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S. Mitra

Publications and source records attributed to S. Mitra.

36 records · Page 2Linked to original sources
arXiv2019

Transport Mechanism of Acetamide in Deep Eutectic Solvents

Over the last couple of decades, deep eutectic solvents (DESs) have emerged as novel alternatives to ionic liquids that are extensively used in synthesis of innovative materials, metal processing, catalysis, etc. However, their usage is limited, primarily because of the large viscosity and poor conductivity. Therefore, an understanding of the molecular origin of these properties is essential to improve their industrial applicability. Here, we present the report of the nanoscopic diffusion mechanism of acetamide in a DES synthesized with lithium perchlorate as studied using neutron scattering and molecular dynamics (MD) simulation techniques. Although, the acetamide based DES (ADES) has remarkably lower freezing point compared to pure acetamide, the molecular mobility is found to be enormously restricted in the former. MD simulation indicates a diffusion model with two distinct processes, corresponding to, long range jump diffusion and localised diffusion within a restricted volume. This model is validated by analysis of neutron scattering data in both molten acetamide and ADES. The long range diffusion process of acetamide is slower by a factor of three in ADES in comparison with molten acetamide. MD simulation reveals that the long range diffusion in ADES is restricted mainly due to the formation of hydrogen bond mediated complexes between the ionic species of the salt and acetamide molecules. Hence, the origin of higher viscosity observed in ADES can be attributed to the complexation. The complex formation also explains the inhibition of the crystallisation process while cooling and thereby results in depression of the freezing point of ADES.

cond-mat.mtrl-sci↗
arXiv2018

Dimensional crossover in the quasi-one-dimensional superconductor Tl$_2$Mo$_6$Se$_6$

Long-range order in quasi-one-dimensional (q1D) arrays of superconducting nanowires is established via a dimensional crossover from a fluctuating 1D regime to a phase-coherent 3D ground state. If a homogeneous crystalline superconductor exhibits sufficiently high uniaxial anisotropy, a similar 1D$\rightarrow$3D crossover has been predicted to occur, provided that single-particle hopping transverse to the 1D axis is absent in the normal state. Here we present magnetic penetration depth and electrical transport data in single crystals of q1D Tl$_2$Mo$_6$Se$_6$, which reveal a 1D$\rightarrow$3D superconducting dimensional crossover. Both experimental techniques uncover multiple energy scales within the superconducting transition, which describe a sequence of fluctuating regimes. As the temperature is reduced below $T_{ons}=$~6.7~K, 1D pairing fluctuations are replaced by 1D phase slips below $T_p\sim$~5.9~K. These give way to 3D phase fluctuations below $T_{ab}=$~4.9~K, prior to dimensional crossover at $T_{x2}\sim$~4.4~K. The electrical resistivity below $T_{ab}$ is quantitatively consistent with the establishment of phase coherence through gradual binding of Josephson vortex strings to form 3D loops. An anomalously low superfluid density persist down to $\sim$3~K before rising steeply --- in agreement with a theoretical model for crossovers in q1D superconductors, and suggesting that a small population of unbound, weakly-pinned vortices survives below the crossover. The observation of a dimensional crossover within the superconducting state has important consequences for the low-temperature normal state in Tl$_2$Mo$_6$Se$_6$ and similar q1D metals, which may exhibit one-dimensional behavior over far greater temperature ranges than band structure calculations suggest.

cond-mat.supr-con↗
arXiv2017

Probing the superconducting gap symmetry of $α$-PdBi$_{2}$: A penetration depth study

We report measurements of the in-plane London penetration depth $λ$ in single crystals of the $α$-PdBi$_{2}$ superconductor --- the $α$-phase counterpart of the putative topological superconductor $β$-PdBi$_{2}$, down to 0.35~K using a high-resolution tunnel-diode-based technique. Both $λ$ and superfluid density $ρ_{s}$ exhibit an exponential behavior for $T\leq$ 0.35$T_{c}$, with $Δ(0)/k_{B}T_{c}\sim$2.0, $ΔC/γT_{c}$$\sim$2.0 and $λ(0)$$\sim$140~nm, showing that $α$-PdBi$_{2}$ is a moderately-coupling, fully-gapped superconductor. The values of $Δ(0)$ and $ΔC/γT_{c}$ are consistent with each other via strong-coupling corrections.

cond-mat.supr-con↗
arXiv2016

Evidence for a Finite Temperature Insulator

In superconductors the zero-resistance current-flow is protected from dissipation at finite temperatures (T) by virtue of the short-circuit condition maintained by the electrons that remain in the condensed state. The recently suggested finite-T insulator and the "superinsulating" phase are different because any residual mechanism of conduction will eventually become dominant as the finite-T insulator sets-in. If the residual conduction is small it may be possible to observe the transition to these intriguing states. We show that the conductivity of the high magnetic-field insulator terminating superconductivity in amorphous indium-oxide exhibits an abrupt drop, and seem to approach a zero conductance at T<0.04 K. We discuss our results in the light of theories that lead to a finite-T insulator.

cond-mat.supr-con↗
arXiv2013

Diffuse phase transition and electrical properties of lead-free piezoelectric (LixNa1-x)NbO3 (0.04 to x to 0.20) ceramics near morphotropic phase boundary

Temperature-dependent dielectric permittivity of lead-free (LixNa1-x)NbO3 for nominal x = 0.04-0.20, prepared by solid state reaction followed by sintering, was studied to resolve often debated issue pertaining to exactness of morphotropic phase boundary (MPB) location along with structural aspects and phase stability in the system near MPB. Interestingly, a diffuse phase transition has been observed in the dielectric permittivity peak arising from the disorder induced in A-site and structural frustration in the perovskite cell due to Li substitution. A partial phase diagram has been proposed based on temperature-dependent dielectric permittivity studies. The room temperature piezoelectric and ferroelectric properties were investigated and the ceramics with x = 0.12 showed relatively good electrical properties (d33 = 28 pC/N, kp = 13.8%, Qm = 440, Pr = 12.5 {micro}C/cm2, EC = 43.2 kV/cm, Tm = 340 oC). These parameter values make this material suitable for piezoelectric resonator and filter applications. Moreover, a high dielectric permittivity (= 2703) with broad diffuse peak near transition temperature along with low dielectric loss (< 4%) in a wide temperature range (50-250 oC) found in this material may also have a potential application in high-temperature multilayer capacitors in automotive and aerospace related industries.

cond-mat.mtrl-sci↗
arXiv2010

Fast Pixel Space Convolution for CMB Surveys with Asymmetric Beams and Complex Scan Strategies: FEBeCoP

Precise measurement of the angular power spectrum of the Cosmic Microwave Background (CMB) temperature and polarization anisotropy can tightly constrain many cosmological models and parameters. However, accurate measurements can only be realized in practice provided all major systematic effects have been taken into account. Beam asymmetry, coupled with the scan strategy, is a major source of systematic error in scanning CMB experiments such as Planck, the focus of our current interest. We envision Monte Carlo methods to rigorously study and account for the systematic effect of beams in CMB analysis. Toward that goal, we have developed a fast pixel space convolution method that can simulate sky maps observed by a scanning instrument, taking into account real beam shapes and scan strategy. The essence is to pre-compute the "effective beams" using a computer code, "Fast Effective Beam Convolution in Pixel space" (FEBeCoP), that we have developed for the Planck mission. The code computes effective beams given the focal plane beam characteristics of the Planck instrument and the full history of actual satellite pointing, and performs very fast convolution of sky signals using the effective beams. In this paper, we describe the algorithm and the computational scheme that has been implemented. We also outline a few applications of the effective beams in the precision analysis of Planck data, for characterizing the CMB anisotropy and for detecting and measuring properties of point sources.

astro-ph.CO↗
arXiv2009

Dynamic Disorder in Negative Thermal Expansion Compound Zn(CN)2

Dynamical disorder in negative thermal expansion compound Zn(CN)2 is investigated by quasielastic neutron scattering technique in the temperature range 170-320 K. Significant quasielastic broadening is observed above the phase transition temperature of about 250 K, however no broadening is observed at 220 K and below. Data at high temperatures are analyzed assuming the CN reorientation. Characteristic time associated with the CN orientation is estimated as 16 ps and 11 ps at 270 and 320 K respectively.

cond-mat.mtrl-sci↗
arXiv2005

Improving the efficiency of the detection of gravitational wave signals from inspiraling compact binaries: Chebyshev interpolation

Inspiraling compact binaries are promising sources of gravitational waves for ground and space-based laser interferometric detectors. The time-dependent signature of these sources in the detectors is a well-characterized function of a relatively small number of parameters; thus, the favored analysis technique makes use of matched filtering and maximum likelihood methods. Current analysis methodology samples the matched filter output at parameter values chosen so that the correlation between successive samples is 97% for which the filtered output is closely correlated. Here we describe a straightforward and practical way of using interpolation to take advantage of the correlation between the matched filter output associated with nearby points in the parameter space to significantly reduce the number of matched filter evaluations without sacrificing the efficiency with which real signals are recognized. Because the computational cost of the analysis is driven almost exclusively by the matched filter evaluations, this translates directly into an increase in computational efficiency, which in turn, translates into an increase in the size of the parameter space that can be analyzed and, thus, the science that can be accomplished with the data. As a demonstration we compare the present "dense sampling" analysis methodology with our proposed "interpolation" methodology, restricted to one dimension of the multi-dimensional analysis problem. We find that the interpolated search reduces by 25% the number of filter evaluations required by the dense search with 97% correlation to achieve the same efficiency of detection for an expected false alarm probability. Generalized to higher dimensional space of a generic binary including spins suggests an order of magnitude increase in computational efficiency.

gr-qc↗
arXiv2005

Desiccation and Relaxation Regimes in Fracture of Drying Clay Films

A study of crack patterns in laponite films of different thickness is presented. Two cracking regimes are observed. The earlier with a higher rate of desiccation and shrinking has predominantly four-fold vertices in the crack network, while the later regime has less volume shrinking and forms mainly three-fold vertices. The pattern shows a self-similarity under coarse-graining. The graph of area covered by the cracks versus minimum crack-width resolved, scales with the film thickness. Curves representing crack area for different thickness can thus be made to collapse onto a single curve.

cond-mat.soft↗
arXiv2004

Exact expressions for correlations in the ground state of the dense O(1) loop model

Conjectures for analytical expressions for correlations in the dense O$(1)$ loop model on semi infinite square lattices are given. We have obtained these results for four types of boundary conditions. Periodic and reflecting boundary conditions have been considered before. We give many new conjectures for these two cases and review some of the existing results. We also consider boundaries on which loops can end. We call such boundaries ''open''. We have obtained expressions for correlations when both boundaries are open, and one is open and the other one is reflecting. Also, we formulate a conjecture relating the ground state of the model with open boundaries to Fully Packed Loop models on a finite square grid. We also review earlier obtained results about this relation for the three other types of boundary conditions. Finally, we construct a mapping between the ground state of the dense O$(1)$ loop model and the XXZ spin chain for the different types of boundary conditions.

cond-mat.stat-mech↗
arXiv2003

Have mirror micrometeorites been detected?

Slow-moving ($v \sim 15$ km/s) 'dark matter particles' have allegedly been discovered in a recent experiment. We explore the possibility that these slow moving dark matter particles are small mirror matter dust particles originating from our solar system. Ways of further testing our hypothesis, including the possibility of observing these dust particles in cryogenic detectors such as NAUTILUS, are also discussed.

hep-ph↗
arXiv2003

Detecting mirror matter on Earth via its thermal imprint on ordinary matter

Mirror matter type dark matter can exist on the Earth's surface, potentially in enhanced concentrations at various anomalous impact sites. Mirror matter fragments can draw in heat from the ordinary matter environment, radiate mirror photons and thereby cool the surrounding ordinary matter. We quantify this effect and suggest that it could be used to help locate mirror matter deposits. This method, together with the centrifuge technique, seems to provide the most promising means to experimentally detect mirror matter type dark matter in the Earth.

cond-mat↗
arXiv2003

Detecting dark matter using centrifuging techniques

A new and inexpensive technique for detecting self interacting dark matter in the form of small grains in bulk matter is proposed. Depending on the interactions with ordinary matter, dark matter grains in bulk matter may be isolated by using a centrifuge and using ordinary matter as a filter. The case of mirror matter interacting with ordinary matter via photon-mirror photon kinetic mixing provides a concrete example of this type of dark matter candidate.

astro-ph↗
arXiv2002

Mirror matter in the solar system: New evidence for mirror matter from Eros

Mirror matter is an entirely new form of matter predicted to exist if mirror symmetry is a fundamental symmetry of nature. Mirror matter has the right broad properties to explain the inferred dark matter of the Universe and might also be responsible for a variety of other puzzles in particle physics, astrophysics, meteoritics and planetary science. It is known that mirror matter can interact with ordinary matter non-gravitationally via photon-mirror photon kinetic mixing. The strength of this possibly fundamental interaction depends on the (theoretically) free parameter $ε$. We consider various proposed manifestations of mirror matter in our solar system examining in particular how the physics changes for different possible values of $ε$. We find new evidence for mirror matter in the solar system coming from the observed sharp reduction in crater rates (for craters less than about 100 meters in diameter) on the asteroid 433 Eros. We also re-examine various existing ideas including the mirror matter explanation for the anomalous meteorite events, anomalous slow-down of Pioneer spacecraft etc.

astro-ph↗
arXiv2002

Ordinary atom-mirror atom bound states: A new window on the mirror world

Mirror symmetry is a plausible candidate for a fundamental symmetry of particle interactions which can be exactly conserved if a set of mirror particles exist. The properties of the mirror particles seem to provide an excellent candidate to explain the inferred dark matter of the Universe and might also be responsible for a variety of other puzzles in particle physics, astrophysics, meteoritics and planetary science. One such puzzle -- the orthopositronium lifetime problem -- can be explained if there is a small kinetic mixing of ordinary and mirror photons. We show that this kinetic mixing implies the existence of ordinary atom - mirror atom bound states with interesting terrestrial and astrophysical implications. We suggest that sensitive mass spectroscopic studies of ordinary samples containing heavy elements such as lead might reveal the presence of these bound states, as they would appear as anomalously heavy elements. In addition to the effects of single mirror atoms, collective effects from embedded fragments of mirror matter (such as mirror iron microparticles) are also possible. We speculate that such mirror matter fragments might explain a mysterious UV photon burst observed coming from a laser irradiated lead target in a recent experiment.

hep-ph↗
arXiv1997

Boosted three-dimensional black-hole evolutions with singularity excision

Binary black hole interactions provide potentially the strongest source of gravitational radiation for detectors currently under development. We present some results from the Binary Black Hole Grand Challenge Alliance three- dimensional Cauchy evolution module. These constitute essential steps towards modeling such interactions and predicting gravitational radiation waveforms. We report on single black hole evolutions and the first successful demonstration of a black hole moving freely through a three-dimensional computational grid via a Cauchy evolution: a hole moving ~6M at 0.1c during a total evolution of duration ~60M.

gr-qc↗
arXiv1997

Gravitational wave extraction and outer boundary conditions by perturbative matching

We present a method for extracting gravitational radiation from a three-dimensional numerical relativity simulation and, using the extracted data, to provide outer boundary conditions. The method treats dynamical gravitational variables as nonspherical perturbations of Schwarzschild geometry. We discuss a code which implements this method and present results of tests which have been performed with a three dimensional numerical relativity code.

gr-qc↗