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Ruslan Prozorov

Publications and source records attributed to Ruslan Prozorov.

At least 19 recordsLinked to original sources

Magnetic susceptibility and superfluid density of inhomogeneous superconducting films: the Tc-mosaic model

Whole-sample and mutual-inductance part-sample measurements of the linear magnetic susceptibility, $χ$, of superconducting films are routinely used to obtain the London penetration depth, $λ(T)$, assuming uniform superconductivity. However, spatially resolved probes show that many films of current interest are inhomogeneous on micrometer scales. Here we ask whether a distribution of local transition temperatures in a fully gapped film can produce an apparent line-nodal, $T$-linear $λ(T)$. The film is modeled as a random Voronoi mosaic of domains with $T_c$ distributed between $T_{c,\min}$ and $T_{c,\max}$ with s-wave (also d-wave, for comparison) London response inside each domain. We show that detectable screening appears only below the percolation temperature, $T_p$, and the transition broadens with the spread of $T_c$. For s-wave domains, $λ(T)$ remains activated for any $T_{c,\min}>0$. Only for $T_{c,\min}=0$ does it become a power law, $Δλ\propto T^n$ with $n\approx1.7$, but then the onset of screening drops to $T_p=T_{c,\max}/2$. Weighting the $T_{c}$ distribution towards $T_c\to0$ (more low-$T_{c}$ domains) can bring $n$ closer to 1 ($n\approx1.2$), but simultaneously pushes the apparent transition, $T_p$, more than an order of magnitude below $T_{c,\max}$. For d-wave domains, the linear term survives, and its relative slope is enhanced almost fourfold for $T_{c,\min}=0$. Hence, a $T$-linear $λ(T)$ measured in a film with screening onset within a factor of a few of $T_{c,\max}$ by whole-sample or mutual-inductance part-sample measurements cannot originate from $T_c$ mosaicity in a fully gapped superconductor.

cond-mat.supr-con↗

Magnetic Susceptibility of Superconducting Films in the Meissner-London Regime

Extracting the London penetration depth, $λ(T)$, from the measured magnetic susceptibility, $χ(T)$, of a superconducting platelet in a perpendicular magnetic field requires knowing the function $χ(λ)$ computed for the actual sample geometry. Thin films are increasingly important in quantum computing and superconducting electronics, most of which operate at ultra-low excitation fields in the vortex-free regime. Understanding their electromagnetic response in the Meissner--London (finite-$λ$, no vortices) state is therefore essential for extracting intrinsic properties such as the London penetration depth and superfluid phase stiffness. While numerous prior works have addressed different aspects of this problem, here we focus on providing an analytical semi-empirical representation of $χ(λ)$ based on the 2D sheet-current model and establishing the limits of its applicability using two independent full 3D numerical solutions: finite-element modeling and a volume-current integral equation. As a result, we provide $χ(λ)$ for a disc of radius $a$ and thickness $d$ in closed form, valid for all $λ$ and for aspect ratios $δ\equiv d/(2a)\le0.05$, and accurate to $0.1\%$. The two-dimensional sheet description with Pearl length $Λ=2λ^2/d$ is adequate for $δ\lesssim10^{-4}$ and $λ\gtrsim 4d$. Thicker films require the full closed form, which includes the three-dimensional corrections. Using the same numerical analysis, we provide an empirical formula that maps rectangular samples---the geometry most commonly used in experiments---onto a disc with an ``effective radius'' for subsequent calculation of $χ(λ)$, and formulate a complete calibration protocol for whole-sample susceptibility measurements.

cond-mat.supr-con↗

Anisotropic interface-confined superconductivity in FeTe-based heterostructures

Interface-confined superconductivity emerges from the interaction of electronic states across chemically distinct boundaries, providing a route to engineer superconducting phases where magnetism and topology coexist. Determining the intrinsic nature of such superconductivity, however, is challenging because the superconducting layer is only a few nanometers thick and buried beneath several normal layers. Here, we measure the whole-sample Meissner response of six $\mathrm{FeTe}$-based heterostructures in a uniform magnetic field using a frequency-domain tunnel-diode resonator. In the ultrathin limit, the conventional normalization of the measured susceptibility, $χ(T\to0)=-1$, fails by tens of percent. We establish the appropriate calibration and invert $χ(T)$ to determine the London penetration depth $λ(T)$. Two key results emerge. First, the broad transitions observed in $χ(T)$ arise naturally from the extreme geometry and large $λ$, without requiring chemical or structural inhomogeneity; the extracted $λ(T)$ closely tracks the resistive transition. Second, $λ(T)$ and the corresponding superfluid density are inconsistent with a fully gapped isotropic $s$-wave state and instead indicate a strongly anisotropic order parameter possibly with line nodes or deep gap minima. The inferred $λ(0)$ is of order $1\,μ$m, consistent with an independent analysis of the 2D phase stiffness. Despite the distinct chemical, magnetic, and topological character of the three overlayers, all six FeTe heterostructures exhibit similar low-temperature power-law behavior, with no systematic dependence of the superconducting response on overlayer identity. These results point to the interfacial $\mathrm{FeTe}$ layer as the common origin of superconductivity.

cond-mat.supr-con↗

Synthesis of Bulk Superconducting LiNbO$_2$ Crystals through CaH$_2$ Reduction

We have synthesized layered superconducting LiNbO$_2$ crystals through a bulk phase transformation from LiNbO$_3$ single crystals via CaH$_2$ reduction. As the Nb valence is reduced from 5+ to 3+, the material undergoes a structural transformation to the resulting product, LiNbO$_2$, which is accompanied by metallic behavior and a superconducting transition, Tc onset, as high as 14.4 K. Secondary ion mass spectroscopy (SIMS) and X-ray photoelectron spectroscopy (XPS) show that the resulting phase is hole-doped through de-lithiation during the reduction. Magnetization and AC susceptibility measurements from a tunnel diode resonator confirm the bulk nature of superconductivity with a superconducting volume fraction of approximately 77% and an upper critical field approaching 26 T. Our study demonstrates extreme hydride reduction as an effective method to induce phase transformations with non-topotactic pathways and can be used to synthesize bulk materials with exotic properties.

cond-mat.supr-con↗

Campbell penetration depth in a single crystal of heavy fermion superconductor CeCoIn$_5$

The temperature and magnetic field dependent magnetic penetration depth, $λ_m(T,H)$, was measured in a single crystal of a heavy fermion superconductor CeCoIn$_5$ using a frequency-domain tunnel diode resonator. In addition to the London penetration depth, which yields the superfluid density, measurements in a finite DC magnetic field provide Campbell penetration depth, $λ_C(T,H)$, which is directly linked to the true (unrelaxed) critical current density, $J_c$. The measured $λ_C(H)$ in CeCoIn$_5$ deviates significantly from the conventional $\sim \sqrt{H}$ behavior, and its slope changes abruptly at the characteristic magnetic field values. Considering that our sample is in the clean limit, we interpret this deviation as a fingerprint of the vortex lattice symmetry change. The temperature dependence $J_c(T)$ of CeCoIn$_5$ calculated from $λ_C(T)$ is nearly $T$-linear over the entire temperature range, also in stark contrast to expectations in a conventional type-II superconductor. Our results provide new evidence for unconventional superconductivity in CeCoIn$_5$ from the never-before-measured Campbell penetration depth.

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Magnetic flux distribution, quasiparticle spectroscopy, and quality factors in Nb films for superconducting qubits

Niobium is a practical material platform for superconducting microwave circuits; however, device-level performance can vary significantly depending on film growth and processing conditions. We compare three epitaxial Nb films grown on $c-$plane sapphire substrates under nominally identical conditions, except for the deposition temperature. To correlate internal quality factors, $Q_{\mathrm {i}}$, with material properties, we combine magneto-optical imaging of magnetic flux distribution with quasiparticle spectroscopy via measurements of the London penetration depth, $λ(T)$. In the low-$Q_{\mathrm i}$ film, there is a lesser ability to screen the magnetic field and an irregular temperature variation of $λ(T)$, implying the existence of localized in-gap states. High $Q_{\mathrm i}$ films show the opposite trend. We conclude that our measurements provide an efficient method for characterizing and optimizing superconducting films for quantum informatics applications.

cond-mat.supr-con↗

Reaching Quantum Critical Point by Adding Non-magnetic Disorder in Single Crystals of Superconductor $(\text{Ca}_x\text{Sr}_{1-x})_3\text{Rh}_4\text{Sn}_{13}$

The Remeika series superconductor, $(\text{Ca}_x\text{Sr}_{1-x})_3\text{Rh}_4\text{Sn}_{13}$, shows a rare nonmagnetic quantum critical point (QCP) associated with the continuous charge-density wave (CDW) and structural transition under the ``dome'' of superconductivity achieved by tuning composition and applying pressure. Here we use a nonmagnetic point-like disorder induced by 2.5 MeV electron irradiation to suppress the CDW and drive the system to and even beyond the QCP. This conclusion is based on a clear evolution of temperature-dependent resistivity, $ρ\left(T\right)$, from the Fermi liquid to the non-Fermi liquid regime with increasing amount of disorder. Starting on the CDW side, below the suggested QCP concentration of $x_c=0.9$, added disorder resulted in a progressively larger linear term and a reduced quadratic term in $ρ\left(T\right)$. Nearly perfect $T-$linear dependence is observed at the dose at which long-range CDW order is suppressed to $T=$0, consistent with the expectations. We refine the QCP location in this system and place it in the interval between $x=$0.75 and 0.85. Our results strongly support the concept that the disorder can tune the system to the quantum critical regime and even beyond. It follows from the argument by Imry and Ma that any ordered phase is unstable toward quenched disorder. Introduced in a controlled way, this disorder becomes a novel non-thermal tuning parameter likely applicable to a variety of different systems.

cond-mat.supr-con↗

Quasiparticle spectroscopy in tantalum films with different Ta/sapphire interfaces

One of the crucial aspects of current research in quantum information science is the identification and control of loss mechanisms in superconducting circuits. Although microwave measurements directly quantify device performance, additional techniques that probe quasiparticle excitations in superconducting films are needed to understand the microscopic mechanisms underlying dissipation and decoherence. Here, we present results from quasiparticle spectroscopy of Ta/sapphire films by measuring the Meissner-state magnetic susceptibility using a precision frequency-domain resonator specifically designed for thin films. We find direct evidence for additional low-energy excitations in samples with lower internal quality factors. These excitations are consistent with deep subgap states due to two-level systems, Yu-Shiba-Rusinov states near the gap edge, and perhaps other pair-breaking mechanisms. The developed non-destructive frequency-domain quasiparticle spectroscopy is a valuable addition to the quantum materials toolbox.

cond-mat.supr-con↗

Magneto-optical study of Nb thin films for superconducting qubits

Among the recognized sources of decoherence in superconducting qubits, the spatial inhomogeneity of the superconducting state and the possible presence of magnetic-flux vortices remain comparatively underexplored. Niobium is commonly used as a structural material in transmon qubits that host Josephson junctions, and excess dissipation anywhere in the transmon can become a bottleneck that limits overall quantum performance. The metal/substrate interfacial layer may simultaneously host pair-breaking loss channels (e.g., two-level systems, TLS) and control thermal transport, thereby affecting dissipation and temperature stability. Here, we use quantitative magneto-optical imaging of the magnetic-flux distribution to characterize the homogeneity of the superconducting state and the critical current density, $j_{c}$, in niobium films fabricated under different sputtering conditions. The imaging reveals distinct flux-penetration regimes, ranging from a nearly ideal Bean critical state to strongly nonuniform thermo-magnetic dendritic avalanches. By fitting the measured magnetic-induction profiles, we extract $j_{c}$ and correlate it with film physical properties and with measured qubit internal quality factors. Our results indicate that the Nb/Si interlayer can be a significant contributor to decoherence and should be considered an important factor that must be optimized.

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Effect of metal encapsulation on bulk superconducting properties of niobium thin films used in qubits

Niobium metal occupies nearly 100\% of the volume of a typical 2D transmon device. While the aluminum Josephson junction is of utmost importance, maintaining quantum coherence across the entire device means that pair-breaking in Nb leads, capacitive pads, and readout resonators can be a major source of decoherence. The established contributors are surface oxides and hydroxides, as well as absorbed hydrogen and oxygen. Metal encapsulation of freshly grown surfaces with non-oxidizing metals, preferably without breaking the vacuum, is a successful strategy to mitigate these issues. While the positive effects of encapsulation are undeniable, it is important to understand its impact on the macroscopic behavior of niobium films. We present a comprehensive study of the bulk superconducting properties of Nb thin films encapsulated with gold and palladium/gold, and compare them to those of bare Nb films. Magneto-optical imaging, magnetization, resistivity, and London and Campbell penetration depth measurements reveal significant differences in encapsulated samples. Both sputtered, and epitaxial Au-capped films exhibit the highest residual resistivity ratio and superconducting transition temperature, as well as the lowest upper critical field, London penetration depth, and critical current. These results are in good agreement with the microscopic theory of anisotropic normal and superconducting states of Nb. We conclude that pair-breaking in the bulk of niobium films, driven by disorder throughout the film rather than just at the surface, is a significant source of quantum decoherence in transmons. We also conclude that gold capping not only passivates the surface but also affects the properties of the entire film, significantly reducing the scattering rate due to defects likely induced by surface diffusion if the film is not protected immediately after fabrication.

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Identifying Materials-Level Sources of Performance Variation in Superconducting Transmon Qubits

The Superconducting Materials and Systems (SQMS) Center, a DOE National Quantum Information Science Research Center, has conducted a comprehensive and coordinated study using superconducting transmon qubit chips with known performance metrics to identify the underlying materials-level sources of device-to-device performance variation. Following qubit coherence measurements, these qubits of varying base superconducting metals and substrates have been examined with various nondestructive and invasive material characterization techniques at Northwestern University, Ames National Laboratory, and Fermilab as part of a blind study. We find trends in variations of the depth of the etched substrate trench, the thickness of the surface oxide, and the geometry of the sidewall, which when combined, lead to correlations with the T$_1$ lifetime across different devices. In addition, we provide a list of features that varied from device to device, for which the impact on performance requires further studies. Finally, we identify two low-temperature characterization techniques that may potentially serve as proxy tools for qubit measurements. These insights provide materials-oriented solutions to not only reduce performance variations across neighboring devices, but also to engineer and fabricate devices with optimal geometries to achieve performance metrics beyond the state-of-the-art values.

quant-ph↗

Practically universal representation of the Helfand-Werthamer upper critical field for any transport scattering rate

The simplified scaling of the orbital upper critical field, $H_{c2}(T)$, for the isotropic case is discussed. To facilitate the analysis of the experimental data, we suggest a simple but accurate approximation in the entire temperature range of the scaled upper critical field valid for any transport scattering rate $H_{c2}/H_{c2}(0) \approx (1-t^2)/(1+0.42 \,t^{1.47})$.

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Conventional s-wave superconductivity and hidden peak effect in single crystals of Mo$_8$Ga$_41$ superconductor

London and Campbell penetration depths were measured in single crystals of the endohedral gallide cluster superconductor, Mo$_{8}$Ga$_{41}$. The full temperature range superfluid density is consistent with the clean isotropic $s-$wave weak-coupling BCS theory without any signs of the second gap or strong coupling. The temperature dependence of the Campbell length is hysteretic between zero-field cooling (ZFC) and field-cooling (FC) protocols, indicating an anharmonic vortex pinning potential. The field dependence of the effective critical current density, $j_{c}\left(H\right)$, reveals an unusual result. While in the ZFC protocol, $j_{c}\left(H\right)$ is monotonically suppressed by the magnetic field, it exhibits a profound ``hidden'' peak effect in the FC protocol, that is, without a vortex density gradient. We suggest a possible novel mechanism for the formation of the peak effect, which involves both static and dynamic aspects.

cond-mat.supr-con↗

Single-gap Isotropic $s-$wave Superconductivity in Single Crystals $\text{AuSn}_4$

London, $λ_L (T)$, and Campbell, $λ_{C} (T)$, penetration depths were measured in single crystals of a topological superconductor candidate $\text{AuSn}_4$. At low temperatures, $λ_L (T)$ is exponentially attenuated and, if fitted with the power law, $λ(T) \sim T^n$, gives exponents $n>4$, indistinguishable from the isotropic single $s-$wave gap Bardeen-Cooper-Schrieffer (BCS) asymptotic. The superfluid density fits perfectly in the entire temperature range to the BCS theory. The superconducting transition temperature, $T_c = 2.40 \pm 0.05\:\text{K}$, does not change after 2.5 MeV electron irradiation, indicating the validity of the Anderson theorem for isotropic $s-$wave superconductors. Campbell penetration depth before and after electron irradiation shows no hysteresis between the zero-field cooling (ZFC) and field cooling (FC) protocols, consistent with the parabolic pinning potential. Interestingly, the critical current density estimated from the original Campbell theory decreases after irradiation, implying that a more sophisticated theory involving collective effects is needed to describe vortex pinning in this system. In general, our thermodynamic measurements strongly suggest that the bulk response of the $\text{AuSn}_4$ crystals is fully consistent with the isotropic $s-$wave weak-coupling BCS superconductivity.

cond-mat.supr-con↗

Reaching quantum critical point by adding nonmagnetic disorder in single crystals of (Ca$_{x}$Sr$_{1-x}$)$_{3}$Rh$_{4}$Sn$_{13}$ superconductor

The quasi-skutterudites (Ca$_{x}$Sr$_{1-x}$)$_{3}$(Rh, Ir)$_{4}$Sn$_{13}$ show a rare nonmagnetic quantum critical point associated with the second-order charge-density-wave (CDW) and structural distortion transition extended under the superconducting "dome". So far, the non-thermal tuning parameters for accessing the QCP included changing stoichiometry, pressure, and a magnetic field. Here we add another parameter -- a nonmagnetic point-like disorder induced by 2.5 MeV electron irradiation. The non-Fermi liquid regime was inferred from the analysis of the temperature-dependent resistivity, $ρ\left(T\right)$, in single crystals of (Ca$_{x}$Sr$_{1-x}$)$_{3}$Rh$_{4}$Sn$_{13}$. Starting at compositions below the known QCP concentration of $x_c=0.9$, added disorder resulted in a progressively larger linear term and a reduced quadratic term in $ρ\left(T\right)$. This behavior is supported by theoretical analysis based on the idea of superconducting fluctuations encompassing the crossover from quantum to thermal regimes. Our results strongly support the concept that the nonmagnetic disorder can drive the system toward the quantum critical regime.

cond-mat.supr-con↗

On the trapped magnetic moment in type-II superconductors

Measurements of the trapped (remanent) magnetic moment, $M_{trap}\left(H\right)$, when a small magnetic field $H$ is turned off after cooling below the superconducting transition temperature, $T_c$, or ramping a magnetic field up and down after cooling in a zero field, have advantages in difficult cases of small samples and large field-dependent backgrounds, which is relevant for hydrogen-based ultra-high-$T_{c}$ superconductors (UHTS). Until recently, there was no need for a separate paper on the trapped magnetic flux for well-known critical state models due to the simplicity of the physics involved. However, recent publications showed the need for such an analysis. This note summarizes the expectations for the Bean model with constant critical current density and the Kim model with field-dependent critical currents. It is shown that if the trapped moment is fitted to the power law, $M_{trap}\propto H^α$, the fixed exponent $α=2$ is exact for the Bean model, while Kim models show a wide interval of possible values, $2\leqα\leq4$. Furthermore, accounting for reversible magnetization expands the range of possible exponents to $1\leqα\leq4$. In addition, demagnetizing factors are essential and make the trapped moment orientation dependent even in isotropic materials. As a concrete application, it is shown that flux trapping experiments on H$_{3}$S UHTS compounds can be described well using this generalized approach, lending further support to the type-II superconducting nature of H$_{3}$S under ultra-high pressure.

cond-mat.supr-con↗

Anisotropic Paramagnetic Peak Effect in Reversible Magnetization of Crystalline Miassite Superconductor $\text{Rh}_{17}\text{S}_{15}$

We report an unusual anisotropic paramagnetic peak effect observed in reversible magnetization of a single crystalline nodal superconductor $\text{Rh}_{17}\text{S}_{15}$. Both temperature- and field-dependent magnetization measurements reveal a distinct novel vortex state above approximately 1 T. This peak effect is most pronounced when the magnetic field, $H$, is applied parallel to the $\left[111\right]$ direction, whereas it diminishes for $H\parallel\left[110\right]$. Intriguingly, for $H\parallel\left[100\right]$, instead of a peak, we observe a step-like decrease in $M(T)$, with the step amplitude increasing in larger applied magnetic fields. This behavior is opposite to the expectations of conventional Meissner expulsion. The magnitude of the peak effect, expressed in terms of dimensionless volume susceptibility, is on the order of $Δχ=10^{-5}$ (with full diamagnetic screening corresponding to $χ=-1$). The observed anisotropic paramagnetic vortex response is unusual considering the cubic symmetry of $\text{Rh}_{17}\text{S}_{15}$. We propose that in this distinct vortex phase, a small but finite attractive interaction between vortices below $H_{c2}$ may be responsible for this unusual phenomenon. Furthermore, the vortices seem to prefer aligning along the $\left[111\right]$ direction, rotating toward it when the magnetic field is applied in other directions. Our findings add another item to the list of unusual properties of $\text{Rh}_{17}\text{S}_{15}$ that attracted recent attention as the first unconventional superconductor that has a mineral analog, miassite, found in nature.

cond-mat.supr-con↗

Creep-enhanced vortex pinning revealed through nonmonotonic relaxation of the Campbell length

We study the effects of flux creep on the linear AC response of the vortex lattice in single crystals Ca$_3$Ir$_4$Sn$_{13}$ by measuring the Campbell penetration depth, $λ_{\rm \scriptscriptstyle C}(T,H,t)$. Thermal fluctuations release vortices from shallow pinning sites, only for them to become re-trapped by deeper potential wells, causing an initial increase of the effective Labusch parameter, which is proportional to the pinning well curvature. This effect cannot be detected in conventional magnetic relaxation measurements but is revealed by our observation of a nonmonotonic time evolution of $λ_{\rm \scriptscriptstyle C}(T,H,t)$, which directly probes the average curvature of the occupied pinning centers. The time evolution of $λ_{\rm \scriptscriptstyle C}(T,H,t)$ was measured at different temperatures in samples with different densities of pinning centers produced by electron irradiation. The curves can be collapsed together when plotted on a logarithmic time scale $t \to T\ln{(t/t_0)}$ confirming that the time evolution is driven by flux creep. The $λ_{\rm \scriptscriptstyle C}(T,H,t)$ is hysteretic with a noticeable nonmonotonic relaxation in the presence of a vortex density gradient (after zero-field cooling), but is monotonic after field cooling, where the vortex density is uniform. This result quantitatively corroborates the novel picture of vortex creep based on the strong pinning theory.

cond-mat.supr-con↗