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Rosemary Dorsey

Publications and source records attributed to Rosemary Dorsey.

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Origin and evolution of NiI and FeI in the coma of the interstellar comet 3I/ATLAS throughout its trajectory

We present high-resolution UVES+VLT observations of neutral nickel and iron atoms in the coma of the interstellar comet 3I/ATLAS taken after perihelion. Metal emission was strong shortly after perihelion and persisted at large heliocentric distances. At $r_h \sim 2$ au the total metal production rate was found to be at least an order of magnitude larger than that of typical solar-system comets. Post-perihelion production rates exhibit pronounced asymmetry compared to the pre-perihelion behavior: production rates are higher after perihelion and decline more gradually with $r_h$, the difference being stronger for FeI. The NiI/FeI abundance ratio, initially anomalously large before perihelion, evolved toward values comparable to solar-system comets near 2 au, and shows a weaker $r_h$ dependence after perihelion. To interpret these results, we revisited and extended the carbonyl hypothesis in which FeI and NiI are produced by the rapid photodissociation of Fe(CO)$_5$ and Ni(CO)$_4$ vaporized from the nucleus. Fits that include direct sublimation of carbonyls reproduce the observed rates and the high NiI/FeI line ratio, which is determined by the higher volatility of Ni(CO)$_4$. Desorption of carbonyls from sublimating CO$_2$ and H$_2$O ices is found to be negligible. The temperature profiles needed to reproduce the observations were found to be shallower than the equilibrium $T \propto r_h^{-1/2}$ relation, suggesting that the sublimation could occur below the surface of the nucleus. Fits using temperature profiles from thermal models require sublimation from depths of several cm, especially post-perihelion. An additional transient heat source ($T \simeq$ 100-140~K), possibly linked to the amorphous-crystalline ice transition, is proposed to explain the early NiI excess before perihelion.

astro-ph.EP

Pre-perihelion evolution of the NiI/FeI abundance ratio in the coma of the interstellar comet 3I/ATLAS. From extreme to normal

Emission lines of FeI and NiI are commonly found in the coma of Solar System comets, even at large heliocentric distances. These atoms are most likely released from the surface of the comet's nucleus or from a short-lived parent. These lines were also found in the interstellar comet 2I/Borisov, which has a NiI/FeI abundance ratio similar to that observed in Solar System comets. Here, we report observations of the interstellar comet 3I/ATLAS, which were carried out with the ESO Very Large Telescope equipped with the UVES and X-shooter spectrographs. Spectra were obtained at heliocentric distances ranging from 3.14 to 1.85 au. NiI was detected at all epochs. FeI was only detected at heliocentric distances smaller than 2.64 au. We estimated the NiI and FeI production rates by comparing the observed line intensities with those produced by a dedicated fluorescence model. Comet 3I first exhibited extreme and unusual NiI/FeI abundance ratios during the initial stages of its activity. However, as its heliocentric distance decreased, this ratio became indistinguishable from those observed in Solar System comets and in comet 2I/Borisov. Comet 3I was found to be C$_2$-depleted, with a NiI/FeI abundance ratio finally consistent with other C$_2$-depleted comets. Nevertheless, comet 3I remains exceptional due to its high, total production rate of NiI and FeI, which is at least one order of magnitude larger than that of other comets. We interpreted these observations assuming that the NiI and FeI atoms were released through the sublimation of Ni(CO)$_4$ and Fe(CO)$_5$ carbonyls. This scenario provides a straightforward explanation for the asymmetric release of NiI and FeI atoms in the cometary coma and how it depends on the heliocentric distance. It also supports the presence of carbonyls in the cometary material.

astro-ph.EP

Very Large Telescope Observations of Interstellar Comet 3I/ATLAS. II. From Quiescence to Glow: Dramatic Rise of Ni i Emission and Incipient CN Outgassing at Large Heliocentric Distances*

We report VLT spectroscopy of the interstellar comet 3I/ATLAS (C/2025~N1) from $r_{\rm h}\!\simeq\!4.4$ to $2.85$~au using X-shooter (300--550\,nm, $R\!\simeq\!3000$) and UVES (optical, $R\!\simeq\!35k-80k$). The coma is dust-dominated with a fairly constant red optical continuum slope ($\sim$21--22\%/1000Å). We report detection of CN emission and also detect numerous Ni\,\textsc{ii}~lines while Fe\,\textsc{i}~remains undetected, potentially implying efficiently released gas-phase Ni. At $r_{\rm h}\!\simeq\!3.14$~au we derive $3σ$ limits of $Q({\rm OH})<{1.48\times10^{26}}\ {\rm s^{-1}}$, but find no indications for [O\,\textsc{i}], C$_2$, C$_3$ or NH$_2$. From our latest X-shooter measurements conducted on 2025-08-21 ($r_{\rm h} = 2.85$\,au) we measure production rates of $\log~Q(\mathrm{CN}) = {24.81\pm 0.01}$ molecules s$^{-1}$ and $\log~Q$(Ni) $= {23.30\pm0.07}$ atoms s$^{-1}$, and characterize their evolution as the comet approaches perihelion.~We observe a steep heliocentric-distance scaling for the production rates $Q(\mathrm{Ni}) \propto r_h^{-7.7 \pm 1.0}$ and for $Q(\mathrm{CN}) \propto r_h^{-6.7 \pm 0.2}$, and predict a Ni--CO$_{(2)}$ correlation if the Ni\,\textsc{ii}\ emission is driven by the carbonyl formation channel.~Energetic considerations of activation barriers show that this behavior is inconsistent with direct sublimation of canonical metal/sulfide phases and instead favors low--activation--energy release from dust, e.g.~photon-stimulated desorption or mild thermolysis of metalated organics or Ni-rich nanophases, possibly including Ni--carbonyl-like complexes.~These hypotheses are testable with future coordinated ground-based and space-based monitoring as 3I becomes more active during its continued passage through the solar system.

astro-ph.SR

Snapshot of a new interstellar comet: 3I/ATLAS has a red and featureless spectrum

The interstellar comet 3I/ATLAS is only the third interstellar object to be discovered. Pre-perihelion measurements provide a unique opportunity to study its activity and composition, which may alter as it is heated in the coming months. We provide an initial baseline from optical spectroscopic observations obtained only two days after discovery, using the MUSE instrument on the VLT on 2025 July 3, while 3I was at 4.47 au from the Sun and 3.46 au from the Earth. These observations confirm the cometary nature of 3I, and reveal a red coma with a spectral slope of $(18\pm4)\%/1000$~Å, redder than most Solar System comets but similar to the surface colour of some Solar System Trans-Neptunian Objects or Centaurs. We searched for but did not detect gas emission from C$_2$, NH$_2$, CN, and [OI], which is consistent with volatile non-detections for Solar System comets at this heliocentric distance. At present, the coma appears entirely dusty. Future observations of 3I as it comes closer to the Sun will provide an invaluable opportunity to witness the evolution of its activity, study its composition, test predictions of interstellar object population models, and compare 3I to Solar System comets.

astro-ph.EP