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S. Rohlf

Publications and source records attributed to S. Rohlf.

4 recordsLinked to original sources

First-order phase transition driven by competing charge-order fluctuations in 1T'-TaTe$_{2}$

First-order phase transitions, characterized by a discontinuous change in the order parameter, are intriguing phenomena in condensed matter physics. However, the underlying, material-specific, microscopic mechanisms often remain unclear. Here, we unveil a high-temperature incommensurate charge-order precursor with the wave vector $\mathbf{q}^* = (0, \frac{1}{4}+\delta, \frac{1}{2})$ in the 1T' phase of TaTe$_2$, which competes with fluctuating high-temperature Ta trimer bonding states at $\mathbf{q}_\mathrm{CO} =(0, \frac{1}{3}, 0)$. The precursor state follows the temperature dependence of the hidden incommensurability of the $\textit{quasi}$-1D nested Fermi surface. In contrast, the low-temperature commensurate charge order at $\mathbf{q}_\mathrm{CO}$, characterized by a charge disproportionation of the inequivalent Ta sites, appears to be driven by local chemical bonding. Dynamical lattice calculations identify an imaginary optical mode at $\mathbf{q}^*$, involving an in-plane vibration of the Ta atoms forming a chain-like structure that renormalizes below $T_\mathrm{CO}$. Our experimental and theoretical observations suggest that the controversial first-order phase transition, as captured by phenomenological Ginzburg-Landau theory, results from the competition between two order parameters: one involving Fermi surface nesting and the other involving local chemical bonding.

cond-mat.str-el

Oxide Fermi liquid universality revealed by electron spectroscopy

We present a combined soft x-ray and high-resolution vacuum-ultraviolet angle-resolved photoemission spectroscopy study of the electron-overdoped cuprate Pr$_{1.3-x}$La$_{0.7}$Ce$_{x}$CuO$_4$ (PLCCO). Demonstration of its highly two-dimensional band structure enabled precise determination of the in-plane self-energy dominated by electron-electron scattering. Through analysis of this self-energy and the Fermi-liquid cut-off energy scale, we find -- in contrast to hole-doped cuprates -- a momentum isotropic and comparatively weak electron correlation in PLCCO. Yet, the self-energies extracted from multiple oxide systems combine to demonstrate a logarithmic divergent relation between the quasiparticle scattering rate and mass. This constitutes a spectroscopic version of the Kadowaki-Woods relation with an important merit -- the demonstration of Fermi liquid quasiparticle lifetime and mass being set by a single energy scale.

cond-mat.str-el

Momentum-space signatures of Berry flux monopoles in a Weyl semimetal

Since the early days of Dirac flux quantization, magnetic monopoles have been sought after as a potential corollary of quantized electric charge. As opposed to magnetic monopoles embedded into the theory of electromagnetism, Weyl crystals exhibit Berry flux monopoles in reciprocal parameter space. As a function of crystal momentum, such monopoles locate at the degeneracy point of the Weyl cone. Here, we report momentum-resolved spectroscopic signatures of Berry flux monopoles in TaAs as a paradigmatic Weyl semimetal. We have probed the orbital and spin angular momentum (OAM and SAM) of the Weyl-fermion states by angle-resolved photoemission spectroscopy at bulk-sensitive soft X-ray energies (SX-ARPES) combined with photoelectron spin detection and circular dichroism. Supported by first-principles calculations, our measurements image characteristics of a topologically non-trivial winding of the OAM at the Weyl nodes and unveil a chirality-dependent SAM of the Weyl bands. Our results experimentally visualize the non-trivial momentum-space topology in a Weyl semimetal, promising to have profound implications for the study of quantum-geometric effects in solids.

cond-mat.mtrl-sci

Surface states and Rashba-type spin polarization in antiferromagnetic MnBi$_2$Te$_4$

The layered van der Waals antiferromagnet MnBi$_2$Te$_4$ has been predicted to combine the band ordering of archetypical topological insulators such as Bi$_2$Te$_3$ with the magnetism of Mn, making this material a viable candidate for the realization of various magnetic topological states. We have systematically investigated the surface electronic structure of MnBi$_2$Te$_4$(0001) single crystals by use of spin- and angle-resolved photoelectron spectroscopy experiments. In line with theoretical predictions, the results reveal a surface state in the bulk band gap and they provide evidence for the influence of exchange interaction and spin-orbit coupling on the surface electronic structure.

cond-mat.str-el