arXiv subjects

Robert Clark

Publications and source records attributed to Robert Clark.

9 recordsLinked to original sources

arXiv2025

Sub-nm2 ferroelectric domains via charged 180 degree walls in ZrO2

Flat phonon bands in fluorite ferroelectrics (HfO2 or ZrO2) shrink polar domains laterally to an irreducible half-unit-cell width (0.27 nm) within which the vertical arrangement of dipoles is expected to remain uniform. We report on the direct observation of nonuniform and nearly discrete vertical arrangements of dipoles in ZrO2 thin films consisting of closely spaced head-to-head (HH) and tail-to-tail (TT) charged 180 degree walls, each exhibiting a distinct bulk-like structure. These charged domain walls (CDWs) further compress the irreducibly narrow, laterally stacked domains vertically to a thickness of 1-2.75 nm, yielding in-plane domains with sub-nm2 footprints-among the smallest ever reported for any ferroelectric material. The HH and TT walls form due to their flat longitudinal optical (LO) polar bands and are electrostatically stabilized by bound-charge compensation via interstitial oxygen atoms, which act as natural structural defects at the HH walls. Moreover, these walls are predicted to be conducting and to exhibit ultralow propagation barriers, with HH walls (1.6 meV) being far more mobile than TT walls (22.3 meV), indicating strong potential for low-voltage, domain-wall-based nanoelectronics.

cond-mat.mtrl-sci↗

arXiv2025

OmniScience: A Domain-Specialized LLM for Scientific Reasoning and Discovery

Large Language Models (LLMs) have demonstrated remarkable potential in advancing scientific knowledge and addressing complex challenges. In this work, we introduce OmniScience, a specialized large reasoning model for general science, developed through three key components: (1) domain adaptive pretraining on a carefully curated corpus of scientific literature, (2) instruction tuning on a specialized dataset to guide the model in following domain-specific tasks, and (3) reasoning-based knowledge distillation through fine-tuning to significantly enhance its ability to generate contextually relevant and logically sound responses. We demonstrate the versatility of OmniScience by developing a battery agent that efficiently ranks molecules as potential electrolyte solvents or additives. Comprehensive evaluations reveal that OmniScience is competitive with state-of-the-art large reasoning models on the GPQA Diamond and domain-specific battery benchmarks, while outperforming all public reasoning and non-reasoning models with similar parameter counts. We further demonstrate via ablation experiments that domain adaptive pretraining and reasoning-based knowledge distillation are critical to attain our performance levels, across benchmarks.

cs.AI↗

arXiv2025

Estimating Propensities of Selection for Big Datasets via Data Integration

Big data presents potential but unresolved value as a source for analysis and inference. However,selection bias, present in many of these datasets, needs to be accounted for so that appropriate inferences can be made on the target population. One way of approaching the selection bias issue is to first estimate the propensity of inclusion in the big dataset for each member of the big dataset, and then to apply these propensities in an inverse probability weighting approach to produce population estimates. In this paper, we provide details of a new variant of existing propensity score estimation methods that takes advantage of the ability to integrate the big data with a probability sample. We compare the ability of this method to produce efficient inferences for the target population with several alternative methods through an empirical study.

stat.ME↗

arXiv2024

The geographic flow of bank funding and access to credit: Branch networks, local synergies and competition

Geographic dispersion of depositors, borrowers, and banks may prevent funding from flowing to high loan demand areas, limiting credit access. Using bank-county-year level data, we provide evidence of the geographic imbalance of deposits and loans and develop a methodology for investigating the contribution to this imbalance of branch networks, market power, and scope economies. Results are based on a novel measure of imbalance and estimation of a structural model of bank competition that admits interconnections across locations and between deposit and loan markets. Counterfactual experiments show branch networks and competition contribute importantly to credit flow but benefit more affluent markets.

econ.GN↗

arXiv2024

An Empirical Comparison of Methods to Produce Business Statistics Using Non-Probability Data

There is a growing trend among statistical agencies to explore non-probability data sources for producing more timely and detailed statistics, while reducing costs and respondent burden. Coverage and measurement error are two issues that may be present in such data. The imperfections may be corrected using available information relating to the population of interest, such as a census or a reference probability sample. In this paper, we compare a wide range of existing methods for producing population estimates using a non-probability dataset through a simulation study based on a realistic business population. The study was conducted to examine the performance of the methods under different missingness and data quality assumptions. The results confirm the ability of the methods examined to address selection bias. When no measurement error is present in the non-probability dataset, a screening dual-frame approach for the probability sample tends to yield lower sample size and mean squared error results. The presence of measurement error and/or nonignorable missingness increases mean squared errors for estimators that depend heavily on the non-probability data. In this case, the best approach tends to be to fall back to a model-assisted estimator based on the probability sample.

stat.ME↗

arXiv2023

Using Cosmic Ray Muons to Assess Geological Characteristics in the Subsurface

Cosmic rays are energetic nuclei and elementary particles that originate from stars and intergalactic events. The interaction of these particles with the upper atmosphere produces a range of secondary particles that reach the surface of the earth, of which muons are the most prominent. With enough energy, muons can travel up to a few kilometers beneath the surface of the earth before being stopped completely. The terrestrial muon flux profile and associated zenith angle can be utilized to determine geological characteristics of a location without having to use conventional methods. This work intends to use a low-power plastic scintillator-based muon detection system for this non-destructive geological assay methodology. 4 custom designed plastic scintillation panels are used to realize two orthogonal detection planes. Simultaneous triggers between detectors from two planes indicate a coincidence event which is recorded using a data acquisition system from FNAL. In order to quantify the systematic uncertainties associated with the detector, such as energy depositions and angular resolution of the detector design, a Monte Carlo simulation using Geant4 is being developed. Simulated and experimental data will drive the development and validation of a reconstruction algorithm that, upon completion, is expected to predict average overburden and rock density. Extended detector exposure to muons can be used as a means to understand changes in the surrounding environment like rock porosity. On the experimental front, the measured flux data will be used to benchmark independent and established models. Successful proof-of-concept demonstration of this technology can open doors for long term non-invasive geological monitoring. The detector design, and experimental methodology are detailed in this work.

physics.ins-det↗

arXiv2023

Characterization of Fast Ion Transport via Position-Dependent Optical Deshelving

Ion transport is an essential operation in some models of quantum information processing, where fast ion shuttling with minimal motional excitation is necessary for efficient, high-fidelity quantum logic. While fast and cold ion shuttling has been demonstrated, the dynamics and specific trajectory of an ion during diabatic transport have not been studied in detail. Here we describe a position-dependent optical deshelving technique useful for sampling an ion's position throughout its trajectory, and we demonstrate the technique on fast linear transport of a $^{40}\text{Ca}^+$ ion in a surface-electrode ion trap. At high speed, the trap's electrode filters strongly distort the transport potential waveform. With this technique, we observe deviations from the intended constant-velocity (100 m/s) transport: we measure an average speed of 83(2) m/s and a peak speed of 251(6) m/s over a distance of 120 $\mu$m

quant-ph↗

arXiv2021

Antiferroelectric negative capacitance from a structural phase transition in zirconia

Crystalline materials with broken inversion symmetry can exhibit a spontaneous electric polarization, which originates from a microscopic electric dipole moment. Long-range polar or anti-polar order of such permanent dipoles gives rise to ferroelectricity or antiferroelectricity, respectively. However, the recently discovered antiferroelectrics of fluorite structure (HfO$_2$ and ZrO$_2$) are different: A non-polar phase transforms into a polar phase by spontaneous inversion symmetry breaking upon the application of an electric field. Here, we show that this structural transition in antiferroelectric ZrO$_2$ gives rise to a negative capacitance, which is promising for overcoming the fundamental limits of energy efficiency in electronics. Our findings provide insight into the thermodynamically 'forbidden' region of the antiferroelectric transition in ZrO$_2$ and extend the concept of negative capacitance beyond ferroelectricity. This shows that negative capacitance is a more general phenomenon than previously thought and can be expected in a much broader range of materials exhibiting structural phase transitions.

cond-mat.mtrl-sci↗

arXiv2015

Experimental demonstration of a surface-electrode multipole ion trap

We report on the design and experimental characterization of a surface-electrode multipole ion trap. Individual microscopic sugar particles are confined in the trap. The trajectories of driven particle motion are compared with a theoretical model, both to verify qualitative predictions of the model, and to measure the charge-to-mass ratio of the confined particle. The generation of harmonics of the driving frequency is observed as a key signature of the nonlinear nature of the trap. We remark on possible applications of our traps, including to mass spectrometry.

physics.atom-ph↗