arXiv subjects

S. Hofmann

Publications and source records attributed to S. Hofmann.

At least 19 recordsLinked to original sources

arXiv2025

Localisation of hexagonal boron nitride colour centres using patterned dielectric layers on graphene

One of the most promising building blocks for the development of spin qubits, single-photon sources, and quantum sensors at room temperature, as well as 2D ultraviolet light-emitting diodes, are defect colour centres in 2D hexagonal boron nitride (hBN). However, a significant requirement for the realisation of such devices towards scalable technologies is the deterministic localisation of hBN colour centres. Here, we demonstrate a novel approach to the localisation of hBN colour centre emission by using patterned dielectric layers grown on graphene via atomic layer deposition (ALD). While colour centre emission is quenched within areas where hBN is deposited directly on graphene due to charge transfer, it is maintained where hBN is deposited on micron-sized Al2O3 pillars which act as barriers to charge transfer. Importantly, our approach allows for device architectures where graphene layers are used as top and bottom electrodes for the application of vertical electric fields, such as for carrier injection in electroluminescent devices, Stark shifting of colour centre emission, and charge state control of defect colour centres. Furthermore, the use of ALD to grow dielectric layers directly on graphene allows for the control of tunnel barrier thicknesses with atomic layer precision, which is crucial for many of these device applications. Our work represents an important step towards the realisation of a wide range of scalable device applications based on the determinsitic localisation of electrically controlled hBN colour centres

cond-mat.mes-hall↗

arXiv2025

Novel Dark Matter Signatures

Celestial observations often exhibit inexplicable planetary dependencies when the timing of an observable is projected onto planetary heliocentric positions. This is possible only for incident, non-relativistic streams. Notably, the celebrated dark matter (DM) in the Universe can form streams in our vicinity with speeds of about 240 km/s. Since gravitational impact scales with $1/(\text{velocity})^2$, all solar system objects, including the Sun and the Moon, act as strong gravitational lenses, with their focal planes located within the solar system. Even the Moon can focus penetrating particles toward the Earth at speeds of up to approximately 400 km/s, covering a large portion of the phase space of DM constituents. Consequently, the unexpected planetary dependencies of solar system observables may provide an alternative to Zwicky's tension regarding the overestimated visible cosmic mass. In this work, an overlooked but unexpected planetary dependency of any local observable serves as an analogue to Zwicky's cosmic measurements, particularly if a similar mysterious behavior has been previously noted. Thus, a persistent, unexpected planetary dependency represents a new tension between observation and expectation. The primary argument supporting DM in line with Zwicky's paradigm is this planetary dependency, which, on a local scale, constitutes the novel tension between observation and expectation. In particular, the recurrent planetary dependency of diverse observables mirrors Zwicky's cosmic tension with the overestimated visible mass. No other approach accounts for so many otherwise striking and mysterious observations in physics and medicine.

astro-ph.EP↗

arXiv2023

Atmospheric Temperature anomalies as manifestation of the dark Universe

We are investigating the possible origin of small-scale anomalies, like the annual stratospheric temperature anomalies. Unexpectedly within known physics, their observed planetary "dependency", does not match concurrent solar activity, whose impact on the atmosphere is unequivocal; this points at an additional energy source of exo-solar origin. A viable concept behind such observations is based on possible gravitational focusing by the Sun and its planets towards the Earth of low-speed invisible streaming matter; its influx towards the Earth gets temporally enhanced. Only a somehow "strongly" interacting invisible streaming matter with the small upper atmospheric screening can be behind the observed temperature excursions. Ordinary dark matter (DM) candidates like axions or WIMPs, cannot have any noticeable impact. The associated energy deposition is $\mathcal{O}(\sim 1000\, \mathrm{GeV}/{{\mathrm{cm}}^2}/\mathrm{sec})$. The atmosphere has been uninterruptedly monitored for decades. Therefore, the upper atmosphere can serve as a novel (low-threshold) detector for the dark Universe, with built-in spatiotemporal resolution while the solar system gravity acts temporally as a signal amplifier. Interestingly, the anomalous ionosphere shows a relationship with the inner earth activity like earthquakes. Similarly investigating the transient sudden stratospheric warmings within the same reasoning, the nature of the assumed "invisible streams" could be deciphered.

astro-ph.EP↗

arXiv2022

Tracking interfacial changes of graphene/Ge(110) during in-vacuum annealing

Graphene quality indicators obtained by Raman spectroscopy have been correlated to the structural changes of the graphene/Germanium interface as a function of in-vacuum thermal annealing. Specifically, it is found that graphene becomes markedly defected at 650 {\deg}C. By combining scanning tunneling microscopy, x-Ray Photoelectron Spectroscopy and Near Edge x-ray Absorption Fine Structure Spectroscopy, we conclude that these defects are due to the release of H_{2} gas trapped at the graphene/Germanium interface. The H_{2} gas was produced following the transition from the as-grown hydrogen-termination of the Ge(110) surface to the emergence of surface reconstructions in the substrate. Interestingly, a complete self-healing process is observed in graphene upon annealing to 800 {\deg}C. The subtle interplay revealed between the microscopic changes occurring at the graphene/Germanium interface and graphene's defect density is valuable for advancing graphene growth, controlled 2D-3D heterogeneous materials interfacing and integrated fabrication technology on semiconductors.

cond-mat.mtrl-sci↗

arXiv2021

The Dark Universe is not invisible

Dark matter (DM) comes from long-range gravitational observations, and it is considered as something that does not interact with ordinary matter or emits light. However, also on much smaller scales, a number of unexpected observations of the solar activity and the dynamic Earth atmosphere might arise from DM contradicting the aforementioned DM picture. Because, gravitational (self) focusing effects by the Sun or its planets of streaming DM fit as the interpretation of the otherwise puzzling 11-year solar cycle, the mysterious heating of the solar corona, atmospheric transients, etc. Observationally driven, an external impact by overlooked streaming invisible matter reconciles the investigated mysterious behavior showing otherwise unexpected planetary relationships; this is a signature for gravitational focusing of streaming DM by the solar system bodies. Then, focusing of DM streams could also occur in exoplanetary systems, suggesting for the first time the carrying out of investigations by searching for the associated stellar activity as a function of the exoplanetary orbital phases.

astro-ph.SR↗

arXiv2021

Growth and Characterisation Studies of Eu$_3$O$_4$ Thin Films Grown on Si/SiO$_2$ and Graphene

We report the growth, structural and magnetic properties of the less studied Eu-oxide phase, Eu$_3$O$_4$, thin films grown on a Si/SiO$_2$ substrate and Si/SiO$_2$/graphene using molecular beam epitaxy. The X-ray diffraction scans show that highly-textured crystalline Eu$_3$O$_4$(001) films are grown on both substrates, whereas the film deposited on graphene has a better crystallinity than that grown on the Si/SiO$_2$ substrate. The SQUID measurements show that both films have a Curie temperature of about 5.5 K, with a magnetic moment of 0.0032 emu/g at 2 K. The mixed-valency of the Eu cations has been confirmed by the qualitative analysis of the depth-profile X-ray photoelectron spectroscopy measurements with the Eu$^{2+}$ : Eu$^{3+}$ ratio of 28 : 72. However, surprisingly, our films show no metamagnetic behaviour as reported for the bulk and powder form. Furthermore, the Raman spectroscopy scans show that the growth of the Eu$_3$O$_4$ thin films has no damaging effect on the underlayer graphene sheet. Therefore, the graphene layer is expected to retain its properties.

cond-mat.mtrl-sci↗

arXiv2021

Determining the Proximity Effect Induced Magnetic Moment in Graphene by Polarized Neutron Reflectivity and X-ray Magnetic Circular Dichroism

We report the magnitude of the induced magnetic moment in CVD-grown epitaxial and rotated-domain graphene in proximity with a ferromagnetic Ni film, using polarized neutron reflectivity (PNR) and X-ray magnetic circular dichroism (XMCD). The XMCD spectra at the C K-edge confirms the presence of a magnetic signal in the graphene layer and the sum rules give a magnetic moment of up to $\sim\,0.47\,\mu$_B/C atom induced in the graphene layer. For a more precise estimation, we conducted PNR measurements. The PNR results indicate an induced magnetic moment of $\sim$ 0.53 $\mu$_B/C atom at 10 K for rotated graphene and $\sim$ 0.38 $\mu$_B/C atom at 10 K for epitaxial graphene. Additional PNR measurements on graphene grown on a non-magnetic Ni_9Mo_1 substrate, where no magnetic moment in graphene is measured, suggest that the origin of the induced magnetic moment is due to the opening of the graphene's Dirac cone as a result of the strong C pz-3d hybridization.

cond-mat.mes-hall↗

arXiv2020

Stratospheric temperature anomalies as imprints from the dark Universe

The manifestation of the dark Universe begun with unexpected large scale astronomical observations. Here we are investigating the origin of small scale anomalies, like that of the annually observed temperature anomalies in the stratosphere. Unexpectedly, we observe a planetary relationship of the daily stratospheric temperature distribution. Its spectral shape does not match concurrent solar activity, or solar EUV emission, whose impact on the atmosphere is unequivocal. This behavior points at an additional energy source of exosolar origin. A viable concept behind such observations is based on possible gravitational focusing by the solar system towards the Earth of low speed invisible matter. We denote generic constituents from the dark Universe as invisible matter, in order to distinguish them from ordinary dark matter candidates like axions or WIMPs, which cannot have any noticeable impact on the stratosphere. The observed peaking planetary relations exclude on their own any conventional explanation. Only a somehow strongly interacting invisible streaming matter with the little screened upper stratosphere (noverhead about 1 gr/cm 2) can be behind the occasionally observed temperature increases. We also estimate an associated energy deposition O(W/m 2), which is variable over the 11 years solar cycle. For the widely assumed picture of a quasi not interacting dark Universe, this new exosolar energy is enormous. Since the atmosphere is uninterruptedly monitored since decades, it can serve also parasitically as a novel low threshold detector for the dark Universe, with built-in spatiotemporal resolution and the solar system acting temporally as signal amplifier. In future, analyzing more observations, for example, from the anomalous ionosphere, or, the transient sudden stratospheric warmings, the nature of the assumed invisible streams could be deciphered.

astro-ph.EP↗

arXiv2020

Long-Range Propagation and Interference of $d$-wave Superconducting Pairs in Graphene

Recent experiments have shown that proximity with high-temperature superconductors induces unconventional superconducting correlations in graphene. Here we demonstrate that those correlations propagate hundreds of nanometer, allowing for the unique observation of $d$-wave Andreev pair interferences in YBa$_2$Cu$_3$O$_7$-graphene devices that behave as a Fabry-P\'erot cavity. The interferences show as a series of pronounced conductance oscillations analogous to those originally predicted by de Gennes--Saint-James for conventional metal-superconductor junctions. The present work is pivotal to the study of exotic directional effects expected for nodal superconductivity in Dirac materials.

cond-mat.supr-con↗

arXiv2019

High-mobility, wet-transferred graphene grown by chemical vapor deposition

We report high room-temperature mobility in single layer graphene grown by Chemical Vapor Deposition (CVD) after wet transfer on SiO$_2$ and hexagonal boron nitride (hBN) encapsulation. By removing contaminations trapped at the interfaces between single-crystal graphene and hBN, we achieve mobilities up to$\sim70000cm^2 V^{-1} s^{-1}$ at room temperature and$\sim120000cm^2 V^{-1} s^{-1}$ at 9K. These are over twice those of previous wet transferred graphene and comparable to samples prepared by dry transfer. We also investigate the combined approach of thermal annealing and encapsulation in polycrystalline graphene, achieving room temperature mobilities$\sim30000 cm^2 V^{-1} s^{-1}$. These results show that, with appropriate encapsulation and cleaning, room temperature mobilities well above $10000cm^2 V^{-1} s^{-1}$ can be obtained in samples grown by CVD and transferred using a conventional, easily scalable PMMA-based wet approach.

cond-mat.mes-hall↗

arXiv2018

Distributed Conditional Cooperation Model Predictive Control of Interconnected Microgrids

In this paper, we propose a model predictive control based operation strategy that allows for power exchange between interconnected microgrids. Particularly, the approach ensures that each microgrid benefits from power exchange with others. This is realised by including a condition which is based on the islanded operation cost. The overall model predictive control problem is posed as a mixed-integer quadratically-constrained program and solved using a distributed algorithm that iteratively updates continuous and integer variables. For this algorithm, termination, feasibility and computational properties are discussed. The performance and the computational benefits of the proposed strategy are highlighted in an illustrative case study.

eess.SY↗

arXiv2018

Search for streaming dark matter axions or other exotica

We suggest a new approach to search for galactic axions or other similar exotica. Streaming dark matter (DM) could have a better discovery potential because of flux enhancement, due to gravitational lensing when the Sun and/or a planet are aligned with a DM stream. Of interest are also axion miniclusters, in particular, if the solar system has trapped one during its formation. Wide-band axion antennae fit this concept, but also the proposed fast narrow band scanning. A network of detectors can provide full time coverage and a large axion mass acceptance. Other DM searches may profit from this proposal.

astro-ph.IM↗

arXiv2017

Search for axions in streaming dark matter

A new search strategy for the detection of the elusive dark matter (DM) axion is proposed. The idea is based on streaming DM axions, whose flux might get temporally enormously enhanced due to gravitational lensing. This can happen if the Sun or some planet (including the Moon) is found along the direction of a DM stream propagating towards the Earth location. The experimental requirements to the axion haloscope are a wide-band performance combined with a fast axion rest mass scanning mode, which are feasible. Once both conditions have been implemented in a haloscope, the axion search can continue parasitically almost as before. Interestingly, some new DM axion detectors are operating wide-band by default. In order not to miss the actually unpredictable timing of a potential short duration signal, a network of co-ordinated axion antennae is required, preferentially distributed world-wide. The reasoning presented here for the axions applies to some degree also to any other DM candidates like the WIMPs.

physics.ins-det↗

arXiv2015

30 GHz optoelectronic mixing in CVD graphene

We report an optoelectronic mixer based on chemical vapour-deposited graphene. Our device consists in a coplanar waveguide that integrates a graphene channel, passivated with an atomic layer-deposited Al2O3 film. With this new structure, 30 GHz optoelectronic mixing in commercially-available graphene is demonstrated for the first time. In particular, using a 30 GHz intensity-modulated optical signal and a 29.9 GHz electrical signal, we show frequency downconversion to 100 MHz. These results open promising perspectives in the domain of optoelectronics for radar and radio-communication systems.

cond-mat.mes-hall↗

arXiv2014

Direct mapping of nuclear shell effects in the heaviest elements

Quantum-mechanical shell effects are expected to strongly enhance nuclear binding on an "island of stability" of superheavy elements. The predicted center at proton number $Z=114,120$, or $126$ and neutron number $N=184$ has been substantiated by the recent synthesis of new elements up to $Z=118$. However the location of the center and the extension of the island of stability remain vague. High-precision mass spectrometry allows the direct measurement of nuclear binding energies and thus the determination of the strength of shell effects. Here, we present such measurements for nobelium and lawrencium isotopes, which also pin down the deformed shell gap at $N=152$.

nucl-ex↗

arXiv2014

Comparison of Analytical and Numerical Resolution Functions in Sputter Depth Profiling

Quantification of sputter depth profiles is frequently done by fitting the convolution integral over concentration and depth resolution function. For a thin delta layer, there exist analytical solutions. The analytical depth resolution functions of two popular approaches, that of the MRI model and that of Dowsett and coworkers are compared. It is concluded that the analytical depth resolution function of the MRI model gives the correct location of a buried delta layer with respect to the measured profile, and a clear description of the information depth in AES, XPS and SIMS. Both analytical solutions can be extended to larger layer thickness. But they are less flexible with respect to physical parameters which are not constant with concentration or sputtered depth, such as detection sensitivity, atomic mixing, roughness or preferential sputtering. For these cases, numerical solutions have to be used.

cond-mat.mtrl-sci↗

arXiv2011

Mass measurements of very neutron-deficient Mo and Tc isotopes and their impact on rp process nucleosynthesis

The masses of ten proton-rich nuclides, including the N=Z+1 nuclides 85-Mo and 87-Tc, were measured with the Penning trap mass spectrometer SHIPTRAP. Compared to the Atomic Mass Evaluation 2003 a systematic shift of the mass surface by up to 1.6 MeV is observed causing significant abundance changes of the ashes of astrophysical X-ray bursts. Surprisingly low alpha-separation energies for neutron-deficient Mo and Tc are found, making the formation of a ZrNb cycle in the rp process possible. Such a cycle would impose an upper temperature limit for the synthesis of elements beyond Nb in the rp process.

nucl-ex↗

arXiv2009

Manifestly Gauge-Invariant General Relativistic Perturbation Theory: I. Foundations

Linear cosmological perturbation theory is pivotal to a theoretical understanding of current cosmological experimental data provided e.g. by cosmic microwave anisotropy probes. A key issue in that theory is to extract the gauge invariant degrees of freedom which allow unambiguous comparison between theory and experiment. When one goes beyond first (linear) order, the task of writing the Einstein equations expanded to n'th order in terms of quantities that are gauge invariant up to terms of higher orders becomes highly non-trivial and cumbersome. This fact has prevented progress for instance on the issue of the stability of linear perturbation theory and is a subject of current debate in the literature. In this series of papers we circumvent these difficulties by passing to a manifestly gauge invariant framework. In other words, we only perturb gauge invariant, i.e. measurable quantities, rather than gauge variant ones. Thus, gauge invariance is preserved non perturbatively while we construct the perturbation theory for the equations of motion for the gauge invariant observables to all orders. In this first paper we develop the general framework which is based on a seminal paper due to Brown and Kuchar as well as the realtional formalism due to Rovelli. In the second, companion, paper we apply our general theory to FRW cosmologies and derive the deviations from the standard treatment in linear order. As it turns out, these deviations are negligible in the late universe, thus our theory is in agreement with the standard treatment. However, the real strength of our formalism is that it admits a straightforward and unambiguous, gauge invariant generalisation to higher orders. This will also allow us to settle the stability issue in a future publication.

gr-qc↗