arXiv subjects

Robson Christie

Publications and source records attributed to Robson Christie.

8 recordsLinked to original sources

arXiv2026

Quantum Stochastic Inflation

We formulate stochastic inflation in an open quantum system framework. The field coarse-grained in a patch of fixed physical size, and the total momentum of that patch, form a canonical pair and act on a one-mode Fock space which we identify as the "bulk". At each time step, new comoving modes join the coarse-grained patch and the bulk has to be redefined. This redefinition produces an entangled mode that is traced over, yielding a non-unitary evolution equation for the bulk's density matrix. For a free test field in de Sitter, one obtains GKLS dynamics, generated by an effective Hamiltonian and a single non-Hermitian Lindblad operator, hence diffusion and Hubble friction originate from the same quantum channel. The Wigner-Weyl transform of the GKLS equation leads to a Fokker-Planck equation for the Wigner function, which matches the one that applies to the classical phase-space distribution of stochastic inflation. We also provide several schemes under which one can unravel the GKLS dynamics into stochastic Schrodinger equations when continuous measurements of the decoupled mode are performed, making contact with Langevin formulations of stochastic inflation. In the light-field regime, an additional overdamped reduction can be performed by integrating out the momentum variable in the Wigner distribution, leading to Starobinsky's slow-roll Fokker-Planck equation. In that regime, the purity of the patch is strongly suppressed. In contrast, for heavy fields, field diffusion is suppressed and the coarse-grained patch remains close to a pure underdamped oscillator, which prevents a classical stochastic treatment.

hep-th↗

arXiv2026

Non-Equilibrium Dynamics of the Time-Dependent Excitonic Coupling in Fluorescent Protein Dimers

We quantify the excitonic coupling in the homodimer of dimeric Venus fluorescent protein using a quantum-classical hybrid workflow. Employing a transition-density coupling formalism, we calculate $J = 74.38~\mathrm{cm^{-1}}$, which is 5.6 times stronger than the far-field point-dipole estimate of $13.31~\mathrm{cm^{-1}}$. This disparity highlights the critical role of near-field multipolar effects at the 27.6~\r{A} chromophore centroid separation. Furthermore, we argue that a separation of timescales resolves the apparent theoretical tension between robust experimental excitonic couplings and the highly decoherent biological environment. While it has been hypothesised that the fluorescent protein $\beta$-barrel scaffold sustains coupling by attenuating thermal fluctuations, we emphasise that the separation of timescales fundamentally applies irrespective of the exact degree of environmental noise suppression. Collective photoexcitation imprints the Davydov splitting under optical-limit dielectric screening upon absorption, preceding bulk solvent relaxation and sub-picosecond environmental dephasing. To characterise the subsequent post-absorption evolution, we employ stochastic simulations for quantum parts to model the transition from a delocalised exciton superposition to incoherent hopping between localised chromophore states.

physics.chem-ph↗

arXiv2025

Cosmic Lockdown: When Decoherence Saves the Universe from Tunneling

We investigate how quantum decoherence influences the tunneling dynamics of quantum fields in cosmological spacetimes. Specifically, we study a scalar field in an asymmetric double-well potential during inflation, coupled to environmental degrees of freedom provided by a continuum of spectator fields. This setup enables a systematic derivation of both Markovian and non-Markovian master equations, along with their stochastic unravelings, which we solve numerically. We find that, while decoherence is essential for suppressing quantum interference between vacua, its impact on the relative vacuum populations is limited. Fields heavier than the Hubble scale relax adiabatically toward the true vacuum with high probability, while lighter fields exhibit non-adiabatic enhancements of false-vacuum occupation. Once the system has decohered, quantum tunneling between vacua becomes strongly suppressed, effectively locking the system into the stochastically selected local minimum. This ``cosmic lockdown'' mechanism is a manifestation of the quantum Zeno effect: environmental monitoring stabilizes enhanced false-vacuum occupation for light fields by preventing them from tunneling.

hep-th↗

arXiv2024

Quantum Simulation of Dynamical Transition Rates in Open Quantum Systems

Estimating transition rates in open quantum systems is hampered by computing-resource demands that grow rapidly with system size. We present a quantum-simulation framework that enables efficient estimation by recasting the transition rate, given as the time derivative of an equilibrium correlation function, into a set of independently measurable contributions. Each contribution term is evaluated as the expectation value of a parameter-tuned quantum process, thereby circumventing explicit Lindbladian numerics. We validate our method on a spin-1/2 decoherence model using an IBM quantum processor. Further, we apply the method to the Caldeira-Leggett model of quantum Brownian motion as a realistic and practically relevant setting and reaffirm the theoretical soundness and practical implementability. These results provide evidence that quantum simulation can deliver substantial computational advantages in studying open-system kinetics for quantum chemistry on an intermediate-scale quantum computer.

quant-ph↗

arXiv2024

The Sound of Decoherence

We explore an unconventional bridge between quantum mechanical density matrices and sound by mapping elements of the density matrix and their phases to auditory signals, thus introducing a framework for Open Quantum Sonification. Employing the eigenstates of the Hamiltonian operator as a basis, each quantum state contributes a frequency proportional to its energy level. The off-diagonal terms, which encode coherence and phase relationships between energy levels, are rendered as binaural signals presented separately to the left and right ears. We illustrate this method within the context of open quantum system dynamics governed by Lindblad equations, presenting first an example of quantum Brownian motion of a particle in a thermal bath, and second, a recoherence process induced by boundary driving that results in spin-helix states. This document serves as a companion to the corresponding audio visual simulations of these models available on the YouTube channel Open Quantum Sonification with the Python Codes on GitHub. The auditory analogy presented here provides an intuitive and experiential means of describing quantum phenomena such as tunnelling, thermalisation, decoherence, and recoherence.

quant-ph↗

arXiv2024

Transition Path and Interface Sampling of Stochastic Schr\"odinger Dynamics

We study rare transitions in Markovian open quantum systems driven with Gaussian noise, applying transition path and interface sampling methods to trajectories generated by stochastic Schr\"odinger dynamics. Interface and path sampling offer insights into rare event transition mechanisms while simultaneously establishing a quantitative measure of the associated rate constant. Here, we extend their domain to systems described by stochastic Schr\"odinger equations. As a specific example, we explore a model of quantum Brownian motion in a quartic double well, consisting of a particle coupled to a Caldeira-Leggett oscillator bath, where we note significant departures from the Arrhenius law at low temperatures due to the presence of an anti-Zeno effect.

quant-ph↗

arXiv2023

Quantum Tunnelling and Thermally Driven Transitions in a Double Well Potential at Finite Temperature

We explore dissipative quantum tunnelling, a phenomenon central to various physical and chemical processes, using a double-well potential model. This paper aims to bridge gaps in understanding the crossover from thermal activation to quantum tunnelling, a domain still shrouded in mystery despite extensive research. We study a Caldeira-Leggett-derived model of quantum Brownian motion and investigate the Lindblad and stochastic Schr\"{o}dinger dynamics numerically, seeking to offer new insights into the transition states in the crossover region. Our study has implications for quantum computing and understanding fundamental natural processes, highlighting the significance of quantum effects on transition rates and temperature influences on tunnelling. Additionally, we introduce a new model for quantum Brownian motion which takes Lindblad form and is formulated as a modification of the widely known model found in Breuer and Petruccione. In our approach, we remove the zero-temperature singularity resulting in a better description of low-temperature quantum Brownian motion near a potential minima.

quant-ph↗

arXiv2022

Quantum-jump vs stochastic Schr\"{o}dinger dynamics for Gaussian states with quadratic Hamiltonians and linear Lindbladians

The dynamics of Gaussian states for open quantum systems described by Lindblad equations can be solved analytically for systems with quadratic Hamiltonians and linear Lindbladians, showing the familiar phenomena of dissipation and decoherence. It is well known that the Lindblad dynamics can be expressed as an ensemble average over stochastic pure-state dynamics, which can be interpreted as individual experimental implementations, where the form of the stochastic dynamics depends on the measurement setup. Here we consider quantum-jump and stochastic Schr\"odinger dynamics for initially Gaussian states. While both unravellings converge to the same Lindblad dynamics when averaged, the individual dynamics can differ qualitatively. For the stochastic Schr\"odinger equation, Gaussian states remain Gaussian during the evolution, with stochastic differential equations governing the evolution of the phase-space centre and a deterministic evolution of the covariance matrix. In contrast to this, individual pure-state dynamics arising from the quantum-jump evolution do not remain Gaussian in general. Applying results developed in the non-Hermitian context for Hagedorn wavepackets, we formulate a method to generate quantum-jump trajectories that is described entirely in terms of the evolution of an underlying Gaussian state. To illustrate the behaviours of the different unravellings in comparison to the Lindblad dynamics, we consider two examples in detail, which can be largely treated analytically, a harmonic oscillator subject to position measurement and a damped harmonic oscillator. In both cases, we highlight the differences as well as the similarities of the stochastic Schr\"odinger and the quantum-jump dynamics.

quant-ph↗