arXiv subjects

S. R. Giblin

Publications and source records attributed to S. R. Giblin.

At least 19 recordsLinked to original sources

arXiv2026

Demagnetization effect on magnetic noise measurements in spin ice materials

Magnetic noise spectroscopy provides direct access to spontaneous time-dependent magnetization fluctuations in correlated magnetic systems, including spin liquids, spin ices, and spin glasses. Here we investigate how demagnetizing fields shape the magnetic noise spectra measured in spin ice. By combining magnetic noise and ac susceptibility measurements on single-crystal spin ice samples with different sizes and shapes, we show that magnetic noise, like linear response, is strongly renormalized by sample geometry. As a consequence, measured noise spectra do not directly yield the intrinsic fluctuation spectrum, and demagnetization corrections cannot in general be determined from noise data alone. Instead, sample geometry must be treated as a central experimental control parameter for accessing intrinsic dynamics. These results establish the role of boundary conditions in fluctuation spectroscopy and provide a framework for quantitatively comparing noise measurements with microscopic theories of spin dynamics.

cond-mat.str-el↗

arXiv2025

Satisfaction and Violation of the Fluctuation-Dissipation Relation in spin ice materials

We test the fluctuation-dissipation relation (FDR) in spin ice materials Dy$_2$Ti$_2$O$_7$ and Ho$_2$Ti$_2$O$_7$ by measuring both the magnetic noise and the out-of-phase part of the susceptibility and comparing their ratio. We show that it is satisfied at temperatures well into the non-ergodic region below 600 mK, indicating local equilibrium. In both materials, below 400 mK, low frequency violations develop, showing an excess of noise as in spin glasses, with a frequency threshold of 0.1 Hz. New relaxation pathways and aging properties are unveiled in this frequency range in the ac susceptibility. The FDR remains valid at higher frequencies down to 150 mK.

cond-mat.str-el↗

arXiv2025

Magnetoelastic dynamics of the "spin Jahn-Teller" transition in CoTi$_{2}$O$_{5}$

CoTi$_{2}$O$_{5}$ has the paradox that low temperature static magnetic order is incompatible with the crystal structure owing to a mirror plane that exactly frustrates magnetic interactions. Despite no observable structural distortion with diffraction, CoTi$_{2}$O$_{5}$ does magnetically order below $T_{\rm N}$ $\sim$ 25 K with the breaking of spin ground state degeneracy proposed to be a realization of the spin Jahn-Teller effect in analogy to the celebrated orbital Jahn-Teller transition. We apply neutron and Raman spectroscopy to study the dynamics of this transition in CoTi$_{2}$O$_{5}$. We find anomalous acoustics associated with a symmetry breaking strain that characterizes the spin Jahn-Teller transition. Crucially, the energy of this phonon coincides with the energy scale of the magnetic excitations, and has the same symmetry of an optic mode, observed with Raman spectroscopy, which atypically softens in energy with decreasing temperature. Taken together, we propose that the energetics of the spin Jahn-Teller effect in CoTi$_{2}$O$_{5}$ are related to cooperative magnetoelastic fluctuations as opposed to conventional soft critical dynamics which typically drive large measurable static displacements.

cond-mat.str-el↗

arXiv2024

Power spectrum of magnetic relaxation in spin ice: anomalous diffusion in a Coulomb fluid

Magnetization noise measurements on the spin ice Dy${}_2$Ti${}_2$O${}_7$ have revealed a remarkable `pink noise' power spectrum $S(f,T)$ below 4 K, including evidence of magnetic monopole excitations diffusing in a fractal landscape. However, at higher temperatures, the reported values of the anomalous exponent $b(T)$ describing the high frequency tail of $S(f,T)$ are not easy to reconcile with other results in the literature, which generally suggest significantly smaller deviations from the Brownian motion value of $b=2$, that become negligible above $T=20$ K. We accurately estimate $b(T)$ at temperatures between 2~K and 20~K, using a.c. susceptibility measurements that, crucially, stretch up to the relatively high frequency of $f = 10^6$ Hz. We show that previous noise measurements underestimate $b(T)$ and we suggest reasons for this. Our results establish deviations in $b(T)$ from $b=2$ up to about 20 K. However studies on different samples confirms that $b(T)$ is sample dependent: the details of this dependence agree in part, though not completely, with previous studies of the effect of crystal defects on monopole population and diffusion. Our results establish the form of $b(T)$ which characterises the subtle, and evolving, nature of monopole diffusion in the dense Coulomb fluid, a highly correlated state, where several dynamical processes combine. They do not rule out the importance of a fractal landscape picture emerging at lower temperatures where the monopole gas is dilute.

cond-mat.str-el↗

arXiv2024

Magnetic skin effect in Pb(Fe$_{1/2}$Nb$_{1/2}$)O$_3$

Relaxor-ferroelectrics display exceptional dielectric properties resulting from the underlying random dipolar fields induced by strong chemical inhomogeneity. An unusual structural aspect of relaxors is a skin-effect where the near-surface region in single crystals exhibit structures and critical phenomena that differ from the bulk. Relaxors are unique in that this skin effect extends over a macroscopic lengthscale of $\sim$ 100$μ$m whereas usual surface layers only extend over a few unit cells (or $\sim$ nm). We present a muon spectroscopy study of Pb(Fe$_{1/2}$Nb$_{1/2}$)O$_{3}$ (PFN) which displays ferroelectric order, including many relaxor-like dielectric properties such as a frequency broadened dielectric response, and antiferromagnetism with spatially short-range polar correlations and hence can be termed a multiferroic. In terms of the magnetic behavior determined by the Fe$^{3+}$ ($S=5/2$, $L\approx0$) ions, PFN has been characterized as a unique example of a "cluster spin-glass". We use variable momentum muon spectroscopy to study the depth dependence of the slow magnetic relaxations in a large 1 cm$^{3}$ crystal of PFN. Zero-field positive muon spin relaxation is parameterized using a stretched exponential, indicative of a distribution of relaxation rates of the Fe$^{3+}$ spins. This bandwidth of frequencies changes as a function of muon momentum, indicative of a change in the Fe$^{3+}$ relaxation rates as a function of muon implantation depth in our single crystal. Using negative muon elemental analysis, we find small-to-no measurable change in the Fe$^{3+}$/Nb$^{5+}$ concentration with depth implying that chemical concentration alone cannot account for the change in the relaxational dynamics. PFN displays an analogous magnetic skin effect reported to exist in the structural properties of relaxor-ferroelectrics.

cond-mat.str-el↗

arXiv2022

Exploring the phases of 3D artificial spin ice: From Coulomb phase to magnetic monopole crystal

Artificial spin-ices consist of lithographic arrays of single-domain magnetic nanowires organised into frustrated lattices. These geometries are usually two-dimensional, allowing a direct exploration of physics associated with frustration, topology and emergence. Recently, three-dimensional geometries have been realised, in which transport of emergent monopoles can be directly visualised upon the surface. Here we carry out an exploration of the three-dimensional artificial spin-ice phase diagram, whereby dipoles are placed within a diamond-bond lattice geometry. We find a rich phase diagram, consisting of a double-charged monopole crystal, a single-charged monopole crystal and conventional spin-ice with pinch points associated with a Coulomb phase. In our experimental demagnetised systems, broken symmetry forces formation of ferromagnetic stripes upon the surface, a configuration that forbids the formation of the lower energy double-charged monopole crystal. Instead, we observe crystallites of single magnetic charge, superimposed upon an ice background. The crystallites are found to form due to the intricate distribution of magnetic charge around a three-dimensional nanostructured vertex, which locally favours monopole formation. Our work suggests that engineered surface energetics can be used to tune the ground state of experimental three-dimensional ASI systems.

cond-mat.mes-hall↗

arXiv2021

Joint machine learning analysis of muon spectroscopy data from different materials

Machine learning (ML) methods have proved to be a very successful tool in physical sciences, especially when applied to experimental data analysis. Artificial intelligence is particularly good at recognizing patterns in high dimensional data, where it usually outperforms humans. Here we applied a simple ML tool called principal component analysis (PCA) to study data from muon spectroscopy. The measured quantity from this experiment is an asymmetry function, which holds the information about the average intrinsic magnetic field of the sample. A change in the asymmetry function might indicate a phase transition; however, these changes can be very subtle, and existing methods of analyzing the data require knowledge about the specific physics of the material. PCA is an unsupervised ML tool, which means that no assumption about the input data is required, yet we found that it still can be successfully applied to asymmetry curves, and the indications of phase transitions can be recovered. The method was applied to a range of magnetic materials with different underlying physics. We discovered that performing PCA on all those materials simultaneously can have a positive effect on the clarity of phase transition indicators and can also improve the detection of the most important variations of asymmetry functions. For this joint PCA we introduce a simple way to track the contributions from different materials for a more meaningful analysis.

cond-mat.mtrl-sci↗

arXiv2021

Experimental measurement of the isolated magnetic susceptibility

The isolated susceptibility $χ_{\rm I}$ may be defined as a (non-thermodynamic) average over the canonical ensemble, but while it has often been discussed in the literature, it has not been clearly measured. Here, we demonstrate an unambiguous measurement of $χ_{\rm I}$ at avoided nuclear-electronic level crossings in a dilute spin ice system, containing well-separated holmium ions. We show that $χ_{\rm I}$ quantifies the superposition of quasi-classical spin states at these points, and is a direct measure of state concurrence and populations.

quant-ph↗

arXiv2021

Phase Slips and Metastability in Granular Boron-doped Nanocrystalline Diamond Microbridges

A phase slip is a localized disturbance in the coherence of a superconductor allowing an abrupt 2$π$ phase shift. Phase slips are a ubiquitous feature of one-dimensional superconductors and also have an analogue in two-dimensions. Here we present electrical transport measurements on boron-doped nanocrystalline diamond (BNCD) microbridges where, despite their three-dimensional macroscopic geometry, we find clear evidence of phase slippage in both the resistance-temperature and voltage-current characteristics. We attribute this behavior to the unusual microstructure of BNCD. We argue that the columnar crystal structure of BNCD forms an intrinsic Josephson junction array that supports a line of phase slippage across the microbridge. The voltage-state in these bridges is metastable and we demonstrate the ability to switch deterministically between different superconducting states by applying electromagnetic noise pulses. This metastability is remarkably similar to that observed in $δ$-MoN nanowires, but with a vastly greater response voltage.

cond-mat.supr-con↗

arXiv2020

Machine Learning approach to muon spectroscopy analysis

In recent years, Artificial Intelligence techniques have proved to be very successful when applied to problems in physical sciences. Here we apply an unsupervised Machine Learning (ML) algorithm called Principal Component Analysis (PCA) as a tool to analyse the data from muon spectroscopy experiments. Specifically, we apply the ML technique to detect phase transitions in various materials. The measured quantity in muon spectroscopy is an asymmetry function, which may hold information about the distribution of the intrinsic magnetic field in combination with the dynamics of the sample. Sharp changes of shape of asymmetry functions - measured at different temperatures - might indicate a phase transition. Existing methods of processing the muon spectroscopy data are based on regression analysis, but choosing the right fitting function requires knowledge about the underlying physics of the probed material. Conversely, Principal Component Analysis focuses on small differences in the asymmetry curves and works without any prior assumptions about the studied samples. We discovered that the PCA method works well in detecting phase transitions in muon spectroscopy experiments and can serve as an alternative to current analysis, especially if the physics of the studied material are not entirely known. Additionally, we found out that our ML technique seems to work best with large numbers of measurements, regardless of whether the algorithm takes data only for a single material or whether the analysis is performed simultaneously for many materials with different physical properties.

cond-mat.mtrl-sci↗

arXiv2020

Metastable and localized Ising magnetism in $α$-CoV$_{2}$O$_{6}$ magnetization plateaus

$α$-CoV$_{2}$O$_{6}$ consists of $j_{\mathrm{eff}}={1 \over 2}$ Ising spins located on an anisotropic triangular motif with magnetization plateaus in an applied field. We combine neutron diffraction with low temperature magnetization to investigate the magnetic periodicity in the vicinity of these plateaus. We find these steps to be characterized by metastable and spatially short-range ($ξ\sim$ 10 $Å$) magnetic correlations with antiphase boundaries defining a local periodicity of $\langle \hat{T}^{2} \rangle =\ \uparrow \downarrow$ to $\langle \hat{T}^{3} \rangle =\ \uparrow \uparrow \downarrow$, and $\langle \hat{T}^{4} \rangle=\ \uparrow \uparrow \downarrow \downarrow$ or $\uparrow \uparrow \uparrow \downarrow$ spin arrangements. This shows the presence of spatially short range and metastable/hysteretic, commensurate magnetism in Ising magnetization steps.

cond-mat.str-el↗

arXiv2020

Bulk and element specific magnetism of the medium and high entropy Cantor-Wu alloys

Magnetic Compton scattering, x-ray magnetic circular dichroism spectroscopy and bulk magnetometry measurements are performed on a set of medium (NiFeCo and NiFeCoCr) and high (NiFeCoCrPd and NiFeCoCrMn) entropy Cantor-Wu alloys. The bulk spin momentum densities determined by magnetic Compton scattering are remarkably isotropic, and this is a consequence of the smearing of the electronic structure by disorder scattering of the electron quasiparticles. Non-zero x-ray magnetic circular dichroism signals are observed for every element in every alloy indicating differences in the populations of the majority and minority spin states implying finite magnetic moments. When Cr is included in the solid solution, the Cr spin moment is unambiguously antiparallel to the total magnetic moment, while a vanishingly small magnetic moment is observed for Mn, despite calculations indicating a large moment. Some significant discrepancies are observed between the experimental bulk and surface magnetic moments. Despite the lack of quantitative agreement, the element specific surface magnetic moments seem to be qualitatively reasonable.

cond-mat.str-el↗

arXiv2019

Nuclear spin assisted quantum tunnelling of magnetic monopoles in spin ice

Extensive work on single molecule magnets has identified a fundamental mode of relaxation arising from the nuclear-spin assisted quantum tunnelling of nearly independent and quasi-classical magnetic dipoles. Here we show that nuclear-spin assisted quantum tunnelling can also control the dynamics of purely emergent excitations: magnetic monopoles in spin ice. Our low temperature experiments were conducted on canonical spin ice materials with a broad range of nuclear spin values. By measuring the magnetic relaxation, or monopole current, we demonstrate strong evidence that dynamical coupling with the hyperfine fields bring the electronic spins associated with magnetic monopoles to resonance, allowing the monopoles to hop and transport magnetic charge. Our result shows how the coupling of electronic spins with nuclear spins may be used to control the monopole current. It broadens the relevance of the assisted quantum tunnelling mechanism from single molecular spins to emergent excitations in a strongly correlated system.

cond-mat.str-el↗

arXiv2018

Design and development of a low temperature, inductance based high frequency ac susceptometer

We report on the development of an induction based low temperature high frequency ac susceptometer capable of measuring at frequencies up to 3.5 MHz and at temperatures between 2 K and 300 K. Careful balancing of the detection coils and calibration have allowed a sample magnetic moment resolution of $5\times10^{-10} Am^2$ at 1 MHz. We will discuss the design and characterization of the susceptometer, and explain the calibration process. We also include some example measurements on the spin ice material CdEr$_2$S$_4$ and iron oxide based nanoparticles to illustrate functionality.

physics.ins-det↗

arXiv2018

Microscopic effects of Dy-doping in the topological insulator Bi2Te3

Magnetic doping with transition metal ions is the most widely used approach to break timereversal symmetry in a topological insulator, a prerequisite for unlocking the TIs exotic potential. Recently, we reported the doping of Bi2Te3 thin films with rare earth ions, which, owing to their large magnetic moments, promise commensurately large magnetic gap openings in the topological surface states. However, only when doping with Dy has a sizable gap been observed in angle-resolved photoemission spectroscopy, which persists up to room-temperature. Although disorder alone could be ruled out as a cause of the topological phase transition, a fundamental understanding of the magnetic and electronic properties of Dy:Bi2Te3 remained elusive. Here, we present an X-ray magnetic circular dichroism, polarized neutron reflectometry, muon spin rotation, and resonant photoemission study of the microscopic magnetic and electronic properties. We find that the films are not simply paramagnetic but that instead the observed behavior can be well explained by the assumption of slowly fluctuating, inhomogeneous magnetic patches with increasing volume fraction as the temperature decreases. At liquid helium temperatures, a large effective magnetization can be easily introduced by the application of moderate magnetic fields, implying that this material is very suitable for proximity coupling to an underlying ferromagnetic insulator or in a heterostructure with transition metal-doped layers. However, the introduction of some charge carriers by the dopants cannot be excluded at least in these highly doped samples. Nevertheless, we find that the magnetic order is not mediated via the conduction channel in these rare earth doped samples and therefore magnetic order and carrier concentration are expected to be independently controllable. This is not generally the case for transition metal doped topological insulators.

cond-mat.mtrl-sci↗

arXiv2018

Pauling entropy, metastability and equilibrium in Dy$_2$Ti$_2$O$_7$ spin ice

Determining the fate of the Pauling entropy in the classical spin ice material Dy$_2$Ti$_2$O$_7$ with respect to the third law of thermodynamics has become an important test case for understanding the existence and stability of ice-rule states in general. The standard model of spin ice - the dipolar spin ice model - predicts an ordering transition at $T\approx 0.15$ K, but recent experiments by Pomaranski $et\ al.$ suggest an entropy recovery over long time scales at temperatures as high as $0.5$ K, much too high to be compatible with theory. Using neutron scattering and specific heat measurements at low temperatures and with long time scales ($0.35$ K$/10^6$ s and $0.5$ K$/10^5$ s respectively) on several isotopically enriched samples we find no evidence of a reduction of ice-rule correlations or spin entropy. High-resolution simulations of the neutron structure factor show that the spin correlations remain well described by the dipolar spin ice model at all temperatures. Further, by careful consideration of hyperfine contributions, we conclude that the original entropy measurements of Ramirez $et\ al.$ are, after all, essentially correct: the short-time relaxation method used in that study gives a reasonably accurate estimate of the equilibrium spin ice entropy due to a cancellation of contributions.

cond-mat.str-el↗

arXiv2018

Observation of a superconducting glass state in granular superconducting diamond

The magnetic field dependence of the superconductivity in nanocrystalline boron doped diamond thin films is reported. Evidence of a glass state in the phase diagram is presented, as demonstrated by electrical resistance and magnetic relaxation measurements. The position of the phase boundary in the H-T plane is determined from resistance data by detailed fitting to zero-dimensional fluctuation conductivity theory. This allows determination of the boundary between resistive and non-resistive behavior to be made with greater precision than the standard ad hoc onset/midpoint/offset criterion.

cond-mat.supr-con↗

arXiv2017

Fluctuation spectroscopy as a probe of granular superconducting diamond films

We present resistance versus temperature data for a series of boron-doped nanocrystalline diamond films whose grain size is varied by changing the film thickness. Upon extracting the fluctuation conductivity near to the critical temperature we observe three distinct scaling regions -- 3D intragrain, quasi-0D, and 3D intergrain -- in confirmation of the prediction of Lerner, Varlamov and Vinokur. The location of the dimensional crossovers between these scaling regions allows us to determine the tunnelling energy and the Thouless energy for each film. This is a demonstration of the use of \emph{fluctuation spectroscopy} to determine the properties of a superconducting granular system.

cond-mat.supr-con↗