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S. Mori

Publications and source records attributed to S. Mori.

At least 19 recordsLinked to original sources

Causal Discovery to Understand Hot Corrosion

Gas turbine superalloys experience hot corrosion, driven by factors including corrosive deposit flux, temperature, gas composition, and component material. The full mechanism still needs clarification and research often focuses on laboratory work. As such, there is interest in causal discovery to confirm the significance of factors and identify potential missing causal relationships or co-dependencies between these factors. The causal discovery algorithm Fast Causal Inference (FCI) has been trialled on a small set of laboratory data, with the outputs evaluated for their significance to corrosion propagation, and compared to existing mechanistic understanding. FCI identified the salt deposition flux as the most influential corrosion variable for this limited dataset. However, HCl was the second most influential for pitting regions, compared to temperature for more uniformly corroding regions. Thus FCI generated causal links aligned with literature from a randomised corrosion dataset, while also identifying the presence of two different degradation modes in operation.

cond-mat.mtrl-sci

Hot methanol in the [BHB2007] 11 protobinary system: hot corino versus shock origin? : FAUST V

Methanol is a ubiquitous species commonly found in the molecular interstellar medium. It is also a crucial seed species for the building-up of the chemical complexity in star forming regions. Thus, understanding how its abundance evolves during the star formation process and whether it enriches the emerging planetary system is of paramount importance. We used new data from the ALMA Large Program FAUST (Fifty AU STudy of the chemistry in the disk/envelope system of Solar-like protostars) to study the methanol line emission towards the [BHB2007] 11 protobinary system (sources A and B), where a complex structure of filaments connecting the two sources with a larger circumbinary disk has been previously detected. Twelve methanol lines have been detected with upper energies in the range [45-537] K along with one 13CH3OH transition. The methanol emission is compact and encompasses both protostars, separated by only 28 au and presents three velocity components, not spatially resolved by our observations, associated with three different spatial regions, with two of them close to 11B and the third one associated with 11A. A non-LTE radiative transfer analysis of the methanol lines concludes that the gas is hot and dense and highly enriched in methanol with an abundance as high as 1e-5. Using previous continuum data, we show that dust opacity can potentially completely absorb the methanol line emission from the two binary objects. Although we cannot firmly exclude other possibilities, we suggest that the detected hot methanol is resulting from the shocked gas from the incoming filaments streaming towards [BHB2007] 11 A and B, respectively. Higher spatial resolution observations are necessary to confirm this hypothesis.

astro-ph.GA

Glasslike phonon excitation caused by ferroelectric structural instability

Quest for new states of matter near an ordered phase is a promising route for making modern physics forward. By probing thermal properties of a ferroelectric (FE) crystal Ba1-xSrxAl2O4, we have clarified that low-energy excitation of acoustic phonons is remarkably enhanced with critical behavior at the border of the FE phase. The phonon spectrum is significantly damped toward the FE phase boundary and transforms into glasslike phonon excitation which is reminiscent of a boson peak. This system thus links long-standing issues of amorphous solids and structural instability in crystals to pave the way to controlling lattice fluctuation as a new tuning parameter.

cond-mat.mtrl-sci

FAUST I. The hot corino at the heart of the prototypical Class I protostar L1551 IRS5

The study of hot corinos in Solar-like protostars has been so far mostly limited to the Class 0 phase, hampering our understanding of their origin and evolution. In addition, recent evidence suggests that planet formation starts already during Class I phase, which, therefore, represents a crucial step in the future planetary system chemical composition. Hence, the study of hot corinos in Class I protostars has become of paramount importance. Here we report the discovery of a hot corino towards the prototypical Class I protostar L1551 IRS5, obtained within the ALMA Large Program FAUST. We detected several lines from methanol and its isopotologues ($^{13}$CH$_{\rm 3}$OH and CH$_{\rm 2}$DOH), methyl formate and ethanol. Lines are bright toward the north component of the IRS5 binary system, and a possible second hot corino may be associated with the south component. The methanol lines non-LTE analysis constrains the gas temperature ($\sim$100 K), density ($\geq$1.5$\times$10$^{8}$ cm$^{-3}$), and emitting size ($\sim$10 au in radius). All CH$_{\rm 3}$OH and $^{13}$CH$_{\rm 3}$OH lines are optically thick, preventing a reliable measure of the deuteration. The methyl formate and ethanol relative abundances are compatible with those measured in Class 0 hot corinos. Thus, based on the present work, little chemical evolution from Class 0 to I hot corinos occurs.

astro-ph.SR

Lorentz microscopy and small-angle electron diffraction study of magnetic textures in La$_{1-x}$Sr$_x$MnO$_3$ (0.15 $< x <$ 0.30): the role of magnetic anisotropy

Magnetic textures in the ferromagnetic phases of La$_{1-x}$Sr$_x$MnO$_3$ for 0.15 $< x <$ 0.30 have been investigated by Lorentz microscopy combined with small-angle electron diffraction experiments. Various types of magnetic textures characterized by stripe, plate-shaped, and cylindrical (magnetic bubble) domains were found. Two distinct types of magnetic stripe domains appeared in the orthorhombic structure with an inversion symmetry of La$_{0.825}$Sr$_{0.175}$MnO$_3$, depending significantly on magnetocrystalline anisotropy. Based on in-situ observations as functions of temperature and the strength of the external magnetic field, a magnetic field-temperature phase diagram was constructed, showing the stabilization of magnetic bubbles in the ferromagnetic phase of La$_{0.825}$Sr$_{0.175}$MnO$_3$.

cond-mat.str-el

Field-temperature phase diagram of magnetic bubbles spanning charge$/$orbital ordered and metallic phases in La$_{1-x}$Sr$_x$MnO$_3$ ($x = 0.125$)

We report formation of magnetic textures in the ferromagnetic (FM) phase of La$_{1-x}$Sr$_x$MnO$_3$ for $x =$ 0.125; these textures are magnetic bubbles, magnetic stripe domains, and forced FM states. In situ Lorentz microscopy (LM) observations show that magnetic bubbles exist in the FM insulating phase accompanying the formation of the charge$/$orbital ordering (CO$/$OO). Furthermore, stable magnetic bubbles still exist in an intermediate temperature region between the CO$/$OO ($T_{CO} =$ 155 K) and FM ($T_c =$ 190 K) transition temperatures. These magnetic bubbles are believed to originate from the magnetocrystalline anisotropy and the dipole-dipole interaction in the FM phase. Based on in situ LM observations as a function of both temperature and the strength of the external magnetic field applied, a magnetic field-temperature phase diagram is constructed, exhibiting the stabilizing regions of the magnetic bubbles in the FM phase of La$_{0.875}$Sr$_{0.125}$MnO$_{3}$.

cond-mat.str-el

Formation mechanisms of magnetic bubbles in an M-type hexaferrite: the role of chirality reversals at domain walls

We examined the formation mechanisms of magnetic bubbles in an M-type hexaferrite via Lorentz microscopy. When magnetic fields were perpendicularly applied to a thin sample of BaFe$_{12-x-0.05}$Sc$_x$Mg$_{0.05}$O$_{19}$ ($x = 1.6$), Bloch lines, which were identified as reversals of domain-wall chirality, appeared, and magnetic bubbles were formed when the magnetic stripes were pinched off at these Bloch lines. The number of Bloch lines increased with the amount of Sc in BaFe$_{12-x-0.05}$Sc$_x$Mg$_{0.05}$O$_{19}$ probably because of the reduction in magnetic anisotropy. A Lorentz microscopic observation revealed that Bloch lines with high magnetostatic energy may play an important role in the formation of magnetic bubbles.

cond-mat.mtrl-sci

Observation of magnetic domain and bubble structures in magnetoelectric Sr$_3$Co$_2$Fe$_{24}$O$_{41}$

The magnetic domain and bubble structures in the Z-type hexaferrite Sr$_3$Co$_2$Fe$_{24}$O$_{41}$ were investigated using Lorentz microscopy. This hexaferrite exhibits a room-temperature magnetoelectric effect that is attributed to its transverse conical spin structure (TC phase). Upon heating, the TC phase transforms into a ferrimagnetic phase with magnetic moments in the hexagonal $ab$ plane between 410 and 480 K (FM2 phase) and into another ferrimagnetic phase with moments parallel to the $c$ axis between 490 and 680 K (FM1 phase). Accordingly, in this study, the magnetic domain structures in Sr$_3$Co$_2$Fe$_{24}$O$_{41}$ were observed to change dramatically with temperature. In the TC phase, irregular fine magnetic domains were observed after cooling the specimen from the FM2 to TC phase. In the FM1 phase, striped magnetic domain walls with pairs of bright and dark contrast were formed parallel to the $c$ axis. Upon applying an external magnetic field, the striped magnetic domain walls transformed into magnetic bubbles. The topology of the magnetic bubbles was dependent on the angle between the external magnetic field ($H$) direction and the easy $c$ axis. Namely, magnetic bubbles with the topological number $N$ = 1 (type I) were created for $H//c$, whereas magnetic bubbles with $N$ = 0 (type II) were created when the magnetic field was tilted from the c axis by 5°. We attribute the high magnetocrystalline anisotropy of Sr$_3$Co$_2$Fe$_{24}$O$_{41}$ to the emergence of magnetic bubbles in the FM1 phase.

cond-mat.str-el

Glass-like features of crystalline solids in the quantum critical regime

There has been growing interest in structural quantum phase transitions and quantum fluctuations of phonons in the research area of condensed matter physics. Here, we report the observation of glass-like features in the lattice heat capacity of a stuffed tridymite-type crystal, Ba1-xSrxAl2O4, a candidate compound of quantum paraelectrics. Substitutional chemical suppression of the ferroelectric phase transition temperature (TC) of Ba1-xSrxAl2O4 results in the disappearance of the TC at x=0.07. For the compositional window of x=0.2-0.5, the lattice heat capacity is enhanced below approximately 10 K and diverges from the T3-scaling law below 2.5 K. Synchrotron X-ray diffraction experiments on single crystals reveal the weakly correlated disorder in the crystal structure that survives down to low temperature; this disorder is responsible for the observed excess heat capacity. These features can be considered one of the manifestations of structural quantum fluctuations.

cond-mat.mtrl-sci

Topological susceptibility at high temperature on the lattice

QCD topological susceptibility at high temperature, $χ_t(T)$, provides an important input for the estimate of the axion abundance in the present Universe. While the model independent determination of $χ_t(T)$ should be possible from the first principles using lattice QCD, existing methods fail at high temperature, since not only the probability that non-trivial topological sectors appear in the configuration generation process but also the local topological fluctuations get strongly suppressed. We propose a novel method to calculate the temperature dependence of topological susceptibility at high temperature. A feasibility test is performed on a small lattice in the quenched approximation, and the results are compared with the prediction of the dilute instanton gas approximation. It is found that the method works well especially at very high temperature and the result is consistent with the instanton calculus down to $T\sim 2\, T_c$ within the statistical uncertainty.

hep-lat

Giant Thermal Vibrations in the Framework Compounds Ba1-xSrxAl2O4

Synchrotron X-ray diffraction (XRD) experiments were performed on the network compounds Ba1-xSrxAl2O4 at temperatures between 15 and 800 K. The ferroelectric phase of the parent BaAl2O4 is largely suppressed by the Sr-substitution and disappears for $x\geq0.1$. Structural refinements reveal that the isotropic atomic displacement parameter ($B_{\rm iso}$) in the bridging oxygen atom for $x\geq0.05$ is largely independent of temperature and retains an anomalously large value in the adjacent paraelectric phase even at the lowest temperature. The $B_{\rm iso}$ systematically increases as $x$ increases, exhibiting an especially large value for $x\geq0.5$. According to previous electron diffraction experiments for Ba1-xSrxAl2O4 with $x\geq0.1$, strong thermal diffuse scattering occurs at two reciprocal points relating to two distinct soft modes at the M- and K-points over a wide range of temperatures below 800 K [Y. Ishii et al., Sci. Rep. 6, 19154 (2016)]. Although the latter mode disappears at approximately 200 K, the former does not condense, at least down to 100 K. On the contrary, it still survives at low-temperature. The anomalously large $B_{\rm iso}$ observed in this study is ascribed to these soft modes existing in a wide temperature range.

cond-mat.mtrl-sci

Chiral surface twists and skyrmion stability in nanolayers of cubic helimagnets

Lorentz transmission electron microscopy (LTEM) investigations of modulated states in a FeGe wedge and detailed calculations demonstrate that chiral twists arising near the surfaces of noncentrosymmetric ferromagnets (Meynell et al. Phys. Rev. B, 90, 014406 (2014)) provide a stabilization mechanism for skyrmion lattices and helicoids in cubic helimagnet nanolayers. The calculated magnetic phase diagram for free standing cubic helimagnet nanolayers shows that magnetization processes in these compounds fundamentally differ from those in bulk cubic helimagnets and are characterized by the first-order transitions between modulated phases and the formation of specific multidomain states. The paper reports LTEM observations of multidomain patterns in FeGe free-standing nanolayers.

cond-mat.mes-hall

An Unconventional Phase Transition in BaAl2O4 Driven by Two Competing Soft Modes

We investigated the temperature dependence of the superlattice intensity and thermal diffuse scattering intensity of BaAl2O4, which has a network structure with corner-sharing AlO4 tetrahedra, via synchrotron X-ray diffraction experiments. The temperature variation of the superlattice intensity revealed that the structural phase transition occurs at TC = 451.4 K from the P6322 parent crystal structure to the low-temperature superstructure with a cell volume of 2a x 2b x c. BaAl2O4 exhibits an unconventional structural phase transition driven by two competing soft modes, q1/2 ~ (1/2, 1/2, 0) and q1/3 ~ (1/3, 1/3, 0). When approaching the TC from above, the soft mode with q1/3 appeared first and was followed by the q1/2 soft mode. The thermal diffuse scattering intensities from both soft modes increased sharply at TC; therefore, both modes condensed simultaneously. The first principles calculation revealed that structural instabilities exist at the M- and K-points, at which the calculated imaginary frequencies are similar. The small energy difference of these structural instabilities generates the two competing soft modes and determines the eventual low-temperature crystal structure.

cond-mat.mtrl-sci

Is hexagonal InMnO3 ferroelectric?

The presence of ferroelectricity in hexagonal (h-)InMnO3 has been highly under debate. The results of our comprehensive experiments of low-temperature (T) polarization, TEM and HAADF-STEM on well-controlled h-InMnO3 reveal that the ground state is ferroelectric with P6_3cm symmetry, but a non-ferroelectric P-3c1 state exists at high T, and can be quenched to room T. We also found that the ferroelectric P6_3cm state of h-InMnO3 exhibits the domain configuration of topological vortices, as has been observed in h-REMnO3 (RE=rare earths).

cond-mat.mtrl-sci

Direct observation of the proliferation of ferroelectric loop domains and vortex-antivortex pairs

We discovered "stripe" patterns of trimerization-ferroelectric domains in hexagonal REMnO3 (RE=Ho, ---, Lu) crystals (grown below ferroelectric transition temperatures (Tc), reaching up to 1435 oC), in contrast with the vortex patterns in YMnO3. These stripe patterns roughen with the appearance of numerous loop domains through thermal annealing just below Tc, but the stripe domain patterns turn to vortex-antivortex domain patterns through a freezing process when crystals cross Tc even though the phase transition appears not to be Kosterlitz-Thouless-type. The experimental systematics are compared with the results of our six-state clock model simulation and also the Kibble-Zurek Mechanism for trapped topological defects.

cond-mat.mtrl-sci

Solar cycle dependence of the diurnal anisotropy of 0.6 TeV cosmic ray intensity observed with the Matsushiro underground muon detector

We analyze the temporal variation of the diurnal anisotropy of sub-TeV cosmic ray intensity observed with the Matsushiro (Japan) underground muon detector over two full solar activity cycles in 1985-2008. The average sidereal amplitude over the entire period is 0.034+-0.003 %, which is roughly one third of the amplitude reported from AS and deep-underground muon experiments monitoring multi-TeV GCR intensity suggesting a significant attenuation of the anisotropy due to the solar modulation. We find, on the other hand, only weak correlations either with the solar activity- or magnetic-cycles. We examine the temporal variation of the "single-band valley depth" (SBVD) quoted by the Milagro experiment and, by contrast with recent Milagro reports, we find no steady increase in the Matsushiro observations in a 7-year period between 2000 and 2007. We suggest, therefore, that the steady increase of the SBVD reported by the Milagro experiment is not caused by the decreasing solar modulation in the declining phase of the 23rd solar activity cycle.

astro-ph.HE

Moody's Correlated Binomial Default Distributions for Inhomogeneous Portfolios

This paper generalizes Moody's correlated binomial default distribution for homogeneous (exchangeable) credit portfolio, which is introduced by Witt, to the case of inhomogeneous portfolios. As inhomogeneous portfolios, we consider two cases. In the first case, we treat a portfolio whose assets have uniform default correlation and non-uniform default probabilities. We obtain the default probability distribution and study the effect of the inhomogeneity on it. The second case corresponds to a portfolio with inhomogeneous default correlation. Assets are categorized in several different sectors and the inter-sector and intra-sector correlations are not the same. We construct the joint default probabilities and obtain the default probability distribution. We show that as the number of assets in each sector decreases, inter-sector correlation becomes more important than intra-sector correlation. We study the maximum values of the inter-sector default correlation. Our generalization method can be applied to any correlated binomial default distribution model which has explicit relations to the conditional default probabilities or conditional default correlations, e.g. Credit Risk${}^{+}$, implied default distributions. We also compare some popular CDO pricing models from the viewpoint of the range of the implied tranche correlation.

physics.soc-ph

Sky-maps of the sidereal anisotropy of galactic cosmic ray intensity and its energy dependence

We analyze the sidereal daily variations observed between 1985 and 2006 at Matsushiro, Japan (MAT) and between 1993 and 2005 at Liapootah, Tasmania (LPT). These stations comprise the two hemisphere network (THN) of underground muon detectors in Japan and Australia. Yearly mean harmonic vectors at MAT and LPT are more or less stable without any significant change in phase and amplitude in correlation with either the solar activity- or magnetic-cycles. In this paper, therefore, we analyze the average anisotropy over the entire observation periods, i.e. 1985-2006 for MAT and 1993-2005 for LPT. We apply to the THN data a best-fitting analysis based on a model anisotropy in space identical to that adopted by Amenomori et al. (2007) for Tibet III data. The median energies of primary cosmic rays recorded are ~0.5 TeV for THN and ~5 TeV for the Tibet III experiment. It is shown that the intensity distribution of the best-fit anisotropy is quite similar to that derived from Tibet III data, regardless of the order of magnitude difference in energies of primary particles. This, together with the THN observations, confirms that the analysis by Amenomori et al. (2007) based on the Tibet III experiment in the northern hemisphere is not seriously biased. The best-fit amplitudes of the anisotropy, on the other hand, are only one third or less of those reported by the Tibet III experiment, indicating attenuation due to solar modulation. The rigidity dependence of the anisotropy amplitude in the sub-TeV region is consistent with the spectrum reported by Hall et al. (1999), smoothly extending to the Tibet III result in the multi-TeV region. The amplitude at higher energies appears almost constant or gradually decreasing with increasing rigidity.

astro-ph