arXiv subjects

S. J. Gomez Alvarado

Publications and source records attributed to S. J. Gomez Alvarado.

6 recordsLinked to original sources

arXiv2026

Raman scattering spectroscopic observation of a ferroelastic crossover in bond-frustrated PrCd$_3$P$_3$

2D magnetism in triangular lattices has already shown potential for hosting exotic magnetic states. Control of these magnetic states, both in terms of magnetic properties and in terms of charge doping would be the next step. This makes materials which combine triangular lattice magnetic layers with layers hosting interesting structural or electronic properties particularly useful. PrCd$_3$P$_3$, studied in this work, is one of a family of materials where triangular lattice layers of magnetic rare earth ions alternate with semiconducting hexagonal CdP layers. Using Raman scattering spectroscopy we uncover a structural instability in the CdP layers, associated with a soft mode behavior of a phonon in these layers. Raman scattering detects crystal electric field excitations, and confirms a singlet ground state for Pr$^{3+}$ and splitting of the doublet levels as a result of the structural instability in CdP layers. While Pr$^{3+}$ is non-magnetic in PrCd$_3$P$_3$ we speculate that this family of materials can realize control of the magnetic layer through the CdP layer which can become ferroelectric under strain that would relieve frustration.

cond-mat.mtrl-sci↗

arXiv2025

Interleaved bond frustration in a triangular lattice antiferromagnet

Frustration of long-range order via lattice geometries serves to amplify fluctuations of the order parameter and generate unconventional ground states that are highly sensitive to perturbations. Traditionally, this concept of geometric frustration is used to engineer unconventional magnetic states in a variety of materials; however, the charge degree of freedom and bond order can be similarly frustrated. Finding materials that host both frustrated magnetic and bond networks holds promise for engineering structural and magnetic states with the potential of coupling to one another via either the magnetic sector (via magnetic field) or via the lattice sector (via strain). In this paper, we identify an unusual instance of this coexistence in the triangular lattice antiferromagnetic compounds $Ln$Cd$_3$P$_3$ ($Ln$ = La, Ce, Pr, and Nd). These compounds feature two-dimensional planes of unique trigonal-planar CdP$_3$ units that manifest an underlying bond instability with its long-range ordering frustrated via emergent kagome ice bond correlations. Our results establish $Ln$Cd$_3$P$_3$ as a rare class of materials where frustrated magnetism across a tunable rare-earth triangular network is embedded within a dopable semiconductor with a frustrated bond order instability.

cond-mat.str-el↗

arXiv2025

Signatures of three-state Potts nematicity in spin excitations of the van der Waals antiferromagnet FePSe$_3$

In two-dimensional (2D) nearly square-lattice quantum materials, electron correlations can induce an electronic nematic phase with twofold rotational ($C_2$) symmetry that profoundly impacts their properties. For 2D materials with threefold rotational ($C_3$) symmetry, such as the honeycomb lattice, a vestigial three-state Potts nematic order has been observed in the van der Waals antiferromagnet (AFM) FePSe$_3$ via optical and thermodynamic methods under uniaxial strain. Here, we use neutron scattering to study the magnetic order and spin excitations of FePSe$_3$ under uniaxial strain. In the AFM ordered state, we find that $\sim$0.6% tensile strain significantly suppresses one zigzag domain and promotes the other two, lowering the AFM order and spin waves to $C_2$ symmetry. The broken $C_3$ symmetry in spin excitations persists slightly above $T_{\rm{N}}\approx 108.6$ K, where the zigzag AFM order is absent. Our results thus provide direct evidence of magnetoelastic coupling and suggest that the three-state Potts nematicity in paramagnetic spin excitations arises from the vestigial order associated with the low-temperature zigzag AFM order.

cond-mat.str-el↗

arXiv2025

High-pressure floating zone crystal growth of Sr$_2$IrO$_4$

Here we demonstrate the floating zone crystal growth of the $J_\mathrm{eff}=1/2$ Mott insulator Sr$_2$IrO$_4$. Historically, the growth of iridates from a ternary melt has been precluded by the extreme vapor pressure of the metal oxide species and the difficulty of maintaining the correct oxidation state of Ir at high temperatures. Here, we show that the application of a high-pressure oxygen growth environment stabilizes the Sr$_2$IrO$_4$ phase, leading to the first demonstration of cm$^{3}$-scale crystals. In contrast to the conventional SrCl$_2$ flux growth method, where poor control over disorder leads to strong sample dependence, the high-pressure floating zone growth enables active control over the homogeneity of the melt. Crystals grown via this technique possess qualitatively similar properties to those grown via flux, with a relatively sharp onset of antiferromagnetic order observed in temperature-dependent magnetization. Further, we demonstrate that by tuning the mixing rate of the melt, we are able to grow natively hole-doped Sr$_2$Ir$_{1-y}$O$_4$, which exhibits a strongly modified magnetic and electronic response.

cond-mat.str-el↗

arXiv2024

Frustrated Ising charge correlations in the kagome metal ScV$_6$Sn$_6$

Here we resolve the real-space nature of the high-temperature, short-range charge correlations in the kagome metal ScV$_6$Sn$_6$. Diffuse scattering appears along a frustrated wave vector $\textbf{q}_H=(\frac{1}{3},\frac{1}{3},\frac{1}{2})$ at temperatures far exceeding the charge order transition $T_{CO}=92~\mathrm{K}$, preempting long-range charge order with wave vectors along $\textbf{q}_{\bar{K}}=(\frac{1}{3},\frac{1}{3},\frac{1}{3})$. Using a combination of real space and reciprocal space analysis, we resolve the nature of the interactions between the primary out-of-plane Sc-Sn chain instability and the secondary strain-mediated distortion of the in-plane V kagome network. A minimal model of the diffuse scattering data reveals a high-temperature, short-ranged "zig-zag" phase of in-plane correlations that maps to a frustrated triangular lattice Ising model with antiferromagnetic interactions and provides a real-space understanding of the origin of frustrated charge order in this material.

cond-mat.str-el↗

arXiv2023

Frustrated charge order and cooperative distortions in ScV6Sn6

Here we study the stability of charge order in the kagome metal ScV6Sn6. Synchrotron x-ray diffraction measurements reveal high-temperature, short-range charge correlations at the wave vectors along q=(1/3,1/3,1/2) whose inter-layer correlation lengths diverge upon cooling. At the charge order transition, this divergence is interrupted and long-range order freezes in along q=(1/3,1/3,1/3), as previously reported, while disorder enables the charge correlations to persist at the q=(1/3,1/3,1/2) wave vector down to the lowest temperatures measured. Both short-range and long-range charge correlations seemingly arise from the same instability and both are rapidly quenched upon the introduction of larger Y ions onto the Sc sites. Our results validate the theoretical prediction of the primary lattice instability at q=(1/3,1/3,1/2), and we present a heuristic picture for viewing the frustration of charge order in this compound.

cond-mat.str-el↗