arXiv subjects

Riddhi Gupta

Publications and source records attributed to Riddhi Gupta.

3 recordsLinked to original sources

arXiv2026

Improved quantum sampling methods for molecular simulations

Quantum-selected configuration interaction (QSCI) methods use a quantum computer to identify dominant electronic configurations in the molecular ground state, while a classical computer diagonalizes the Hamiltonian within the reduced subspace spanned by those configurations. Sample-based quantum diagonalization (SQD), a leading QSCI approach, uses iterative classical post-processing to correct noisy quantum measurement to ensure that the corresponding configurations remain physically sensible. In this work, we show that SQD performance can be strongly influenced by uncontrolled growth of the classical diagonalization subspace. When classical resources are not explicitly constrained, classical uniform random sampling can reproduce SQD benchmarks as noise increases the diversity of sampled configurations. We show any fair benchmarking protocol of SQD must explicitly control diagonalization size over unique samples. We then address the problem of efficiently discovering physically relevant, energy-lowering configurations by introducing a measurement protocol based on non-orthogonal configuration interaction (NOCI). By distributing measurements across orbital bases optimized with respect to the molecular Hamiltonian, we obtain improved sample efficiency relative to measurements performed solely in the Hartree--Fock basis. Importantly, these improvements persist even under fixed classical resource budgets, demonstrating that the resulting configurations are of higher quality rather than being more numerous. Under our proposed benchmarking procedure, we establish measurement-basis engineering as a promising route to improving quantum sampling methods for electronic structure.

quant-ph↗

arXiv2025

Exploiting biased noise in variational quantum models

Variational quantum algorithms (VQAs) are promising tools for demonstrating quantum utility on near-term quantum hardware, with applications in optimisation, quantum simulation, and machine learning. While researchers have studied how easy VQAs are to train, the effect of quantum noise on the classical optimisation process is still not well understood. Contrary to expectations, we find that twirling, which is commonly used in standard error-mitigation strategies to symmetrise noise, actually degrades performance in the variational setting, whereas preserving biased or non-unital noise can help classical optimisers find better solutions. Analytically, we study a universal quantum regression model and demonstrate that relatively uniform Pauli channels suppress gradient magnitudes and reduce expressivity, making optimisation more difficult. Conversely, asymmetric noise such as amplitude damping or biased Pauli channels introduces directional bias that can be exploited during optimisation. Numerical experiments on a variational eigensolver for the transverse-field Ising model confirm that non-unital noise yields lower-energy states compared to twirled noise. Finally, we show that coherent errors are fully mitigated by re-parameterisation. These findings challenge conventional noise-mitigation strategies and suggest that preserving noise biases may enhance VQA performance.

quant-ph↗

arXiv2025

Quantum advantage without exponential concentration: Trainable kernels for symmetry-structured data

Quantum kernel methods promise enhanced expressivity for learning structured data, but their usefulness has been limited by kernel concentration and barren plateaus. Both effects are mathematically equivalent and suppress trainability. We analytically prove that covariant quantum kernels tailored to datasets with group symmetries avoid exponential concentration, ensuring stable variance and guaranteed trainability independent of system size. Our results extend beyond prior two-coset constructions to arbitrary coset families, broadening the scope of problems where quantum kernels can achieve advantage. We further derive explicit bounds under coherent noise models - including unitary errors in fiducial state preparation, imperfect unitary representations, and perturbations in group element selection - and show through numerical simulations that the kernel variance remains finite and robust, even under substantial noise. These findings establish a family of quantum learning models that are simultaneously trainable, resilient to coherent noise, and linked to classically hard problems, positioning group-symmetric quantum kernels as a promising foundation for near-term and scalable quantum machine learning.

quant-ph↗