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S. D. Le Picard

Publications and source records attributed to S. D. Le Picard.

2 recordsLinked to original sources

Absolute measurements of state-to-state rotational energy transfer between CO and H2 at interstellar temperatures

Experimental measurements and theoretical calculations of state-to-state rate coefficients for rotational energy transfer of CO in collision with H$_2$ are reported at the very low temperatures prevailing in dense interstellar clouds (5 - 20 K). Detailed agreement between quantum state-selected experiments performed in cold supersonic flows using time-resolved infrared - vacuum-ultraviolet double resonance spectroscopy and close-coupling quantum scattering calculations confirms the validity of the calculations for collisions between the two most abundant molecules in the interstellar medium.

physics.chem-ph↗

The 2014 KIDA network for interstellar chemistry

Chemical models used to study the chemical composition of the gas and the ices in the interstellar medium are based on a network of chemical reactions and associated rate coefficients. These reactions and rate coefficients are partially compiled from data in the literature, when available. We present in this paper kida.uva.2014, a new updated version of the kida.uva public gas-phase network first released in 2012. In addition to a description of the many specific updates, we illustrate changes in the predicted abundances of molecules for cold dense cloud conditions as compared with the results of the previous version of our network, kida.uva.2011.

astro-ph.GA↗