arXiv subjects

S. A. Wolf

Publications and source records attributed to S. A. Wolf.

18 recordsLinked to original sources

arXiv2022

Nitrogen-vacancy singlet manifold ionization energy

The singlet states of the negatively-charged nitrogen-vacancy centers in diamond play a key role in its optical spin control and readout. In this work, the hitherto unknown ionization energy of the singlet is measured experimentally and found to be between 1.91-2.25 eV. This is obtained by analyzing photoluminescence measurements incorporating spin control and NV charge state differentiation, along with simulations based on the nitrogen-vacancy's master equation. This work establishes a protocol for a more accurate estimate of this ionization energy, which can possibly lead to improved read-out methods.

quant-ph↗

arXiv2019

Nano-engineering of electron correlation in oxide superlattices

Oxide heterostructures and superlattices have attracted a great deal of attention in recent years owing to the rich exotic properties encountered at their interfaces. We focus on the potential of tunable correlated oxides by investigating the spectral function of the prototypical correlated metal SrVO3, using soft x-ray absorption spectroscopy (XAS) and resonant inelastic soft x-ray scattering (RIXS) to access both unoccupied and occupied electronic states, respectively. We demonstrate a remarkable level of tunability in the spectral function of SrVO3 by varying its thickness within the SrVO3/SrTiO3 superlattice, showing that the effects of electron correlation can be tuned from dominating the energy spectrum in a strongly correlated Mott-Hubbard insulator, towards a correlated metal. We show that the effects of dimensionality on the correlated properties of SrVO3 are augmented by interlayer coupling, yielding a highly flexible correlated oxide that may be readily married with other oxide systems.

cond-mat.str-el↗

arXiv2019

Observation of weakened V-V dimers in the monoclinic metallic phase of strained VO2

Emergent order at mesoscopic length scales in condensed matter can provide fundamental insight into the underlying competing interactions and their relationship with the order parameter. Using spectromicroscopy, we show that mesoscopic stripe order near the metal-insulator transition (MIT) of strained VO2 represent periodic modulations in both crystal symmetry and V-V dimerization. Above the MIT, we unexpectedly find the long range order of V-V dimer strength and crystal symmetry become dissociated beyond ~ 200 nm, whereas the conductivity transition proceeds homogeneously in a narrow temperature range.

cond-mat.str-el↗

arXiv2017

Negative charge enhancement of near-surface nitrogen vacancy centers by multicolor excitation

Nitrogen-Vacancy (NV) centers in diamond have been identified over the past few years as promising systems for a variety of applications, ranging from quantum information science to magnetic sensing. This relies on the unique optical and spin properties of the negatively charged NV. Many of these applications require shallow NV centers, i.e. NVs that are close (a few nm) to the diamond surface. In recent years there has been increasing interest in understanding the dynamics of NV centers under various illumination conditions, specifically under infra-red (IR) excitation, which has been demonstrated to have significant impact on the NV centers' emission and charge state. Nevertheless, a full understanding of all experimental data is still lacking, with further complications arising from potential differences between the photo-dynamics of bulk vs. shallow NVs. Here we suggest a generalized quantitative model for NV center spin and charge state dynamics under both green and IR excitation. We experimentally extract the relevant transition rates, providing a comprehensive model which reconciles all existing results in the literature. Moreover, we identify key differences between the photo-dynamics of bulk and shallow NVs, and use them to significantly enhance the initialization fidelity of shallow NVs to the useful negatively-charged state.

quant-ph↗

arXiv2015

Effect of inhomogeneities and substrate on the dynamics of the metal-insulator transition in VO$_2$ thin films

We study the thermal relaxation dynamics of VO$_2$ films after the ultrafast photo-induced metal-insulator transition for two VO$_2$ film samples grown on Al$_2$O$_3$ and TiO$_2$ substrates. We find two orders of magnitude difference in the recovery time (a few ns for the VO$_2$/Al$_2$O$_3$ sample vs. hundreds of ns for the VO$_2$/TiO$_2$ sample). We present a theoretical model that accurately describes the MIT thermal properties and interpret the experimental measurements. We obtain quantitative results that show how the microstructure of the VO$_2$ film and the thermal conductivity of the interface between the VO$_2$ film and the substrate affect long time-scale recovery dynamics. We also obtain a simple analytic relationship between the recovery time-scale and some of the film parameters.

cond-mat.mtrl-sci↗

arXiv2015

Substrate-induced microstructure effects on the dynamics of the photo-induced Metal-insulator transition in VO$_2$ thin films

We investigate the differences in the dynamics of the ultrafast photo-induced metal-insulator transition (MIT) of two VO$_2$ thin films deposited on different substrates, TiO$_2$ and Al$_2$O$_3$, and in particular the temperature dependence of the threshold laser fluence values required to induce various MIT stages in a wide range of sample temperatures (150 K - 320 K). We identified that, although the general pattern of MIT evolution was similar for the two samples, there were several differences. Most notably, the threshold values of laser fluence required to reach the transition to a fully metallic phase in the VO$_2$ film on the TiO$_2$ substrate were nearly constant in the range of temperatures considered, whereas the VO$_2$/Al$_2$O$_3$ sample showed clear temperature dependence. Our analysis qualitatively connects such behavior to the structural differences in the two VO$_2$ films.

physics.optics↗

arXiv2014

Direct Observation of Decoupled Structural and Electronic Transitions and an Ambient Pressure Monoclinic-Like Metallic Phase of VO$_2$

We report the simultaneous measurement of the structural and electronic components of the metal-insulator transition of VO$_2$ using electron and photoelectron spectroscopies and microscopies. We show that these evolve over different temperature scales, and are separated by an unusual monoclinic-like metallic phase. Our results provide conclusive evidence that the new monoclinic-like metallic phase, recently identified in high-pressure and nonequilibrium measurements, is accessible in the thermodynamic transition at ambient pressure, and we discuss the implications of these observations on the nature of the MIT in VO$_2$.

cond-mat.str-el↗

arXiv2013

Resonant soft x-ray emission as a bulk probe of correlated electron behavior in metallic Sr$_x$Ca$_{1-x}$VO$_3$

The evolution of electron correlation in Sr$_{x}$Ca$_{1-x}$VO$_3$ has been studied using a combination of bulk-sensitive resonant soft x-ray emission spectroscopy (RXES), surface-sensitive photoemission spectroscopy (PES), and ab initio band structure calculations. We show that the effect of electron correlation is enhanced at the surface. Strong incoherent Hubbard subbands are found to lie ~ 20% closer in energy to the coherent quasiparticle features in surface-sensitive PES measurements compared with those from bulk-sensitive RXES, and a ~ 10% narrowing of the overall bandwidth at the surface is also observed.

cond-mat.str-el↗

arXiv2013

Strain-induced enhancement of coercivity in amorphous TbFeCo films

We report a strong size dependence of coercivity in amorphous ferrimagnetic TbFeCo films. The as-deposited film exhibited a low saturation magnetization (Ms=100 emu/cc) and a high perpendicular anisotropy (Ku=10^6 erg/cc). Hall-bar devices were fabricated for characterizing the magneto-transport behaviors. A significant increase in coercivity (up to 300 %) was observed at room temperature as the width of Hall bar was reduced. The large coercivity enhancement was attributed to the relaxation of film stress. The effect of strain and dimensionality on the coercivity in TbFeCo makes it attractive for tunable coercivity and the magnetization reversal in future nanoscale devices.

cond-mat.mtrl-sci↗

arXiv2013

Substrate Effect on Optical Properties of Insulator-Metal Transition in VO2 Thin Films

In this paper we used Raman spectroscopy to investigate the optical properties of vanadium dioxide (VO2) thin films during the thermally induced insulating to metallic phase transition. We observed a significant difference in transition temperature in similar VO2 films grown on quartz and sapphire substrates: the film grown on quartz displayed the phase transition at a lower temperature (Tc=50C) compared a film grown on sapphire (Tc=68C). We also investigated differences in the detected Raman signal for different wavelengths and polarizations of the excitation laser. We found that for either substrate, a longer wavelength (in our case 785 nm) yielded the clearest VO2 Raman spectra, with no polarization dependence.

cond-mat.mtrl-sci↗

arXiv2012

Photoemission evidence for crossover from Peierls-like to Mott-like transition in highly strained VO$_2$

We present a spectroscopic study that reveals that the metal-insulator transition of strained VO$_2$ thin films may be driven towards a purely electronic transition, which does not rely on the Peierls dimerization, by the application of mechanical strain. Comparison with a moderately strained system, which does involve the lattice, demonstrates the crossover from Peierls- to Mott-like transitions.

cond-mat.str-el↗

arXiv2012

Strain dependence of bonding and hybridization across the metal-insulator transition of VO2

Soft x-ray spectroscopy is used to investigate the strain dependence of the metal-insulator transition of VO2. Changes in the strength of the V 3d - O 2p hybridization are observed across the transition, and are linked to the structural distortion. Furthermore, although the V-V dimerization is well-described by dynamical mean-field theory, the V-O hybridization is found to have an unexpectedly strong dependence on strain that is not predicted by band theory, emphasizing the relevance of the O ion to the physics of VO2.

cond-mat.str-el↗

arXiv2009

Electron-lattice interaction and its impact on high Tc superconductivity

In this Colloquium, the main features of the electron-lattice interaction are discussed and high values of the critical temperature up to room temperature could be provided. While the issue of the mechanism of superconductivity in the high Tc cuprates continues to be controversial, one can state that there have been many experimental results demonstrating that the lattice makes a strong impact on the pairing of electrons. The polaronic nature of the carriers is also a manifestation of strong electron-lattice interaction. One can propose an experiment that allows an unambiguous determination of the intermediate boson (phonon, magnon, exciton, etc.) which provides the pairing. The electron-lattice interaction increases for nanosystems, and this is due to an effective increase in the density of states.

cond-mat.supr-con↗

arXiv2008

Propagation of Exchange Bias in CoFe/FeMn/CoFe Trilayers

CoFe/FeMn, FeMn/CoFe bilayers and CoFe/FeMn/CoFe trilayers were grown in magnetic field and at room temperature. The exchange bias field $H_{eb}$ depends strongly on the order of depositions and is much higher at CoFe/FeMn than at FeMn/CoFe interfaces. By combining the two bilayer structures into symmetric CoFe/FeMn($t_\mathrm{FeMn}$)/CoFe trilayers, $H_{eb}^t$ and $H_{eb}^b$ of the top and bottom CoFe layers, respectively, are both enhanced. Reducing $t_\mathrm{FeMn}$ of the trilayers also results in enhancements of both $H_{eb}^b$ and $H_{eb}^t$. These results evidence the propagation of exchange bias between the two CoFe/FeMn and FeMn/CoFe interfaces mediated by the FeMn antiferromagnetic order.

cond-mat.mtrl-sci↗

arXiv2008

Impact of in-plane currents on magnetoresistance properties of an exchange-biased spin-valve with insulating antiferromagnetic layer

The impact of in-plane alternating currents on the exchange bias, resistance, and magnetoresistance of a CoFe/NiCoO/CoFe/Cu/CoFe spin-valve is studied. With increasing current, the resistance is increased while the maximum magnetoresistance ratio decreases. Noticeably, the reversal of the pinned layer is systematically suppressed in both field sweeping directions. Since the NiCoO oxide is a good insulator, it is expected that the ac current flows only in the CoFe/Cu/CoFe top layers, thus ruling out any presence of spin-transfer torque acting on the spins in the antiferromagnetic layer. Instead, our measurements show clear evidences for the influence of Joule heating caused by the current. Moreover, results from temperature-dependent measurements very much resemble those of the current dependence, indicating that the effect of Joule heating plays a major role in the current-in-plane spin-valve configurations. The results also suggest that spin-transfer torques between ferromagnetic layers might still exist and compete with the exchange bias at sufficiently high currents.

cond-mat.mtrl-sci↗

arXiv1998

The Isotope Effect in Superconductors

We review some aspects of the isotope effect (IE) in superconductors. Our focus is on the influence of factors not related to the pairing mechanism. After summarizing the main results obtained for conventional superconductors, we review the effect of magnetic impurities, the proximity effect and non-adiabaticity on the value of the isotope coefficient (IC). We discuss the isotope effect of $T_c$ and of the penetration depth $δ$. The theory is applied to conventional and high-$T_c$ superconductors. Experimental results obtained for YBa$_2$Cu$_3$O$_{7-δ}$ related materials (Zn and Pr-substituted as well as oxygen-depleted systems) and for La$_{2-x}$Sr$_x$CuO$_4$ are discussed.

cond-mat.supr-con↗

arXiv1998

Effect of Magnetic Impurity Correlations on Josephson Tunneling

The ordering trend of magnetic impurities at low temperature results in the frustration of the pair-breaking effect and induces a ``recovery'' of superconducting properties. We show that this effect manifests itself in the deviation of the Josephson current amplitude from the values obtained within the Ambegaokar-Baratoff and the Abrikosov-Gor'kov models. We consider both weak and strong-coupling cases. The theory is applied to describe the experimental data obtained for the low-$T_c$ superconductor SmRh$_4$B$_4$. We further predict a ``recovery'' effect of the Josephson current in high-temperature superconductors.

cond-mat.supr-con↗

arXiv1998

Isotope Effect for the Penetration Depth in Superconductors

We show that various factors can lead to an isotopic dependence of the penetration depth $δ$. Non-adiabaticity (Jahn-Teller crossing) leads to the isotope effect of the charge carrier concentration $n$ and, consequently, of $δ$ in doped superconductors such as the cuprates. A general equation relating the isotope coefficients of $T_c$ and of $δ$ is presented for London superconductors. We further show that the presence of magnetic impurities or a proximity contact also lead to an isotopic dependence of $δ$; the isotope coefficient turns out to be temperature dependent, $β(T)$, in these cases. The existence of the isotope effect for the penetration depth is predicted for conventional as well as for high-temperature superconductors. Various experiments are proposed and/or discussed.

cond-mat.supr-con↗