arXiv subjects

S. -H. Lee

Publications and source records attributed to S. -H. Lee.

At least 127 records · Page 7Linked to original sources

arXiv2010

Ferromagnetically coupled Shastry-Sutherland quantum spin singlets in (CuCl)LaNb$_2$O$_7$

Using inelastic neutron scattering, x-ray, neutron diffraction, and the first-principle calculation techniques, we show that the crystal structure of the two-dimensional quantum spin system (CuCl)LaNb$_2$O$_7$ is orthorhombic with $Pbam$ symmetry in which CuCl$_4$O$_2$ octahedra are tilted from their high symmetry positions and the Cu$^{2+} (s = 1/2)$ ions form a distorted square lattice. The dominant magnetic interactions are the fourth nearest neighbor antiferromagnetic interactions with a Cu-Cl--Cl-Cu exchange path, which lead to the formation of spin singlets. The two strongest interactions between the singlets are ferromagnetic, which makes (CuCl)LaNb$_2$O$_7$ the first system of ferromagnetically coupled Shastry-Sutherland quantum spin singlets.

cond-mat.str-el↗

arXiv2010

Investigation of the spin-glass regime between the antiferromagnetic and superconducting phases in Fe$_{1+y}$Se$_x$Te$_{1-x}$

Using bulk magnetization along with elastic and inelastic neutron scattering techniques, we have investigated the phase diagram of Fe$_{1+y}$Se$_{x}$Te$_{1-x}$ and the nature of magnetic correlations in three nonsuperconducting samples of Fe$_{1.01}$Se$_{0.1}$Te$_{0.9}$, Fe$_{1.01}$Se$_{0.15}$Te$_{0.85}$ and Fe$_{1.02}$Se$_{0.3}$Te$_{0.7}$. A cusp and hysteresis in the temperature dependence of the magnetization for the $x=0.15$ and 0.3 samples indicates spin-glass (SG) ordering below $T_{\rm sg} = 23$K. Neutron scattering measurements indicate that the spin-glass behavior is associated with short-range spin density wave (SDW) ordering characterized by a static component and a low-energy dynamic component with a characteristic incommensurate wave vector of ${\bf Q}_m = (0.46, 0, 0.50)$ and an anisotropy gap of $\sim$ 2.5 meV. Our high ${\bf Q}$-resolution data also show that the systems undergo a glassy structural distortion that coincides with the short-range SDW order.

cond-mat.supr-con↗

arXiv2009

Universal magnetic structure of the half-magnetization phase in Cr-based spinels

Using an elastic neutron scattering technique under a pulsed magnetic field up to 30 T, we determined the magnetic structure in the half-magnetization plateau phase in the spinel CdCr$_2$O$_4$. The magnetic structure has a cubic $P4_3$32 symmetry, which is the same as that observed in HgCr$_2$O$_4$. This suggests that there is a universal field induced spin-lattice coupling mechanism at work in the Cr-based spinels.

cond-mat.mtrl-sci↗

arXiv2009

Glassy Spin Freezing and Gapless Spin Dynamics in a Spatially Anisotropic Triangular Antiferromagnet Ag2MnO2

Using elastic and inelastic neutron scattering techniques, we show that upon cooling a spatially anisotropic triangular antiferromagnet Ag$_2$MnO$_2$ freezes below $T_f ~\sim 50$ K into short range collinear state. The static spin correlations are extremely two-dimensional, and the spin fluctuations are gapless with two characteristic relaxation rates that behave linearly with temperature.

cond-mat.str-el↗

arXiv2009

Spin-lattice order in frustrated ZnCr2O4

Using synchrotron X-rays and neutron diffraction we disentangle spin-lattice order in highly frustrated ZnCr$_2$O$_4$ where magnetic chromium ions occupy the vertices of regular tetrahedra. Upon cooling below 12.5 K the quandary of anti-aligning spins surrounding the triangular faces of tetrahedra is resolved by establishing weak interactions on each triangle through an intricate lattice distortion. The resulting spin order is however, not simply a Néel state on strong bonds. A complex co-planar spin structure indicates that antisymmetric and/or further neighbor exchange interactions also play a role as ZnCr$_2$O$_4$ resolves conflicting magnetic interactions.

cond-mat.str-el↗

arXiv2009

A reassessment of the Burns temperature and its relationship to the diffuse scattering, lattice dynamics, and thermal expansion in the relaxor PMN

We have used neutron scattering techniques to characterize the diffuse scattering and lattice dynamics in single crystals of the relaxor PMN from 10K to 900K. We observed two distinct types of diffuse scattering. The first is weak, relatively temperature independent, persists to at least 900 K, and forms bow-tie-shaped patterns in reciprocal space centered on (h00) Bragg peaks. We associate this primarily with chemical short-range order. The second is strong, temperature dependent, and forms butterfly-shaped patterns centered on (h00) Bragg peaks. This diffuse scattering has been attributed to the PNR because it responds to an electric field and vanishes near Td ~ 620K when measured with thermal neutrons. Surprisingly, it vanishes at 420K when measured with cold neutrons, which provide ~4 times superior energy resolution. That this onset temperature depends on the instrumental energy resolution demands a reassessment of the Burns temperature Td. Neutron backscattering measurements made with 300 times better energy resolution confirm the onset temperature of 420+/-20K. The energy width of the diffuse scattering is resolution limited, indicating that the PNR are static on timescales of at least 2 nsec. Transverse acoustic (TA) phonon lifetimes are temperature independent up to 900K for q < 0.2 1/A. This motivates a physical picture in which sufficiently long-wavelength TA phonons average over the PNR; only those TA phonons having wavelengths comparable to the size of the PNR are affected. The PMN lattice constant changes by less than 0.001 Angstroms below 300K, but expands rapidly at a rate of 2.5x10^-5 1/K at high temperature. The regimes of low and high thermal expansion bracket the revised value of Td, which suggests the anomalous thermal expansion results from the condensation of static PNR.

cond-mat.mtrl-sci↗

arXiv2009

Magnetic field-induced phase transitions in a weakly coupled s = 1/2 quantum spin dimer system Ba$_{3}$Cr$_{2}$O$_{8}$

By using bulk magnetization, electron spin resonance (ESR), heat capacity, and neutron scattering techniques, we characterize the thermodynamic and quantum phase diagrams of Ba$_3$Cr$_2$O$_8$. Our ESR measurements indicate that the low field paramagnetic ground state is a mixed state of the singlet and the S$_z$ = 0 triplet for $H \perp c$. This suggests the presence of an intra-dimer Dzyaloshinsky-Moriya (DM) interaction with a DM vector perpendicular to the c-axis.

cond-mat.str-el↗

arXiv2009

Neutron scattering investigation of the magnetic order in single crystalline BaFe2As2

The magnetic structure of BaFe2As2 was completely determined from polycrystalline neutron diffraction measurements soon after the ThCr2Si2-type FeAs-based superconductors were discovered. Both the moment direction and the in-plane antiferromagnetic wavevector are along the longer a-axis of the orthorhombic unit cell. There is only one combined magnetostructural transition at about 140 K. However, a later single-crystal neutron diffraction work reported contradicting results. Here we show neutron diffraction results from a clean single crystal sample, grown by a self-flux method, that support the original polycrystalline work.

cond-mat.supr-con↗

arXiv2008

Hidden quantum spin gap state in the static stripe phase of La$_{2-x}$Sr$_{x}$CuO$_{4}$

Low energy spin excitations were investigated in the static stripe phase of La_{2-x}Sr_xCuO_4 using elastic and inelastic neutron scattering on single crystals. For x = 1/8 in which long-range static stripe order exists, an energy gap of E_g = 4 meV exists in the excitation spectrum in addition to strong quasi-elastic, incommensurate spin fluctuations associated with the static stripes. When x increases, the spectral weight of the spin fluctuations shifts from the quasi-elastic continuum to the excitation spectrum above E_g. The dynamic correlation length as a function of energy and the temperature evolution of the energy spectrum suggest a phase separation of two distinct magnetic phases in real space.

cond-mat.supr-con↗

arXiv2008

Weakly coupled $s = 1/2$ quantum spin singlets in Ba$_{3}$Cr$_{2}$O$_{8}$

Using single crystal inelastic neutron scattering with and without application of an external magnetic field and powder neutron diffraction, we have characterized magnetic interactions in Ba$_3$Cr$_2$O$_8$. Even without field, we found that there exist three singlet-to-triplet excitation modes in $(h,h,l)$ scattering plane. Our complete analysis shows that the three modes are due to spatially anisotropic interdimer interactions that are induced by local distortions of the tetrahedron of oxygens surrounding the Jahn-Teller active Cr$^{5+} (3d^1)$. The strong intradimer coupling of $J_0 = 2.38(2)$ meV and weak interdimer interactions ($|J_{\rm inter}| \leq 0.52(2)$ meV) makes Ba$_3$Cr$_2$O$_8$ a good model system for weakly-coupled $s = 1/2$ quantum spin dimers.

cond-mat.str-el↗

arXiv2008

Short-range Charge and Spin Superstructures in Doped Layered Co Perovskites

We have investigated cobaltite relatives of the layered perovskite cuprates and nickelates, Pr$_{2-x}$Ca$_x$CoO$_4$ ($0.39 \leq x \leq 0.73$) and La$_{2-x}$Sr$_x$CoO$_4$ ($x = 0.61$), using elastic neutron scattering. We have discovered doping-dependent incommensurate short-range ordering of charges and magnetic moments, which in cobaltites occur in the range of heavy doping, $ 0.5 \lesssim x \lesssim 0.75$. The charge order exists already at room temperature and shows no change on cooling. The incommensurability of its propagation vector, ${\bf Q}_c = (ε_c,0,l)$, roughly scales with the concentration of Co$^{2+}$ ions, $ε_c \sim (1-x)$. Magnetic order is only established at low T$\lesssim 40$ K and has twice larger periodicity, indicating a dominant antiferromagnetic correlation between the nearest Co$^{2+}$ spins.

cond-mat.str-el↗

arXiv2008

External magnetic field effects on a distorted kagome antiferromagnet

We report bulk magnetization, and elastic and inelastic neutron scattering measurements under an external magnetic field, $H$, on the weakly coupled distorted kagome system, Cu_{2}(OD)_3Cl. Our results show that the ordered state below 6.7 K is a canted antiferromagnet and consists of large antiferromagnetic $ac$-components and smaller ferromagnetic $b$-components. By first-principle calculations and linear spin wave analysis, we present a simple spin hamiltonian with non-uniform nearest neighbor exchange interactions resulting in a system of coupled spin trimers with a single-ion anisotropy that can qualitatively reproduce the spin dynamics of Cu_{2}(OD)_3Cl.

cond-mat.str-el↗

arXiv2008

Neutron scattering study of the oxypnictide superconductor La(O,F)FeAs

The newly discovered superconductor La(O,F)FeAs (Tc = 26 K) was investigated using the neutron scattering technique. No spin-density-wave (SDW) order was observed in the normal state nor in the superconducting state, both with and without an applied magnetic field of 9 T, consistent with the proposal that SDW and superconductivity are competing in the laminar materials. While our inelastic measurements offer no constraints on the spin dynamic response from d-wave pairing, an upper limit for the magnetic resonance peak predicted from an extended s-wave pairing mechanism is provided. Our measurements also support the energy scale of the calculated phonon spectrum which is used in electron-phonon coupling theory, and fails to produce the high observed Tc.

cond-mat.supr-con↗

arXiv2008

Complex Spin Structures and Origin of the Magneto-Electric Coupling in YMn2O5

By combining neutron four-circle diffraction and polarized neutron diffraction techniques we have determined the complex spin structures of a multiferroic, YMn2O5, that exhibits two ferroelectric phases at low temperatures. The obtained magnetic structure has spiral components in both the low temperature ferroelectric phases that are magnetically commensurate and incommensurate, respectively. Among proposed microscopic theories for the magneto-electric coupling, our results are consistent with both the spin-current model that requires a magnetic transverse (cycloidal) spiral structure in order to induce a spontaneous electric polarization and the magneto-restriction model. Our results also explain why the electric polarization changes at the commensurate-to-incommensurate phase transition.

cond-mat.str-el↗

arXiv2007

Neel to Spin-Glass-like Phase Transition versus Dilution in Geometrically Frustrated ZnCr_{2-2x}Ga_{2x}O_4

ZnCr2O4 undergoes a first order spin-Peierls-like phase transition at 12.5 K from a cubic spin liquid phase to a tetragonal Neel state. Using powder diffraction and single crystal polarized neutron scattering, we determined the complex spin structure of the Neel phase. This phase consisted of several magnetic domains with different characteristic wave vectors. This indicates that the tetragonal phase of ZnCr2O4 is very close to a critical point surrounded by many different Neel states. We have also studied, using elastic and inelastic neutron scattering techniques, the effect of nonmagnetic dilution on magnetic correlations in ZnCr_{2-2x}Ga_{2x}O_4 (x=0.05 and 0.3). For x=0.05, the magnetic correlations do not change qualitatively from those in the pure material, except that the phase transition becomes second order. For x= 0.3, the spin-spin correlations become short range. Interestingly, the spatial correlations of the frozen spins in the x=0.3 material are the same as those of the fluctuating moments in the pure and the weakly diluted materials.

cond-mat.str-el↗

arXiv2007

Frustrated minority spins in GeNi2O4

Recently, two consecutive phase transitions were observed, upon cooling, in an antiferromagnetic spinel GeNi$_2$O$_4$ at $T_{N1}=12.1$ K and $T_{N2}=11.4$ K, respectively \cite{matsuno, crawford}. Using unpolarized and polarized elastic neutron scattering we show that the two transitions are due to the existence of frustrated minority spins in this compound. Upon cooling, at $T_{N1}$ the spins on the $<111>$ \kagome planes order ferromagnetically in the plane and antiferromagnetically between the planes (phase I), leaving the spins on the $<111>$ triangular planes that separate the \kagome planes frustrated and disordered. At the lower $T_{N2}$, the triangular spins also order in the $<111>$ plane (phase II). We also present a scenario involving exchange interactions that qualitatively explains the origin of the two purely magnetic phase transitions.

cond-mat.str-el↗

arXiv2007

Doping Dependence of Low-energy Spin Fluctuations in Electron-Doped Cuprates Pr$_{1-x}$LaCe$_x$CuO$_4$

The low-energy spin fluctuations in the electron-doped Pr$_{1-x}$LaCe$_{x}$CuO$_{4}$ have been investigated over a wide concentration range of 0.07$\leqslant$ $x$ $\leqslant$0.18 that spans from the antiferromagnetic and non-superconducting phase to the superconducting and paramagnetic phase. For all concentrations considered, the low energy excitations exhibit commensurate peaks centered at the ($π$, $π$) position. Our data show that the characteristics of the excitations, such as the relaxation rate and the overall spectral weight, change rapidly when the system enters the superconducting phase. The spin stiffness also decreases with increasing $x$ in the superconducting phase and is extrapolated to zero at $x$ = 0.21 when the superconductivity disappears. These indicate a close relation between the spin fluctuations and the superconductivity in the electron-doped system.

cond-mat.str-el↗

arXiv2007

Spin-lattice instability to a fractional magnetization state in the spinel HgCr2O4

Magnetic systems are fertile ground for the emergence of exotic states when the magnetic interactions cannot be satisfied simultaneously due to the topology of the lattice - a situation known as geometrical frustration. Spinels, AB2O4, can realize the most highly frustrated network of corner-sharing tetrahedra. Several novel states have been discovered in spinels, such as composite spin clusters and novel charge-ordered states. Here we use neutron and synchrotron X-ray scattering to characterize the fractional magnetization state of HgCr2O4 under an external magnetic field, H. When the field is applied in its Neel ground state, a phase transition occurs at H ~ 10 Tesla at which each tetrahedron changes from a canted Neel state to a fractional spin state with the total spin, Stet, of S/2 and the lattice undergoes orthorhombic to cubic symmetry change. Our results provide the microscopic one-to-one correspondence between the spin state and the lattice distortion.

cond-mat.str-el↗