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S. Brazovskii

Publications and source records attributed to S. Brazovskii.

At least 19 recordsLinked to original sources

Phase transitions and pattern formation in ensembles of phase-amplitude solitons in quasi-one-dimensional electronic systems

Most common types of symmetry breaking in quasi-one-dimensional electronic systems possess a combined manifold of states degenerate with respect to both the phase $θ$ and the amplitude $A$ sign of the order parameter $A\exp(iθ)$. These degrees of freedom can be controlled or accessed independently via either the spin polarization or the charge densities. To understand statistical properties and the phase diagram in the course of cooling under the controlled parameters, we present here an analytical treatment supported by Monte Carlo simulations for a generic coarse-grained two-fields model of XY-Ising type. The degeneracies give rise to two coexisting types of topologically nontrivial configurations: phase vortices and amplitude kinks -- the solitons. In 2D, 3D states with long-range (or BKT type) orders, the topological confinement sets in at a temperature $T=T_1$ which binds together the kinks and unusual half-integer vortices. At a lower $T=T_2$, the solitons start to aggregate into walls formed as rods of amplitude kinks which are ultimately terminated by half-integer vortices. With lowering $T$, the walls multiply passing sequentially across the sample. The presented results indicate a possible physical realization of a peculiar system of half-integer vortices with rods of amplitude kinks connecting their cores. Its experimental realization becomes feasible in view of recent successes in real space observations and even manipulations of domain walls in correlated electronic systems.

cond-mat.stat-mech

Phase transitions in ensembles of solitons induced by an optical pumping or a strong electric field

The latest trend in studies of modern electronically and/or optically active materials is to provoke phase transformations induced by high electric fields or by short (femtosecond) powerful optical pulses. The systems of choice are cooperative electronic states whose broken symmetries give rise to topological defects. For typical quasi-one-dimensional architectures, those are the microscopic solitons taking from electrons the major roles as carriers of charge or spin. Because of the long-range ordering, the solitons experience unusual super-long-range forces leading to a sequence of phase transitions in their ensembles: the higher-temperature transition of the confinement and the lower one of aggregation into macroscopic walls. Here we present results of an extensive numerical modeling for ensembles of both neutral and charged solitons in both two- and three-dimensional systems. We suggest a specific Monte Carlo algorithm preserving the number of solitons, which substantially facilitates the calculations, allows to extend them to the three-dimensional case and to include the important long-range Coulomb interactions. The results confirm the first confinement transition, except for a very strong Coulomb repulsion, and demonstrate a pattern formation at the second transition of aggregation.

cond-mat.str-el

Critical dynamics and domain motion from permittivity of the electronic ferroelectric (TMTTF)2AsF6

The quasi one-dimensional organic conductor (TMTTF)2AsF6 shows the charge ordering transition at Tc101K to a state of the ferroelectric Mott insulator which is still well conducting. We present and interpret the experimental data on the gigantic dielectric response in the vicinity of TCO, concentrating on the frequency dependence of the inverse $1/ε$ of the complex permittivity $ε=ε^\prime+iε^{\prime\prime}$. Surprisingly for a ferroelectric, we could closely approach the 2nd order phase transition and to deeply reach the critical dynamics of the polarization. We could analyse the critical slowing-down when approaching Tc from both sides and to extract the anomalous power law for the frequency dependence of the order parameter viscosity. Moreover, below Tc we could extract a sharp absorption feature coming from a motion of domain walls which shows up at a frequency well below the relaxation rate.

cond-mat.str-el

Multi-vortex dynamics in junctions of charge density waves

Ground state reconstruction by creation of topological defects in junctions of CDWs is a convenient playground for modern efforts of field-effect transformations in strongly correlated materials with spontaneous symmetry breakings. Being transient, this effect contributes also to another new science of pump-induced phase transitions. We present a dynamical model for behavior of the CDW in restricted geometries of junctions under an applied voltage or a passing current. The model takes into account multiple interacting fields: the amplitude and the phase of the CDW complex order parameter, distributions of the electric field, the density and the current of various normal carriers. A particular challenge was to monitor the local conservation of the condensed and the normal charge densities. That was done easily invoking the chiral invariance and the associated anomaly, but prize is an unconventional Ginsburg-Landau type theory which is not analytic with respect to the order parameter. The numerical modeling poses unusual difficulties but still can demonstrate that vortices are nucleated at the junction boundary when the voltage across, or the current through, exceed a threshold.

cond-mat.str-el

Fast non-thermal switching between macroscopic charge-ordered quantum states induced by charge injection

The functionality of logic and memory elements in current electronics is based on multi-stability, driven either by manipulating local concentrations of electrons in transistors, or by switching between equivalent states of a material with a degener- ate ground state in magnetic or ferroelectric materials. Another possibility is offered by phase transitions with switching between metallic and insulating phases, but classical phase transitions are limited in speed by slow nucleation, proliferation of domains and hysteresis. We can in principle avoid these problems by using quantum states for switching, but microscopic systems suffer from decoherence which prohibits their use in everyday devices. Macroscopic quantum states, such as the superconducting ground state have the advantage that on a fundamental level they do not suffer from decoherence plaguing microscopic systems. Here we demonstrate for the first time ultrafast non-thermal switching between different metastable electronically ordered states by pulsed electrical charge injection. The macroscopic nature of the many-body quantum states(1-4) - which are not part of the equilibrium phase diagram - gives rise to unprecedented stability and remarka- bly sharp switching thresholds. Fast sub-50 ps switching, large associated re- sistance changes, 2-terminal operation and demonstrable high fidelity of bi-stability control suggest new opportunities for the use of macroscopic quantum states in electronics, particularly for an ultrafast non-volatile quantum charge-order resistive random access memory (QCOR-RAM).

cond-mat.mes-hall

Ultrafast switching to a stable hidden topologically protected quantum state in an electronic crystal

Hidden states of matter with novel and unusual properties may be created if a system out of equilibrium can be induced to follow a trajectory to a state which is inaccessible or does not even exist under normal equilibrium conditions. Here we report on the discovery of a hidden (H) topologically protected electronic state in a layered dichalcogenide 1T-TaS2 crystal reached as a result of a quench caused by a single 35 fs laser pulse. The properties of the H state are markedly different from any other state of the system: it exhibits a large drop of electrical resistance, strongly modified single particle and collective mode spectra and a marked change of optical reflectivity. Particularly important and unusual, the H state is stable for an arbitrarily long time until a laser pulse, electrical current or thermal erase procedure is applied, causing it to revert to the thermodynamic ground state. Major observed events can be reproduced by a kinetic model describing the conversion of photo excited electrons and holes into an electronically ordered crystal, thus converting a Mott insulator to a conducting H state. Its long-time stability follows from the topological protection of the number of periods in the electronic crystal.

cond-mat.str-el

Coherent dynamics of macroscopic electronic order through a symmetry-breaking transition

The temporal evolution of systems undergoing symmetry breaking phase transitions (SBTs) is of great fundamental interest not only in condensed matter physics, but extends from cosmology to brain function and finance \cite{topology,Kibble,Eltsov,Finance}. However, the study of such transitions is often hindered by the fact that they are difficult to repeat, or they occur very rapidly. Here we report for the first time on a high-time-resolution study of the evolution of both bosonic and fermionic excitations through a second order electronic charge-ordering SBT in a condensed matter system. Using a new three-pulse femtosecond spectroscopy technique, we periodically quench our model system into the high-symmetry state, detecting hitherto unrecorded coherent aperiodic undulations of the order parameter (OP), critical slowing down of the collective mode, and evolution of the particle-hole gap appearing through the Peierls-BCS mechanism as the system evolves through the transition. Numerical modeling based on Ginzburg-Landau theory is used to reproduce the observations without free parameters. The close analogy with other Higgs potentials in particle physics\cite{Higgs} gives new insight into hitherto unexplored dynamics of both single particle and collective excitations through a SBT. Of particular interest is the observation of spectro-temporal distortions caused by disturbances of the field arising from spontaneous annihilation of topological defects, similar to those discussed by the Kibble-Zurek cosmological model.

cond-mat.stat-mech

Solitons: from Charge Density Waves to FFLO in superconductors

This short review aims to summarize on "What the Charge Density Waves can tell to other inhomogeneous states in strongly correlated systems, particularly to spin-polarized superconductors". We shall update on expanding observations of solitons in quasi 1D CDW conductors and link them to the growing information and demands related to inhomogeneous spin-polarized states in superconductors. The related theory, existent or awaited for, stretches from solitons in 1D models to vortex-like elementary excitations in 2D,3D ordered incommensurate CDWs and superconductors.

cond-mat.str-el

New Routes to Solitons in Quasi One-Dimensional Conductors

We collect evidences on existence of microscopic solitons, and their determining role in electronic processes of quasi-1D conductors. The ferroelectric charge ordering gives access to several types of solitons in conductivity and permittivity, and to solitons' bound pairs in optics - both in insulating and conducting cases of TMTTF and TMTSF subfamilies. The excursion to physics of conjugated polymers allows to suggest further experiments. Internal tunnelling in Charge Density Waves goes through the channel of "amplitude solitons", which correspond to the long sought quasi-particle - the spinon. The same experiment gives an access to the reversible reconstruction of the junction via spontaneous creation of a lattice of 2Pi solitons - a grid of dislocations. The individual 2Pi solitons have been visually captured in recent STM experiments. Junctions of organic and oxide conductors are anticipated to show similar effects of reconstruction.

cond-mat.str-el

Theory of subgap interchain tunneling in quasi one-dimensional conductors

We suggest a theory of internal coherent tunneling in the pseudogap region, when the applied voltage U is below the free electron gap 2Delta_0. We address quasi 1D systems, where the gap is originated by spontaneous lattice distortions of the Incommensurate Charge Density Wave (ICDW) type. Results can be adjusted also to quasi-1D superconductors. The instanton approach allows to calculate the interchain tunneling current both in single electron (amplitude solitons, i.e. spinons) and bi-electron (phase slips) channels. Transition rates are governed by a dissipative dynamics originated by emission of gapless phase excitations in the course of the instanton process. We find that the single-electron tunneling is allowed below the nominal gap 2Delta_0 down to the true pair-breaking threshold at 2W_as<2Delta, where W_as=2Delta/pi is the amplitude soliton energy. Most importantly, the bi-electronic tunneling stretches down to U=0 (in the 1D regime). In both cases, the threshold behavior is given by power laws J (U-U_c)^beta, where the exponent beta v_F/u is large as the ratio of the Fermi velocity v_F and the phase one u. In the 2D or 3D ordered phases, at temperature T<T_c, the one-electron tunneling current does not vanish at the threshold U_c anymore, but saturates above it at U-U_c T_c<<Delta. Also the bi-particle channel acquires a finite threshold U_c=W_ph T_c<<Delta at the energy W_ph of the 2πphase soliton.

cond-mat.str-el

Subgap tunneling through channels of polarons and bipolarons in chain conductors

We suggest a theory of internal coherent tunneling in the pseudogap region where the applied voltage is below the free electron gap. We consider quasi 1D systems where the gap is originated by a lattice dimerization like in polyacethylene, as well as low symmetry 1D semiconductors. Results may be applied to several types of conjugated polymers, to semiconducting nanotubes and to quantum wires of semiconductors. The approach may be generalized to tunneling in strongly correlated systems showing the pseudogap effect, like the family of High Tc materials in the undoped limit. We demonstrate the evolution of tunneling current-voltage characteristics from smearing the free electron gap down to threshold for tunneling of polarons and further down to the region of bi-electronic tunneling via bipolarons or kink pairs.

cond-mat.str-el

Theory of the ferroelectric phase in organic conductors: optics and physics of solitons

Recently the ferroelectric anomaly (Nad, Monceau, et al) followed by the charge disproportionation (Brown, et al) have been discovered in (TMTTF)2X compounds. The corresponding theory of the combined Mott-Hubbard state describes both effects by interference of the build-in nonequivalence of bonds and the spontaneous one of sites. The state gives rise to three types of solitons: πsolitons (holons) are observed via the activation energy Δin the conductivity $G$; noninteger αsolitons (the FE domain walls) provide the frequency dispersion of the ferroelectric response; combined spin-charge solitons determine G(T) below subsequent structural transitions of the tetramerisation. The photoconductivity gap 2Δis determined by creations of soliton - antisoliton pairs. The optical edge lies well below, given by the collective ferroelectric mode which coexists with the combined electron-phonon resonance and the phonon antiresonance. The charge disproportionation and the ferroelectricity can exist hiddenly even in the Se subfamily giving rise to the unexplained yet low frequency optical peak, the enhanced pseudogap and traces of phonons activation.

cond-mat.str-el

Theory of pseudogaps in charge density waves in application to photo electron or tunneling spectroscopy

For a one-dimensional electron-phonon system we consider the photon absorption involving electronic excitations within the pseudogap energy range. In the framework of the adiabatic approximation for the electron - phonon interactions these processes are described by nonlinear configurations of an instanton type. We calculate the subgap absorption as it can be observed by means of photo electron or tunneling spectroscopies. In details we consider systems with gapless modes: 1D semiconductors with acoustic phonons and incommensurate charge density waves. We find that below the free particle edge the pseudogap starts with the exponential decrease of transition rates changing to a power law deeply within the pseudogap, near the absolute edge.

cond-mat.str-el

Ferroelectric Mott-Hubbard phase in organic conductors

We present key issues of related phenomenons of the Ferroelectricity and the Charge Disproportionation in organic metals. In (TMTTF_2X the dielectric susceptibility demonstrates clear cases of the ferroelectric and anti-ferroelectric phase transitions. Both the susceptibility and the conductivity prove independence and occasional coexistence of "structurless" ferroelectric transitions and usual "anionic" ones. Their sequence gives access to physics of three types of solitons emerging upon cooling via several steps of symmetry breaking. The theory invokes a concept of the Combined Mott-Hubbard State which focuses upon weak processes of electronic Umklapp scattering coming from both the build-in nonequivalence of bonds and the spontaneous one of sites. We propose that the charge ordering in its form of the ferroelectricity exists hiddenly even in the Se subfamily (TMTSF)_2X, giving rise to the unexplained yet low frequency optical peak and the enhanced pseudogap.

cond-mat.str-el

Pseudogaps due to sound modes: from incommensurate charge density waves to semiconducting wires

We consider pseudogap effects for electrons interacting with gapless modes. We study both generic 1D semiconductors with acoustic phonons and incommensurate charge density waves. We calculate the subgap absorption as it can be observed by means of the photo electron or tunneling spectroscopy. Within the formalism of functional integration and the adiabatic approximation, the probabilities are described by nonlinear configurations of an instanton type. Particularities of both cases are determined by the topological nature of stationary excited states (acoustic polarons or amplitude solitons) and by presence of gapless phonons which change the usual dynamics to the regime of the quantum dissipation. Below the free particle edge the pseudogap starts with the exponential (stretched exponential for gapful phonons) decrease of transition rates. Deeply within the pseudogap they are dominated by a power law, in contrast with nearly exponential law for gapful modes.

cond-mat.str-el

Topological Confinement of Spins and Charges: Spinons as pi-junctions

Topologically nontrivial states, the solitons, emerge as elementary excitations in 1D electronic systems. In a quasi 1D material the topological requirements originate the spin- or charge- roton like excitations with charge- or spin- kinks localized in the core. They result from the spin-charge recombination due to confinement and the combined symmetry. The rotons possess semi-integer winding numbers which may be relevant to configurations discussed in connection to quantum computing schemes. Practically important is the case of the spinon functioning as the single electronic pi- junction in a quasi 1D superconducting material.

cond-mat.mes-hall

The ferroelectric Mott-Hubbard phase of organic (TMTTF)2X conductors

We present experimental evidences for a ferro-electric transition in the family of quasi one- dimensional conductors (TMTTF)2X. We interpret this new transition in the frame of the combined Mott-Hubbard state taking into account the double action of the spontaneous charge disproportionation on the TMTTF molecular stacks and of the X anionic potentials.

cond-mat.str-el

X-Ray Scattering Evidence for Macroscopic Strong Pinning Centers in the Sliding CDW state of NbSe_3

Using high-resolution X-ray scattering techniques, we measure the variation, q(x), of the position in reciprocal space of the CDW satellite, in the sliding state, along the length of NbSe_3 whiskers. We show that structural defects and intentionally X-ray radiation-damaged regions increase locally the CDW pinning force, and induce CDW phase distortions which are consistent with those observed near contacts. Using the semi-microscopic model from Brazovskii describing the normal-condensed carrier conversion, with spatially varying parameters, we account for the experimental spatial dependence of the CDW phase gradient near both types of defects.

cond-mat.str-el