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Rishabh Shukla

Publications and source records attributed to Rishabh Shukla.

At least 19 recordsLinked to original sources

A Hierarchical Approach to Imitation Learning for Manipulation Tasks Requiring Time Varying Forces

Diffusion policies have shown strong performance in learning complex, multi-modal behaviors for robotic manipulation. However, their application to contact-rich disassembly tasks remains limited by a key trade-off: the iterative denoising process introduces inference latencies that makes high frequency control difficult, which is essential for realizing dynamic interactions such as chiseling and prying. Recent action-chunking techniques mitigate latency but use an open-loop execution window, rendering the system blind to rapid force transients caused by fracture events. To bridge this gap, we introduce the Diffusion Policy Augmented by Fast Trajectory Generation (DPA-FTG). Compared to recent visual-tactile approaches that focus on positional correction, DPA-FTG decouples low-frequency planning from high-frequency force regulation. At the high level ($5$ Hz), a conditional diffusion model predicts a sequence of latent parameters for selecting a strategy from a learned vocabulary of task primitives. At the low level ($60$ Hz), a lightweight, force-conditioned policy acts as a neural impedance controller, modulating execution in real-time to maintain contact stability. We validate our approach on a bimanual battery disassembly task involving the separation of a compliant sheet. Experimental evaluation demonstrates that DPA-FTG outperforms state-of-the-art baselines, including Reactive Diffusion Policy (RDP).

cs.RO

IJCB-AFMFR 2026: Competition on Adapting Foundation Models for Face Recognition Using Synthetic Training Data

This paper presents a summary of the Competition on Adapting Foundation Models for Face Recognition Using Synthetic Training Data (AFMFR), held at the 2026 International Joint Conference on Biometrics (IJCB 2026). The competition received a total of eight valid submissions from four distinct teams across two complementary tracks: a Full Data Track, in which participants adapt the CLIP ViT-L/14 foundation model using large-scale synthetic identity data, and a Limited Data Track, designed to reflect more resource-constrained adaptation regimes. All training data was generated exclusively using IDPERTURB. Submitted solutions are ranked based on verification and identification performance across a diverse suite of benchmarks, including LFW, CFP-FP, AgeDB-30, CALFW, CPLFW, IJB-B, IJB-C, and TinyFace, using the Borda count method. Fairness evaluation is additionally conducted on the RFW dataset across four demographic groups. The results demonstrate that adaptation of the CLIP foundation model with synthetic training data substantially improves over the off-the-shelf model and, in several cases, surpasses the baseline. Notably, full fine-tuning with Sub-Center ArcFace (DMSTI-Neurotechnology) leads the Full Data Track, while rank-stabilized LoRA adaptation (Idiap-BSP) proves most effective under limited-data conditions.

cs.CV

Infrastructure-Guided Connectivity-Enhanced Road Crack Detection and Estimation

In this paper, we report the world's first infrastructure-guided communication-enhanced road crack detection pipeline that is effective and implementable on passenger vehicles. We first design a customized communication protocol to transmit the region of interest from the infrastructure to the vehicle. With proper camera image processing (e.g., dynamic cropping and frame selection), the focused images are provided to the crack detection model. Leveraging state-of-the-art crack detection model backbones and a carefully prepared dataset comprising a forward-facing view with a crack, we train the model to improve crack-detection performance. We demonstrate the full detection pipeline on an experimental vehicle platform, showcase the detection effectiveness, and project future research directions.

cs.CV

Finite element analysis of a nonlinear heat Equation with damping and pumping effects

We study the following nonlinear heat equation with damping and pumping effects (a reaction-diffusion equation) posed on a bounded simply connected convex domain $Ω\subset \mathbb{R}^d$, $d \geq 1$ with Lipschitz boundary $\partialΩ$: $$ \frac{\partial u(t)}{\partial t} - νΔu(t) + α|u(t)|^{p-2}u(t) - \sum_{\ell=1}^M β_{\ell} |u(t)|^{q_{\ell}-2}u(t) = f(t), \quad t>0, $$ subject to homogeneous Dirichlet boundary conditions and the initial condition $u(0)=u_0$, where $2 \leq p < \infty$ and $2 \leq q_{\ell} < p$ for $1 \leq \ell \leq M$. For $u_0 \in L^2(Ω)$ and $f \in L^2(0,T;H^{-1}(Ω))$, we establish the existence and uniqueness of a weak solution for all dimensions $d \in \mathbb{N}$ and damping exponents $2 \leq p < \infty$. Furthermore, for $u_0 \in H^2(Ω) \cap H_0^1(Ω)$ and $f \in H^1(0,T;H^1(Ω))$, we obtain regularity results: these hold for every $2 \leq p < \infty$ when $1 \leq d \leq 4$, and for $2 \leq p \leq \frac{2d-6}{d-4}$ when $d \geq 5$. We further conduct finite element analysis using conforming, nonconforming, and discontinuous Galerkin methods, deriving a priori error estimates for both semi- and fully discrete schemes, supported by numerical results. To relax restrictions on $p$ in the semidiscrete analysis, we use appropriate projection/interpolation operators: the Ritz projection in the conforming case ($2 \le p \le \frac{2d}{d-2}$), the Scott-Zhang interpolation for $\frac{2d}{d-2} < p \le \frac{2d-6}{d-4}$, the Clément interpolation in the nonconforming setting, and the $L^2$-projection in the DG framework. In the fully discrete case, error estimates hold for the above $p$-range under $u_0 \in D(A^{3/2})$ and $f \in H^1(0,T;H^1(Ω))$.

math.NA

Frustrated magnetism in antiferromagnetic nonsymmorphic square-net lattice: NdSbSe

Spintronics has emerged as a field of vast applicability, and layered magnetic materials have served as a ground for advancement in this direction. Here, we report the synthesis and detailed magnetic and specific heat studies on NdSbSe, (a ZrSiS-based structure) magnetic topological material. The temperature-dependent magnetization shows the presence of competing magnetic interactions ($T_N<T<150$ K) in addition to a long-range antiferromagnetic (AFM) ordering below 4.2~K. In the AFM state, the isothermal magnetization confirms spin reorientation to the critical magnetic field of 40 kOe. Frequency-dependent ac-susceptibility measurements have probed the nonequilibrium dynamics of frustrated magnetic moments (near 150 K). The $λ$-like peak at 3.8~K observed in the specific heat shifts to a lower temperature with applied magnetic fields and validates the AFM order. In addition, the specific heat does not exhibit any sign corresponding to the short-range magnetic order near 150 K (spin-glass-like memory effect). In addition, the derived parameters from specific heat suggest the presence of a strong electronic correlation in NdSbSe, resulting in a Kondo-like signature in temperature-dependent resistivity data.

cond-mat.str-el

Observation of an unconventional giant negative exchange bias effect in La$_{0.5}$Sr$_{0.5}$Co$_{0.85}$Nb$_{0.15}$O$_3$

We find an unconventional giant negative exchange bias (EB) of $H_{\rm EB}$ = --14.1~kOe at 2~K (cooling field of 50~kOe) in the cluster spin-glass (CSG) La$_{0.5}$Sr$_{0.5}$Co$_{0.85}$Nb$_{0.15}$O$_3$ perovsikte cobaltites. The magnetic memory effect, aging measurements, and nonlineraity in specific heat capacity reveal the glassy magnetic state at low temperatures. Further, the detailed analysis of {\it ac-}magnetic susceptibility confirms the glassy state below $\sim$58~K and the obtained characteristic spin-relaxation time-scale of $τ_0$ = 8.4$\times$10$^{-10}$~s indicates the presence of CSG. Moreover, the analysis of magnetic training effect using the classical EB relaxation model reveals that the frozen spins relax slowly as compared to the rotatable spins at the interface of antiferromagnetic/ferromagnetic (AFM/FM) regions in CSG. Interestingly, the dependence of EB parameters is found to be unconventional for cooling field $>$50~kOe as the $H\rm_{EB}$ and $M\rm_{EB}$ show decreasing trend instead of expected saturation at higher fields. This unusual nature emerges due to large negative values of intrinsic interface exchange coupling ($J_i$), i.e., --10.24$\pm$0.22~meV and --12.55$\pm$0.49~meV for the measuring fields of $\pm$50~kOe and $\pm$90~kOe, respectively, whereas the number of spins in the FM cluster ($N_{\rm FM}$) are found to be small in the range of 2.4--3.1. These obtained values of $J_i $ and $N_{\rm FM}$ indicate the dominant AFM interactions and the presence of FM clusters in the AFM matrix, respectively, which correlate well with the observed unconventional behavior of giant negative exchange bias in the present sample.

cond-mat.str-el

Evolution of complex magnetic phases and metal-insulator transition through Nb substitution in La$_{0.5}$Sr$_{0.5}$Co$_{1-x}$Nb$_x$O$_3$

We report the evolution of structural, magnetic, transport, and electronic properties of bulk polycrystalline La$_{0.5}$Sr$_{0.5}$Co$_{1-x}$Nb$_x$O$_3$ ($x =$ 0.025--0.25) samples. The Rietveld refinement of the x-ray diffraction patterns with R$\bar3$c space group reveals that the lattice parameters and rhombohedral distortion monotonously increase with the Nb$^{5+}$(4$d^0$) substitution ($x$). The magnetic susceptibility exhibits a decrease in the magnetic ordering temperature and net magnetization with $x$, which manifests that the Nb substitution dilutes the ferromagnetic (FM) double exchange interaction and enhances the antiferromagnetic (AFM) super-exchange interaction. Interestingly, for the $x>$ 0.1 samples the FM order is completely suppressed and the emergence of a glassy state is clearly evident. Moreover, the decrease in the coercivity (H$\rm_{C}$) and remanence (M$\rm_{r}$) with $x$ in the magnetic isotherms measured at 5~K further confirms the dominance of AFM interactions and reduction of FM volume fraction for the $x>$ 0.1 samples. More interestingly, we observe resistivity minima for the $x=$ 0.025 and 0.05 samples, which are analyzed using the quantum corrections in the conductivity, and found that the weak localization effect dominates over the renormalized electron-electron interactions in the 3D limit. Further, a semiconducting resistivity behavior is obtained for $x>$ 0.05, which follows the Arrhenius law at high temperatures ($\sim$160--320~K), and the 3D-variable range hopping prevails in the low-temperature region ($<$160~K). The core-level photoemission spectra confirm the valence state of constituent elements and the absence of Co$^{2+}$ is discernible.

cond-mat.str-el

Secure and Privacy Preserving Proxy Biometrics Identities

With large-scale adaption to biometric based applications, security and privacy of biometrics is utmost important especially when operating in unsupervised online mode. This work proposes a novel approach for generating new artificial fingerprints also called proxy fingerprints that are natural looking, non-invertible, revocable and privacy preserving. These proxy biometrics can be generated from original ones only with the help of a user-specific key. Instead of using the original fingerprint, these proxy templates can be used anywhere with same convenience. The manuscripts walks through an interesting way in which proxy fingerprints of different types can be generated and how they can be combined with use-specific keys to provide revocability and cancelability in case of compromise. Using the proposed approach a proxy dataset is generated from samples belonging to Anguli fingerprint database. Matching experiments were performed on the new set which is 5 times larger than the original, and it was found that their performance is at par with 0 FAR and 0 FRR in the stolen key, safe key scenarios. Other parameters on revocability and diversity are also analyzed for protection performance.

cs.CV

Investigation of lattice dynamics, magnetism and electronic transport in $β$-Na$_{0.33}$V$_2$O$_{5}$

We investigate the electronic and magnetic properties as well as lattice dynamics and spin-phonon coupling of $β$-Na$_{0.33}$V$_2$O$_5$ using temperature-dependent Raman scattering, dc-magnetization and dc-resistivity, x-ray photoemission, and absorption spectroscopy. The Rietveld refinement of XRD pattern with space group C2/m confirms the monoclinic structure. The analysis of temperature-dependent Raman spectra in a temperature range of 13--673~K reveals an anharmonic dependence of the phonon frequency and full width at half maximum, which is accredited to the symmetric phonon decay. However, below about 40 K, the hardening of the phonon frequency beyond anharmonicity is attributed to the spin-phonon coupling. Interestingly, the estimated effective magnetic moment $μ_{\rm eff}=$ 0.63~$μ_B$ from the magnetization data manifests a mixed-valence state of V ions in 4+ (18$\pm$1\%) and 5+ (82$\pm$1\%). A similar ratio of V$^{4+}$ to V$^{5+}$ is also observed in the x-ray photoemission and x-ray absorption near-edge spectra and that is found to be consistent with the sample stoichiometry. In addition, the V$^{4+}$ ions are distributed between different vanadium (V1 and V3) sites. The analysis of extended x-ray absorption fine structure at different V-sites gives the corresponding V--O bond lengths, which are utilized in the assignment of Raman modes. Moreover, the temperature-dependent resistivity resembles a semiconducting behavior where the charge carrier transport is facilitated by the band conduction at higher temperatures and via hopping $\le$260~K.

cond-mat.mtrl-sci

Probing the electronic and local structure of Sr$_{2-x}$La$_x$CoNbO$_6$ using near-edge and extended x-ray absorption fine structures

We report the electronic and local structural investigation of double pervoskites Sr$_{2-x}$La$_x$CoNbO$_6$ ($x=$ 0--1) using x-ray absorption near edge structure (XANES) and extended x-ray absorption fine structures (EXAFS) at the Nb, Co, and Sr $K$-edges. The $ab$ $initio$ simulations and detailed analysis of the Nb and Co $K$-edge XANES spectra demonstrate that the observed pre-edge features arise from the transition of 1$s$ electrons to the mixed $p-d$ hybridized states. We reveal a $z$-out Jahn-Teller (JT) distortion in the CoO$_6$ octahedra, which decreases monotonically due to an enhancement in the JT inactive Co$^{2+}$ ions with $x$ . On the other hand, the $z$-in distortion in NbO$_6$ octahedra remains unaltered up to $x=$ 0.4 and then decreases with further increase in $x$. This sudden change in the local coordination around Nb atoms is found to be responsible for the evolution of the antiferromagnetic interactions in $x \geqslant$ 0.6 samples. Also, we establish a correlation between the degree of octahedral distortion and intensity of the white line feature in the XANES spectra and possible reason for this are discussed. More interestingly, we observe the signature of KN$_1$ double electron excitation in the Sr $K$-edge EXAFS spectra for all the samples, which is found to be in good agreement with the $Z$+1 approximation. Further, the Co L$_{2,3}$ edge shows the reduction in the crystal field strength and hence an increase in the charge transfer energy ($Δ_{ct}$) with the La substitution.

cond-mat.str-el

Structural phase transition and its consequences on optical behavior of LaV$_{1-x}$Nb$_x$O$_4$

We present the structural, electronic, vibrational, and photoluminescence properties of polycrystalline LaV$_{1-x}$Nb$_x$O$_4$ ($x =$ 0--0.2) samples at room temperature. The substitution of Nb at the V site shows the fascinating structural and optical behavior due to their isoelectronic character and larger ionic radii of Nb$^{5+}$ as compared to the V$^{5+}$. The Rietveld refinement of x-ray diffraction patterns demonstrate that the $x=$ 0 sample exist in a monoclinic (P2$_1$/n) phase, whereas for the $x >$ 0, both monoclinic and scheelite-tetragonal (I4$_1$/a) phases co-exist in a certain proportion. Interestingly, a monotonous enhancement in the Raman spectral intensity with Nb substitution is correlated with the substitution induced increase in the scheelite-tetragonal phase. The x-ray absorption measurements reveal that the La ions exist in a trivalent oxidation state, while V and Nb cations possess 5+ oxidation state in tetrahedral coordination. Moreover, the Fourier-transform infrared (FTIR) spectra indicate that the Nb substitution give origin to some additional IR modes owing to the deformation of the VO$_4$$^{3-}$ tetrahedra and mixing of monoclinic and tetragonal phases. The photoluminescence measurements on these samples exhibit broadband spectra and their deconvolution designate the availability of more than one electron-hole pairs recombination center.

cond-mat.mtrl-sci

X-ray Absorption Spectroscopy Study of La$_{1-y}$Sr$_{y}$Co$_{1-x}$Nb$_x$O$_3$

We use x-ray absorption spectroscopy to investigate the local structure and electronic properties of bulk La$_{1-y}$Sr$_{y}$Co$_{1-x}$Nb$_x$O$_3$ ($y=$ 2$x$ as LSCNO and $y=$ 0 as LCNO) samples. The x-ray absorption near-edge spectra (XANES) of LSCNO at Co K-edge affirm the valence state of Co in 3+. However, in the case of the LCNO, a subtle variation in the valence state of Co ions from 3+ to 2+ is evident with Nb substitution. The detailed analysis of the Fourier transform (FT) of the extended x-ray absorption fine structure (EXAFS) for the LSCNO samples exhibit the two groups of the bond-lengths owing to the Jahn-Teller (JT) distortion in the CoO$_6$ octahedra, which manifest that the Co$^{3+}$ ions exist in the intermediate spin-state (t$^5_{2g}$e$^1_g$) at room temperature. However, we find that the JT distortion is not present in LCNO samples for $x>$0.025 due to an increase in the high-spin Co$^{2+}$/Co$^{3+}$ ions accompanied by the Nb--induced structural transformation. Intriguingly, the La L$_3$-edge spectra for the LSCNO samples exhibit that the La ions exist in the trivalent state and the local disorder around La atoms decreases with Sr and Nb substitution. Interestingly, the simulated FT of the EXAFS spectra at the La L$_3$-edge demonstrates the three groups of La--O bond lengths, which exhibit a monotonous change with Sr and Nb substitution. Moreover, the XANES measured at Sr and Nb K-edges confirm their oxidation state to be in 2+ and 5+, respectively.

cond-mat.mtrl-sci

Structural, transport, optical and electronic properties of Sr$_2$CoNbO$_6$ thin films

We study the effect of substrate induced strain on the structural, transport, optical and electronic properties of Sr$_2$CoNbO$_6$ double perovskite thin films. The reciprocal space mapping, $ϕ$-scan and high-resolution $θ$-2$θ$ scans of x-ray diffraction patterns suggest the epitaxial nature and high-quality of the films deposited on various single crystal ceramic substrates. A systematic enhancement in the dc electronic conductivity is observed with increase in the compressive strain, while a sharp reduction in case of tensile strain, which are further supported by change in the activation energy and density of states near the Fermi level. The optical band gap extracted from two distinct absorption bands, observed in the visible-near infrared spectroscopy show a non-monotonic behavior in case of compressive strain while significant enhancement with tensile strain. Unlike the bulk Sr$_2$CoNbO$_6$ (Co$^{3+}$ and Nb$^{5+}$), we observe different valence states of Co namely 2+, 3+ and 4+, and tetravalent Nb (4$d^1$) in the x-ray photoemission spectroscopy measurements. Moreover, a reduction in the average oxygen valency with the compressive strain due to enhancement in the covalent character of Co/Nb--O bond is evident. Interestingly, we observe sharp Raman active modes in these thin films, which indicates a significant enhancement in structural ordering as compared to the bulk.

cond-mat.mtrl-sci

Structural and transport properties of La$_{1-x}$Sr$_x$Co$_{1-y}$Nb$_y$O$_3$ thin films

We present the structural and transport properties of La$_{1-x}$Sr$_x$Co$_{1-y}$Nb$_y$O$_3$ ($y=$ 0.1 and $x=$ 0; $y=$ 0.15 and $x=$ 0.3) thin films grown on (001) orientated single crystalline ceramic substrates to investigate the effect of lattice induced compressive and tensile strain. The high resolution x-ray diffraction measurements, including $θ$-2$θ$ scan, $Φ$-scan, and reciprocal space mapping, affirm single phase; four-fold symmetry; good quality of deposited thin films. The atomic force micrographs confirm that these films have small root mean square roughness in the range of $\sim$0.5--7~nm. We observed additional Raman active modes in the films owing to the lowered crystal symmetry as compared to the bulk. More interestingly, the temperature dependent dc-resistivity measurements reveal that films become insulating due to induced lattice strain in comparison to bulk, however for the larger compressive strained films conductivity increase significantly owing to the higher degree of $p-d$ hybridization and reduction in bandwidth near the Fermi level.

cond-mat.mtrl-sci

Na-ion diffusion and electrochemical performance of NaVO$_3$ anode in Li/Na batteries

We study Na ion diffusion and electrochemical performance of NaVO$_3$ (NVO) as anode material in Li/Na--ion batteries with the specific capacity of $\approx$350 mAhg$^{-1}$ at the current density 11~mAg$^{-1}$ after 300 cycles. Remarkably, the capacity retains $\ge$200~mAhg$^{-1}$ even after 400~cycles at 44~mAg$^{-1}$ with Coulombic efficiency $>$99\%. The deduced diffusion coefficient from galvanostatic intermittent titration technique (GITT), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) measurements for NVO as anode in Li--ion battery is in the range of 10$^{-10}$--10$^{-12}$~cm$^2$s$^{-1}$. In case of Na-ion batteries, the NVO electrode exhibits initial capacity of 385~mAhg$^{-1}$ at 7~mAg$^{-1}$ current rate, but the capacity degradation is relatively faster in subsequent cycles. We find the diffusion coefficient of NVO--Na cells similar to that of NVO--Li. On the other hand, our charge discharge measurements suggest that the overall performance of NVO anode is better in Li--ion battery than Na-ion. Moreover, we use the density functional theory to simulate the energetics of Na vacancy formation in the bulk of the NVO structure, which is found to be 0.88~eV higher than that of the most stable (100) surface. Thus, the Na ion incorporation at the surface of the electrode material is more facile compared to the bulk.

physics.app-ph

Spin dynamics and unconventional magnetism in insulating La$_{(1-2x)}$Sr$_{2x}$Co$_{(1-x)}$Nb$_{x}$O$_3$

We study the structural, magnetic, transport and electronic properties of LaCoO$_3$ with Sr/Nb co-substitution, i.e., La$_{(1-2x)}$Sr$_{2x}$Co$_{(1-x)}$Nb$_{x}$O$_3$ using x-ray and neutron diffraction, dc and ac-magnetization, neutron depolarization, dc-resistivity and photoemission measurements. The powder x-ray and neutron diffraction data were fitted well with the rhombohedral crystal symmetry (space group \textit{R$\bar{3}$c}) in Rietveld refinement analysis. The calculated effective magnetic moment ($\approx$3.85~$μ_B$) and average spin ($\approx$1.5) of Co ions from the analysis of magnetic susceptibility data are consistent with 3+ state of Co ions in intermediate-spin (IS) and high-spin (HS) states in the ratio of $\approx$50:50, i.e., spin-state of Co$^{3+}$ is preserved at least up to $x=$ 0.1 sample. Interestingly, the magnetization values were significantly increased with respect to the $x=$ 0 sample, and the M-H curves show non-saturated behavior up to an applied maximum magnetic field of $\pm$70 kOe. The ac-susceptibility data show a shift in the freezing temperature with excitation frequency and the detailed analysis confirm the slower dynamics and a non-zero value of the Vogel-Fulcher temperature T$_0$, which suggests for the cluster spin glass. The unusual magnetic behavior indicates the presence of complex magnetic interactions at low temperatures. The dc-resistivity measurements show the insulating nature in all the samples. However, relatively large density of states $\approx$10$^{22}$ eV$^{-1}$cm$^{-3}$ and low activation energy $\approx$130~meV are found in $x=$ 0.05 sample. Using x-ray photoemission spectroscopy, we study the core-level spectra of La 3$d$, Co 2$p$, Sr 3$d$, and Nb 3$d$ to confirm the valence state.

cond-mat.str-el

Electrochemical properties of Na$_{0.66}$V$_4$O$_{10}$ nanostructures as cathode material in rechargeable batteries for energy storage applications

We report the electrochemical performance of nanostructures of Na$_{0.66}$V$_4$O$_{10}$ as cathode material for rechargeable batteries. The Rietveld refinement of room temperature x-ray diffraction pattern shows the monoclinic phase with C2/m space group. The cyclic voltammetry curves of prepared half-cells exhibit redox peaks at ~3.1 and 2.6~V, which are due to two-phase transition reaction between V$^{5+/4+}$ and can be assigned to the single step deintercalation/intercalation of Na-ion. We observe a good cycling stability with specific discharge capacity (measured vs. Na$^+$/Na) between 80 ($\pm$2) and 30 ($\pm$2) mAh g$^{-1}$ at a current density 3 and 50~mA g$^{-1}$, respectively. The electrochemical performance of Na$_{0.66}$V$_4$O$_{10}$ electrode was also tested with Li anode, which showed higher capacity, but decay faster than Na. Using density functional theory, we calculate the Na vacancy formation energies; 3.37~eV in the bulk of the material and 2.52~eV on the (100) surface, which underlines the importance of nanostructures.

cond-mat.mtrl-sci

Physical properties and electrochemical performance of Zn-substituted Na$_{0.44}$Mn$_{1-x}$Zn$_x$O$_2$ nanostructures as cathode in Na-ion batteries

We report the synthesis, physical properties and electrochemical performance of Zn substituted Na$_{0.44}$Mn$_{1-x}$Zn$_x$O$_2$ ($x=$ 0 -- 0.02) nanostructures as cathode in Na-ion batteries for energy storage applications. These samples stabilize in the orthorhombic structure and the morphology is found to be slab like with 100 -- 200~nm width and few micrometer of length. The resistivity measurements show highly insulating nature for all the samples, where the activation energy decreases with increasing Zn concentration indicating more defect levels in the band gap. The cyclic voltammogram (CV) shows reversible oxidation and reduction peaks, which clearly shift towards higher/lower potentials with increasing Zn concentration up to 2\%. We observed the specific capacity of about 100~mAh/g at current density of 4 mA/g and improved cycle life for Zn substituted $x=$ 0.005 sample. However, with further increasing the Zn concentration ($x=$ 0.02), the specific capacity decreases, which can be a manifestation of the decreased number of reduction peaks in the CV data.

cond-mat.mtrl-sci