a strong day-night temperature contrast. Dedicated space-based monitoring of the planet in the infrared revealed a modulation of the thermal flux as 55 Cancri e revolves around its star in a tidally locked configuration. These observations reveal a hot spot that is located 41 +- 12 degrees east of the substellar point (the point at which incident light from the star is perpendicular to the surface of the planet). From the orbital phase curve, we also constrain the nightside brightness temperature of the planet to 1380 +- 400 kelvin and the temperature of the warmest hemisphere (centred on the hot spot) to be about 1300 kelvin hotter (2700 +- 270 kelvin) at a wavelength of 4.5 microns, which indicates inefficient heat redistribution from the dayside to the nightside. Our observations are consistent with either an optically thick atmosphere with heat recirculation confined to the planetary dayside, or a planet devoid of atmosphere with low-viscosity magma flows at the surface.

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The MUSCLES Treasury Survey III: X-ray to Infrared Spectra of 11 M and K Stars Hosting Planets

We present a catalog of panchromatic spectral energy distributions (SEDs) for 7 M and 4 K dwarf stars that span X-ray to infrared wavelengths (5 Å - 5.5 μm). These SEDs are composites of Chandra or XMM-Newton data from 5 - ~50 Å, a plasma emission model from ~50 - 100 Å, broadband empirical estimates from 100 - 1170 Å, HST data from 1170 - 5700 Å, including a reconstruction of stellar Lyα emission at 1215.67 Å, and a PHOENIX model spectrum from 5700 - 55000 Å. Using these SEDs, we computed the photodissociation rates of several molecules prevalent in planetary atmospheres when exposed to each star's unattenuated flux ("unshielded" photodissociation rates) and found that rates differ among stars by over an order of magnitude for most molecules. In general, the same spectral regions drive unshielded photodissociations both for the minimally and maximally FUV active stars. However, for ozone visible flux drives dissociation for the M stars whereas NUV flux drives dissociation for the K stars. We also searched for an FUV continuum in the assembled SEDs and detected it in 5/11 stars, where it contributes around 10% of the flux in the range spanned by the continuum bands. An ultraviolet continuum shape is resolved for the star ε Eri that shows an edge likely attributable to Si II recombination. The 11 SEDs presented in this paper, available online through the Mikulski Archive for Space Telescopes, will be valuable for vetting stellar upper-atmosphere emission models and simulating photochemistry in exoplanet atmospheres.

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Tracing the fate of carbon and the atmospheric evolution of Mars

The climate of Mars likely evolved from a warmer, wetter early state to the cold, arid current state. However, no solutions for this evolution have previously been found to satisfy the observed geological features and isotopic measurements of the atmosphere. Here we show that a family of solutions exist, invoking no missing reservoirs or loss processes. Escape of carbon via CO photodissociation and sputtering enriches heavy carbon (13C) in the Martian atmosphere, partially compensated by moderate carbonate precipitation. The current atmospheric 13C/12C and rock and soil carbonate measurements indicate an early atmosphere with a surface pressure <1 bar. Only scenarios with large amounts of carbonate formation in open lakes permit higher values up to 1.8 bar. The evolutionary scenarios are fully testable with data from the MAVEN mission and further studies of the isotopic composition of carbonate in the Martian rock record through time.

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Studying atmosphere-dominated hot Jupiter Kepler phase curves: Evidence that inhomogeneous atmospheric reflection is common

(abridged) We identify 3 Kepler transiting planets, Kepler-7b, Kepler-12b, and Kepler-41b, whose orbital phase-folded light curves are dominated by planetary atmospheric processes including thermal emission and reflected light, while the impact of non-atmospheric (i.e. gravitational) processes, including beaming (Doppler boosting) and tidal ellipsoidal distortion, is negligible. Therefore, those systems allow a direct view of their atmospheres without being hampered by the approximations used in the inclusion of both atmospheric and non-atmospheric processes when modeling the phase curve shape. Here we analyze Kepler-12b and Kepler-41b atmosphere based on their Kepler phase curve, while the analysis of Kepler-7b was presented elsewhere. The model we used efficiently computes reflection and thermal emission contributions to the phase curve, including inhomogeneous atmospheric reflection due to longitudinally varying cloud coverage. We confirm Kepler-12b and Kepler-41b show a westward phase shift between the brightest region on the planetary surface and the substellar point, similar to Kepler-7b. We find that reflective clouds located on the west side of the substellar point can explain the phase shift. The existence of inhomogeneous atmospheric reflection in all 3 of our targets, selected due to their atmosphere-dominated Kepler phase curve, suggests this phenomenon is common. Therefore it is likely to be present also in planetary phase curves that do not allow a direct view of the planetary atmosphere as they contain additional orbital processes. We discuss the implications of a bright-spot shift on the analysis of phase curves where both atmospheric and gravitational processes appear. We also discuss the potential detection of non-transiting but otherwise similar planets, whose mass is too small to show a gravitational photometric signal but their atmospheric signal is detectable.

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Stability of CO2 Atmospheres on Desiccated M Dwarf Exoplanets

We investigate the chemical stability of CO2-dominated atmospheres of desiccated M dwarf terrestrial exoplanets using a 1-dimensional photochemical model. Around Sun-like stars, CO2 photolysis by Far-UV (FUV) radiation is balanced by recombination reactions that depend on water abundance. Planets orbiting M dwarf stars experience more FUV radiation, and could be depleted in water due to M dwarfs' prolonged, high-luminosity pre-main sequences (Luger & Barnes 2015). We show that, for water-depleted M dwarf terrestrial planets, a catalytic cycle relying on H2O2 photolysis can maintain a CO2 atmosphere. However, this cycle breaks down for atmospheric hydrogen mixing ratios <1 ppm, resulting in ~40% of the atmospheric CO2 being converted to CO and O2 on a time scale of 1 Myr. The increased O2 abundance leads to high O3 concentrations, the photolysis of which forms another CO2-regenerating catalytic cycle. For atmospheres with <0.1 ppm hydrogen, CO2 is produced directly from the recombination of CO and O. These catalytic cycles place an upper limit of ~50% on the amount of CO2 that can be destroyed via photolysis, which is enough to generate Earth-like abundances of (abiotic) O2 and O3. The conditions that lead to such high oxygen levels could be widespread on planets in the habitable zones of M dwarfs. Discrimination between biological and abiotic O2 and O3 in this case can perhaps be accomplished by noting the lack of water features in the reflectance and emission spectra of these planets, which necessitates observations at wavelengths longer than 0.95 microns.

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Helium Atmospheres on Warm Neptune- and Sub-Neptune-Sized Exoplanets and Applications to GJ 436 b

Warm Neptune- and sub-Neptune-sized exoplanets in orbits smaller than Mercury's are thought to have experienced extensive atmospheric evolution. Here we propose that a potential outcome of this atmospheric evolution is the formation of helium-dominated atmospheres. The hydrodynamic escape rates of Neptune- and sub-Neptune-sized exoplanets are comparable to the diffusion-limited escape rate of hydrogen, and therefore the escape is heavily affected by diffusive separation between hydrogen and helium. A helium atmosphere can thus be formed -- from a primordial hydrogen-helium atmosphere -- via atmospheric hydrodynamic escape from the planet. The helium atmosphere has very different abundances of major carbon and oxygen species from those of a hydrogen atmosphere, leading to distinctive transmission and thermal emission spectral features. In particular, the hypothesis of a helium-dominated atmosphere can explain the thermal emission spectrum of GJ 436 b, a warm Neptune-sized exoplanet, while also consistent with the transmission spectrum. This model atmosphere contains trace amounts of hydrogen, carbon, and oxygen, with the predominance of CO over CH4 as the main form of carbon. With our atmospheric evolution model, we find that if the mass of the initial atmosphere envelope is 1E-3 planetary mass, hydrodynamic escape can reduce the hydrogen abundance in the atmosphere by several orders of magnitude in ~10 billion years. Observations of exoplanet transits may thus detect signatures of helium atmospheres and probe the evolutionary history of small exoplanets.

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Characterizing the Habitable Zones of Exoplanetary Systems with a Large Ultraviolet/Visible/Near-IR Space Observatory

Understanding the surface and atmospheric conditions of Earth-size, rocky planets in the habitable zones (HZs) of low-mass stars is currently one of the greatest astronomical endeavors. Knowledge of the planetary effective surface temperature alone is insufficient to accurately interpret biosignature gases when they are observed in the coming decades. The UV stellar spectrum drives and regulates the upper atmospheric heating and chemistry on Earth-like planets, is critical to the definition and interpretation of biosignature gases, and may even produce false-positives in our search for biologic activity. This white paper briefly describes the scientific motivation for panchromatic observations of exoplanetary systems as a whole (star and planet), argues that a future NASA UV/Vis/near-IR space observatory is well-suited to carry out this work, and describes technology development goals that can be achieved in the next decade to support the development of a UV/Vis/near-IR flagship mission in the 2020s.

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A Semi-Analytical Model of Visible-Wavelength Phase Curves of Exoplanets and Applications to Kepler-7 b and Kepler-10 b

Kepler has detected numerous exoplanet transits by precise measurements of stellar light in a single visible-wavelength band. In addition to detection, the precise photometry provides phase curves of exoplanets, which can be used to study the dynamic processes on these planets. However, the interpretation of these observations can be complicated by the fact that visible-wavelength phase curves can represent both thermal emission and scattering from the planets. Here we present a semi-analytical model framework that can be applied to study Kepler and future visible-wavelength phase curve observations of exoplanets. The model efficiently computes reflection and thermal emission components for both rocky and gaseous planets, considering both homogeneous and inhomogeneous surfaces or atmospheres. We analyze the phase curves of the gaseous planet Kepler-7 b and the rocky planet Kepler-10 b using the model. In general, we find that a hot exoplanet's visible-wavelength phase curve having a significant phase offset can usually be explained by two classes of solutions: one class requires a thermal hot spot shifted to one side of the substellar point, and the other class requires reflective clouds concentrated on the same side of the substellar point. The two solutions would require very different Bond albedos to fit the same phase curve; atmospheric circulation models or eclipse observations at longer wavelengths can effectively rule out one class of solutions, and thus pinpoint the albedo of the planet, allowing decomposition of the reflection and the thermal emission components in the phase curve. Particularly for Kepler-7 b, reflective clouds located on the west side of the substellar point can best explain its phase curve. We further derive that the reflectivity of the clear part of the atmosphere should be less than 7% and that of the cloudy part should be greater than 80% (abridged)

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Ammonia, Water Clouds and Methane Abundances of Giant Exoplanets and Opportunities for Super-Earth Exoplanets

Future direct-imaging exoplanet missions such as WFIRST/AFTA, Exo-C, and Exo-S will measure the reflectivity of exoplanets at visible wavelengths. The exoplanets to be observed will be located further away from their parent stars than is Earth from the Sun. These "cold" exoplanets have atmospheric environments conducive for the formation of water and/or ammonia clouds, like Jupiter in the Solar System. We study the science return from direct-imaging exoplanet missions, focusing on the exoplanet atmospheric compositions. First, the study shows that a low-resolution (R=70) reflection spectrum of a giant exoplanet at 600 - 1000 nm, for a moderate signal-to-noise ratio of 20, will allow measurements of both the pressure of the uppermost cloud deck and the mixing ratio of methane, if the uppermost cloud deck is located at the pressure level of 0.6 - 1.5 bars. Further increasing the signal-to-noise ratio can improve the measurement range of the cloud deck pressure to 0.2 - 4 bars. The strong and the weak absorption bands of methane allow the simultaneous measurements of cloud and gas; when the uppermost cloud deck is located shallower than the pressure level of 0.2, the weak bands are muted, and the cloud deck pressure and the mixing ratio of methane are not distinguishable from a single reflection spectrum. Second, future direct-imaging exoplanet missions may detect the broadband reflectivity of a few super-Earth exoplanets. If having H2O-dominated atmospheres, directly imaged super Earths are likely to have water clouds located shallower than 1E-3 bars. The very high clouds on these planets would mute most gas absorption features except for H2O, and these planets would occupy a confined phase space in the color-color diagrams.

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Photochemistry in Terrestrial Exoplanet Atmospheres III: Photochemistry and Thermochemistry in Thick Atmospheres on Super Earths and Mini Neptunes

Some super Earths and mini Neptunes will likely have thick atmospheres that are not H2-dominated. We have developed a photochemistry-thermochemistry kinetic-transport model for exploring the compositions of thick atmospheres on super Earths and mini Neptunes, applicable for both H2-dominated atmospheres and non-H2-dominated atmospheres. Using this model to study thick atmospheres for wide ranges of temperatures and elemental abundances, we classify them into hydrogen-rich atmospheres, water-rich atmospheres, oxygen-rich atmospheres, and hydrocarbon-rich atmospheres. We find that carbon has to be in the form of CO2 rather than CH4 or CO in a H2-depleted water-dominated thick atmosphere, and that the preferred loss of light elements from an oxygen-poor carbon-rich atmosphere leads to formation of unsaturated hydrocarbons (C2H2 and C2H4). We apply our self-consistent atmosphere models to compute spectra and diagnostic features for known transiting low-mass exoplanets GJ 1214 b, HD 97658 b, and 55 Cnc e. For GJ 1214 b like planets we find that (1) C2H2 features at 1.0 and 1.5 micron in transmission and C2H2 and C2H4 features at 9-14 micron in thermal emission are diagnostic for hydrocarbon-rich atmospheres; (2) a detection of water-vapor features and a confirmation of nonexistence of methane features would provide sufficient evidence for a water-dominated atmosphere. In general, our simulations show that chemical stability has to be taken into account when interpreting the spectrum of a super Earth/mini Neptune. Water-dominated atmospheres only exist for carbon to oxygen ratios much lower than the solar ratio, suggesting that this kind of atmospheres could be rare.

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Photochemistry in Terrestrial Exoplanet Atmospheres II: H2S and SO2 Photochemistry in Anoxic Atmospheres

Sulfur gases are common components in the volcanic and biological emission on Earth, and are expected to be important input gases for atmospheres on terrestrial exoplanets. We study the atmospheric composition and the spectra of terrestrial exoplanets with sulfur compounds (i.e., H2S and SO2) emitted from their surfaces. We use a comprehensive one-dimensional photochemistry model and radiative transfer model to investigate the sulfur chemistry in atmospheres ranging from reducing to oxidizing. The most important finding is that both H2S and SO2 are chemically short-lived in virtually all types of atmospheres on terrestrial exoplanets, based on models of H2, N2, and CO2 atmospheres. This implies that direct detection of surface sulfur emission is unlikely, as their surface emission rates need to be extremely high (>1000 times Earth's volcanic sulfur emission) for these gases to build up to a detectable level. We also find that sulfur compounds emitted from the surface lead to photochemical formation of elemental sulfur and sulfuric acid in the atmosphere, which would condense to form aerosols if saturated. For terrestrial exoplanets in the habitable zone of Sun-like stars or M stars, Earth-like sulfur emission rates result in optically thick haze composed of elemental sulfur in reducing H2-dominated atmospheres for a wide range of particle diameters (0.1-1 micron), which is assumed as a free parameter in our simulations. In oxidized atmospheres composed of N2 and CO2, optically thick haze, composed of elemental sulfur aerosols (S8) or sulfuric acid aerosols (H2SO4), will form if the surface sulfur emission is 2 orders of magnitude more than the volcanic sulfur emission of Earth. Although direct detection of H2S and SO2 by their spectral features is unlikely, their emission might be inferred by observing aerosol-related features in reflected light with future generation space telescopes.

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Photochemistry in Terrestrial Exoplanet Atmospheres I: Photochemistry Model and Benchmark Cases

We present a comprehensive photochemistry model for exploration of the chemical composition of terrestrial exoplanet atmospheres. The photochemistry model is designed from the ground up to have the capacity to treat all types of terrestrial planet atmospheres, ranging from oxidizing through reducing, which makes the code suitable for applications for the wide range of anticipated terrestrial exoplanet compositions. The one-dimensional chemical transport model treats up to 800 chemical reactions, photochemical processes, dry and wet deposition, surface emission and thermal escape of O, H, C, N and S bearing species, as well as formation and deposition of elemental sulfur and sulfuric acid aerosols. We validate the model by computing the atmospheric composition of current Earth and Mars and find agreement with observations of major trace gases in Earth's and Mars' atmospheres. We simulate several plausible atmospheric scenarios of terrestrial exoplanets, and choose three benchmark cases for atmospheres from reducing to oxidizing. The most interesting finding is that atomic hydrogen is always a more abundant reactive radical than the hydroxyl radical in anoxic atmospheres. Whether atomic hydrogen is the most important removal path for a molecule of interest also depends on the relevant reaction rates. We also find that volcanic carbon compounds (i.e., CH4 and CO2) are chemically long-lived and tend to be well mixed in both reducing and oxidizing atmospheres, and their dry deposition velocities to the surface control the atmospheric oxidation states. Furthermore, we revisit whether photochemically produced oxygen can cause false positives for detecting oxygenic photosynthesis, and find that in 1-bar CO2-rich atmospheres oxygen and ozone may build up to levels that have been previously considered unique signatures of life, if there is no surface emission of reducing gases...

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Quasars' Optical Polarization and Balmer Edge Feature Revealed by Ultra-Violet, and Polarized Visible to Near Infrared Emissions

Polarized emission from a quasar is produced by wavelength-independent electron scattering surrounding its accretion disc, and thus avoid the contamination from its host galaxy and reveal the intrinsic emission spectrum of the accretion disc. Ultra-violet (UV) emission from a quasar is normally free from the contamination from its host galaxy. Polarization fraction of the quasar's disc emission can therefore be determined by comparing total UV emission with polarized visible to near-infrared (NIR) emission; and the resulting continuum spectrum from UV to infrared can reveal the theoretically expected Balmer edge absorption feature. We fit the polarized spectra in visible and NIR bands together with the total UV spectra of two type-1 quasars (3C 95, 4C 09.72), to an extended geometrically thin and optically thick accretion disc model. In addition to the standard model, we include the Balmer edge absorption due to co-rotational neutral gas on a narrow annulus of the accretion disc. We find that the extended thin accretion disc model provides adequate description on the continuum spectra of the two quasars from UV to NIR wavelengths. A Monte-Carlo-Markov-Chain fitting to the continuum spectra is able to well constrain the true polarization fraction of the disk emission, which allows the Balmer edge feature to be completely revealed from polarized visible to UV continua. The Balmer edge feature is prominent in both quasars' spectra, and is significantly broadened due to the orbital motion of gas in the accretion disc. The broadening of the Balmer edge feature is therefore related to the quasar's inclination. This work proves the concept of determining quasar's inclination from the Balmer edge feature in their continuum spectra.

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Theoretical Spectra of Terrestrial Exoplanet Surfaces

We investigate spectra of airless rocky exoplanets with a theoretical framework that self-consistently treats reflection and thermal emission. We find that a silicate surface on an exoplanet is spectroscopically detectable via prominent Si-O features in the thermal emission bands of 7 - 13 μm and 15 - 25 μm. The variation of brightness temperature due to the silicate features can be up to 20 K for an airless Earth analog, and the silicate features are wide enough to be distinguished from atmospheric features with relatively high-resolution spectra. The surface characterization thus provides a method to unambiguously identify a rocky exoplanet. Furthermore, identification of specific rocky surface types is possible with the planet's reflectance spectrum in near-infrared broad bands. A key parameter to observe is the difference between K band and J band geometric albedos (A_g (K)-A_g (J)): A_g (K)-A_g (J) > 0.2 indicates that more than half of the planet's surface has abundant mafic minerals, such as olivine and pyroxene, in other words primary crust from a magma ocean or high-temperature lavas; A_g (K)-A_g (J) < -0.09 indicates that more than half of the planet's surface is covered or partially covered by water ice or hydrated silicates, implying extant or past water on its surface. Also, surface water ice can be specifically distinguished by an H-band geometric albedo lower than the J-band geometric albedo. The surface features can be distinguished from possible atmospheric features with molecule identification of atmospheric species by transmission spectroscopy. We therefore propose that mid-infrared spectroscopy of exoplanets may detect rocky surfaces, and near-infrared spectrophotometry may identify ultramafic surfaces, hydrated surfaces and water ice.

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