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S. Speller

Publications and source records attributed to S. Speller.

11 recordsLinked to original sources

Evaluating the performance of ionic liquid coatings for mitigation of spacecraft surface charges

To reduce the impact of charging effects on satellites, cheap and lightweight conductive coatings are desirable. We mimic space-like charging environments in ultra-high vacuum (UHV) chambers during deposition of charges via the electron beam of a scanning electron microscope (SEM). We use the charge induced signatures in SEM images of a thin ionic liquid (IL) film on insulating surfaces such as glass, to assess the general performance of such coatings. In order to get a reference structure in SEM, the samples were structured by nanosphere lithography and coated with IL. The IL film (we choose BMP DCA, due to its beneficial physical properties) was applied ex situ and a thickness of 10 to 30 nm was determined by reflectometry. Such an IL film is stable under vacuum conditions. It would also only lead to additional mass of below 20 mg/m$^2$. At about 5 A/m$^2 \approx 3\cdot10^{19}$ e/(s$\cdot$m$^2$), a typical sample charging rate in SEM, imaging is possible with no noticeable contrast changes over many hours; this electron current density is already 6 orders of magnitudes higher than "worst case geosynchronous environments" of $3\cdot10^{-6}$ A/m$^2$. Measurements of the surface potential are used for further insights in the reaction of IL films to the electron beam of a SEM. Participating mechanisms such as polarization or reorientation will are discussed.

cond-mat.mes-hall

The nanomorphology of cell surfaces of adhered osteoblasts

Functionality of living cells is inherently linked to subunits with dimensions on the nanoscale. In case of osteoblasts the cell surface plays a particularly important role for adhesion and spreading which are crucial properties with regard to bone implants. Here we present a comprehensive characterization of the 3D nanomorphology of living as well as fixed osteoblastic cells using scanning ion conductance microscopy (SICM) which is a nanoprobing method largely avoiding forces. Dynamic ruffles are observed, manifesting themselves in characteristic membrane protrusions. They contribute to the overall surface corrugation which we systematically study by introducing the relative 3D excess area as a function of projected adhesion area. A clear anticorrelation is found upon analysis of ~40 different cells on glass as well as on amine covered surfaces. At the rim of lamellipodia characteristic edge heights between 100 nm and ~300 nm are observed. Power spectral densities of membrane fluctuations show frequency-dependent decay exponents in excess of -2 on living osteoblasts. We discuss the capability of apical membrane features and fluctuation dynamics in aiding assessment of adhesion and migration properties on a single-cell basis.

physics.bio-ph

Correlative Microscopy of Morphology and Luminescence of Cu porphyrin aggregates

Transfer of energy and information through molecule aggregates requires as one important building block anisotropic, cable-like structures. Knowledge on the spatial correlation of luminescence and morphology represents a prerequisite in the understanding of internal processes and will be important for architecting suitable landscapes. In this context we study the morphology, fluorescence and phosphorescence of molecule aggregate structures on surfaces in a spatially correlative way. We consider as two morphologies, lengthy strands and isotropic islands. It turns out that phosphorescence is quite strong compared to fluorescence and the spatial variation of the observed intensities is largely in line with the amount of dye. However in proportion, the strands exhibit more fluorescence than the isotropic islands suggesting weaker non-radiative channels. The ratio fluorescence to phosphorescence appears to be correlated with the degree of aggregation or internal order. The heights at which luminescence saturates is explained in the context of attenuation and emission multireflection, inside the dye. This is supported by correlative photoemission electron microscopy which is more sensitive to the surface region. The lengthy structures exhibit a pronounced polarization dependence of the luminescence with a relative dichroism up to about 60%, revealing substantial perpendicular orientation preference of the molecules with respect to the substrate and parallel with respect to the strands.

cond-mat.mes-hall

Evolution of the Fermi surface of the nematic superconductors FeSe1-xSx

We investigate the evolution of the Fermi surfaces and electronic interactions across the nematic phase transition in single crystals of FeSe1-xSx using Shubnikov-de Haas oscillations in high magnetic fields up to 45 tesla in the low temperature regime. The unusually small and strongly elongated Fermi surface of FeSe increases monotonically with chemical pressure, x, due to the suppression of the in-plane anisotropy except for the smallest orbit which suffers a Lifshitz-like transition once nematicity disappears. Even outside the nematic phase the Fermi surface continues to increase, in stark contrast to the reconstructed Fermi surface detected in FeSe under applied external pressure. We detect signatures of orbital-dependent quasiparticle mass renomalization suppressed for those orbits with dominant dxz=yz character, but unusually enhanced for those orbits with dominant dxy character. The lack of enhanced superconductivity outside the nematic phase in FeSe1-xSx suggest that nematicity may not play the essential role in enhancing Tc in these systems.

cond-mat.supr-con

Aluminium Nanowires: Influence of Work Hardening on Conductance Histograms

Conductance histograms of work-hardened Al show a series up to 11 equidistant peaks with a period of 1.15 +/- 0.02 of the quantum conductance unit G_0 = 2e^2/h. Assuming the peaks originate from atomic discreteness, this agrees with the value of 1.16 G_0 per atom obtained in numerical calculations by Hasmy et al.

cond-mat.mes-hall

Atomic size oscillations in conductance histograms for gold nanowires and the influence of work hardening

Nanowires of different nature have been shown to self-assemble as a function of stress at the contact between two macroscopic metallic leads. Here we demonstrate for gold wires that the balance between various metastable nanowire configurations is influenced by the microstructure of the starting materials and we discover a new set of periodic structures, which we interpret as due to the atomic discreteness of the contact size for the three principal crystal orientations.

cond-mat.mes-hall

Conductance of Pd-H nanojunctions

Results of an experimental study of palladium nanojunctions in hydrogen environment are presented. Two new hydrogen-related atomic configurations are found, which have a conductances of ~0.5 and ~1 quantum unit (2e^2/h). Phonon spectrum measurements demonstrate that these configurations are situated between electrodes containing dissolved hydrogen. The crucial differences compared to the previously studied Pt-H_2 junctions, and the possible microscopic realizations of the new configurations in palladium-hydrogen atomic-sized contacts are discussed.

cond-mat.mes-hall

Hydrogen-assisted distortion of gold nanowires

In this paper the influence of adsorbed hydrogen on the behavior of gold nanojunctions is investigated. It is found, that the hydrogen environment has a strong effect on the conductance of atomic-sized gold junctions, which is markedly reflected by the growth of an additional peak in the conductance histogram at 0.5 quantum unit, 2e^2/h. The statistical analysis of the conductance traces implies that the new peak arises due to the hydrogen-assisted distortion of atomic gold chains.

cond-mat.mtrl-sci

Quantum interference structures in the conductance plateaus of gold nanojunctions

The conductance of breaking metallic nanojunctions shows plateaus alternated with sudden jumps, corresponding to the stretching of stable atomic configurations and atomic rearrangements, respectively. We investigate the structure of the conductance plateaus both by measuring the voltage dependence of the plateaus' slope on individual junctions and by a detailed statistical analysis on a large amount of contacts. Though the atomic discreteness of the junction plays a fundamental role in the evolution of the conductance, we find that the fine structure of the conductance plateaus is determined by quantum interference phenomenon to a great extent.

cond-mat.mes-hall

Transition from tunneling to direct contact in tungsten nanojunctions

We apply the mechanically controllable break junctions technique to investigate the transition from tunneling to direct contact in tungsten. This transition is quite different from that of other metals and is determined by the local electronic properties of the tungsten surface and the relief of the electrodes at the point of their closest proximity. The conductance traces show a rich variety of patterns from the avalanche-like jump to a mesoscopic contact to the completely smooth transition between direct contact and tunneling. Due to the occasional absence of an adhesive jump the conductance of the contact can be continuously monitored at ultra-small electrode separations. The conductance histograms of tungsten are either featureless or show two distinct peaks related to the sequential opening of spatially separated groups of conductance channels. The role of surface states of tungsten and their contribution to the junction conductance at sub-Angstrom electrode separations are discussed.

cond-mat.mes-hall

Driving forces for Ag-induced periodic faceting of vicinal Cu(111)

Adsorption of submonolayer amounts of Ag on vicinal Cu(111) induces periodic faceting. The equilibrium structure is characterized by Ag-covered facets that alternate with clean Cu stripes. In the atomic scale, the driving force is the matching of Ag(111)-like packed rows with Cu(111) terraces underneath. This determines the preference for the facet orientation and the evolution of different phases as a function of coverage. Both Cu and Ag stripe widths can be varied smoothly in the 3-30 nm range by tuning Ag coverage, allowing to test theoretical predictions of elastic theories.

cond-mat.mtrl-sci