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Richard D. Starr

Publications and source records attributed to Richard D. Starr.

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Evidence for Widespread Hydrogen Sequestration within the Moon's South Polar Cold Traps

The measured neutron flux from the Moons south polar region shows evidence of locally enhanced hydrogen concentrations, likely in the form of water ice, within most permanently shadowed regions (PSR), poleward of 77 deg S latitude. Results are consistent with the original findings of Watson et al, 1961, which found that the PSRs cryogenic surfaces create exclusive conditions for the sequestration of water ice, due to their extremely low sublimation rates. Widespread PSR hydrogenation is demonstrated in several studies by showing that the contrasting PSR area distribution is being instrumentally blurred. The PSRs expected hydrogen observations are correlated by their area fraction of the fixed 30 km diameter footprint area of the Collimated Sensor for Epithermal Neutrons (CSETN), which is part of the Lunar Exploration Neutron Detector (LEND) onboard the Lunar Reconnaissance Orbiter (LRO). The correlation indicates that the PSRs are similarly hydrogenated, with an expected concentration = 0.27 wt%, relative to that of the anhydrous reference terrain (lower bounds). Hydrogen concentrations are demonstrated to be correlated to maximum temperature distributions within the basins of Haworth, Shoemaker and Faustini PSRs. Cabeus-1 PSR shows an anomalously enhanced hydrogen concentration indicating a second process contributes to its hydrogen budget. Results are consistent with ongoing processes that introduce volatiles to the surface including outgassing, solar wind production with regolith silicates, and mixing from small scale meteor impacts and diurnal temperature variation. We validate the bandpass filter used to subtract CSETNs detection of uncollimated neutrons with profiles of several PSRs neutron suppression before and after processing. Keywords: Moon, Epithermal Neutron, Hydrogen, Water, Ice, Volatiles, LRO, LEND, Diviner, LOLA

astro-ph.EP

Chromium on Mercury: New results from the MESSENGER X-Ray Spectrometer and implications for the innermost planet's geochemical evolution

Mercury, the innermost planet, formed under highly reduced conditions, based mainly on surface Fe, S, and Si abundances determined from MESSENGER mission data. The minor element Cr may serve as an independent oxybarometer, but only very limited Cr data have been previously reported for Mercury. We report Cr/Si abundances across Mercury's surface based on MESSENGER X-Ray Spectrometer data throughout the spacecraft's orbital mission. The heterogeneous Cr/Si ratio ranges from 0.0015 in the Caloris Basin to 0.0054 within the high-magnesium region, with an average southern hemisphere value of 0.0008 (corresponding to about 200 ppm Cr). Absolute Cr/Si values have systematic uncertainty of at least 30%, but relative variations are more robust. By combining experimental Cr partitioning data along with planetary differentiation modeling, we find that if Mercury formed with bulk chondritic Cr/Al, Cr must be present in the planet's core and differentiation must have occurred at log fO2 in the range of IW-6.5 to IW-2.5 in the absence of sulfides in its interior, and a range of IW-5.5 to IW-2 with an FeS layer at the core-mantle boundary. Models with large fractions of Mg-Ca-rich sulfides in Mercury's interior are more compatible with moderately reducing conditions (IW-5.5 to IW-4) owing to the instability of Mg-Ca-rich sulfides at elevated fO2. These results indicate that if Mercury differentiated at a log fO2 lower than IW-5.5, the presence of sulfides whether in the form of a FeS layer at the top of the core or Mg-Ca-rich sulfides within the mantle would be unlikely.

astro-ph.EP

Global Major-Element Maps of Mercury from Four Years of MESSENGER X-Ray Spectrometer Observations

The X-Ray Spectrometer (XRS) on the MESSENGER spacecraft provided measurements of major-element ratios across Mercury's surface. We present global maps of Mg/Si, Al/Si, S/Si, Ca/Si, and Fe/Si derived from XRS data collected throughout MESSENGER's orbital mission. We describe the procedures we used to select and filter data and to combine them to make the final maps, which are archived in NASA's Planetary Data System. Areal coverage is variable for the different element-ratio maps, with 100% coverage for Mg/Si and Al/Si, but only 18% coverage for Fe/Si north of 30 $^{\circ}$ N, where the spatial resolution is highest. The spatial resolution is improved over previous maps by 10-15% because of the inclusion of higher-resolution data from late in the mission when the spacecraft periapsis altitude was low. Unlike typical planetary data maps, however, the spatial resolution of the XRS maps can vary from pixel to pixel, and thus care must be taken in interpreting small-scale features. We provide several examples of how the XRS maps can be used to investigate elemental variations in the context of geological features on Mercury, which range in size from single $\sim$100-km-diameter craters to large impact basins. We expect that these maps will provide the basis for and/or contribute to studies of Mercury's origin and geological history for many years to come.

astro-ph.EP

Modeling Orbital Gamma-Ray Spectroscopy Experiments at Carbonaceous Asteroids

To evaluate the feasibility of measuring differences in bulk composition among carbonaceous meteorite parent bodies from an asteroid or comet orbiter, we present the results of a performance simulation of an orbital gamma-ray spectroscopy ("GRS") experiment in a Dawn-like orbit around spherical model asteroids with a range of carbonaceous compositions. The orbital altitude was held equal to the asteroid radius for 4.5 months. Both the asteroid gamma-ray spectrum and the spacecraft background flux were calculated using the MCNPX Monte-Carlo code. GRS is sensitive to depths below the optical surface (to ~20--50 cm depth depending on material density). This technique can therefore measure underlying compositions beneath a sulfur-depleted (e.g., Nittler et al. 2001) or desiccated surface layer. We find that 3σ uncertainties of under 1 wt% are achievable for H, C, O, Si, S, Fe, and Cl for five carbonaceous meteorite compositions using the heritage Mars Odyssey GRS design in a spacecraft- deck-mounted configuration at the Odyssey end-of-mission energy resolution, FWHM = 5.7 keV at 1332 keV. The calculated compositional uncertainties are smaller than the compositional differences between carbonaceous chondrite subclasses.

astro-ph.EP