arXiv subjects

S. R. Federman

Publications and source records attributed to S. R. Federman.

49 records · Page 3Linked to original sources

arXiv2003

Reanalysis of Copernicus Measurements on Interstellar Carbon Monoxide

We used archival data acquired with the Copernicus satellite to reexamine CO column densities because self-consistent oscillator strengths are now available. Our focus is on lines of sight containing modest amounts of molecular species. Our resulting column densities are small enough that self-shielding from photodissociation is not occurring in the clouds probed by the observations. While our sample shows that the column densities of CO and H2 are related, no correspondence with the CH column density is evident. The case for the CH+ column density is less clear. Recent chemical models for these sight lines suggest that CH is mainly a by-product of CH+ synthesis in low density gas. The models are most successful in reproducing the amounts of CO in the densest sight lines. Thus, much of the CO absorption must arise from denser clumps along the line of sight to account for the trend with H2.

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arXiv2003

Cloud Structure and Physical Conditions in Star-forming Regions from Optical Observations. I. Data and Component Structure

We present high-resolution optical spectra (at ~0.6--1.8 km s-1) of interstellar CN, CH, CH^+, \ion{Ca}{1}, \ion{K}{1}, and \ion{Ca}{2} absorption toward 29 lines of sight in three star-forming regions, ρOph, Cep OB2, and Cep OB3. The observations and data reduction are described. The agreement between earlier measurements of the total equivalent widths and our results is quite good. However, our higher resolution spectra reveal complex structure and closely blended components in most lines of sight. The velocity component structure of each species is obtained by analyzing the spectra of the six species for a given sight line together. The tabulated column densities and Doppler parameters of individual components are determined by using the method of profile fitting. Total column densities along lines of sight are computed by summing results from profile fitting for individual components and are compared with column densities from the apparent optical depth method. A more detailed analysis of these data and their implications will be presented in a companion paper.

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arXiv2003

FUSE Measurements of Rydberg Bands of Interstellar CO between 925 and 1150 A

We report the detection of 11 Rydberg bands of CO in FUSE spectra of the sight line toward HD203374A. Eight of these electronic bands are seen in the interstellar medium for the first time. Our simultaneous fit of five non-Rydberg A-X bands together with the strongest Rydberg band of CO, C-X (0-0), yields a 4-component cloud structure toward the stellar target. With this model we synthesize the other Rydberg bands in order to derive their oscillator strengths. We find that the strength of some bands was underestimated in previously published results from laboratory measurements. The implication is important for theoretical calculations of the abundance of interstellar CO, because its dissociation and self shielding depend on oscillator strengths for these bands.

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arXiv2003

Further Evidence for Chemical Fractionation from Ultraviolet Observations of Carbon Monoxide

Ultraviolet absorption from interstellar 12CO and 13CO was detected toward rho Oph A and chi Oph. The measurements were obtained at medium resolution with the Goddard High Resolution Spectrograph on the Hubble Space Telescope. Column density ratios, N(12CO)/N(13CO), of 125 \pm 23 and 117 \pm 35 were derived for the sight lines toward rho Oph A and chi Oph, respectively. A value of 1100 \pm 600 for the ratio N(12C16O)/N(12C18O) toward rho Oph A was also obtained. Absorption from vibrationally excited H_2 (v" = 3) was clearly seen toward this star as well. The ratios are larger than the isotopic ratios for carbon and oxygen appropriate for ambient interstellar material. Since for both carbon and oxygen the more abundant isotopomer is enhanced, selective isotopic photodissociation plays the key role in the fractionation process for these directions. The enhancement arises because the more abundant isotopomer has lines that are more optically thick, resulting in more self shielding from dissociating radiation. A simple argument involving the amount of self shielding [from N(12CO)] and the strength of the ultraviolet radiation field premeating the gas (from the amount of vibrationally excited H_2) shows that selective isotopic photodissociation controls the fractionation seen in these two sight lines, as well as the sight line to zeta Oph.

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arXiv2003

Non-Thermal Chemistry in Diffuse Clouds with Low Molecular Abundances

High quality archival spectra of interstellar absorption from C I toward 9 stars, taken with the Goddard High Resolution Spectrograph on the Hubble Space Telescope, were analyzed. Our sample was supplemented by two sight lines, 23 Ori and B1 Sco, for which the C I measurements of Federman, Welty, & Cardelli were used. Directions with known CH+ absorption, but only upper limits on absorption from C2 and CN, were considered for our study. This restriction allows us to focus on regions where CH+ chemistry dominates the production of carbon-bearing molecules. Profile synthesis of several multiplets yielded column densities and Doppler parameters for the C I fine structure levels. Equilibrium excitation analyses, using the measured column densities as well as the temperature from H2 excitation, led to values for gas density. These densities, in conjunction with measurements of CH, CH+, C2, and CN column densities, provided estimates for the amount of CH associated with CH+ production, which in turn set up constraints on the present theories for CH+ formation in this environment. We found for our sample of interstellar clouds that on average, 30--40 % of the CH originates from CH+ chemistry, and in some cases it can be as high as 90 %. A simple chemical model for gas containing non-equilibrium production of CH+ was developed for the purpose of predicting column densities for CH, CO, HCO+, CH2+, and CH3+ generated from large abundances of CH+. Again, our results suggest that non-thermal chemistry is necessary to account for the observed abundance of CH and probably that of CO in these clouds.

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arXiv2003

Small scale structure in molecular gas from multi-epoch observations of HD 34078

We present spectroscopic observations of the runaway reddened star HD 34078 acquired during the last three years at Observatoire de Haute Provence and McDonald Observatory as well as other spectra obtained since 1990. The drift of the line of sight through the foreground cloud due to the large transverse velocity of HD 34078 allows us to probe the spatial distribution of CH, CH+, CN and DIBs carriers at scales ranging from about 1 AU up to 150 AU. In particular, time variations in the equivalent width of absorption lines are examined. A few past and recent high resolution observations of CH and CH+ absorption are used to search for line profile variations and to convert equivalent widths into column densities. The data set reveals a 20 % increase in CH column density over the past 10 years with no corresponding variation in the column density of CH+ or in the strengths of the 5780 and 5797 AA DIBs. CN observations indicate that its excitation temperature has significantly increased from < 3.1 K in 1993 to 3.6 +- 0.17 K in 1998 while the CN column shows only a modest rise of ~ 12 +- 6 %. The data also strongly suggest the existence of weak correlated variations in CH and CH+ columns over periods of 6 - 12 months (or ~ 10 AU). These results are discussed in relation to CH+ production mechanisms. A dense newly intervening clump is considered in order to explain the long-term increase in the column density of CH, but such a scenario does not account for all observational constraints. Instead, the observations are best described by CH+ production in a photodissociation region, like that suggested for the Pleiades and IC 348.

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arXiv2002

An Ultra-High-Resolution Survey of the Interstellar ^7Li-to-^6Li Isotope Ratio in the Solar Neighborhood

In an effort to probe the extent of variations in the interstellar ^7Li/^6Li ratio seen previously, ultra-high-resolution (R ~ 360,000), high signal-to-noise spectra of stars in the Perseus OB2 and Scorpius OB2 Associations were obtained. These measurements confirm our earlier findings of an interstellar ^7Li/^6Li ratio of about 2 toward o Per, the value predicted from models of Galactic cosmic ray spallation reactions. Observations of other nearby stars yield limits consistent with the isotopic ratio ~ 12 seen in carbonaceous chondrite meteorites. If this ratio originally represented the gas toward o Per, then to decrease the original isotope ratio to its current value an order of magnitude increase in the Li abundance is expected, but is not seen. The elemental K/Li ratio is not unusual, although Li and K are formed via different nucleosynthetic pathways. Several proposals to account for the low ^7Li/^6Li ratio were considered, but none seems satisfactory. Analysis of the Li and K abundances from our survey highlighted two sight lines where depletion effects are prevalent. There is evidence for enhanced depletion toward X Per, since both abundances are lower by a factor of 4 when compared to other sight lines. Moreover, a smaller Li/H abundance is observed toward 20 Aql, but the K/H abundance is normal, suggesting enhanced Li depletion (relative to K) in this direction. Our results suggest that the ^7Li/^6Li ratio has not changed significantly during the last 4.5 billion years and that a ratio ~ 12 represents most gas in the solar neighborhood. In addition, there appears to be a constant stellar contribution of ^7Li, indicating that one or two processes dominate its production in the Galaxy.

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arXiv2002

Ultraviolet Detection of Interstellar 12C17O and the CO Isotopomeric Ratios toward X Persei

We report the detection of fully resolved absorption lines of A-X bands from interstellar 12C17O and 12C18O, through high-resolution spectroscopy of X Per with the Space Telescope Imaging Spectrograph. The first ultraviolet measurement of an interstellar 12C17O column density shows that its isotopomeric ratio is 12C16O/12C17O = 8700 \pm 3600. Simultaneously, the second ultraviolet detection of interstellar 12C18O establishes its isotopomeric ratio at 3000 \pm 600. These ratios are about five times higher than local ambient oxygen isotopic ratios in the ISM. Such severe fractionation of rare species shows that both 12C17O and 12C18O are destroyed by photodissociation, whereas 12C16O avoids destruction through self-shielding. This is to be contrasted with our ratio of 12C16O/13C16O = 73 \pm 12 toward X Per, which is indistinguishable from 12C/13C, the result of a balance between photodissociation of 13C16O and its preferential formation via the isotope exchange reaction between CO and C^+.

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arXiv2002

High-Resolution Measurements of Intersystem Bands of Carbon Monoxide toward X Persei

In an echelle spectrum of X Per acquired with the Space Telescope Imaging Spectrograph we have identified individual rotational lines of 11 triplet-singlet (intersystem) absorption bands of ^12CO. Four bands provide first detections for interstellar clouds. From a comparison with the zeta Oph sight line we find that X Per is obscured by a higher 12CO column density of 1.4 x 10^16 cm-2. Together with the high spectral resolution of 1.3 km s-1, this allows (i) an improved measurement of previously published f-values for seven bands, and (ii) an extraction of the first astrophysical oscillator strengths for d-X (8-0), (9-0), and (10-0), as well as for e-X (12-0). The ^13CO d-X (12-0) band, previously suspected to exist toward zeta Oph, is now readily resolved and modeled. Our derived intersystem f-values for ^12CO include a few mild (leq 34%) disagreements with recent predictions from a perturbation analysis calculated for the interstellar excitation temperature. Overall, the comparison confirms the superiority of employing multiple singlet levels in the calculations of mixing coefficients over previous single-level predictions.

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arXiv2001

Density Variations over Subparsec Scales in Diffuse Molecular Gas

We present high-resolution observations of interstellar CN, CH, CH^{+}, \ion{Ca}{1}, and \ion{Ca}{2} absorption lines toward the multiple star systems HD206267 and HD217035. Substantial variations in CN absorption are observed among three sight lines of HD206267, which are separated by distances of order 10,000 AU; smaller differences are seen for CH, CH^{+}, and \ion{Ca}{1}. Gas densities for individual velocity components are inferred from a chemical model, independent of assumptions about cloud shape. While the component densities can differ by factors of 5.0 between adjacent sightlines, the densities are always less than 5000 cm^{-3}. Calculations show that the derived density contrasts are not sensitive to the temperature or reaction rates used in the chemical model. A large difference in the CH^{+} profiles (a factor of 2 in column density) is seen in the lower density gas toward HD217035.

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arXiv2001

Atomic Physics with the Goddard High Resolution Spectrograph on the Hubble Space Telescope. V. Oscillator Strengths for Neutral Carbon Lines below 1200 Angstrom

We analyzed high resolution spectra of interstellar neutral carbon absorption toward $λ$ Ori, 1 Sco, and $δ$ Sco that were obtained with the Goddard High Resolution Spectrograph on the Hubble Space Telescope. Several multiplets were detected within the wavelength interval 1150 to 1200 A, where most neutral carbon lines have ill-defined oscillator strength; multiplets at longer wavelengths with well-defined atomic parameters were also seen. We extracted accurate column densities and Doppler parameters from lines with precise laboratory-based f-values. These column densities and b-values were used to obtain a self-consistent set of f-values for all the observed neutral carbon lines. For many of the lines with wavelength below 1200 A, the derived f-values differ appreciably from the values quoted in the compilation by Morton (1991). The present set of f-values extends and in some cases supersedes those given in Zsargo et al. (1997), which were based on lower resolution data.

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arXiv2001

Physical Conditions in the Foreground Gas of Reflection Nebulae: NGC 2023, vdB 102, and NGC 7023

High resolution optical spectra of HD 37903 and HD 147009, which illuminate the reflection nebulae, NGC 2023 and vdB 102, were obtained for comparison with our results for HD 200775 and NGC 7023. Ground-based measurements of the molecules, CH, C$_2$, and CN, and the atoms, Na I and K I, were analyzed to extract physical conditions in the foreground cloud. Estimates of the gas density, gas temperature and flux of ultraviolet radiation were derived and were compared with the results from infrared and radio studies of the main molecular cloud. The conditions are similar to those found in studies of diffuse clouds. The foreground material is less dense than the gas in the molecular cloud behind the star(s). The gas temperature was set at 40 K, the temperature determined for the foreground gas in NGC 7023. The flux of ultraviolet radiation was found to be less intense than in the molecular material behind the star(s). The column densities of Na I and K I were reproduced reasonably well when the extinction curve for the specific line of sight was adopted. We obtained NEWSIPS data from the IUE archive for HD 37903 and HD 200775. The ultraviolet data on C I and CO allow extraction of the physical conditions by alternate methods. General agreement among the various diagnostics was found, leading to self-consistent pictures of the foreground photodissociation regions. An Appendix describes checks on the usefulness of IUE NEWSIPS data for interstellar studies. (Abridged)

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arXiv2001

Oscillator Strengths for B-X, C-X, and E-X Transitions in Carbon Monoxide

Band oscillator strengths for electronic transitions in CO were obtained at the Synchrotron Radiation Center of the University of Wisconsin-Madison. Our focus was on transitions that are observed in interstellar spectra with the Far Ultraviolet Spectroscopic Explorer; these transitions are also important in studies of selective isotope photodissociation where fractionation among isotopomers can occur. Absorption from the ground state (X ^1Sigma^+ v'' = 0) to A ^1Pi (v'= 5), B ^1Sigma^+ (v' = 0, 1), C ^1Sigma^+ (v' = 0, 1), and E ^1Pi (v' = 0) was measured. Fits to the A - X (5, 0) band, whose oscillator strength is well known, yielded the necessary column density and excitation temperature. These parameters were used in a least-squares fit of the observed profiles for the transitions of interest to extract their band oscillator strengths. Our oscillator strengths are in excellent agreement with results from recent experiments using a variety of techniques. This agreement provides the basis for a self-consistent set of f-values at far ultraviolet wavelengths for studies of interstellar (and stellar) CO.

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