arXiv subjects

Roland Willa

Publications and source records attributed to Roland Willa.

At least 19 recordsLinked to original sources

arXiv2026

Statistical stability of random potentials to thermal and quantum activation

In numerous physical, chemical, and biological systems the dynamics can be reduced to the motion of state variables in a complex potential landscape. In case the manifold is known, the motion and response of the embedded object can be described deterministically up to stochastic effects usually associated with a noise. In contrast, if the manifold is unknown, the static and dynamic response of the state variable may be used as a spectroscopic tool to characterize the potential landscape. Inspired by a seminal work of L.\ Embon and co-workers, [Sci.\ Rep.\ \textbf{5}, 7598 (2015)] we investigate the statistical properties of potential minima, in particular, their stability to thermal and quantum activation. For Gaussian random manifolds, we derive an algebraic expression to evaluate the statistical probability of the potential character (value, slope, curvature, ...). With this tool, we compute the expectation value for the rate of thermal and quantum activation and link these findings to the principal characteristics of the Gaussian potential, i.e., its Green's function. This link provides the opportunity to access information on the potential's Green's function by studying the activation behavior of an object in this manifold.

cond-mat.stat-mech↗

arXiv2023

Cascade of vestigial orders in two-component superconductors: nematic, ferromagnetic, s-wave charge-4e, and d-wave charge-4e states

Electronically ordered states that break multiple symmetries can melt in multiple stages, similarly to liquid crystals. In the partially-melted phases, known as vestigial phases, a bilinear made out of combinations of the multiple components of the primary order parameter condenses. Multi-component superconductors are thus natural candidates for vestigial order, since they break both the U(1)-gauge and also time-reversal or lattice symmetries. Here, we use group theory to classify all possible real-valued and complex-valued bilinears of a generic two-component superconductor on a tetragonal or hexagonal lattice. While the more widely investigated real-valued bilinears correspond to vestigial nematic or ferromagnetic order, the little explored complex-valued bilinears correspond to a vestigial charge-$4e$ condensate, which itself can have an underlying $s$-wave, $d_{x^2-y^2}$-wave, or $d_{xy}$-wave symmetry. To properly describe the fluctuating regime of the superconducting Ginzburg-Landau action and thus access these competing vestigial phases, we employ both a large-N and a variational method. We show that while vestigial order can be understood as a weak-coupling effect in the large-N approach, it is akin to a moderate-coupling effect in the variational method. Despite these distinctions, both methods yield similar results in wide regions of the parameter space spanned by the quartic Landau coefficients. Specifically, we find that the nematic and ferromagnetic phases are the leading vestigial instabilities, whereas the various types of charge-$4e$ order are attractive albeit subleading vestigial channels. The only exception is for the hexagonal case, in which the nematic and $s$-wave charge-4e vestigial states are degenerate. We discuss the limitations of our approach, as well as the implications of our results for the realization of exotic charge-4e states in material candidates.

cond-mat.supr-con↗

arXiv2023

Identification of multiple-flux-quanta vortices by core states in the two-band superconductor Pb

Superconductors are of type I or II depending on whether they form an Abrikosov vortex lattice. Although bulk lead (Pb) is classified as a prototypical type-I superconductor, we observe single-flux-quantum and multiple-flux-quanta vortices in the intermediate state using mK scanning tunneling microscopy. We show that the winding number of individual vortices can be determined from the real space wave function of its Caroli-de Gennes-Matricon bound states. This generalizes the index theorem put forward by Volovik for isotropic electronic states to realistic electronic structures. In addition, the bound states due to the two superconducting bands of Pb can be separately detected. This yields strong evidence for low inter-band coupling and an independent closure of the gaps inside vortices.

cond-mat.supr-con↗

arXiv2022

3DSC - A New Dataset of Superconductors Including Crystal Structures

Data-driven methods, in particular machine learning, can help to speed up the discovery of new materials by finding hidden patterns in existing data and using them to identify promising candidate materials. In the case of superconductors, which are a highly interesting but also a complex class of materials with many relevant applications, the use of data science tools is to date slowed down by a lack of accessible data. In this work, we present a new and publicly available superconductivity dataset ('3DSC'), featuring the critical temperature $T_\mathrm{c}$ of superconducting materials additionally to tested non-superconductors. In contrast to existing databases such as the SuperCon database which contains information on the chemical composition, the 3DSC is augmented by the approximate three-dimensional crystal structure of each material. We perform a statistical analysis and machine learning experiments to show that access to this structural information improves the prediction of the critical temperature $T_\mathrm{c}$ of materials. Furthermore, we see the 3DSC not as a finished dataset, but we provide ideas and directions for further research to improve the 3DSC in multiple ways. We are confident that this database will be useful in applying state-of-the-art machine learning methods to eventually find new superconductors.

cond-mat.supr-con↗

arXiv2022

Interplay of stripe and double-Q magnetism with superconductivity in $\mathrm{Ba}_{1-x}\mathrm{K}_{x}\mathrm{Fe}_{2}\mathrm{As}_{2}$ under the influence of magnetic fields

At $x\approx0.25$ $\mathrm{Ba}_{1-x}\mathrm{K}_{x}\mathrm{Fe}_{2}\mathrm{As}_{2}$ undergoes a novel first-order transition from a four-fold symmetric double-Q magnetic phase to a two-fold symmetric single-Q phase, which was argued to occur simultaneously with the onset of superconductivity (Böhmer et al., Nat. Comm. 6, 7911 (2015)). Here, by applying magnetic fields up to 10T, we investigate in more detail the interplay of superconductivity with this magneto-structural transition using a combination of high-resolution thermal-expansion and heat-capacity measurements. We find that a magnetic field suppresses the reentrance of the single-Q orthorhombic phase more strongly than the superconducting transition, resulting in a splitting of the zero-field first-order transition. The suppression rate of the orthorhombic reentrance transition is stronger for out-of-plane than for in-plane fields and scales with the anisotropy of the superconducting state. These effects are captured within a phenomenological Ginzburg-Landau model, strongly suggesting that the suppression of the reentrant orthorhombic single-Q phase is primarily linked to the field-induced weakening of the superconducting order. Not captured by this model is however a strong reduction of the orthorhombic distortion for out-of-plane fields, which deserves further theoretical attention.

cond-mat.supr-con↗

arXiv2022

An Electronic Nematic Liquid in BaNi$_2$As$_2$

Understanding the organizing principles of interacting electrons and the emergence of novel electronic phases is a central endeavor of condensed matter physics. Electronic nematicity, in which the discrete rotational symmetry in the electron fluid is broken while the translational one remains unaffected, is a prominent example of such a phase. It has proven ubiquitous in correlated electron systems, and is of prime importance to understand Fe-based superconductors. Here, we find that fluctuations of such broken symmetry are exceptionally strong over an extended temperature range above phase transitions in \bnap, the nickel homologue to the Fe-based systems. This provides evidence for a type of electronic nematicity, dynamical in nature, which exhibits an unprecedented coupling to the underlying crystal lattice. Fluctuations between degenerate nematic configurations cause a splitting of phonon lines, without lifting degeneracies nor breaking symmetries, akin to spin liquids in magnetic systems.

cond-mat.str-el↗

arXiv2022

A topological flux trap: Majorana bound states at screw dislocations

The engineering of non-trivial topology in superconducting heterostructures is a very challenging task. Reducing the number of components in the system would facilitate the creation of the long-sought Majorana bound states. Here, we explore a route toward emergent topology in a trivial superconductor without a need for other proximitized materials. Specifically, we show that a vortex hosting an even number of flux quanta is capable of forming a quasi-one-dimensional topological sub-system that can be mapped to the Kitaev wire, if the vortex is trapped at a screw dislocation. This crystallographic defect breaks inversion symmetry and thereby threads a local spin-orbit coupling through the superconductor. The vortex-dislocation pair in the otherwise trivial bulk can harbor a pair of Majorana bound states located at the two surface terminations. We explain the topological transition in terms of a band inversion in the Caroli-de Gennes-Matricon vortex bound states and discuss favorable material parameters.

cond-mat.supr-con↗

arXiv2021

Hessian characterization of a vortex in a maze

Recent advances in vortex imaging allow for tracing the position of individual vortices with high resolution. Pushing an isolated vortex through the sample with the help of a controlled $dc$ transport current and measuring its local $ac$ response, the pinning energy landscape could be reconstructed along the vortex trajectory [$\text{L. Embon } et\ al.$, $\text{Scientific Reports}$ $\mathbf{5}$, $7598$ $(2015)$]. This setup with linear tilts of the potential landscape reminds about the dexterity game where a ball is balanced through a maze. The controlled motion of objects through such tilted energy landscapes is fundamentally limited to those areas of the landscape developing local minima under appropriate tilt. We introduce the Hessian stability map and the Hessian character of a pinning landscape as new quantities to characterize a pinning landscape. We determine the Hessian character, the area fraction admitting stable vortex positions, for various types of pinning potentials: assemblies of cut parabolas, Lorentzian- and Gaussian-shaped traps, as well as a Gaussian random disordered energy landscape, with the latter providing a universal result of $(3-\sqrt{3})/6 \approx 21\%$ of stable area. Furthermore, we discuss various aspects of the vortex-in-a-maze experiment.

cond-mat.supr-con↗

arXiv2021

Designing high-performance superconductors with nanoparticle inclusions: comparisons to strong pinning theory

One of the most promising routes for achieving unprecedentedly high critical currents in superconductors is to incorporate dispersed, non-superconducting nanoparticles to control the dissipative motion of vortices. However, these inclusions reduce the overall superconducting volume and can strain the interlaying superconducting matrix, which can detrimentally reduce $T_c$. Consequently, an optimal balance must be achieved between the nanoparticle density $n_p$ and size $d$. Determining this balance requires garnering a better understanding of vortex-nanoparticle interactions, described by strong pinning theory. Here, we map the dependence of the critical current on nanoparticle size and density in (Y$_{0.77}$,Gd$_{0.23}$)Ba$_2$Cu$_3$O$_{7-δ}$ films in magnetic fields up to 35 T, and compare the trends to recent results from time-dependent Ginzburg-Landau simulations. We identify consistencies between the field-dependent critical current $J_c(B)$ and expectations from strong pinning theory. Specifically, we find that that $J_c \propto B^{-α}$, where $α$ decreases from $0.66$ to $0.2$ with increasing density of nanoparticles and increases roughly linearly with nanoparticle size $d/ξ$ (normalized to the coherence length). At high fields, the critical current decays faster ($\sim B^{-1}$), suggestive that each nanoparticle has captured a vortex. When nanoparticles capture more than one vortex, a small, high-field peak is expected in $J_c(B)$. Due to a spread in defect sizes, this novel peak effect remains unresolved here. Lastly, we reveal that the dependence of the vortex creep rate $S$ on nanoparticle size and density roughly mirrors that of $α$, and compare our results to low-$T$ nonlinearities in $S(T)$ that are predicted by strong pinning theory.

cond-mat.supr-con↗

arXiv2021

Perspective: Challenges and Transformative Opportunities in Superconductor Vortex Physics

In superconductors, the motion of vortices introduces unwanted dissipation that is disruptive to applications. Fortunately, material defects can immobilize vortices, acting as vortex pinning centers, which engenders dramatic improvements in superconductor material properties and device operation. This has motivated decades of research into developing methods of tailoring the disorder landscape in superconductors to increase the strength of vortex pinning. Yet efficacious materials engineering still alludes us. The electromagnetic properties of real (disordered) superconducting materials cannot yet be reliably predicted, such that designing superconductors for applications remains a largely inefficient process of trial and error. This is ultimately due to large gaps in our knowledge of vortex dynamics: the field is challenged by the extremely complex interplay between vortex elasticity, vortex-vortex interactions, and material disorder. In this Perspective, we review obstacles and recent successes in understanding and controlling vortex dynamics in superconducting materials and devices. We further identify major open questions and discuss opportunities for transformative research in the field. This includes improving our understanding of vortex creep, determining and reaching the ceiling for the critical current, advanced microscopy to garner accurate structure-property relationships, frontiers in predictive simulations and the benefits of artificial intelligence, as well as controlling and exploiting vortices in quantum information applications.

cond-mat.supr-con↗

arXiv2020

Inhomogeneous time-reversal symmetry breaking in $\mathrm{Sr}_{2}\mathrm{Ru}\mathrm{O}_{4}$

We show that the observed time-reversal symmetry breaking (TRSB) of the superconducting state in $\mathrm{Sr}_{2}\mathrm{Ru}\mathrm{O}_{4}$ can be understood as originating from inhomogeneous strain fields near edge dislocations of the crystal. Specifically, we argue that, without strain inhomogeneities, $\mathrm{Sr}_{2}\mathrm{Ru}\mathrm{O}_{4}$ is a single-component, time-reversal symmetric superconductor, likely with $d_{x^{2}-y^{2}}$ symmetry. However, due to the strong strain inhomogeneities generated by dislocations, a slowly-decaying sub-leading pairing state contributes to the condensate in significant portions of the sample. As it phase winds around the dislocation, time-reversal symmetry is locally broken. Global phase locking and TRSB occur at a sharp Ising transition that is not accompanied by a change of the single-particle gap and yields a very small heat capacity anomaly. Our model thus explains the puzzling absence of a measurable heat capacity anomaly at the TRSB transition in strained samples, and the dilute nature of the time-reversal symmetry broken state probed by muon spin rotation experiments. We propose that plastic deformations of the material may be used to manipulate the onset of broken time-reversal symmetry.

cond-mat.supr-con↗

arXiv2020

Symmetry-mixed bound-state order: extended degeneracy of $(d + ig)$-superconductivity in $\mathrm{Sr}_{2}\mathrm{Ru}\mathrm{O}_{4}$

We report a fluctuation-driven state of matter that develops near an accidental degeneracy point of two symmetry-distinct primary phases. Due to symmetry mixing, this bound-state order exhibits unique signatures, incompatible with either parent phase. Within a field-theoretical formalism, we derive the generic phase diagram for system with bound-state order, study its response to strain, and evaluate analytic expressions for a specific model. Our results support the $(d + ig)$-superconducting state as a candidate for $\mathrm{Sr}_{2}\mathrm{Ru}\mathrm{O}_{4}$: Most noticeably, the derived strain-dependence is in excellent agreement with recent experiments [Hicks \textit{et al.} Science (2014) and Grinenko \textit{et al.} arXiv (2020)]. The evolution above a non-vanishing strain from a joint onset of superconductivity and time-reversal symmetry-breaking to two split phase transitions provides a testable prediction for this scenario.

cond-mat.str-el↗

arXiv2019

Vortex phases and glassy dynamics in the highly anisotropic superconductor HgBa$_2$CuO$_{4+δ}$

We present an extensive study of vortex dynamics in a high-quality single crystal of HgBa$_2$CuO$_{4+δ}$ (Hg1201), a highly anisotropic superconductor that is a model system for studying the effects of anisotropy. From magnetization $M$ measurements over a wide range of temperatures $T$ and fields $H$, we construct a detailed vortex phase diagram. We find that the temperature-dependent vortex penetration field $H_p(T)$, second magnetization peak $H_{smp}(T)$, and irreversibility field $H_{irr}(T)$ all decay exponentially at low temperatures and exhibit an abrupt change in behavior at high temperatures $T/T_c \gtrsim 0.5$. By measuring the rates of thermally activated vortex motion (creep) $S(T,H)=|d \ln M(T,H) / d \ln t|$, we reveal glassy behavior involving collective creep of bundles of 2D pancake vortices as well as temperature- and time-tuned crossovers from elastic (collective) dynamics to plastic flow. Based on the creep results, we show that the second magnetization peak coincides with the elastic-to-plastic crossover at low $T$, yet the mechanism changes at higher temperatures.

cond-mat.supr-con↗

arXiv2019

Thermal creep emerging from cooling a tilted vortex lattice in uniaxial superconductor

A perturbed system relaxes towards an equilibrium given by a minimum in the potential energy landscape. This often occurs by thermally activated jumps over metastable states. The corresponding dynamics is named creep and follows Arrhenius' law. Here we consider the situation where the equilibrium position depends on temperature. We show that this effect occurs in the vortex lattice of the anisotropic superconductor $2\mathrm{H}$-$\mathrm{Nb}\mathrm{Se}_{2}$ when the magnetic field is tilted away from the principal axes, and that it leads to the peculiar appearance of creep when cooling the sample. Temperature determines the system's ground state and at the same time brings the system back to equilibrium, playing a dual and antagonistic role. We expect that cooling induced creep occurs in correlated systems with many degrees of freedom allowing to tune the equilibrium state via heat treatment.

cond-mat.supr-con↗

arXiv2019

Strain tuning and anisotropic spin correlations in iron-based systems

Nematic order in the iron-based superconductors is closely tied to a lattice distortion and a structural transition from tetragonal to orthorhombic symmetry. External stress of the appropriate symmetry acts as a conjugate field of the nematic order parameter and can be utilized to detwin nematic domains but also smears an otherwise sharp nematic transition. On the other hand, applying stress in proper symmetry channels allows one to tune the nematic phase transition. Recent experiments analyzed the stress-induced changes of the nematic and magnetic phase transition temperature. Here we show that the observed trends can be understood in terms of spin-induced nematicity. The strain sensitivity is shown to be a fluctuation effect. The strong sensitivity to antisymmetric strain is a consequence of the anisotropic nature of the magnetic excitation spectrum. The formalism presented here can be naturally generalized to determine the strain-sensitivity of vestigial phases related to other magnetic states that have been observed in the iron-based systems, such as e.g.\ the spin-charge density wave and the spin-vortex crystals.

cond-mat.str-el↗

arXiv2019

Nanocalorimetric Evidence for Nematic Superconductivity in the Doped Topological Insulator Sr$_{0.1}$Bi$_{2}$Se$_{3}$

Spontaneous rotational-symmetry breaking in the superconducting state of doped $\mathrm{Bi}_2\mathrm{Se}_3$ has attracted significant attention as an indicator for topological superconductivity. In this paper, high-resolution calorimetry of the single-crystal $\mathrm{Sr}_{0.1}\mathrm{Bi}_2\mathrm{Se}_3$ provides unequivocal evidence of a two-fold rotational symmetry in the superconducting gap by a \emph{bulk thermodynamic} probe, a fingerprint of nematic superconductivity. The extremely small specific heat anomaly resolved with our high-sensitivity technique is consistent with the material's low carrier concentration proving bulk superconductivity. The large basal-plane anisotropy of $H_{c2}$ is attributed to a nematic phase of a two-component topological gap structure $\vecη = (η_{1}, η_{2})$ and caused by a symmetry-breaking energy term $δ(|η_{1}|^{2} - |η_{2}|^{2}) T_{c}$. A quantitative analysis of our data excludes more conventional sources of this two-fold anisotropy and provides the first estimate for the symmetry-breaking strength $δ\approx 0.1$, a value that points to an onset transition of the second order parameter component below 2K.

cond-mat.supr-con↗

arXiv2019

Phase transition preceding magnetic long-range order in the double perovskite Ba2NaOsO6

Recent theoretical studies [Chen et al., Phys. Rev. B 82, 174440 (2010), Ishizuka et al., Phys. Rev. B 90, 184422 (2014)] for the magnetic Mott insulator Ba2NaOsO6 have proposed a low-temperature order parameter that breaks lattice rotational symmetry without breaking time reversal symmetry leading to a nematic phase just above magnetic ordering temperature. We present high-resolution calorimetric and magnetization data of the same Ba2NaOsO6 single crystal and show evidence for a weakly field-dependent phase transition occurring at a temperature of Ts ~ 9.5K, above the magnetic ordering temperature of Tc ~ 7.5K. This transition appears as a broadened step in the low-field temperature dependence of the specific heat. The evolution of the phase boundary with applied magnetic field suggests that this phase coincides with the phase of broken local point symmetry seen in high field NMR experiments [Lu et al., Nat.\ Comm. 8 14407 (2017)]. Furthermore, the magnetic field dependence of the specific heat provides clear indications for magnetic correlations persisting at temperatures between Tc and Ts where long-range magnetic order is absent giving support for the existence of the proposed nematic phase.

cond-mat.str-el↗

arXiv2019

Thermal hysteresis of the Campbell response as a probe for bulk pinscape spectroscopy

In type-II superconductors, the macroscopic response of vortex matter to an external perturbation depends on the local interaction of flux lines with the pinning landscape (pinscape). The (Campbell) penetration depth $λ_{\mathrm{\scriptscriptstyle C}}$ of an $ac$ field perturbation is often associated with a phenomenological pinning curvature. However, this basic approach is unable to capture thermal hysteresis effects observed in a variety of superconductors. The recently developed framework of strong-pinning theory has established a quantitative relationship between the microscopic pinscape and macroscopic observables. Specifically, it identifies history-dependent vortex arrangements as the primary source for thermal hysteresis in the Campbell response. In this work, we show that this interpretation is well suited to capture the experimental results of the clean superconductor $\mathrm{Nb}\mathrm{Se}_{2}$; as observed through Campbell response (linear $ac$ susceptibility) and small-angle neutron scattering measurements. Furthermore, we exploit the hysteretic Campbell response upon thermal cycling to extract the temperature dependence of microscopic pinning parameters from bulk measurements; specifically the pinning force and pinning length. This spectroscopic tool may stimulate further pinscape characterization in other superconducting systems.

cond-mat.supr-con↗