Ruediger G. Ballas | Searcharxiv

arXiv2026

Piezoelectricity: A Brief History of its Discovery and Physical Principles Using the Example of Low Quartz

Piezoelectricity is a key phenomenon in solid-state physics and has significant technological relevance. In teaching, however, it is often treated either without a historical context or an explicit link to the microscopic crystal structure, meaning that a crucial level of understanding remains untapped. This study combines the history of the discovery of piezoelectricity with its physical description within a didactically coherent framework. Building on the work of the brothers, Jacques and Pierre Curie (1880 - 1882), it demonstrated how investigations into pyroelectricity led to the identification of polarization induced by mechanical compression in hemihedral crystals such as tourmaline and quartz. The development from early qualitative experiments towards the first quantitative determination of piezoelectric constants is traced in a structured manner. Using low quartz as an example, the microscopic cause of piezoelectricity was attributed to the asymmetric displacements of silicon and oxygen ions within the orthosilicate ion tetrahedral network. This leads to the formation of macroscopic polarization owing to uncompensated dipole moments in the crystal lattice. The direct and reciprocal piezoelectric effects are qualitatively distinguished and discussed in the context of mechanical-electrical coupling. The article is aimed at students in physics and engineering as well as lecturers. It was conceived as a didactic review article (tutorial article) and serves as a structured introduction to the physical and historical foundations of piezoelectricity.

physics.hist-ph↗

arXiv2026

Pyroelectricity: A Brief History of its Discovery and Physical Principles - an Overview

This paper deals with the historical development and physical mechanisms of pyroelectricity, a phe-nomenon whose roots date back over 2000 years to ancient times. This paper is aimed at students and engineers as a concise introduction to the subject area. While the attractive effect of heated tourma-line was already described by Theophrastus, scientific systematization did not occur until the 18th century by researchers, such as Aepinus and Canton, who identified the effect of electrical polarization resulting from temperature changes. This essay highlights the path from early analogies to magnetism to the modern crystallographic description by Haüy and Thomson. In the physics section, pyroelectricity is defined as the temperature dependence of the spontaneous polarization in anisotropic solids. At the microscopic level, the permanent dipole moment of an elementary cell is described by the vector sum of individual moments. It is mathematically demonstrated that the macroscopic spontaneous polarization correlates with the surface charge density and is linked to the temperature change via the pyroelectric cofficient. A distinction was made between the primary pyroelectric effect and the secondary effect resulting from the thermal deformation of the crystal. Finally, the renaissance of this field of research through the development of modern infrared detectors and ferroelectric materials in the 20th century was highlighted.

physics.hist-ph↗