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Rolf Güsten

Publications and source records attributed to Rolf Güsten.

At least 37 records · Page 2Linked to original sources

Detection of vibrational emissions from the helium hydride ion (HeH$^+$) in the planetary nebula NGC 7027

We report the detection of emission in the v=1-0 P(1) (3.51629 micron) and P(2) (3.60776 micron) rovibrational lines of the helium hydride cation (HeH+) from the planetary nebula NGC 7027. These detections were obtained with the iSHELL spectrograph on NASA's Infrared Telescope Facility (IRTF) on Maunakea. The confirm the discovery of HeH+ reported recently by Guesten et al. (2019), who used the GREAT instrument on the SOFIA airborne observatory to observe its pure rotational J=1-0 transition at 149.137 micron. The flux measured for the HeH+ v=1-0 P(1) line is in good agreement with our model for the formation, destruction and excitation of HeH+ in NGC 7027. The measured strength of the J=1-0 pure rotational line, however, exceeds the model prediction significantly, as does that of the v=1-0 P(2) line, by factors of 2.9 and 2.3 respectively. Possible causes of these discrepancies are discussed. Our observations of NGC 7027, covering the 3.26 - 3.93 micron spectral region, have led to the detection of more than sixty spectral lines including nine rovibrational emissions from CH+. The latter are detected for the first time in an astronomical source.

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Fingerprinting the effects of hyperfine structure on CH and OH far infrared spectra using Wiener filter deconvolution

In this paper, we investigate the influence of hyperfine splitting on complex spectral lines, with the aim of evaluating canonical abundances by decomposing their dependence on hyperfine structures. This is achieved from first principles through deconvolution. We present high spectral resolution observations of the rotational ground state transitions of CH near 2 THz seen in absorption toward the strong FIR-continuum sources AGAL010.62$-$00.384, AGAL034.258+00.154, AGAL327.293$-$00.579, AGAL330.954$-$00.182, AGAL332.826$-$00.549, AGAL351.581$-$00.352 and SgrB2(M). These were observed with the GREAT instrument on board SOFIA. The observed line profiles of CH were deconvolved from the imprint left by the lines' hyperfine structures using the Wiener filter deconvolution, an optimised kernel acting on direct deconvolution. The quantitative analysis of the deconvolved spectra first entails the computation of CH column densities. Reliable N(CH) values are of importance owing to the status of CH as a powerful tracer for H$_2$ in the diffuse regions of the interstellar medium. The N(OH)/N(CH) column density ratio is found to vary within an order of magnitude with values ranging from one to 10, for the individual sources that are located outside the Galactic centre. Using CH as a surrogate for H$_2$, we determined the abundance of the OH molecule to be X(OH)=1.09$\times$10$^{-7}$ with respect to H$_2$. The radial distribution of CH column densities along the sightlines probed in this study, excluding SgrB2(M), showcase a dual peaked distribution peaking between 5 and 7 kpc. The similarity between the correspondingly derived column density profile of H$_2$ with that of the CO-dark H$_2$ gas traced by the cold neutral medium component of [CII] 158$~μ$m emission across the Galactic plane, further emphasises the use of CH as a tracer for H$_2$.

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First astrophysical detection of the helium hydride ion (HeH$^+$)

During the dawn of chemistry when the temperature of the young Universe had fallen below $\sim$4000 K, the ions of the light elements produced in Big Bang nucleosynthesis recombined in reverse order of their ionization potential. With its higher ionization potentials, He$^{++}$ (54.5 eV) and He$^+$ (24.6 eV) combined first with free electrons to form the first neutral atom, prior to the recombination of hydrogen (13.6 eV). At that time, in this metal-free and low-density environment, neutral helium atoms formed the Universe's first molecular bond in the helium hydride ion HeH$^+$, by radiative association with protons (He + H$^+$ $\rightarrow$ HeH$^+$ + h$ν$). As recombination progressed, the destruction of HeH$^+$ (HeH$^+$ + H $\rightarrow$ He + H$_2^+$) created a first path to the formation of molecular hydrogen, marking the beginning of the Molecular Age. Despite its unquestioned importance for the evolution of the early Universe, the HeH$^+$ molecule has so far escaped unequivocal detection in interstellar space. In the laboratory, the ion was discovered as long ago as 1925, but only in the late seventies was the possibility that HeH$^+$ might exist in local astrophysical plasmas discussed. In particular, the conditions in planetary nebulae were shown to be suitable for the production of potentially detectable HeH$^+$ column densities: the hard radiation field from the central hot white dwarf creates overlapping Strömgren spheres, where HeH$^+$ is predicted to form, primarily by radiative association of He$^+$ and H. With the GREAT spectrometer onboard SOFIA, the HeH$^+$ rotational ground-state transition at $λ$149.1 $μ$m is now accessible. We report here its detection towards the planetary nebula NGC7027.

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Velocity profiles of [CII], [CI], CO, and [OI] and physical conditions in four star-forming regions in the Large Magellanic Cloud

The aim of our study is to investigate the physical properties of the star-forming interstellar medium (ISM) in the Large Magellanic Cloud (LMC) by separating the origin of the emission lines spatially and spectrally. Following Okada et al. (2015, Paper I), we investigate different phases of the ISM traced by carbon-bearing species in four star-forming regions in the LMC, and model the physical properties using the KOSMA-tau PDR model. We mapped 3--13 arcmin$^2$ areas in 30 Dor, N158, N160 and N159 along the molecular ridge of the LMC in [CII]158um with GREAT on board SOFIA, and in CO(2-1) to (6-5), $^{13}$CO(2-1) and (3-2), [CI]3P1-3P0 and 3P2-3P1 with APEX. In all four star-forming regions, the line profiles of CO, $^{13}$CO, and [CI] emission are similar, whereas [CII] typically shows wider line profiles or an additional velocity component. For selected positions in N159 and 30 Dor, we observed the velocity-resolved [OI] 145um and 63um lines for the first time with upGREAT. At some positions, the [OI] line profiles match those of CO, at other positions they are more similar to the [CII] profiles. We interpret the different line profiles of CO, [CII] and [OI] as contributions from spatially separated clouds and/or clouds in different physical phases, which give different line ratios depending on their physical properties. We model the emission from the CO, [CI], [CII], and [OI] lines and the far-infrared continuum emission using the latest KOSMA-tau PDR model, which treats the dust-related physics consistently and computes the dust continuum SED together with the line emission of the chemical species. We find that the line and continuum emissions are not well-reproduced by a single clump ensemble. Toward the CO peak at N159~W, we propose a scenario that the CO, [CII], and [OI] 63um emission are weaker than expected because of mutual shielding among clumps. (abridged for arXiv)

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Unveiling the chemistry of interstellar CH: Spectroscopy of the 2 THz $N=2\leftarrow 1$ ground state line

The methylidyne radical CH is commonly used as a proxy for H$_2$ in the cold, neutral phase of the interstellar medium. The optical spectroscopy of CH is limited by interstellar extinction, whereas far-infrared observations provide an integral view through the Galaxy. While the HF ground state absorption, another H$_2$ proxy in diffuse gas, frequently suffers from saturation, CH remains transparent both in spiral-arm crossings and high-mass star forming regions, turning this light hydride into a universal surrogate for H$_2$. However, in slow shocks and in regions dissipating turbulence its abundance is expected to be enhanced by an endothermic production path, and the idea of a "canonical" CH abundance needs to be addressed. The $N=2\leftarrow 1$ ground state transition of CH at $λ149\,μ$m has become accessible to high-resolution spectroscopy thanks to GREAT aboard SOFIA. Its unsaturated absorption and the absence of emission makes it an ideal candidate for the determination of column densities with a minimum of assumptions. Here we present an analysis of four sightlines towards distant, far-infrared bright Galactic star forming regions. If combined with the sub-millimeter line of CH at $λ560\,μ$m, environments forming massive stars can be analyzed. For this we present a case study on the "proto-Trapezium" cluster W3 IRS5, and demonstrate that the sub-millimeter/far-infrared lines of CH reliably trace not only diffuse but also dense, molecular gas. While we confirm the global correlation between the column densities of HF and those of CH, clear signposts of an over-abundance of CH are observed towards lower densities. A quiescent ion-neutral chemistry alone cannot account for this over-abundance. Vortices forming in turbulent, diffuse gas may be the setting for an enhanced production path.

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Detection of [O III] at z~3: A Galaxy above the Main Sequence, Rapidly Assembling its Stellar Mass

We detect bright emission in the far infrared fine structure [O III] 88$μ$m line from a strong lensing candidate galaxy, H-ATLAS J113526.3-014605, hereafter G12v2.43, at z=3.127, using the $\rm 2^{nd}$ generation Redshift (z) and Early Universe Spectrometer (ZEUS-2) at the Atacama Pathfinder Experiment Telescope (APEX). This is only the fifth detection of this far-IR line from a sub-millimeter galaxy at the epoch of galaxy assembly. The observed [O III] luminosity of $7.1\times10^{9}\,\rm(\frac{10}μ)\,\rm{L_{\odot}}\,$ likely arises from HII regions around massive stars, and the amount of Lyman continuum photons required to support the ionization indicate the presence of $(1.2-5.2)\times10^{6}\,\rm(\frac{10}μ)$ equivalent O5.5 or higher stars; where $μ$ would be the lensing magnification factor. The observed line luminosity also requires a minimum mass of $\sim 2\times 10^{8}\,\rm(\frac{10}μ)\,\rm{M_{\odot}}\,$ in ionized gas, that is $0.33\%$ of the estimated total molecular gas mass of $6\times10^{10}\,\rm(\frac{10}μ)\,\rm{M_{\odot}}\,$. We compile multi-band photometry tracing rest-frame UV to millimeter continuum emission to further constrain the properties of this dusty high redshift star-forming galaxy. Via SED modeling we find G12v2.43 is forming stars at a rate of 916 $\rm(\frac{10}μ)\,\rm{M_{\odot}}\,\rm{yr^{-1}}$ and already has a stellar mass of $8\times 10^{10}\,\rm(\frac{10}μ)\,\rm{M_{\odot}}\,$. We also constrain the age of the current starburst to be $\leqslant$ 5 million years, making G12v2.43 a gas rich galaxy lying above the star-forming main sequence at z$\sim$3, undergoing a growth spurt and, could be on the main sequence within the derived gas depletion timescale of $\sim$66 million years.

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Deuteration of ammonia in the starless core Ophiuchus/H-MM1

Ammonia and its deuterated isotopologues probe physical conditions in dense molecular cloud cores. With the aim of testing the current understanding of the spin-state chemistry of these molecules, we observed spectral lines of NH3, NH2D, NHD2, ND3, and N2D+ towards a dense, starless core in Ophiuchus with the APEX, GBT, and IRAM 30-m telescopes. The observations were interpreted using a gas-grain chemistry model combined with radiative transfer calculations. The chemistry model distinguishes between the different nuclear spin states of light hydrogen molecules, ammonia, and their deuterated forms. High deuterium fractionation ratios with NH2D/NH3=0.4, NHD2/NH2D=0.2, and ND3/NHD2=0.06 were found in the core. The observed ortho/para ratios of NH2D and NHD2 are close to the corresponding nuclear spin statistical weights. The chemistry model can approximately reproduce the observed abundances, but predicts uniformly too low ortho/para-NH2D, and too large ortho/para-NHD2 ratios. The longevity of N2H+ and NH3 in dense gas, which is prerequisite to their strong deuteration, can be attributed to the chemical inertia of N2 on grain surfaces. The discrepancies between the chemistry model and the observations are likely to be caused by the fact that the model assumes complete scrambling in principal gas-phase deuteration reactions of ammonia, which means that all the nuclei are mixed in reactive collisions. If, instead, these reactions occur through proton hop/hydrogen abstraction processes, statistical spin ratios are to be expected. The present results suggest that while the deuteration of ammonia changes with physical conditions and time, the nuclear spin ratios of ammonia isotopologues do not probe the evolutionary stage of a cloud.

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Cold CO gas in the disk of the young eruptive star EX Lup

EX Lupi-type objects (EXors) form a sub-class of T Tauri stars, defined by sudden sporadic flare-ups of 1-5 magnitudes at optical wavelengths. These eruptions are attributed to enhanced mass accretion from the circumstellar disk to the star, and may constitute important events in shaping the structure of the inner disk and the forming planetary system. Although disk properties must play a fundamental role in driving the outbursts, they are surprisingly poorly known. In order to characterize the dust and gas components of EXor disks, here we report on observations of the $^{12}$CO J=3-2 and 4-3 lines, and the $^{13}$CO 3-2 line in EX Lup, the prototype of the EXor class. We reproduce the observed line fluxes and profiles with a line radiative transfer model, and compare the obtained parameters with corresponding ones of other T Tauri disks.

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Velocity resolved [CII], [CI], and CO observations of the N159 star-forming region in the Large Magellanic Cloud: a complex velocity structure and variation of the column densities

The [CII]158um line is one of the dominant cooling lines in star-forming active regions. The commonly assumed clumpy UV-penetrated cloud models predict a [CII] line profile similar to that of CO. However, recent spectral-resolved observations show that they are often very different, indicating a more complex origin of the line emission including the dynamics of the source region. The aim of our study is to investigate the physical properties of the star-forming ISM in the Large Magellanic Cloud (LMC) by separating the origin of the emission lines spatially and spectrally. In this paper, we focus on the spectral characteristics and the origin of the emission lines, and the phases of carbon-bearing species in the N159 star-forming region in the LMC. We mapped a 4'x(3-4)' region in N159 in [CII]158um and [NII]205um with the GREAT on board SOFIA, and in CO(3-2), (4-3), (6-5), 13CO(3-2), and [CI]3P1-3P0 and 3P2-3P1 with APEX. The emission of all transitions observed shows a large variation in the line profiles across the map and between the different species. At most positions the [CII] emission line profile is substantially wider than that of CO and [CI]. We estimated the fraction of the [CII] integrated line emission that cannot be fitted by the CO line profile to be 20%-50%. We derived the relative contribution from C+, C, and CO to the column density in each velocity bin. The contribution from C+ dominates the velocity range far from the velocities traced by the dense molecular gas, and the region located between the CO cores of N159 W and E. We estimate the contribution of the ionized gas to the [CII] emission using the ratio to the [NII] emission to be < 19% to the [CII] emission at its peak position, and <15% over the whole observed region. Using the integrated line intensities, we present the spatial distribution of I([CII])/I(FIR). (abridged for arXiv)

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The fine structure line deficit in S 140

We try to understand the gas heating and cooling in the S 140 star forming region by spatially and spectrally resolving the distribution of the main cooling lines with GREAT/SOFIA. We mapped the fine structure lines of [OI] (63 μm) and [CII] (158 μm) and the rotational transitions of CO 13-12 and 16-15 with GREAT/SOFIA and analyzed the spatial and velocity structure to assign the emission to individual heating sources. We measure the optical depth of the [CII] line and perform radiative transfer computations for all observed transitions. By comparing the line intensities with the far-infrared continuum we can assess the total cooling budget and measure the gas heating efficiency. The main emission of fine structure lines in S 140 stems from a 8.3'' region close to the infrared source IRS 2 that is not prominent at any other wavelength. It can be explained by a photon-dominated region (PDR) structure around the embedded cluster if we assume that the [OI] line intensity is reduced by a factor seven due to self-absorption. The external cloud interface forms a second PDR at an inclination of 80-85 degrees illuminated by an UV field of 60 times the standard interstellar radiation field. The main radiation source in the cloud, IRS 1, is not prominent at all in the fine structure lines. We measure line-to-continuum cooling ratios below 10^(-4), i.e. values lower than in any other Galactic source, rather matching the far-IR line deficit seen in ULIRGs. In particular the low intensity of the [CII] line can only be modeled by an extreme excitation gradient in the gas around IRS 1. We found no explanation why IRS 1 shows no associated fine-structure line peak, while IRS 2 does. The inner part of S 140 mimics the far-IR line deficit in ULIRGs thereby providing a template that may lead to a future model.

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APEX observations of non-stationary magneto-hydrodynamical shocks in W44

Supernova remnants (SNRs) are considered as being the sources of galactic cosmic rays. In order to understand the origin, acceleration, and composition of these cosmic rays, detailed knowledge of the physical conditions in the local interstellar medium is needed. The shock interaction of SNRs with molecular clouds that gives rise to strong molecular emission in the far-IR and sub-mm wavelength regimes can be used as a highly valuable tracer of these conditions. The application of MHD shock models in the interpretation of the resulting line emission can yield information on the energetic and chemical impact of supernova remnants. We have mapped two regions in the supernova remnant W44 with the APEX telescope in ${}^{12}$CO (3-2), (4-3), (6-5), (7-6) and ${}^{13}$CO (3-2). The extraction of integrated intensities on five different positions, corresponding to local maxima of CO emission, allows to compare these intensities to the outputs of a grid of models, which combine an MHD shock code with a radiative transfer module based on the 'large velocity gradient' approximation. We find that the observed CO line emission is compatible with non-stationary shocks and a pre-shock density of $10^4$ cm${}^{-3}$. Our models furthermore allow to constrain shock ages, velocities, the pre-shock magnetic field strength components perpendicular to the line-of-sight, and the full ladder of CO transitions. Finally, our analysis can be used to estimate the contribution of such SNRs to, e.g. the galactic energy balance and the momentum-injection into the surrounding interstellar medium.

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APEX-CHAMP+ high-J CO observations of low-mass young stellar objects: IV. Mechanical and radiative feedback

During the embedded stage of star formation, bipolar molecular outflows and UV radiation from the protostar are important feedback processes. Our aim is to quantify the feedback, mechanical and radiative, for a large sample of low-mass sources. The outflow activity is compared to radiative feedback in the form of UV heating by the accreting protostar to search for correlations and evolutionary trends. Large-scale maps of 26 young stellar objects, which are part of the Herschel WISH key program are obtained using the CHAMP+ instrument on the APEX (12CO and 13CO 6-5), and the HARP-B instrument on the JCMT (12CO and 13CO 3-2). Maps are used to determine outflow parameters and envelope models are used to quantify the amount of UV-heated gas and its temperature from 13CO 6-5 observations. All sources in our sample show outflow activity and the outflow force, F_CO, is larger for Class 0 sources than for Class I sources, even if their luminosities are comparable. The outflowing gas typically extends to much greater distances than the power-law envelope and therefore influences the surrounding cloud material directly. Comparison of the CO 6-5 results with Herschel-HIFI H2O and PACS high-J CO lines, both tracing currently shocked gas, shows that the two components are linked, even though the transitions do not probe the same gas. The link does not extend down to CO 3-2. The conclusion is that CO 6-5 depends on the shock characteristics (density and velocity), whereas CO 3-2 is more sensitive to conditions in the surrounding environment (density). The radiative feedback is responsible for increasing the gas temperature by a factor of two, up to 30-50 K, on scales of a few thousand AU, particularly along the direction of the outflow. The mass of the UV heated gas exceeds the mass contained in the entrained outflow in the inner ~3000 AU and is therefore at least as important on small scales.

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Submillimeter Polarimetry with PolKa, a reflection-type modulator for the APEX telescope

Imaging polarimetry is an important tool for the study of cosmic magnetic fields. In our Galaxy, polarization levels of a few up to $\sim$10\% are measured in the submillimeter dust emission from molecular clouds and in the synchrotron emission from supernova remnants. Only few techniques exist to image the distribution of polarization angles, as a means of tracing the plane-of-sky projection of the magnetic field orientation. At submillimeter wavelengths, polarization is either measured as the differential total power of polarization-sensitive bolometer elements, or by modulating the polarization of the signal. Bolometer arrays such as LABOCA at the APEX telescope are used to observe the continuum emission from fields as large as $\sim0\fdg2$ in diameter. %Here we present the results from the commissioning of PolKa, a polarimeter for Here we present PolKa, a polarimeter for LABOCA with a reflection-type waveplate of at least 90\% efficiency. The modulation efficiency depends mainly on the sampling and on the angular velocity of the waveplate. For the data analysis the concept of generalized synchronous demodulation is introduced. The instrumental polarization towards a point source is at the level of $\sim0.1$\%, increasing to a few percent at the $-10$db contour of the main beam. A method to correct for its effect in observations of extended sources is presented. Our map of the polarized synchrotron emission from the Crab nebula is in agreement with structures observed at radio and optical wavelengths. The linear polarization measured in OMC1 agrees with results from previous studies, while the high sensitivity of LABOCA enables us to also map the polarized emission of the Orion Bar, a prototypical photon-dominated region.

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The water abundance behind interstellar shocks: results from $Herschel$/PACS and $Spitzer$/IRS observations of H$_2$O, CO, and H$_2$

We have investigated the water abundance in shock-heated molecular gas, making use of $Herschel$ measurements of far-infrared CO and H$_2$O line emissions in combination with $Spitzer$ measurements of mid-IR H$_2$ rotational emissions. We present far-infrared line spectra obtained with $Herschel$'s PACS instrument in range spectroscopy mode towards two positions in the protostellar outflow NGC 2071 and one position each in the supernova remnants W28 and 3C391. These spectra provide unequivocal detections, at one or more positions, of 12 rotational lines of water, 14 rotational lines of CO, 8 rotational lines of OH (4 lambda doublets), and 7 fine-structure transitions of atoms or atomic ions. We first used a simultaneous fit to the CO line fluxes, along with H$_2$ rotational line fluxes measured previously by $Spitzer$, to constrain the temperature and density distribution within the emitting gas; and we then investigated the water abundances implied by the observed H$_2$O line fluxes. The water line fluxes are in acceptable agreement with standard theoretical models for nondissociative shocks that predict the complete vaporization of grain mantles in shocks of velocity $v \sim 25$ km/s, behind which the characteristic gas temperature is $\sim 1300$ K and the H$_2$O/CO ratio is 1.2

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The 2nd Generation z(Redshift) and Early Universe Spectrometer Part I: First-light observation of a highly lensed local-ULIRG analog at high-z

We report first science results from our new spectrometer, the 2nd generation z(Redshift) and Early Universe Spectrometer (ZEUS-2), recently commissioned on the Atacama Pathfinder Experiment telescope (APEX). ZEUS-2 is a submillimeter grating spectrometer optimized for detecting the faint and broad lines from distant galaxies that are redshifted into the telluric windows from 200 to 850 microns. It utilizes a focal plane array of transition-edge sensed bolometers, the first use of these arrays for astrophysical spectroscopy. ZEUS-2 promises to be an important tool for studying galaxies in the years to come due to its synergy with ALMA and its capabilities in the short submillimeter windows that are unique in the post Herschel era. Here we report on our first detection of the [CII] 158 $μm$ line with ZEUS-2. We detect the line at z ~ 1.8 from H-ATLAS J091043.1-000322 with a line flux of $(6.44 \pm 0.42) \times 10^{-18} W m^{-2}$. Combined with its far-infrared luminosity and a new Herschel-PACS detection of the [OI] 63 $μm $ line we model the line emission as coming from a photo-dissociation region with far-ultraviolet radiation field, $G \approx 2 \times 10^{4} G_{0}$, gas density, $n \approx 1 \times 10^{3} cm^{-3}$ and size between ~ 0.4 and 1 kpc. Based on this model, we conclude that H-ATLAS J091043.1-000322 is a high redshift analogue of a local ultra-luminous infrared galaxy, i.e. it is likely the site of a compact starburst due to a major merger. Further identification of these merging systems is important for constraining galaxy formation and evolution models.

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The Excitation of HCN and HCO+ in the Galactic Center Circumnuclear Disk

We present new observations of HCN and HCO+in the circumnuclear disk (CND) of the Galaxy, obtained with the APEX telescope. We have mapped emission in rotational lines of HCN J = 3-2, 4-3, and 8-7, as well as HCO+ J = 3-2, 4-3, and 9-8. We also present spectra of H13CN and H13CO+ toward four positions in the CND. Using the intensities of all of these lines, we present an excitation analysis for each molecule using the non-LTE radiative transfer code RADEX. The HCN line intensities toward the northern emission peak of the CND yield log densities (cm^-3) of 5.6 +0.6/-0.6, consistent with those measured with HCO+, as well as with densities recently reported for this region from an excitation analysis of highly-excited lines of CO. These densities are too low for the gas to be tidally stable. The HCN line intensities toward the CND's southern emission peak yield log densities of 6.5 +0.5/-0.7, higher than densities determined for this part of the CND with CO (although the densities measured with HCO+, log [n] = 5.6 +0.2/-0.2, are more consistent with the CO-derived densities). We investigate whether the higher densities we infer from HCN are affected by mid-infrared radiative excitation of this molecule through its 14 micron rovibrational transitions. We find that radiative excitation is important for at least one clump in the CND, where we additionally detect the J = 4-3, v2=1 vibrationally-excited transition of HCN, which is excited by dust temperatures of > 125-150 K. If this hot dust is present elsewhere in the CND, it could lower our inferred densities, potentially bringing the HCN-derived densities for the Southern part of the CND into agreement with those measured using HCO+ and CO. Additional sensitive, high-resolution submillimeter observations, as well as mid-infrared observations, would be useful to assess the importance of the radiative excitation of HCN in this environment.

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Dimethyl ether in its ground state, v=0, and lowest two torsionally excited states, v11=1 and v15=1, in the high-mass star-forming region G327.3-0.6

The goal of this paper is to determine the respective importance of solid state vs. gas phase reactions for the formation of dimethyl ether. This is done by a detailed analysis of the excitation properties of the ground state and the torsionally excited states, v11=1 and v15=1, toward the high-mass star-forming region G327.3-0.6. With the Atacama Pathfinder EXperiment 12 m submillimeter telescope, we performed a spectral line survey. The observed spectrum is modeled assuming local thermal equilibrium. CH3OCH3 has been detected in the ground state, and in the torsionally excited states v11=1 and v15=1, for which lines have been detected here for the first time. The emission is modeled with an isothermal source structure as well as with a non-uniform spherical structure. For non-uniform source models one abundance jump for dimethyl ether is sufficient to fit the emission, but two components are needed for the isothermal models. This suggests that dimethyl ether is present in an extended region of the envelope and traces a non-uniform density and temperature structure. Both types of models furthermore suggest that most dimethyl ether is present in gas that is warmer than 100 K, but a smaller fraction of 5%-28% is present at temperatures between 70 and 100 K. The dimethyl ether present in this cooler gas is likely formed in the solid state, while gas phase formation probably is dominant above 100 K. Finally, the v11=1 and v15=1 torsionally excited states are easily excited under the density and temperature conditions in G327.3-0.6 and will thus very likely be detectable in other hot cores as well.

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High-resolution absorption spectroscopy of the OH 2Pi 3/2 ground state line

The chemical composition of the interstellar medium is determined by gas phase chemistry, assisted by grain surface reactions, and by shock chemistry. The aim of this study is to measure the abundance of the hydroxyl radical (OH) in diffuse spiral arm clouds as a contribution to our understanding of the underlying network of chemical reactions. Owing to their high critical density, the ground states of light hydrides provide a tool to directly estimate column densities by means of absorption spectroscopy against bright background sources. We observed onboard the SOFIA observatory the 2Pi3/2, J = 5/2 3/2 2.5 THz line of ground-state OH in the diffuse clouds of the Carina-Sagittarius spiral arm. OH column densities in the spiral arm clouds along the sightlines to W49N, W51 and G34.26+0.15 were found to be of the order of 10^14 cm^-2, which corresponds to a fractional abundance of 10^-7 to 10^-8, which is comparable to that of H_2O. The absorption spectra of both species have similar velocity components, and the ratio of the derived H_2O to OH column densities ranges from 0.3 to 1.0. In W49N we also detected the corresponding line of ^18OH.

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