arXiv subjects

S. Ishiwata

Publications and source records attributed to S. Ishiwata.

At least 19 recordsLinked to original sources

arXiv2025

Mass enhancement and metal-nonmetal transition driven by d-f hybridization in perovskites La1-xPrxCuO3

We report the large electron-mass enhancement and the metal to nonmetal transition upon the Pr doping in perovskite-type La1-xPrxCuO3. With increasing the Pr content x around 0.6, the LaCuO3-type three-dimensional structure with trivalent Cu ions changes to the quasi-one-dimensional structure with nearly divalent Cu ions, which accompanies significant changes in the electronic properties. Based on the resistivity, optical conductivity, specific heat measurements and the first-principles calculations, we discuss the formation of a nearly localized nonmetallic state stabilized by the hybridization between Cu 3d, O 2p, and Pr 4f orbitals in the quasi-one-dimensional lattice. The present perovskite-type cuprates offer a unique opportunity to explore novel quantum phases of correlated electrons in low-dimensional lattice, where the spin/charge/orbital degrees of freedom of A- and B-site ions are entangled.

cond-mat.str-el↗

arXiv2024

Unusual photoinduced crystal structure dynamics in TaTe$_2$ with double zigzag chain superstructure

Transition metal dichalcogenides with superperiodic lattice distortions have been widely investigated as the platform of ultrafast structural phase manipulations. Here we performed ultrafast electron diffraction on room-temperature TaTe$_2$, which exhibits peculiar double zigzag chain pattern of Ta atoms. From the time-dependent electron diffraction pattern, we revealed a photoinduced change in the crystal structure occurring within <0.5 ps, though there is no corresponding high-temperature equilibrium phase. We further clarified the slower response (~1.5 ps) reflecting the lattice thermalization. Our result suggests the unusual ultrafast crystal structure dynamics specific to the non-equilibrium transient process in TaTe$_2$.

cond-mat.mtrl-sci↗

arXiv2023

Observation of local atomic displacements intrinsic to the double zigzag chain structure of 1T-MTe2 (M = V, Nb, Ta)

We describe the existence of local distortion discovered in the synchrotron x-ray single-crystal structure analysis of layered ditelluride 1T-MTe2 (M = V, Nb, Ta). In 1T-TaTe2, the double zigzag chain structure of Ta is deformed at about 170 K, and heptamer molecules are formed periodically at low temperatures. We found that some of the Ta atoms that compose the double zigzag chain structure appearing at high temperatures are locally displaced, resulting in local dimerization. This tendency weakens when Ta is replaced by V or Nb. Our results indicate that the local distortion persistently survives in these ditellurides, where the electronic degrees of freedom, including orbitals, are weakened. We further discuss the origin of local distortion in these ditellurides, which is different from many usual material systems where molecular formation occurs at low temperatures.

cond-mat.str-el↗

arXiv2020

High-pressure synthesis of Ba$_2$RhO$_4$, a rhodate analogue of the layered perovskite Sr-ruthenate

A new layered perovskite-type oxide Ba$_2$RhO$_4$ was synthesized by a high-pressure technique with the support of convex-hull calculations. The crystal and electronic structure were studied by both experimental and computational tools. Structural refinements for powder x-ray diffraction data showed that Ba$_2$RhO$_4$ crystallizes in a K$_2$NiF$_4$-type structure, isostructural to Sr$_2$RuO$_4$ and Ba$_2$IrO$_4$. Magnetic, resistivity, and specific heat measurements for polycrystalline samples of Ba$_2$RhO$_4$ indicate that the system can be characterized as a correlated metal. Despite the close similarity to its Sr$_2$RuO$_4$ counterpart in the electronic specific heat coefficient and the Wilson ratio, Ba$_2$RhO$_4$ shows no signature of superconductivity down to 0.16 K. Whereas the Fermi surface topology has reminiscent pieces of Sr$_2$RuO$_4$, an electron-like e$_g$-($d_{x^2-y^2}$) band descends below the Fermi level, making of this compound unique also as a metallic counterpart of the spin-orbit-coupled Mott insulator Ba$_2$IrO$_4$.

cond-mat.str-el↗

arXiv2020

Structure analysis of high-pressure phase for skyrmion-hosting multiferroic Cu2OSeO3

Cu2OSeO3 is known as a unique example of insulating multiferroic compounds with skyrmion spin texture, which is characterized by the chiral cubic crystal structure at ambient pressure. Recently, it has been reported that this compound shows pressure-induced structural transition with large enhancement of magnetic ordering temperature Tc. In the present study, we have investigated the detailed crystal structure in the high pressure phase, by combining the synchrotron X-ray diffraction experiment with the diamond anvil cell and the analysis based on the genetic algorithm. Our results suggest that the original pyrochlore Cu network is sustained even after the structural transition, while the orientation of SeO3 molecule as well as the position of oxygen in the middle of Cu tetrahedra are significantly modified. The latter features may be the key for the reported enhancement of Tc and associated stabilization of skyrmion phase at room temperature.

cond-mat.str-el↗

arXiv2020

Switching of band inversion and topological surface states by charge density wave

Topologically nontrivial materials host protected edge states associated with the bulk band inversion through the bulk-edge correspondence. Manipulating such edge states is highly desired for developing new functions and devices practically using their dissipation-less nature and spin-momentum locking. Here we introduce a transition-metal dichalcogenide VTe$_2$, that hosts a charge density wave (CDW) coupled with the band inversion involving V3$d$ and Te5$p$ orbitals. Spin- and angle-resolved photoemission spectroscopy with first-principles calculations reveal the huge anisotropic modification of the bulk electronic structure by the CDW formation, accompanying the selective disappearance of Dirac-type spin-polarized topological surface states that exist in the normal state. Thorough three dimensional investigation of bulk states indicates that the corresponding band inversion at the Brillouin zone boundary dissolves upon CDW formation, by transforming into anomalous flat bands. Our finding provides a new insight to the topological manipulation of matters by utilizing CDWs' flexible characters to external stimuli.

cond-mat.mtrl-sci↗

arXiv2020

Nanoscale imaging of unusual photo-acoustic waves in thin flake VTe$_2$

Controlling acoustic phonons, the carriers of sound and heat, has been attracting great attention toward the manipulation of sonic and thermal properties in nanometric devices. In particular, the photo-acoustic effect using ultrafast optical pulses has a promising potential to optically manipulate phonons in picoseconds time regime. However, its mechanism has been so far mostly based on the commonplace thermoelastic expansion in isotropic media, limiting the spectrum of potential applications. We investigate a conceptually new mechanism of photo-acoustic effect involving the structural instability, by utilizing a transition-metal dichalcogenide VTe$_2$ with the ribbon-type charge-density-wave (CDW). Ultrafast electron microscope imaging and diffraction measurements reveal the generation and propagation of unusual acoustic waves in the nanometric thin plate associated with the optically induced instantaneous charge-density-wave dissolution. Our results highlight the capability of photo-induced structural instability as a source of coherent acoustic waves.

cond-mat.mtrl-sci↗

arXiv2020

Field-induced spin reorientation in the antiferromagnetic Dirac material EuMnBi$_2$ revealed by neutron and resonant x-ray diffraction

Field-dependent magnetic structure of a layered Dirac material EuMnBi$_2$ was investigated in detail by the single crystal neutron diffraction and the resonant x-ray magnetic diffraction techniques. On the basis of the reflection conditions in the antiferromagnetic phase at zero field, the Eu moments were found to be ordered ferromagnetically within the $ab$ plane and stacked antiferromagnetically along the $c$ axis in the sequence of up-up-down-down. Upon the spin-flop transition under the magnetic field parallel to the $c$ axis, the Eu moments are reoriented from the $c$ to the $a$ or $b$ directions forming two kinds of spin-flop domains, whereas the antiferromagnetic structure of the Mn sublattice remains intact as revealed by the quantitative analysis of the change in the neutron diffraction intensities. The present study provides a concrete basis to discuss the dominant role of the Eu sublattice on the enhanced two-dimensionality of the Dirac fermion transport in EuMnBi$_2$.

cond-mat.mtrl-sci↗

arXiv2018

Observation of Magnetopiezoelectric Effect in Antiferromagnetic Metal EuMnBi2

We have experimentally studied a magnetopiezoelectric effect predicted recently for magnetic metals with low crystal symmetries. In EuMnBi2 with antiferromagnetic Mn moments at 77 K, dynamic displacements emerge along the $a$ direction upon application of ac electric fields in the $c$ direction, and increase in proportion to the applied electric fields. Such displacements are not observed along the $c$ direction of EuMnBi2 or EuZnBi2 with nonmagnetic Zn ions. As temperature increases from 77 K, the displacement signals decrease and disappear at about 200 K, above which electric conduction changes from coherent to incoherent. These results demonstrate the emergence of the magnetopiezoelectric effect in a magnetic metal lacking inversion and time-reversal symmetries.

cond-mat.mtrl-sci↗

arXiv2018

Negative-pressure-induced helimagnetism in ferromagnetic cubic perovskites Sr$_{1-x}$Ba$_{x}$CoO$_{3}$

Helimagnetic materials are identified as promising for novel spintronic applications. Since helical spin order is manifested as a compromise of competing magnetic exchange interactions, its emergence is limited by unique constraints imposed by the crystalline lattice and the interaction geometries, as exemplified by the multiferroic perovskite manganites with large orthorhombic distortion. Here we show that a simple cubic perovskite SrCoO$_3$ with room-temperature ferromagnetism has the potential to host helimagnetic order upon isotropic lattice expansion. Increasing the Ba content $x$ in Sr$_{1-x}$Ba$_x$CoO$_3$ continuously expands the cubic lattice, eventually suppressing the ferromagnetic order near $x$=0.4, where helimagnetic correlations are observed as incommensurate diffuse magnetic scattering by neutron diffraction measurements. The emergence of helimagnetism is semi-quantitatively reproduced by first-principles calculations, leading to the conjecture that a simple cubic lattice with strong $d$-$p$ hybridisation can exhibit a variety of novel magnetic phases originating from competing exchange interactions.

cond-mat.str-el↗

arXiv2018

Impact of antiferromagnetic order on Landau level splitting of quasi-two-dimensional Dirac fermions in EuMnBi$_2$

We report spin-split Landau levels of quasi-two-dimensional Dirac fermions in a layered antiferromagnet EuMnBi$_2$, as revealed by interlayer resistivity measurements in a tilted magnetic field up to $\sim$35 T. The amplitude of Shubnikov-de Haas (SdH) oscillation in interlayer resistivity is strongly modulated by changing the tilt angle of the field, i.e., the Zeeman-to-cyclotron energy ratio. The effective $g$ factor estimated from the tilt angle, where the SdH oscillation exhibits a phase inversion, differs by approximately 50% between two antiferromagnetic phases. This observation signifies a marked impact of the magnetic order of Eu sublattice on the Dirac-like band structure. The origin may be sought in strong exchange coupling with the local Eu moments, as verified by the first-principles calculation.

cond-mat.str-el↗

arXiv2018

Emergent topological spin structures in a centrosymmetric cubic perovskite

The skyrmion crystal (SkX) characterized by a multiple-q helical spin modulation has been reported as a unique topological state that competes with the single-q helimagnetic order in non-centrosymmetric materials. Here we report the discovery of a rich variety of multiple-q helimagnetic spin structures in the centrosymmetric cubic perovskite SrFeO3. On the basis of neutron diffraction measurements, we have identified two types of robust multiple-q topological spin structures that appear in the absence of external magnetic fields: an anisotropic double-q spin spiral and an isotropic quadruple-q spiral hosting a three-dimensional lattice of hedgehog singularities. The present system not only diversifies the family of SkX host materials, but furthermore provides an experimental missing link between centrosymmetric lattices and topological helimagnetic order. It also offers perspectives for integration of SkXs into oxide electronic devices.

cond-mat.str-el↗

arXiv2017

High-pressure synthesis of an unusual antiferromagnetic metal CaCoO$_{3}$ with GdFeO$_{3}$-type perovskite structure

The GdFeO$_{3}$-type perovskite CaCoO$_{3}$ has been successfully synthesized by high-pressure oxygen annealing for the oxygen deficient perovskite. A detailed structural analysis based on synchrotron X-ray diffraction data and a thermogravimetric analysis show that the valence of Co is +4 and the sample is free from oxygen deficiency. This compound shows an antiferromagnetic ordering at 95 K, which has presumably helical spin arrangement, with keeping the incoherent metallic state down to the lowest temperature. This work demonstrates that the Co$^{4+}$-perovskite oxides exhibit a variety of magnetic phases by the band-width control through the lattice distortion.

cond-mat.str-el↗

arXiv2017

Quantum Hall effect in a bulk antiferromagnet EuMnBi$_2$ with magnetically confined two-dimensional Dirac fermions

For the innovation of spintronic technologies, Dirac materials, in which the low-energy excitation is described as relativistic Dirac fermions, are one of the most promising systems, because of the fascinating magnetotransport associated with the extremely high mobility. To incorporate Dirac fermions into spintronic applications, their quantum transport phenomena are desired to be manipulated to a large extent by magnetic order in a solid. We here report a bulk half-integer quantum Hall effect in a layered antiferromagnet EuMnBi$_2$, in which field-controllable Eu magnetic order significantly suppresses the interlayer coupling between the Bi layers with Dirac fermions. In addition to the high mobility more than 10,000 cm$^2$/Vs, Landau level splittings presumably due to the lifting of spin and valley degeneracy are noticeable even in a bulk magnet. These results will pave a route to the engineering of magnetically functionalized Dirac materials.

cond-mat.str-el↗

arXiv2017

Critical enhancement of thermopower in a chemically tuned polar semimetal MoTe$_{\bf 2}$

Ferroelectrics with spontaneous electric polarization play an essential role in today's device engineering, such as capacitors and memories. Their physical properties are further enriched by suppressing the long-range polar order, as is exemplified by quantum paraelectrics with giant piezoelectric and dielectric responses at low temperatures. Likewise in metals, a polar lattice distortion has been theoretically predicted to give rise to various unusual physical properties. So far, however, a "ferroelectric"-like transition in metals has seldom been controlled and hence its possible impacts on transport phenomena remain unexplored. Here we report the discovery of anomalous enhancement of thermopower near the critical region between the polar and nonpolar metallic phases in 1T'-Mo$_{1-x}$Nb$_{x}$Te$_2$ with a chemically tunable polar transition. It is unveiled from the first-principles calculations and magnetotransport measurements that charge transport with strongly energy-dependent scattering rate critically evolves towards the boundary to the nonpolar phase, resulting in large cryogenic thermopower. Such a significant influence of the structural instability on transport phenomena might arise from the fluctuating or heterogeneous polar metallic states, which would pave a novel route to improving thermoelectric efficiency.

cond-mat.mtrl-sci↗

arXiv2017

Anticorrelation between polar lattice instability and superconductivity in the Weyl semimetal candidate MoTe2

The relation between the polar structural instability and superconductivity in a Weyl semimetal candidate MoTe2 has been clarified by finely controlled physical and chemical pressure. The physical pressure as well as the chemical pressure, i.e., the Se substitution for Te, enhances the superconducting transition temperature Tc at around the critical pressure where the polar structure transition disappears. From the heat capacity and thermopower measurements, we ascribe the significant enhancement of Tc at the critical pressure to a subtle modification of the phonon dispersion or the semimetallic band structure upon the polar-to-nonpolar transition. On the other hand, the physical pressure, which strongly reduces the interlayer distance, is more effective on the suppression of the polar structural transition and the enhancement of Tc as compared with the chemical pressure, which emphasizes the importance of the interlayer coupling on the structural and superconducting instability in MoTe2.

cond-mat.supr-con↗

arXiv2017

Observation of spin-polarized bands and domain-dependent Fermi arcs in polar Weyl semimetal MoTe$_2$

We investigate the surface electronic structures of polar 1T'-MoTe2, the Weyl semimetal candidate realized through the nonpolar-polar structural phase transition, by utilizing the laser angle-resolved photoemission spectroscopy (ARPES) combined with first-principles calculations. Two kinds of domains with different surface band dispersions are observed from a single-crystalline sample. The spin-resolved measurements further reveal that the spin polarizations of the surface and the bulk-derived states show the different domain-dependences, indicating the opposite bulk polarity. For both domains, some segment-like band features resembling the Fermi arcs are clearly observed. The patterns of the arcs present the marked contrast between the two domains, respectively agreeing well with the slab calculation of (0 0 1) and (0 0 -1) surfaces. The present result strongly suggests that the Fermi arc connects the identical pair of Weyl nodes on one side of the polar crystal surface, whereas it connects between the different pairs of Weyl nodes on the other side.

cond-mat.mtrl-sci↗

arXiv2017

Diagonal magnetoelectric susceptibility and effect of Fe-doping in a polar ferrimagnet Mn2Mo3O8

We investigate a large variation in a diagonal component of the linear magnetoelectric (ME) susceptibility in a polar ferrimagnet Mn2Mo3O8 while changing the magnetic-ion site from orbital-quenched Mn2+ to Fe2+ with strong uniaxial anisotropy. In Mn2Mo3O8, the linear ME susceptibility is dominated by the non-relativistic exchange striction mechanism, showing a positive value at low temperature and a critical behavior toward negative divergence around the transition temperature. This negative peak value becomes four times larger when 50% of Mn2+ ions are replaced with Fe2+ ion, highlighting the beneficial perspective of the compositionally-tunable ME effect. As the doped Fe increases in fraction, gradual negative shift of the ME coefficient is observed around the lowest temperature, which manifests relativistic single-site origin of the ME susceptibility. Further doping with x >= 75% in (Mn1-xFex)2Mo3O8, the ME coefficient becomes negative in the entire temperature region. Such a composition dependence can be explained in terms of the chemical preference for the two types of magnetic sites of Mn/Fe ions. The present study demonstrates the large tunability of ME effect by substituting the magnetic ion with the primary structural/magnetic characters kept intact.

cond-mat.str-el↗