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Ruizhe Kang

Publications and source records attributed to Ruizhe Kang.

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Kondo driven suppression of charge density wave in Van der Waals material UTe$_3$

Competing electronic instabilities lie at the heart of emergent phenomena in quantum materials. In low-dimensional metals, Fermi-surface nesting can drive charge density wave (CDW) formation through a Peierls-like mechanism, while in strongly correlated systems, Kondo hybridization reconstructs the electronic structure by entangling localized moments with itinerant electrons. How these two fundamentally different instabilities interact$-$whether they coexist, compete, or mutually exclude each other$-$remains an open question. Here, we present suppression of charge density wave via the Kondo interaction in van der Waals material UTe$_3$. The angle-resolved photoemission spectroscopy (ARPES) data reveals Fermi surface nesting under similar conditions as seen in RETe$_3$ compounds. Despite that, no CDW is found in UTe$_3$ after an extensive search. We demonstrate that strong hybridization between U 5$f$ electrons and Te $p$ states reconstructs the low-energy electronic structure, removes the instability, and preempts CDW formation. Our results reveal a rare example where Kondo hybridization preempts density wave formation, offering a new route to controlling ordering phenomena in correlated 2D materials.

cond-mat.str-el

Kondo Reshapes Multiple Orders in a $5f$ van der Waals Material

Electron interactions can drive magnetism, superconductivity, and topology. However, the realization of these phases remains limited in van der Waals materials, and the full landscape of strong correlations remains uncharted in any context. While interactions between conduction electrons and localized spins yield a well-known competition between heavy fermions (Kondo hybridization) and magnetic order (RKKY exchange), such spin-driven competition represents only part of the correlated electron phase diagram. Here we demonstrate that a heavy-fermion state can also compete with charge order, such as the charge density wave (CDW) state typical in the van der Waals $4f$ rare-earth tritellurides (RTe$_3$). We exploit the spatially-extended $5f$ orbitals of $\beta$-UTe$_3$ to enhance Kondo hybridization compared to its isostructural RTe$_3$ cousins. Our scanning tunneling spectroscopy on $\beta$-UTe$_3$ shows Fano resonances characteristic of the heavy fermion state, while our quasiparticle interference imaging reveals the disappearance of Fermi-level nesting and the appearance of flat bands. We extend the tritelluride tight-binding model to include Kondo coupling and quantify the Fermi surface reconstruction. Consistent with the destruction of nesting, we observe no CDW in $\beta$-UTe$_3$. Our expansion of the Kondo phase diagram beyond spin-mediated competition opens new possibilities for proximity-induced phase engineering in correlated van der Waals heterostructures.

cond-mat.str-el

Nanoscale variation of the Rashba energy in BiTeI

BiTeI is a polar semiconductor with strong spin-orbit coupling (SOC) that produces large Rashba spin splitting. Due to its potential utility in spintronics and magnetoelectrics, it is essential to understand how defects impact the spin transport in this material. Using scanning tunneling microscopy and spectroscopy, we image ring-like charging states of single-atom defects on the iodine surface of BiTeI. We observe nanoscale variations in the Rashba energy around each defect, which we correlate with the local electric field extracted from the bias dependence of each ring radius. Our data demonstrate the local impact of atomic defects on the Rashba effect, which is both a challenge and an opportunity for the development of future nanoscale spintronic devices.

cond-mat.mes-hall

Alternate cleavage structure and electronic inhomogeneity in Ca-doped YBa$_2$Cu$_3$O$_{7-\delta}$

YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) has favorable macroscopic superconducting properties of $T_\mathrm{c}$ up to 93 K and $H_{c2}$ up to 150 T. However, its nanoscale electronic structure remains mysterious because bulk-like electronic properties are not preserved near the surface of cleaved samples for easy access by local or surface-sensitive probes. It has been hypothesized that Ca-doping at the Y site could induce an alternate cleavage plane that mitigates this issue. We use scanning tunneling microscopy (STM) to study both Ca-free and 10% Ca-doped YBCO, and find that the Ca-doped samples do indeed cleave on an alternate plane, yielding a spatially-disordered partial (Y,Ca) layer. Our density functional theory calculations support the increased likelihood of this new cleavage plane in Ca-doped YBCO. On this surface, we image a superconducting gap with average value 24 $\pm$ 3 meV and characteristic length scale 1-2 nm, similar to Bi-based high-$T_\mathrm{c}$ cuprates, but the first map of gap inhomogeneity in the YBCO family.

cond-mat.supr-con

Imaging Se diffusion across the FeSe/SrTiO$_3$ interface

Monolayer FeSe on SrTiO$_3$ superconducts with reported $T_\mathrm{c}$ as high as 100 K, but the dramatic interfacial $T_\mathrm{c}$ enhancement remains poorly understood. Oxygen vacancies in SrTiO$_3$ are known to enhance the interfacial electron doping, electron-phonon coupling, and superconducting gap, but the detailed mechanism is unclear. Here we apply scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) to FeSe/SrTiO$_3$ to image the diffusion of selenium into SrTiO$_3$ to an unexpected depth of several unit cells, consistent with the simultaneously observed depth profile of oxygen vacancies. Our density functional theory (DFT) calculations support the crucial role of oxygen vacancies in facilitating the thermally driven Se diffusion. In contrast to excess Se in the FeSe monolayer or FeSe/SrTiO$_3$ interface that is typically removed during post-growth annealing, the diffused Se remains in the top few unit cells of the SrTiO$_3$ bulk after the extended post-growth annealing that is necessary to achieve superconductivity. Thus, the unexpected Se in SrTiO$_3$ may contribute to the interfacial electron doping and electron-phonon coupling that enhance $T_\mathrm{c}$, suggesting another important role for oxygen vacancies as facilitators of Se diffusion.

cond-mat.supr-con

Magnetization of potassium doped p-terphenyl and p-quaterphenyl by high pressure synthesis

By using high pressure synthesis method, we have fabricated the potassium doped para-terphenyl. The temperature dependence of magnetization measured in both zero-field-cooled and field-cooled processes shows step like transitions at about 125 K. This confirms earlier report about the possible superconductivity like transition in the same system. However, the magnetization hysteresis loop exhibits a weak ferromagnetic background. After removing this ferromagnetic background, a Meissner effect like magnetic shielding can be found. A simple estimate on the diamagnetization of this step tells that the diamagnetic volume is only about 0.0427% at low temperatures, if we assume the penetration depth is much smaller than the size of possible superconducting grains. This magnetization transition does not shift with magnetic field but is suppressed and becomes almost invisible above 1.0 T. The resistivity measurements are failed because of an extremely large resistance. By using the same method, we also fabricated the potassium doped para-quaterphenyl. A similar step like transition at about 125 K was also observed by magnetization measurement. Since there is an unknown positive background and the diamagnetic volume is too small, it is insufficient to conclude that this step is derived from superconductivity although it looks like.

cond-mat.supr-con