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Ruoyu Xiong

Publications and source records attributed to Ruoyu Xiong.

3 recordsLinked to original sources

Stable High-Order Interpolation on the Grassmann Manifold by Maximum-Volume Coordinates and Arnoldi Orthogonalization

High-order interpolation on the Grassmann manifold $\Gr(n, p)$ is often hindered by the computational overhead and derivative instability of SVD-based geometric mappings. To solve the challenges, we propose a stabilized framework that combines Maximum-Volume (MV) local coordinates with Arnoldi-orthogonalized polynomial bases. First, manifold data are mapped to a well-conditioned Euclidean domain via MV coordinates. The approach bypasses the costly matrix factorizations inherent to traditional Riemannian normal coordinates. Within the coordinate space, we use the Vandermonde-with-Arnoldi (V+A) method for Lagrange interpolation and its confluent extension (CV+A) for derivative-enriched Hermite interpolation. By constructing discrete orthogonal bases directly from the parameter nodes, the solution of ill-conditioned linear system is avoided. Theoretical bounds are established to verify the stability of the geometric mapping and the polynomial approximation. Extensive numerical experiments demonstrate that the proposed MV-(C)V+A framework can produce highly accurate approximation in high-degree polynomial interpolation.

math.NA

Decoupled measurement and modeling of interface reaction kinetics of ion-intercalation battery electrodes

Ultrahigh rate performance of active particles used in lithium-ion battery electrodes has been revealed by single-particle measurements, which indicates a huge potential for developing high-power batteries. However, the charging/discharging behaviors of single particles at ultrahigh C-rates can no longer be described by the traditional electrochemical kinetics in such ion-intercalation active materials. In the meantime, regular kinetic measuring methods meet a challenge due to the coupling of interface reaction and solid-state diffusion processes of active particles. Here, we decouple the reaction and diffusion kinetics via time-resolved potential measurements with an interval of 1 ms, revealing that the classical Butler-Volmer equation deviates from the actual relation between current density, overpotential, and Li+ concentration. An interface ion-intercalation model is developed which considers the excess driving force of Li+ (de)intercalation in the charge transfer reaction for ion-intercalation materials. Simulations demonstrate that the proposed model enables accurate prediction of charging/discharging at both single-particle and electrode scales for various active materials. The kinetic limitation processes from single particles to composite electrodes are systematically revealed, promoting rational designs of high-power batteries.

physics.chem-ph

Overpotential decomposition enabled decoupling of complex kinetic processes in battery electrodes

Identifying overpotential components of electrochemical systems enables quantitative analysis of polarization contributions of kinetic processes under practical operating conditions. However, the inherently coupled kinetic processes lead to an enormous challenge in measuring individual overpotentials, particularly in composite electrodes of lithium-ion batteries. Herein, the full decomposition of electrode overpotential is realized by the collaboration of single-layer structured particle electrode (SLPE) constructions and time-resolved potential measurements, explicitly revealing the evolution of kinetic processes. Perfect prediction of the discharging profiles is achieved via potential measurements on SLPEs, even in extreme polarization conditions. By decoupling overpotentials in different electrode/cell structures and material systems, the dominant limiting processes of battery rate performance are uncovered, based on which the optimization of electrochemical kinetics can be conducted. Our study not only shades light on decoupling complex kinetics in electrochemical systems, but also provides vitally significant guidance for the rational design of high-performance batteries.

physics.chem-ph