arXiv subjects

S. Kanungo

Publications and source records attributed to S. Kanungo.

4 recordsLinked to original sources

arXiv2025

Magnetic ground state, critical analysis of magnetization, and large magnetocaloric effect in the ferromagnetically coupled kagome lattice YCa$_3$(MnO)$_3$(BO$_3$)$_4$

We report a detailed study of the magnetic properties, critical analysis of magnetization, and magnetocaloric effect of a spin-$2$ kagome lattice YCa$_3$(MnO)$_3$(BO$_3$)$_4$. The experiments are complemented by the density functional band structure calculations. The magnetic measurements suggest a highly frustrated nature of the compound due to competing ferro- and antiferromagnetic interactions with the dominant one being ferromagnetic. It undergoes a unconventional ferromagnetic ordering at $T^* \simeq 7.8$ K and a field induced metamagnetic transition in low fields, implying spin canting. A $H$-$T$ phase diagram is constructed that features three phase regimes. Indeed, the band structure calculations reveal dominant ferromagnetic interaction along the chains that are coupled antiferromagnetically yielding a frustrated kagome geometry. This compound shows a large magnetocaloric effect with isothermal entropy change $ΔS_{\rm m} \simeq 12$ J/kg-K, adiabatic temperature change $ΔT_{\rm ad} \simeq 8.4$ K, and relative cooling power $RCP \simeq 349$ J/kg for a field change of 7 T. The critical analysis of magnetization and magnetocaloric parameters suggests that the transition is a second order phase transition and it is tricritical mean field type. Owing to it's large magnetocaloric parameters, second order phase transition, and no thermal hysteresis, YCa$_3$(MnO)$_3$(BO$_3$)$_4$ emerges as a potential rare-earth free material for magnetic refrigeration.

cond-mat.mtrl-sci↗

arXiv2024

Hydrostatic and chemical pressure driven crossover from commensurate to the incommensurate state of the Weyl semimetal Mn$_{3+x}$Sn$_{1-x}$

The observation of large intrinsic anomalous Hall conductivity (AHC) in the non-collinear antiferromagnetic (AFM) phase of the Weyl semimetal Mn$_3$Sn generates enormous interest in uncovering the entanglement between the real space magnetic ordering and the momentum space band structure. Previous studies show that changes in the magnetic structure induced by the application of hydrostatic and chemical pressure can significantly affect the AHC of Mn$_{3+x}$Sn$_{1-x}$ system. Here, we employ the muon spin relaxation/rotation ($μ^+$SR) technique to systematically investigate the evolution of different magnetic states in the Mn$_{3+x}$Sn$_{1-x}$ as a function of hydrostatic and chemical pressure. We find two muon sites experimentally, which is also supported by our \textit{ab initio} calculations. Our $μ^+$SR experiments affirm that the $x = 0.05$ compound exhibits a commensurate magnetic state throughout the magnetically ordered phase below the Neel temperature $T_N \approx 420$~K in ambient pressure. In contrast, we observe an incommensurate magnetic state below $T_{IC} \sim 175$~K when a hydrostatic pressure of 1.5~GPa is applied. A similar transition from the commensurate to incommensurate state is also found with chemical pressure for $x = 0.04$ and $x = 0.03$, using $μ^+$SR and elastic neutron scattering experiments. Using band structure calculations, we have shown the emergence of Fermi nesting in Mn$_3$Sn and the subsequent development of incommensurate magnetic ordering under hydrostatic/chemical pressure.

cond-mat.str-el↗

arXiv2023

Non-equilibrium VLS-grown stable ST12-Ge thin film on Si substrate: A study on strain-induced band-engineering

The current work describes a novel method of growing thin films of stable crystalline ST12-Ge, a high pressure polymorph of Ge, on Si substrate by a non-equilibrium VLS-technique. The study explores the scheme of band engineering of ST12-Ge by inducing process-stress into it as a function of the growth temperature and film thickness. In the present work, ST12-Ge films are grown at 180 C - 250 C to obtain thicknesses of ~4.5-7.5 nm, which possess extremely good thermal stability up to a temperature of ~350 C. Micro-Raman study shows the stress induced in such ST12-Ge films to be compressive in nature and vary in the range of ~0.5-7.5 GPa. The measured direct band gap is observed to vary within 0.688 eV to 0.711 eV for such stresses, and four indirect band gaps are obtained to be 0.583 eV, 0.614-0.628 eV, 0.622-0.63 eV and 0.623-0.632 eV, accordingly. The corresponding band structures for unstrained and strained ST12-Ge are calculated by performing DFT simulation, which shows that a compressive stress transforms the fundamental band gap at M-G valley from indirect to direct one. Henceforth, the possible route of strain induced band engineering in ST12-Ge is explored by analyzing all the transitions in strained and unstrained band structures along with substantiation of the experimental results and theoretical calculations. The investigation shows that unstrained ST12-Ge is a natural n-type semiconductor which transforms into p-type upon incorporation of a compressive stress of ~5 GPa, with the in-plane electron effective mass components at M-G band edge to be ~0.09 me. Therefore, such band engineered ST12-Ge exhibits superior mobility along with its thermal stability and compatibility with Si, which can have potential applications to develop high-speed MOS devices for advanced CMOS technology.

cond-mat.mtrl-sci↗

arXiv2019

Pronounced 2/3 magnetization plateau in a frustrated $S$ = 1 isolated spin-triangle compound: Interplay between Heisenberg and biquadratic exchange interactions

We report the synthesis and characterization of a new quantum magnet [2-[Bis(2-hydroxybenzyl)aminomethyl]pyridine]Ni(II)-trimer (BHAP-Ni3) in single-crystalline form. Our combined experimental and theoretical investigations reveal an exotic spin state that stabilizes a robust 2/3 magnetization plateau between 7 and 20 T in an external magnetic field. AC-susceptibility measurements show the absence of any magnetic order/glassy state down to 60 mK. The magnetic ground state is disordered and specific-heat measurements reveal the gapped nature of the spin excitations. Most interestingly, our theoretical modeling suggests that the 2/3 magnetization plateau emerges due to the interplay between antiferromagnetic Heisenberg and biquadratic exchange interactions within nearly isolated spin $S$ = 1 triangles.

cond-mat.str-el↗