arXiv subjects

S. R. Krishnakumar

Publications and source records attributed to S. R. Krishnakumar.

10 recordsLinked to original sources

arXiv2023

Spin-Flop Ordering from Frustrated Ferro- and Antiferromagnetic Interactions: A Combined Theoretical and Experimental Study of a $\mathrm{Mn}/\mathrm{Fe}(100)$ Monolayer

The occurrence of a noncollinear magnetic structure at a Mn monolayer grown epitaxially on Fe(100) is predicted theoretically, using spinor density-functional theory, and observed experimentally, using x-ray magnetic circular dichroism (XMCD) and linear dichroism (XMLD) spectroscopies. The combined use of XMCD and XMLD at the Mn-absorption edge allows us to assess the existence of ferromagnetic and antiferromagnetic order at the interface, and also to determine the moment orientations with element specificity. The experimental results thus obtained are in excellent agreement with the magnetic structure determined theoretically.

cond-mat.mtrl-sci↗

arXiv2007

Absence of local magnetic moments in Ru and Rh impurities and clusters on Ag(100) and Pt(997)

The magnetism of quench-condensed Ru and Rh impurities and metal films on Ag(100) and Pt(997) has been studied using x-ray magnetic circular dichroism. In the coverage range between 0.22 ML and 2.0 ML no dichroic signal was detected at the M3,2 absorption edges of Ru on Ag(100) at a temperature of 5 K in the presence of an applied magnetic field. The same was found for coverages between 0.12 ML and 0.5 ML of Rh on Ag(100) and Pt(997). It is concluded that the magnetic moments of single impurities, small clusters of various shape and monolayers of the 4d metals are below the detection limit of 0.04 muB per atom. These results provide an unambiguous determination of the local magnetic moment of Ru and Rh deposited on nonmagnetic transition-metal surfaces, which are in contrast with theoretical predictions.

cond-mat.other↗

arXiv2006

A microspectroscopic study of the electronic homogeneity of ordered and disordered Sr2FeMoO6

Besides a drastic reduction in saturation magnetization of disordered Sr2FeMoO6 compared to highly ordered samples, magnetizations as a function of the temperature for different disordered samples may also show qualitatively different behaviors. We investigate the origin of such diversity by performing spatially resolved photoemission spectroscopy on various disordered samples. Our results establish that extensive electronic inhomogeneity, arising most probably from an underlying chemical inhomogeneity in disordered samples is responsible for the observed magnetic inhomogeneity. It is further pointed out that these inhomogeneities are connected with composition fluctuations of the type Sr2Fe1+xMo1-xO6 with Fe-rich (x>0) and Mo-rich (x<0) regions.

cond-mat.mtrl-sci↗

arXiv2004

Direct observation of electronic domains in manganites by spatially resolved spectroscopy

We use a spatially resolved, direct spectroscopic probe for electronic structure with an additional sensitivity to chemical compositions to investigate high-quality single crystal samples of La_{1/4}Pr_{3/8}Ca_{3/8}MnO_{3}, establishing the formation of distinct insulating domains embedded in the metallic host at low temperatures. These domains are found to be at least an order of magnitude larger in size compared to previous estimates and exhibit memory effects on temperature cycling in the absence of any perceptible chemical inhomogeneity, suggesting long-range strains as the probable origin.

cond-mat.mtrl-sci↗

arXiv2003

X-ray photoemission study of NiS_{2-x}Se_x (x = 0.0 - 1.2)

Electronic structure of NiS_{2-x}Se_x system has been investigated for various compositions (x) using x-ray photoemission spectroscopy. An analysis of the core level as well as the valence band spectra of NiS_2 in conjunction with many-body cluster calculations provides a quantitative description of the electronic structure of this compound. With increasing Se content, the on-site Coulomb correlation strength (U) does not change, while the band width W of the system increases, driving the system from a covalent insulating state to a pd-metallic state.

cond-mat.str-el↗

arXiv2003

Metal-insulator Crossover Behavior at the Surface of NiS_2

We have performed a detailed high-resolution electron spectroscopic investigation of NiS$_2$ and related Se-substituted compounds NiS$_{2-x}$Se$_x$, which are known to be gapped insulators in the bulk at all temperatures. A large spectral weight at the Fermi energy of the room temperature spectrum, in conjunction with the extreme surface sensitivity of the experimental probe, however, suggests that the surface layer is metallic at 300 K. Interestingly, the evolution of the spectral function with decreasing temperature is characterized by a continuous depletion of the single-particle spectral weight at the Fermi energy and the development of a gap-like structure below a characteristic temperature, providing evidence for a metal-insulator crossover behavior at the surfaces of NiS$_2$ and of related compounds. These results provide a consistent description of the unusual transport properties observed in these systems.

cond-mat.str-el↗

arXiv2002

Electronic structure of Millerite NiS

We investigate the electronic structure of Nickel sulphide (NiS) in the millerite phase using electron spectroscopic measurements and band structure as well as model Hamiltonian calculations. While band structure calculations are found to be relatively more successful in describing the experimental valence band spectrum of this highly conducting phase compared to the hexagonal phase of NiS, cluster calculations including electron correlation effects are found to be necessary for the description of certain features in the experimental spectra, indicating importance of correlation effects even in a highly metallic system. The electronic parameter strengths obtained from these calculations confirm that the millerite NiS is a highly covalent pd-metal. The comparative study of hexagonal and millerite forms of NiS, provides the information concerning the evolution of the spectral function in a pd-metal as a function of covalency.

cond-mat.str-el↗

arXiv2000

Electronic structure of NiS_{1-x}Se_x

We investigate the electronic structure of the metallic NiS$_{1-x}$Se$_x$ system using various electron spectroscopic techniques. The band structure results do not describe the details of the spectral features in the experimental spectrum, even for this paramagnetic metallic phase. However, a parameterized many-body multi-band model is found to be successful in describing the Ni~2$p$ core level and valence band, within the same model. The asymmetric line shape as well as the weak intensity feature in the Ni~2$p$ core level spectrum has been ascribed to extrinsic loss processes in the system. The presence of satellite features in the valence band spectrum shows the existence of the lower Hubbard band, deep inside the $pd$ metallic regime, consistent with the predictions of the dynamical mean field theory.

cond-mat.str-el↗

arXiv1998

Disorder effects in electronic structure of substituted transition metal compounds

Investigating LaNi(1-x)M(x)O3 (M = Mn and Fe), we identify a characteristic evolution of the spectral function with increasing disorder in presence of strong interaction effects across the metal-insulator transition. We discuss these results vis-a-vis existing theories of electronic structure in simultaneous presence of disorder and interaction.

cond-mat.str-el↗

arXiv1998

Electronic structure of NiS$_{1-x}$Se$_x$ across the phase transition

We report very highly resolved photoemission spectra of NiS(1-x)Se(x) across the so-called metal-insulator transition as a function of temperature as well as composition. The present results convincingly demonstrate that the low temperature, antiferromagnetic phase is metallic, with a reduced density of states at E$_F$. This decrease is possibly due to the opening of gaps along specific directions in the Brillouin zone caused by the antiferromagnetic ordering.

cond-mat.str-el↗