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Roman V. Li

Publications and source records attributed to Roman V. Li.

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A state chaining-based objective collapse model

The quantum-to-classical transition hinges on the nature of wavefunction collapse, which remains a central controversy in foundational physics. Objective collapse theories aim to modify quantum mechanics by introducing a physical, non-subjective mechanism for irreversible events, but existing models face significant conceptual and empirical challenges. Here, we propose a novel collapse mechanism based on a specific form of quantum correlation termed "chaining", formalized within a new diagrammatic framework (quantum illustrations, or qils). This approach does not rely on system size or environmental complexity, but on the probabilistic occurrence of a collapse event with a fixed, universal probability $1/\Sigma$ per chaining step. We demonstrate that this model naturally explains the emergence of classicality in paradigmatic scenarios (measurement devices, Schrodinger's cat, spontaneous decay) and makes testable predictions for interference experiments. The theory is shown to be consistent with existing data from delayed-choice quantum eraser and matter-wave interference experiments, yielding an estimate for the fundamental constant $\Sigma \geq 1.5$. By providing a unified, parameter-sparse mechanism for objective collapse, this work bridges quantum and classical descriptions and has implications for the interpretation of quantum experiments, the design of quantum computers/sensors, and the understanding of decoherence in complex systems.

physics.gen-ph

Quantum field theory approach for multistage chemical kinetics in liquids

Reaction-diffusion processes play an important role in a variety of physical, chemical, and biological systems. Conventionally, the kinetics of these processes are described by the law of mass action. However, there are various cases where these equations are insufficient. A fundamental challenge lies in accurately accounting for the microscopic correlations that inevitably arise in bimolecular reactions. While approaches to describe microscopic correlations in many specific cases exist, no general theory for multistage reactions has been established. In this article, we apply the quantum field theory approach to derive kinetic equations for general multistage reactive systems termed CMET (complete modified encounter theory). CMET can be formulated as a set of coupled partial differential equations that can be easily integrated numerically, thereby serving as a versatile tool for investigating reaction-diffusion processes. Across multiple case studies, we demonstrated that CMET reproduces the kinetics predicted by many other theories within their respective scopes of applicability.

physics.chem-ph