arXiv subjects

S. Michel

Publications and source records attributed to S. Michel.

5 recordsLinked to original sources

arXiv2025

Phonon-polaritons in Zn(1-x)MgxTe (x<0.09): A Raman scattering study

Phonon-polaritons (PP) are phonon-photon coupled modes. Using near-forward Raman scattering, the PP of the cubic Zn(1-x)MgxTe (x<0.09) semiconductor alloy could be measured. While the PP-coupling hardly develops in pure ZnTe, minor Mg-alloying suffices to stabilize a long-lifetime PP strongly bound to the lattice, i.e., with a pronounced phonon character, and yet a fast one originating from the highly dispersive photon-like bottleneck of the PP-dispersion. By combining the advantages of a phonon and of a photon, the long-lifetime PP generated by minor Mg-alloying of ZnTe marks an improvement over the PP of pristine ZnTe, that, from the Raman cross section calculation, can only achieve a balanced compromise between the two kinds of advantages, intensity and speed. The discussion of the PP-related lattice dynamics of Zn(1-x)MgxTe (x<0.09) is grounded in a preliminary study of the lattice macro- and microstructure using X-ray diffraction and solid-state nuclear magnetic resonance, respectively, and further relies on ab initio calculations of the native phonon modes behind the PP in the Mg-dilute limit of Zn(1-x)MgxTe (x~0), considering various Mg-isotopes.

cond-mat.mtrl-sci↗

arXiv2024

Exploring the dynamic interplay of cognitive load and emotional arousal by using multimodal measurements: Correlation of pupil diameter and emotional arousal in emotionally engaging tasks

Multimodal data analysis and validation based on streams from state-of-the-art sensor technology such as eye-tracking or emotion recognition using the Facial Action Coding System (FACTs) with deep learning allows educational researchers to study multifaceted learning and problem-solving processes and to improve educational experiences. This study aims to investigate the correlation between two continuous sensor streams, pupil diameter as an indicator of cognitive workload and FACTs with deep learning as an indicator of emotional arousal (RQ 1a), specifically for epochs of high, medium, and low arousal (RQ 1b). Furthermore, the time lag between emotional arousal and pupil diameter data will be analyzed (RQ 2). 28 participants worked on three cognitively demanding and emotionally engaging everyday moral dilemmas while eye-tracking and emotion recognition data were collected. The data were pre-processed in Phyton (synchronization, blink control, downsampling) and analyzed using correlation analysis and Granger causality tests. The results show negative and statistically significant correlations between the data streams for emotional arousal and pupil diameter. However, the correlation is negative and significant only for epochs of high arousal, while positive but non-significant relationships were found for epochs of medium or low arousal. The average time lag for the relationship between arousal and pupil diameter was 2.8 ms. In contrast to previous findings without a multimodal approach suggesting a positive correlation between the constructs, the results contribute to the state of research by highlighting the importance of multimodal data validation and research on convergent vagility. Future research should consider emotional regulation strategies and emotional valence.

cs.CY↗

arXiv2023

Vibrational and mechanical properties of the highly mismatched (Cd,Be)Te semiconductor alloy : Experiment and ab initio calculations

The (Cd, Be)Te semiconductor alloy that exhibits a dramatic mismatch in bond covalency and stiffness clarifying its vibrational and mechanical properties is used as a benchmark to test the limits of the percolation model (PM) worked out to explain the complex Raman spectra of the related but less contrasted (Zn, Be) chalcogenides. The test is done by way of experiment (x smaller than 0.11) combining Raman scattering with X ray diffraction at high pressure and ab initio calculations (x around 0, 0.5 and 1). The (macroscopic) bulk modulus B drops below the CdTe value on minor Be incorporation, at variance with a linear B versus x increase predicted ab initio, thus hinting at large anharmonic effects in the real crystal. Yet, no anomaly occurs at the microscopic (bond) scale as the regular bimodal PM Raman signal predicted ab initio for the BeTe bond in minority (x around 0 and 0.5) is (barely) detected experimentally. Although at large Be content (x around 1) the same bimodal signal relaxes down to inversion, an unprecedented case, specific pressure dependencies of the regular (x around 0 and 0.5) and inverted (x around 1) BeTe Raman doublets are in line with PM predictions. Hence, the PM applies as such to (Cd, Be)Te albeit in a relaxed form, without further refinement. This enhances the scheme validity as a generic descriptor of phonons in alloys.

cond-mat.mtrl-sci↗

arXiv2019

Investigation of the surface properties of different highly aligned N-MWCNT carpets

We investigated the physicochemical surface properties of different highly aligned nitrogen-doped multi-walled carbon nanotube (N-MWCNT) carpets, synthesized using toluene/pyrazine, toluene/benzylamine and acetonitrile via a sublimation-based chemical vapor deposition (SCVD) method at 760°C. The surfaces of the N-MWCNT carpets synthesized using toluene/pyrazine and toluene/benzylamine were very hydrophobic. In contrast, we observed a complete wetting of the N-MWCNT carpets synthesized using acetonitrile. The difference in the wetting behavior of these N-MWCNT carpets is the main focus in this study and was not investigated before. Here, we show that not only the presence or concentration of nitrogen inside the carbon lattice, but especially it's kind of incorporation have an important influence on the surface polarity.

cond-mat.mes-hall↗

arXiv2018

Design and development of a low temperature, inductance based high frequency ac susceptometer

We report on the development of an induction based low temperature high frequency ac susceptometer capable of measuring at frequencies up to 3.5 MHz and at temperatures between 2 K and 300 K. Careful balancing of the detection coils and calibration have allowed a sample magnetic moment resolution of $5\times10^{-10} Am^2$ at 1 MHz. We will discuss the design and characterization of the susceptometer, and explain the calibration process. We also include some example measurements on the spin ice material CdEr$_2$S$_4$ and iron oxide based nanoparticles to illustrate functionality.

physics.ins-det↗