arXiv subjects
Publications and source records attributed to Roman Schubert.
A quantum version of a recent formulation of transition state theory in {\em phase space} is presented. The theory developed provides an algorithm to compute quantum reaction rates and the associated Gamov-Siegert resonances with very high accuracy. The algorithm is especially efficient for multi-degree-of-freedom systems where other approaches are no longer feasible.
We study the semiclassical behaviour of eigenfunctions of quantum systems with ergodic classical limit. By the quantum ergodicity theorem almost all of these eigenfunctions become equidistributed in a weak sense. We give a simple derivation of an upper bound of order $\abs{\ln\hbar}^{-1}$ on the rate of quantum ergodicity if the classical system is ergodic with a certain rate. In addition we obtain a similar bound on transition amplitudes if the classical system is weak mixing. Both results generalise previous ones by Zelditch. We then extend the results to some classes of quantised maps on the torus and obtain a logarithmic rate for perturbed cat-maps and a sharp algebraic rate for parabolic maps.
We study the behaviour of time evolved quantum mechanical expectation values in Lagrangian states in the limit $\hbar\to 0$ and $t\to\infty$. We show that it depends strongly on the dynamical properties of the corresponding classical system. If the classical system is strongly chaotic, i.e. Anosov, then the expectation values tend to a universal limit. This can be viewed as an analogue of mixing in the classical system. If the classical system is integrable, then the expectation values need not converge, and if they converge their limit depends on the initial state. An additional difference occurs in the timescales for which we can prove this behaviour, in the chaotic case we get up to Ehrenfest time, $t\sim \ln(1/\hbar)$, whereas for integrable system we have a much larger time range.
We introduce generalized Husimi functions at the interfaces of dielectric systems. Four different functions can be defined, corresponding to the incident and departing wave on both sides of the interface. These functions allow to identify mechanisms of wave confinement and escape directions in optical microresonators, and give insight into the structure of resonance wave functions. Off resonance, where systematic interference can be neglected, the Husimi functions are related by Snell's law and Fresnel's coefficients.
We study the amplitude distribution of irregular eigenfunctions in systems with mixed classical phase space. For an appropriately restricted random wave model a theoretical prediction for the amplitude distribution is derived and good agreement with numerical computations for the family of limacon billiards is found. The natural extension of our result to more general systems, e.g. with a potential, is also discussed.
We study the autocorrelation function of different types of eigenfunctions in quantum mechanical systems with either chaotic or mixed classical limits. We obtain an expansion of the autocorrelation function in terms of the correlation length. For localized states, like bouncing ball modes or states living on tori, a simple model using only classical input gives good agreement with the exact result. In particular, a prediction for irregular eigenfunctions in mixed systems is derived and tested. For chaotic systems, the expansion of the autocorrelation function can be used to test quantum ergodicity on different length scales.
We study eigenstates of chaotic billiards in the momentum representation and propose the radially integrated momentum distribution as useful measure to detect localization effects. For the momentum distribution, the radially integrated momentum distribution, and the angular integrated momentum distribution explicit formulae in terms of the normal derivative along the billiard boundary are derived. We present a detailed numerical study for the stadium and the cardioid billiard, which shows in several cases that the radially integrated momentum distribution is a good indicator of localized eigenstates, such as scars, or bouncing ball modes. We also find examples, where the localization is more strongly pronounced in position space than in momentum space, which we discuss in detail. Finally applications and generalizations are discussed.