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S. Thoms

Publications and source records attributed to S. Thoms.

5 recordsLinked to original sources

Formation of brine channels in sea-ice

Liquid salty micro-channels (brine) between growing ice platelets in sea ice are an important habitat for $CO_2$ - binding microalgaea with great impact on polar ecosystems. The structure formation of ice platelets is microscopically described and a phase field model is developed. The pattern formation during solidification of the two-dimensional interstitial liquid is considered by two coupled order parameters, the tetrahedricity as structure of ice and the salinity. The coupling and time-evolution of these order parameters are described by a consistent set of three model parameters. They determine the velocity of the freezing process and the structure formation, the phase diagram, the super-cooling and super-heating region, and the specific heat. The model is used to calculate the short-time frozen micro-structures. The obtained morphological structure is compared with the vertical brine pore space obtained from Xray computed tomography.

nlin.PS

Dynamical mechanism of antifreeze proteins to prevent ice growth

The fascinating ability of algae, insects and fishes to survive at temperatures below normal freezing is realized by antifreeze proteins (AFPs). These are surface-active molecules and interact with the diffusive water/ice interface thus preventing complete solidification. We propose a new dynamical mechanism on how these proteins inhibit the freezing of water. We apply a Ginzburg-Landau type approach to describe the phase separation in the two-component system (ice, AFP). The free energy density involves two fields: one for the ice phase with a low AFP concentration, and one for liquid water with a high AFP concentration. The time evolution of the ice reveals microstructures resulting from phase separation in the presence of AFPs. We observed a faster clustering of pre-ice structure connected to a locking of grain size by the action of AFP, which is an essentially dynamical process. The adsorption of additional water molecules is inhibited and the further growth of ice grains stopped. The interfacial energy between ice and water is lowered allowing the AFPs to form smaller critical ice nuclei. Similar to a hysteresis in magnetic materials we observe a thermodynamic hysteresis leading to a nonlinear density dependence of the freezing point depression in agreement with the experiments.

physics.bio-ph

Stability of 3D Cubic Fixed Point in Two-Coupling-Constant ϕ^4-Theory

For an anisotropic euclidean $ϕ^4$-theory with two interactions $[u (\sum_{i=1^M ϕ_i^2)^2+v \sum_{i=1}^M ϕ_i^4]$ the $β$-functions are calculated from five-loop perturbation expansions in $d=4-\varepsilon$ dimensions, using the knowledge of the large-order behavior and Borel transformations. For $\varepsilon=1$, an infrared stable cubic fixed point for $M \geq 3$ is found, implying that the critical exponents in the magnetic phase transition of real crystals are of the cubic universality class. There were previous indications of the stability based either on lower-loop expansions or on less reliable Pad\'{e approximations, but only the evidence presented in this work seems to be sufficently convincing to draw this conclusion.

quant-ph

Resummation of anisotropic quartic oscillator. Crossover from anisotropic to isotropic large-order behavior

We present an approximative calculation of the ground-state energy for the anisotropic anharmonic oscillator Using an instanton solution of the isotropic action $δ= 0$, we obtain the imaginary part of the ground-state energy for small negative $g$ as a series expansion in the anisotropy parameter $δ$. From this, the large-order behavior of the $g$-expansions accompanying each power of $δ$ are obtained by means of a dispersion relation in $g$. These $g$-expansions are summed by a Borel transformation, yielding an approximation to the ground-state energy for the region near the isotropic limit. This approximation is found to be excellent in a rather wide region of $δ$ around $δ= 0$. Special attention is devoted to the immediate vicinity of the isotropic point. Using a simple model integral we show that the large-order behavior of an $δ$-dependent series expansion in $g$ undergoes a crossover from an isotropic to an anisotropic regime as the order $k$ of the expansion coefficients passes the value $k_{{\rm cross} \sim 1/ |δ|$.

quant-ph

Large-Order Behavior of Two-coupling Constant $ϕ^4$-Theory with Cubic Anisotropy

For the anisotropic $[u (\sum_{i=1^N ϕ_i^2)^2+v \sum_{i=1^N ϕ_i^4]$-theory with {$N=2,3$} we calculate the imaginary parts of the renormalization-group functions in the form of a series expansion in $v$, i.e., around the isotropic case. Dimensional regularization is used to evaluate the fluctuation determinants for the isotropic instanton near the space dimension 4. The vertex functions in the presence of instantons are renormalized with the help of a nonperturbative procedure introduced for the simple $g{ϕ^4$-theory by McKane et al.

hep-th