arXiv subjects

Ronnie Kosloff

Publications and source records attributed to Ronnie Kosloff.

At least 91 records · Page 5Linked to original sources

arXiv2009

A Chebychev propagator for inhomogeneous Schrödinger equations

We present a propagation scheme for time-dependent inhomogeneous Schrödinger equations which occur for example in optimal control theory or in reactive scattering calculations. A formal solution based on a polynomial expansion of the inhomogeneous term is derived. It is subjected to an approximation in terms of Chebychev polynomials. Different variants for the inhomogeneous propagator are demonstrated and applied to two examples from optimal control theory. Convergence behavior and numerical efficiency are analyzed.

quant-ph↗

arXiv2008

Two-photon coherent control of femtosecond photoassociation

Photoassociation with short laser pulses has been proposed as a technique to create ultracold ground state molecules. A broad-band excitation seems the natural choice to drive the series of excitation and deexcitation steps required to form a molecule in its vibronic ground state from two scattering atoms. First attempts at femtosecond photoassociation were, however, hampered by the requirement to eliminate the atomic excitation leading to trap depletion. On the other hand, molecular levels very close to the atomic transition are to be excited. The broad bandwidth of a femtosecond laser then appears to be rather an obstacle. To overcome the ostensible conflict of driving a narrow transition by a broad-band laser, we suggest a two-photon photoassociation scheme. In the weak-field regime, a spectral phase pattern can be employed to eliminate the atomic line. When the excitation is carried out by more than one photon, different pathways in the field can be interfered constructively or destructively. In the strong-field regime, a temporal phase can be applied to control dynamic Stark shifts. The atomic transition is suppressed by choosing a phase which keeps the levels out of resonance. We derive analytical solutions for atomic two-photon dark states in both the weak-field and strong-field regime. Two-photon excitation may thus pave the way toward coherent control of photoassociation. Ultimately, the success of such a scheme will depend on the details of the excited electronic states and transition dipole moments. We explore the possibility of two-photon femtosecond photoassociation for alkali and alkaline-earth metal dimers and present a detailed study for the example of calcium.

physics.atom-ph↗

arXiv2008

The Quantum Refrigerator: The quest for absolute zero

The scaling of the optimal cooling power of a reciprocating quantum refrigerator is sought as a function of the cold bath temperature as $T_c \to 0$. The working medium consists of noninteracting particles in a harmonic potential. Two closed-form solutions of the refrigeration cycle are analyzed, and compared to a numerical optimization scheme, focusing on cooling toward zero temperature. The optimal cycle is characterized by linear relations between the heat extracted from the cold bath, the energy level spacing of the working medium and the temperature. The scaling of the optimal cooling rate is found to be proportional to $T_c^{3/2}$ giving a dynamical interpretation to the third law of thermodynamics.

quant-ph↗

arXiv2008

Protecting coherence in Optimal Control Theory: State dependent constraint approach

Optimal control theory is developed for the task of obtaining a primary objective in a subspace of the Hilbert space while avoiding other subspaces of the Hilbert space. The primary objective can be a state-to-state transition or a unitary transformation. A new optimization functional is introduced which leads to monotonic convergence of the algorithm. This approach becomes necessary for molecular systems subject to processes implying loss of coherence such as predissociation or ionization. In these subspaces controllability is hampered or even completely lost. Avoiding the lossy channels is achieved via a functional constraint which depends on the state of the system at each instant in time. We outline the resulting new algorithm, discuss its convergence properties and demonstrate its functionality for the example of a state-to-state transition and of a unitary transformation for a model of cold Rb2.

quant-ph↗

arXiv2007

The dynamical hole in ultrafast photoassociation: analysis of the compression effect

Photoassociation of a pair of cooled atoms by excitation with a short chirped laser pulse creates a dynamical hole in the initial continuum wavefunction. This hole is manifested by a void in the pair wavefunction and a momentum kick. Photoassociation into loosely bound levels of the external well in Cs_2 0$_g^-$(6S + 6P$_{3/2}$ is considered as a case study. After the pulse, the free evolution of the ground triplet state wavepacket is analyzed. Due to a negative momentum kick, motion to small distances is manifested and a compression effect is pointed out, markedly increasing the density of atom pairs at short distance. A consequence of the hole is the redistribution of the vibrational population in the ground triplet state, with population of the last bound level and creation of pairs of hot atoms. The physical interpretation makes use of the time dependence of the probability current and population on each channel to understand the role of the parameters of the photoassociation pulse. By varying such parameters, optimization of the compression effect in the ground state wavepacket is demonstrated. Due to an increase of the short range density probability by more than two orders of magnitude, we predict important photoassociation rates into deeply bound levels of the excited state by a second pulse, red-detuned relative to the first one and conveniently delayed.

quant-ph↗

arXiv2007

The rise and fall of quantum and classical correlations in open-system dynamics

Interacting quantum systems evolving from an uncorrelated composite initial state generically develop quantum correlations -- entanglement. As a consequence, a local description of interacting quantum system is impossible as a rule. A unitarily evolving (isolated) quantum system generically develops extensive entanglement: the magnitude of the generated entanglement will increase without bounds with the effective Hilbert space dimension of the system. It is conceivable, that coupling of the interacting subsystems to local dephasing environments will restrict the generation of entanglement to such extent, that the evolving composite system may be considered as approximately disentangled. This conjecture is addressed in the context of some common models of a bipartite system with linear and nonlinear interactions and local coupling to dephasing environments. Analytical and numerical results obtained imply that the conjecture is generally false. Open dynamics of the quantum correlations is compared to the corresponding evolution of the classical correlations and a qualitative difference is found.

quant-ph↗

arXiv2006

Theoretical model for ultracold molecule formation via adaptive feedback control

We investigate pump-dump photoassociation of ultracold molecules with amplitude- and phase-modulated femtosecond laser pulses. For this purpose a perturbative model for the light-matter interaction is developed and combined with a genetic algorithm for adaptive feedback control of the laser pulse shapes. The model is applied to the formation of 85Rb2 molecules in a magneto-optical trap. We find for optimized pulse shapes an improvement for the formation of ground state molecules by more than a factor of 10 compared to unshaped pulses at the same pump-dump delay time, and by 40% compared to unshaped pulses at the respective optimal pump-dump delay time. Since our model yields directly the spectral amplitudes and phases of the optimized pulses, the results are directly applicable in pulse shaping experiments.

physics.atom-ph↗

arXiv2006

On exact identity between thermodynamic and informatic entropies in a unitary model of friction

An elementary collision model of a molecular reservoir is considered upon which an external field is applied and the work is dissipated into heat. To realize macroscopic irreversibility at the microscopic level, we introduce a ``graceful'' irreversible map which randomly mixes the identities of the molecules. This map is expected to generate informatic entropy exactly equal to the independently calculable irreversible thermodynamic entropy.

quant-ph↗

arXiv2006

Irreversible Performance of a Quantum Harmonic Heat Engine

The unavoidable irreversible losses of power in a heat engine are found to be of quantum origin. Following thermodynamic tradition a model quantum heat engine operating by the Otto cycle is analyzed. The working medium of the model is composed of an ensemble of harmonic oscillators. A link is established between the quantum observables and thermodynamical variables based on the concept of canonical invariance. These quantum variables are sufficient to determine the state of the system and with it all thermodynamical variables. Conditions for optimal work, power and entropy production show that maximum power is a compromise between the quasistatic limit of adiabatic following on the compression and expansion branches and a sudden limit of very short time allocation to these branches. At high temperatures and quasistatic operating conditions the efficiency at maximum power coincides with the endoreversible result. The optimal compression ratio varies from the square root of the temperature ratio in the quasistatic limit where their reversibility is dominated by heat conductance to the temperature ratio to the power of 1/4 in the sudden limit when the irreversibility is dominated by friction. When the engine deviates from adiabatic conditions the performance is subject to friction. The origin of this friction can be traced to the noncommutability of the kinetic and potential energy of the working medium.

quant-ph↗

arXiv2006

Decoherence control: A feedback mechanism based on hamiltonian tracking

Enviroment - caused dissipation disrupts the hamiltonian evolution of all quantum systems not fully isolated from any bath. We propose and examine a feedback-control scheme to eliminate such dissipation, by tracking the free hamiltonian evolution. We determine a driving-field that maximizes the projection of the actual molecular system onto the freely propagated one. The evolution of a model two level system in a dephasing bath is followed, and the driving field that overcomes the decoherence is calculated. An implementation of the scheme in the laboratory using feedback control is suggested.

quant-ph↗

arXiv2006

Short-pulse photoassociation in rubidium below the D$_1$ line

Photoassociation of two ultracold rubidium atoms and the subsequent formation of stable molecules in the singlet ground and lowest triplet states is investigated theoretically. The method employs laser pulses inducing transitions via excited states correlated to the $5S+5P_{1/2}$ asymptote. Weakly bound molecules in the singlet ground or lowest triplet state can be created by a single pulse while the formation of more deeply bound molecules requires a two-color pump-dump scenario. More deeply bound molecules in the singlet ground or lowest triplet state can be produced only if efficient mechanisms for both pump and dump steps exist. While long-range $1/R^3$-potentials allow for efficient photoassociation, stabilization is facilitated by the resonant spin-orbit coupling of the $0_u^+$ states. Molecules in the singlet ground state bound by a few wavenumbers can thus be formed. This provides a promising first step toward ground state molecules which are ultracold in both translational and vibrational degrees of freedom.

physics.atom-ph↗

arXiv2005

Quantum Lubrication: Suppression of Friction in a First Principle Four Stroke Heat Engine

A quantum model of a heat engine resembling the Otto cycle is employed to explore strategies to suppress frictional losses. These losses are caused by the inability of the engine's working medium to follow adiabatically the change in the Hamiltonian during the expansion and compression stages. By adding external noise to the engine, frictional losses can be suppressed.

quant-ph↗

arXiv2005

On the temperature dependence of the interaction-induced entanglement

Both direct and indirect weak nonresonant interactions are shown to produce entanglement between two initially disentangled systems prepared as a tensor product of thermal states, provided the initial temperature is sufficiently low. Entanglement is determined by the Peres-Horodeckii criterion, which establishes that a composite state is entangled if its partial transpose is not positive. If the initial temperature of the thermal states is higher than an upper critical value $T_{uc}$ the minimal eigenvalue of the partially transposed density matrix of the composite state remains positive in the course of the evolution. If the initial temperature of the thermal states is lower than a lower critical value $T_{lc}\leq T_{uc}$ the minimal eigenvalue of the partially transposed density matrix of the composite state becomes negative which means that entanglement develops. We calculate the lower bound $T_{lb}$ for $T_{lc}$ and show that the negativity of the composite state is negligibly small in the interval $T_{lb}<T<T_{uc}$. Therefore the lower bound temperature $T_{lb}$ can be considered as \textit{the} critical temperature for the generation of entanglement.

quant-ph↗

arXiv2004

Characteristics of the Limit Cycle of a Reciprocating Quantum Heat Engine

When a reciprocating heat engine is started it eventually settles to a stable mode of operation. The approach of a first principle quantum heat engine toward this stable limit cycle is studied. The engine is based on a working medium consisting of an ensemble of quantum systems composed of two coupled spins. A four stroke cycle of operation is studied, with two {\em isochore} branches where heat is transferred from the hot/cold baths and two {\em adiabats} where work is exchanged. The dynamics is generated by a completely positive map. It has been shown that the performance of this model resembles an engine with intrinsic friction. The quantum conditional entropy is employed to prove the monotonic approach to a limit cycle. Other convex measures, such as the quantum distance display the same monotonic approach. The equations of motion of the engine are solved for the different branches and are combined to a global propagator that relates the state of the engine in the beginning of the cycle to the state after one period of operation of the cycle. The eigenvalues of the propagator define the rate of relaxation toward the limit cycle. A longitudinal and transverse mode of approach to the limit cycle is identified. The entropy balance is used to explore the necessary conditions which lead to a stable limit cycle. The phenomena of friction can be identified with a zero change in the von Neumann entropy of the working medium.

quant-ph↗

arXiv2004

Stabilization of Ultracold Molecules Using Optimal Control Theory

In recent experiments on ultracold matter, molecules have been produced from ultracold atoms by photoassociation, Feshbach resonances, and three-body recombination. The created molecules are translationally cold, but vibrationally highly excited. This will eventually lead them to be lost from the trap due to collisions. We propose shaped laser pulses to transfer these highly excited molecules to their ground vibrational level. Optimal control theory is employed to find the light field that will carry out this task with minimum intensity. We present results for the sodium dimer. The final target can be reached to within 99% if the initial guess field is physically motivated. We find that the optimal fields contain the transition frequencies required by a good Franck-Condon pumping scheme. The analysis is able to identify the ranges of intensity and pulse duration which are able to achieve this task before other competing process take place. Such a scheme could produce stable ultracold molecular samples or even stable molecular Bose-Einstein condensates.

quant-ph↗

arXiv2003

A Pulse Shaping Algorithm of a Coherent Matter Wave. Controlling Reaction Dynamics

A pulse shaping algorithm for a matter wave with the purpose of controlling a binary reaction has been designed. The scheme is illustrated for an Eley-Rideal reaction where an impinging matter-wave atom recombines with an adsorbed atom on a metal surface. The wave function of the impinging atom is shaped such that the desorbing molecule leaves the surface in a specific vibrational state.

quant-ph↗

arXiv2003

The Quantum Four Stroke Heat Engine: Thermodynamic Observables in a Model with Intrinsic Friction

The fundamentals of a quantum heat engine are derived from first principles. The study is based on the equation of motion of a minimum set of operators which is then used to define the state of the system. The relation between the quantum framework and thermodynamical observables is examined. A four stroke heat engine model with a coupled two-level-system as a working fluid is used to explore the fundamental relations. In the model used, the internal Hamiltonian does not commute with the external control field which defines the two adiabatic branches. Heat is transferred to the working fluid by coupling to hot and cold reservoirs under constant field values. Explicit quantum equation of motion for the relevant observables are derived on all branches. The dynamics on the heat transfer constant field branches is solved in closed form. On the adiabats, a general numerical solution is used and compared with a particular analytic solution. These solutions are combined to construct the cycle of operation. The engine is then analyzed in terms of frequency-entropy and entropy-temperature graphs. The irreversible nature of the engine is the result of finite heat transfer rates and friction-like behavior due to noncommutability of the internal and external Hamiltonian.

quant-ph↗

arXiv2003

Two-Pulse Atomic Coherent Control (2PACC) Spectroscopy of Eley-Rideal Reactions. An Application of an Atom Laser

A spectroscopic application of the atom laser is suggested. The spectroscopy termed 2PACC employs the coherent properties of matter-waves from a two pulse atom laser. These waves are employed to control a gas-surface chemical recombination reaction. The method is demonstrated for an Eley-Rideal reaction of a hydrogen or alkali atom-laser pulse where the surface target is an adsorbed hydrogen atom. The reaction yields either a hydrogen or alkali hydride molecule. The desorbed gas phase molecular yield and its internal state is shown to be controlled by the time and phase delay between two atom-laser pulses. The calculation is based on solving the time-dependent Schrodinger equation in a diabatic framework. The probability of desorption which is the predicted 2PACC signal has been calculated as a function of the pulse parameters.

quant-ph↗