arXiv subjects

Ricardo P. S. M. Lobo

Publications and source records attributed to Ricardo P. S. M. Lobo.

4 recordsLinked to original sources

arXiv2026

Bonding Signatures of Incipient Electron Localization in Topological Chiral Semimetals Near the Metal-Insulator Transition

How do electronic localization and delocalization compete in solids beyond the traditional limiting cases of metals and iono-covalent insulators? Topological chiral semimetals (TCSMs), characterized by their unique crystal symmetry, offer an intriguing platform to explore this question. Here, we systematically compare TCSMs with covalent compounds, ordinary metals, and metavalent solids (incipient metals), and show that TCSMs occupy a distinct region in a multidimensional property fingerprint. Atom probe tomography reveals an unusual bond-rupture signature, consistent with a bonding regime intermediate between electron localization and delocalization. This interpretation is supported by measurements of optical properties showing a transfer of spectral weight from interband to intraband transitions. For highly conductive TCSMs, this transition is accompanied by the disappearance of the Born effective charge, a measure of chemical bond polarizability, while less conductive TCSMs retain a nonzero value. Together, these results identify a property based bonding perspective on TCSMs that distinguishes them from metals, covalent solids, and metavalent compounds. Although metavalent solids and TCSMs both lie near the metal-insulator transition and exhibit distorted crystal structures, ultrafast coherent phonon spectroscopy reveals fundamentally different lattice-dynamical responses: a phonon-driven Peierls-like instability in metavalent solids versus a robust chiral B20 bonding motif in TCSMs.

cond-mat.mtrl-sci↗

arXiv2024

Near-critical dark opalescence in out-of-equilibrium SF$_6$

The first-order phase transition between the liquid and gaseous phases ends at a critical point. Critical opalescence occurs at this singularity. Discovered in 1822, it is known to be driven by diverging fluctuations in the density. During the past two decades, boundaries between the gas-like and liquid-like regimes have been theoretically proposed and experimentally explored. Here, we show that fast cooling of near-critical sulfur hexafluoride (SF$_6$), in presence of Earth's gravity, favors dark opalescence, where visible photons are not merely scattered, but also absorbed. When the isochore fluid is quenched across the critical point, its optical transmittance drops by more than three orders of magnitude in the whole visible range, a feature which does not occur during slow cooling. We show that transmittance shows a dip at 2eV near the critical point, and the system can host excitons with binding energies ranging from 0.5 to 4 eV. The spinodal decomposition of the liquid-gas mixture, by inducing a periodical modulation of the fluid density, can provide a scenario to explain the emergence of this platform for coupling between light and matter. The possible formation of excitons and polaritons points to the irruption of quantum effects in a quintessentially classical context.

cond-mat.mtrl-sci↗

arXiv2022

Magnetic freeze-out and anomalous Hall effect in ZrTe$_5$

The ultra-quantum limit is achieved when a magnetic field confines an electron gas in its lowest spin-polarised Landau level. Here we show that in this limit, electron doped ZrTe$_5$ shows a metal-insulator transition followed by a sign change of the Hall and Seebeck effects at low temperature. We attribute this transition to a magnetic freeze-out of charge carriers on the ionised impurities. The reduction of the charge carrier density gives way to an anomalous Hall response of the spin-polarised electrons. This behaviour, at odds with the usual magnetic freeze-out scenario, occurs in this Dirac metal because of its tiny Fermi energy, extremely narrow band gap and a large $g$-factor. We discuss the different possible sources (intrinsic or extrinsic) for this anomalous Hall contribution.

cond-mat.mtrl-sci↗

arXiv2021

A counterexample to the conjectured Planckian bound on transport

It has recently been conjectured that the transport relaxation rate in metals is bounded above by the temperature of the system. In this work, we discuss the transport phenomenology of overdoped electron-doped cuprates, which we show constitute an unambiguous counterexample to this putative "Planckian" bound, raising serious questions about the efficacy of the bound.

cond-mat.str-el↗