arXiv subjects

S. Viti

Publications and source records attributed to S. Viti.

At least 19 recordsLinked to original sources

arXiv2026

Sulphur within the extreme environment of the central molecular zone of NGC 253: a chemical modelling approach

Sulphur(S)-bearing species are ubiquitous in Galactic star-forming regions, from dense cold cores to outflows and shocks linked to protostellar activity. A recent observational study investigated the origin of S-bearing species towards the central molecular zone (CMZ) of NGC 253 and showed that Sulphur emission is linked to the presence of forming stars. However, more extensive modelling of these observations are required to determine the exact origin of the Sulphur emission (e.g. shock or thermal evaporation). Using chemical modelling, we examine how S-bearing species behave in the more extreme environment of the starburst galaxy NGC 253, and more generally, how they can help us improve our understanding of the emission linked with the dense star-forming gas in external galaxies. We use the gas-grain time-dependent chemical model UCLCHEM to model static warm clouds and C-type shocks under the physical conditions found in the CMZ of NGC 253. We compare observed abundances and abundance ratios to the modelled output abundances. We found that depending on the model type (shock, post-shock or static cloud), the highest abundance reached by the S-bearing species varies significantly. Hence, we can use their observed abundances of S-bearing species to distinguish between shocked, post-shocked or a quiescent (non-shocked) gas. We also confirm observationally-based conclusions on their emission origins, including in the case of unresolved emission. Comparing GMC-scale observations with chemical modelling is a powerful method to investigate and constrain the origin of molecular emission towards extragalactic star-forming regions. Sulphur-bearing species are useful to distinguish between different types of ISM components (shocked/post-shocked/quiescent gas).

astro-ph.GA↗

arXiv2026

Chemical modelling of interstellar MgS

The detection of magnesium sulphide (MgS) and sodium sulphide (NaS) towards the Galactic Center molecular cloud G+0.693 constitutes the first detection of metal sulphides in the interstellar medium (ISM). However, there is scarce information about the key reactions (either in the gas phase or on grains) involved in their formation. In this paper, we model the chemistry of MgS simulating the passage of a low-velocity shock to recover the abundances recently measured towards G+0.693. Through this chemical modelling, we analyse the dominant reactions involved in the formation and destruction of this molecule, their associated chemical time-scales, and the depletion factor needed to recover the observed abundances. We build the initial chemical network of MgS by using SiS as a proxy for this metal sulphide, and we investigate the exothermicity of these and additional, uniquely proposed reactions through quantum chemical computations. We run a three-phase model (initial translucent cloud, cloud collapse phase and shock interaction stage) that mimics the evolution and physical conditions of G+0.693. Our results show that a depletion factor of 1000 is required for elemental Mg to recover the observed abundances of MgS. This implies that potentially more than 99.9% of Mg is locked in dust grains. The dominant reaction leading to the formation of MgS is the neutral-neutral reaction between MgH and S in the gas phase. This work represents the first analysis of the chemistry of the metal-sulphide MgS and suggests that Mg is largely incorporated into dust grains, most likely in the form of silicates. However, additional laboratory and/or theoretical studies of the key MgS formation reactions are essential to obtain more reliable constraints. Future missions, such as PRIMA, will provide insights into the amount of metal-sulphides locked into interstellar dust grains.

astro-ph.GA↗

arXiv2026

FAUST XXXI. Grain properties and variability of three sources in GSS 30

To advance our understanding of dust properties in class 0/I young stellar objects, it is crucial to resolve their structures at multiple wavelengths and investigate how grain growth and environmental effects shape their spectral properties. We present 0.5 arcsec resolution ALMA observations of the GSS 30 complex at 1.2-3.0 mm from the FAUST large programme, achieving a linear resolution of 69 au. We analyse the dust continuum emission and perform modelling to constrain dust properties and disk structures. For IRS3, the spectral index increases radially from 2.0 at the centre to 2.5 at the disk edge, while decreasing to 1.6-1.8 along the outflow direction. The asymmetric low-alpha region towards the northeastern blueshifted lobe may result from cold outer envelope dust obscuring warmer inner regions. SED fitting suggests maximum grain sizes of tens of microns and a dust mass of 650-1510 M_earth. IRS1 is associated with an extended north-eastern structure, which may represent an outflow-disk complex, a trailing structure linked to a circumbinary disk, or a gas streamer accreting onto IRS1. The central IRS1 shows alpha < 0.8, consistent with marginally optically thick free-free emission. IRS2 displays brightness variations over 420 s, and multi-epoch comparison suggests a flare lasting tens of minutes, likely caused by magnetic activity in the protostar. Our results highlight the importance of environmental effects, including dust obscuration and streamer structures, in shaping the observed properties of young disks, and reveal millimetre variability associated with possible protostellar magnetic flares.

astro-ph.SR↗

arXiv2026

Class I CH3OH Maser Emission from Bar-Driven Inflow Colliding with the Central Molecular Zone

The Central Molecular Zone of the Milky Way is shaped by the interplay of bar-driven inflows, shocks, and star formation. At Galactic longitude l=1.3, gas inflowing along the near-side dust lane has been proposed to interact with the CMZ boundary and overshoot above the Galactic plane, making this a key site to investigate how large-scale gas dynamics regulates star formation. We aim to investigate the presence of Class I methanol maser emission in this transitional region, testing whether large-scale gas interactions in the CMZ can trigger widespread maser activity via star formation or shocks. We conducted a dedicated search for the 36.2 and 44.1 GHz Class I CH3OH maser lines, along with the 48.4 GHz thermal transition, using the Yebes 40m telescope. We complemented these data with archival data from the Herschel-HiGAL survey and the CHIMPS2 survey to explore links between masers, shocks, and star formation. We detect widespread 36.2 GHz maser emission and two candidate 44.1 GHz masers in a region extending several parsecs. The brightest maser has an isotropic luminosity 0.9x10^-3 L_Sun, placing it among the most luminous Galactic Class I masers. Thermal CH3OH and SiO emission extend over mapped area of 24 pc, with both species showing enhanced fractional abundances. CO position-velocity analysis further shows that the masers are associated with an extended velocity feature at VLSR~100 km/s. We conclude that the observed masers are primarily associated with shock-processed gas in a kinematically complex bar-CMZ interface region. Large-scale gas interactions are likely to play an important role in producing the maser emission, although a subset of the masers may also be linked to shocks driven by local star-formation activity. This region therefore provides a promising Galactic analogue of shock-dominated Class I CH3OH maser environments observed in nuclear regions of barred galaxies.

astro-ph.GA↗

arXiv2026

CHEMOUT: CHEMical complexity in star-forming regions of the OUTer Galaxy. V. Chemical composition gradients as a function of the galactocentric radius

The outer Galaxy is characterized by a lower metallicity than regions near the Sun, suggesting differences in the formation and survival of molecules in star-forming regions. To understand chemical evolution across the Milky Way, deriving molecular abundances in star-forming regions in the outer Galaxy is essential for refining models of sub-Solar metallicity environments. We analyzed IRAM 30 m observations at 3 and 2 mm toward 35 sources at Galactocentric distances of 9$-$24 kpc, within the "CHEMical complexity in star-forming regions of the outer Galaxy" (CHEMOUT) project. We focused on species with the highest detection rates (i.e., HCN, HCO$^+$, c-C$_3$H$_2$, H$^{13}$CO$^+$, HCO, SO) and searched for trends in column densities, abundances, and line widths with Galactocentric distance. Abundances for H$_2$CO and CH$_3$OH were updated using H$_2$ column densities from new NIKA2 dust maps. Fractional abundances relative to H$_2$ of most species (HCN, HCO$^+$, c-C$_3$H$_2$, HCO, H$_2$CO, CH$_3$OH) scale at most with the elemental carbon abundance ([C/H]) up to $\sim$24 kpc. SO shows a steeper gradient than sulfur abundance ([S/H]), while H$^{13}$CO$^+$ shows a shallower gradient than [$^{13}$C/H]. Gas turbulence, inferred from line widths, decreases with Galactocentric distance, suggesting a more quiescent environment in the outer Galaxy with respect to the inner Galaxy. In the outer Galaxy, the formation efficiency of most molecules, following the parent element availability, is comparable or higher (e.g., for H$^{13}$CO$^+$) than in the local Galaxy, whereas SO forms less efficiently. These results have significant implications for chemical models of the outermost star-forming regions and for understanding molecule formation under lower metallicity conditions.

astro-ph.GA↗

arXiv2026

The GUAPOS project. VI: the chemical inventory of shocked gas

The study of the chemical composition of star-forming regions is key to understanding the chemical ingredients available during the formation of planetary systems. Because the chemical inventory of interstellar dust grains in prestellar phases might be altered by protostellar warming, an alternative to inferring the chemical composition of the grains might be to observe regions that are affected by shocks associated with molecular outflows. These shocks can desorb the molecules and might produce less chemical processing because the timescales are shorter. We present a detailed study of the chemical reservoir of a shocked region located in the G31.41+0.31 protocluster using data from the G31.41+0.31 Unbiased ALMA sPectral Observational Survey (GUAPOS). We report the detection of 30 molecular species (plus 18 isotopologs). We compared the molecular ratios in the shocked region with those derived toward the hot core of G31.41+0.31. They are poorly correlated, with the exception of N-bearing species. Our results confirm observationally that a different level of chemical alteration is present in hot cores and in shocks. While the former likely alter the molecular ratios by thermal processing during longer timescales, the latter might represent freshly desorbed material that constitutes a better proxy of the composition of the ice mantle. The similarity of the molecular ratios of the N-bearing species in the G31.41+0.31 shock and the hot core suggests that these species are predominantly formed at early evolutionary stages. Interestingly, the abundances in the G31.41+0.31 shock are better correlated with other shock-dominated regions (two protostellar outflows and a molecular cloud in the Galactic center). This suggests that gas-phase chemistry after shock-induced ejection from grains is negligible and that the composition of the ice mantle is similar regardless of the Galactic environment.

astro-ph.GA↗

arXiv2025

Chemical complexity in star formation induced by stellar feedback: cores shock-formed by the supernova remnant W44

Low-velocity shocks from Supernova Remnants (SNRs) may set the physical and chemical conditions of star formation in molecular clouds. Recent evidence suggests that the Sun might have formed through this process. However, the chemical conditions of shock-induced star forming region remain poorly constrained. We study the chemical complexity of a shock-impacted clump, with potential to yield star formation, named the Clump, and located at the interface between the SNR W44 and the infrared dark cloud G034.77-00.55. We test whether the Clump has chemical properties consistent with those observed in star forming regions unaffected by SNRs. We use high-sensitivity, broad spectral surveys at 3 and 7 mm obtained with the 30m antenna at IIRAM and the 40 m YEBES antenna, to identify D-bearing species and complex organic molecules (COMs) toward the Clump. For all species, we estimate molecular abundances and compare them with those observed across star forming regions at different evolutionary stages and masses, as well as comets. We detect multiple deuterated molecules (DCO+, DNC, DCN, CH2DOH) and COMs (CH3OH, CH3CHO, CH3CCH, CH3CN, CH3SH) with excitation temperatures of 5-13 K. To the best of our knowledge, this is the first detection of COMs toward a site of SNR-cloud interaction. The derived D/H ratios (0.01-0.04) and COM abundances are consistent with those reported toward typical low-mass starless cores and comparable to cometary values. The overall level of chemical complexity is relatively low, in line with an early evolutionary stage. We suggest that the Clump is a early stage shock-induced low-mass star forming region, not yet protostellar. We speculate that SNR shocks may set the physical and chemical conditions to form stars. The resulting chemical budget may be preserved along the formation process of a planetary system, being finally incorporated into planetesimals and cometesimals.

astro-ph.GA↗

arXiv2025

PRUSSIC III -- ALMA and NOEMA survey of dense gas in high-redshift star-forming galaxies

Characterising the relationship between dense gas and star formation is critical for understanding the assembly of galaxies throughout cosmic history. However, due to the faintness of standard dense-gas tracers - HCN, HCO+, and HNC - dense gas in high-redshift galaxies remains largely unexplored. We present ALMA and NOEMA observations targeting HCN/HCO+/HNC (3-2) and (4-3) emission lines in eleven (mostly) gravitationally lensed dusty star-forming galaxies (DSFGs) at redshift z = 1.6--3.2. We detect at least one line in 10 out of 11 galaxies. Altogether, we detect 34 dense-gas transitions, more than quadrupling the number of extant high-redshift detections. Additionally, in two targets, we detect lower-abundance CO isotopologues 13^CO and C^18O, as well as CN emission. We derive excitation coefficients for HCN, HCO+ and HNC in DSFGs, finding them to be systematically higher than those in nearby luminous infrared galaxies. Assuming a canonical dense-mass conversion factor (alpha_HCN = 10), we find that DSFGs have shorter dense- gas depletion times (median 23 Myr) than nearby galaxies (~60 Myr), with a star-forming efficiency per free-fall time of 1-2%, a factor of a few higher than in local galaxies. We find a wide range of dense-gas fractions, with HCN/CO ratios ranging between 0.01 and 0.15. Finally, we put the first constraints on the redshift evolution of the cosmic dense-gas density, which increases by a factor of 7+/-4 between z = 0 and z = 2.5, consistent with the evolution of the cosmic molecular-gas density.

astro-ph.GA↗

arXiv2025

High resolution mapping of molecular tori with ALMA

Recent high resolution mapping of the circum-nuclear regions of Active Galactic Nuclei (AGN) has revealed the existence of geometrically thin nuclear disks, in general randomly oriented with respect to their galaxy hosts. These molecular tori have typical radii of 10~pc, and contain a few 10$^7$ M$_\odot$ of H$_2$, with H$_2$ column densities between 10$^{23}$ and 10$^{25}$ cm$^{-2}$. We mapped two of the most massive of these molecular tori with higher resolution, in order to unveil their morphology and kinematics, their possible warp and clumpiness, and derive their stability and life-time. We used the highest resolution possible with ALMA (16~km baseline) in Band 7, taking into account for mapping CO(3-2) and HCO$^+$(4-3) the compromise between sensitivity and resolution. New features are discovered at the high resolution, obtained with a beam of 0.015\arcsec, equivalent to $\sim$ 1~pc scale, at their $\sim$ 15~Mpc distance. The molecular torus in NGC~613 appears like a ring, depleted in molecular gas near the center. The depletion region is displaced by 3~pc toward the NW from the AGN position, meaning some $m=1$ asymmetry in the torus. The molecular torus in NGC~1672 has a different position angle from previous lower-resolution observations, and is edge-on, revealing a geometrically very thin torus (axis ratio 6.5 to 10), with a clear warp. This confirms that the classical model of a simple geometrically thick dusty torus is challenged by high resolution observations. The nuclear disks appear clumpy, and slightly lopsided. The molecular outflow in NGC~613 is now resolved out. Well inside the sphere of influence of the black holes (BH), we are now able to determine more accurately their mass, for those Seyfert spiral galaxies, in a region of the M-sigma relation where the scatter is maximum.

astro-ph.GA↗

arXiv2025

Investigating solid-state CH3OH formation with chemical modelling

Context. Recent Monte Carlo simulations and laboratory studies of interstellar ices have proposed an alternative pathway involving the radical-molecule H-atom abstraction reaction in the overall mechanism of methanol (CH3OH) formation in dark molecular clouds. Aims. A computational study was conducted to investigate the contribution of the radical-molecule H-atom abstraction route in CH3OH formation in interstellar ices, both in non-shocked and shocked environments, and to examine how the physical conditions of the interstellar medium (ISM) affect the overall CH3OH synthesis pathway. Methods. A set of chemical models were ran using the gas-grain chemical code UCLCHEM to systematically explore methanol synthesis in various physical scenarios, including non-shock and low- and high-velocity C-shocks. Results. This work demonstrated for the first time that, under non-shock and shocked-influenced environments, the primary reaction leading to the formation of methanol in the inner layers of interstellar ices is indeed the radical-molecule H-atom abstraction route. However, such route is dependent on the gas kinetic temperature (Tk), gas volume density (nH2 ), velocity of the C-shock wave (vshock), and cosmic ray ionisation rate (ζ). Furthermore, gaseous formaldehyde may trace C-type shocks and serve to differentiate methanol formation pathways in low-velocity C-shocked environments, as its abundance varies more significantly than that of CH3OH with the inclusion of the H-atom abstraction reaction in UCLCHEM. The H2CO/CH3OH ratio thus represents a potential diagnostic tool for this purpose.

astro-ph.GA↗

arXiv2025

CO Depletion in Infrared Dark Clouds

Infrared Dark Clouds (IRDCs) are cold, dense structures representative of the initial conditions of star formation. Many studies of IRDCs employ CO to investigate cloud dynamics. However, CO can be highly depleted from the gas phase in IRDCs, impacting its fidelity as tracer. CO depletion is also of great interest in astrochemistry, since CO ice in dust grain mantles provides the raw material for forming complex organic molecules. We study CO depletion toward four IRDCs to investigate how it correlates with volume density and dust temperature, calculated from Herschel images. We use 13CO(1-0) and (2-1) maps to measure CO depletion factor, $f_D$, across IRDCs G23.46-00.53, G24.49-00.70, G24.94-00.15, and G25.16-00.28. We also consider a normalized CO depletion factor, f_D', which takes a value of unity, i.e., no depletion, in the outer, lower density, warmer regions. We then investigate the dependence of f_D and f_D' on gas density, $n_H$ and dust temperature, $T_{dust}$. We find CO depletion rises as density increases, reaching maximum values of f_D'$\sim$10 in regions with $n_H>3\times10^5\:{cm}^{-3}$, although with significant scatter at a given density. We find a tighter, less scattered relation of f_D' with temperature, rising rapidly for temperatures <18 K. We propose a functional form $f_D^\prime = \:{exp}(T_0/[T_{dust}-T_1])$ with $T_0\simeq4\:$K and $T_1\simeq12\:$K to reproduce this behaviour. We conclude that CO is heavily depleted from the gas phase in cold, dense regions of IRDCs. Thus CO depletion can lead to underestimation of total cloud masses based on CO line fluxes by factors up to 5. These results indicate a dominant role for thermal desorption in setting near equilibrium abundances of gas phase CO in IRDCs, providing important constraints for both astrochemical models and the chemodynamical history of gas during the early stages of star formation.

astro-ph.GA↗

arXiv2025

Low-velocity large-scale shocks in the infrared dark cloud G035.39-00.33: bubble-driven cloud-cloud collisions

Low-velocity large-scale shocks impacting on the ISM may efficiently shape molecular clouds and trigger star formation within them. These shocks, both driven by galactic bubbles and/or cloud-cloud collisions, leave specific signatures in the gas morphology and kinematics. Observational studies of such signatures are crucial to investigate if and how shocks affect the clouds formation process and trigger their future star formation. We have analysed the shocked and dense gas tracers SiO(2-1) and H13CO+(1-0) emission toward the IRDC G035.39-00.33, using new, larger-scale maps obtained with the 30m telescope at the Instituto de Radioastronomìa Millimétrica. We find that the dense gas is organised into a northern and a southern filament having different velocities and tilted orientation with respect to each other. The two filaments are spatially separated yet connected by a faint bridge feature also seen in a position-velocity diagram extracted across the cloud. This bridge-feature, typical of cloud-cloud collisions, also coincides with a very spectrally narrow SiO-traced emission. The northern filament is suggested to be interacting with the nearby supernova remnant G035.6-0.4. Toward the southern filament, we also report the presence of a parsec-scale, spectrally narrow SiO emission likely driven by the interaction between this filament and a nearby expanding shell. The shell is visible in the 1.3 GHz and 610 MHz continuum images and our preliminary analysis suggests it may be the relic of a supernova remnant. We conclude that the two filaments represent the densest part of two colliding clouds, pushed toward each other by nearby Supernova Remnants. We speculate that this cloud-cloud collision driven by stellar feedback may have assembled the infrared dark cloud. We also evaluate the possibility that star formation may have been triggered within G035.39-00.33 by the collision.

astro-ph.GA↗

arXiv2025

High resolution ALMA observations of H$_2$S in LIRGS (Dense gas and shocks in outflows and CNDs)

Molecular gas plays a critical role in regulating star formation and nuclear activity in galaxies. Sulphur bearing molecules, such as H2S, are sensitive to the physical and chemical environments in which they reside and are potential tracers of shocked, dense gas in galactic outflows and active galactic nuclei (AGN). We aim to investigate the origin of H2S emission and its relation to dense gas and outflow activity in the central regions of nearby infrared luminous galaxies. We present ALMA Band 5 observations of the ortho H2S 1(1,0) 1(0,1) transition in three nearby galaxies: NGC 1377, NGC 4418, and NGC 1266. We perform radiative transfer modelling using RADEX to constrain the physical conditions of the H2S emitting gas and compare the results to ancillary CO and continuum data. We detect compact H2S emission in all three galaxies, arising from regions smaller than approximately 150 parsecs. The H2S spectral profiles exhibit broad line wings, suggesting an association with outflowing or shocked gas. In NGC 4418, H2S also appears to be tracing gas that is counterrotating. A peculiar red shifted emission feature may correspond to inflowing gas, or possibly a slanted outflow. RADEX modelling indicates that the H2S emitting gas has high densities (molecular hydrogen density greater than 10^7 cm^-3) and moderately warm temperatures (between 40 and 200 Kelvin). The derived densities exceed those inferred from CO observations, implying that H2S traces denser regions of the interstellar medium.

astro-ph.GA↗

arXiv2025

FAUST XXVI. The dust opacity spectral indices of protostellar envelopes bridge the gap between interstellar medium and disks

The sub-millimetre dust opacity spectral index is a critical observable to constrain dust properties, such as the maximum grain size of an observed dust population. It has been widely measured at galactic scales and down to protoplanetary disks. However, because of observational and analytical challenges, quite a gap exists in measuring dust properties in the envelopes that feed newborn protostars and their disks. To fill this gap, we use sensitive dust continuum emission data at 1.2 and 3.1 mm from the ALMA FAUST Large Program and constrain the dust opacity millimetre spectral index around a sample of protostars. Our high-resolution data, along with a more refined methodology with respect to past efforts, allow us to disentangle disk and envelope contributions in the uv-plane, and thus measure spectral indices for the envelopes uncontaminated by the optically thick emission of the inner regions. First, we find that the young disks are small and optically thick. Secondly, we measure the dust opacity spectral index at envelope scales for n=11 sources: the beta of n=9 sources had never been constrained in the literature. We effectively double the number of sources for which the dust opacity spectral index beta has been measured at these scales. Third, combining the available literature measurements with our own (total n=18), we show how envelope spectral indices distribute between ISM-like and disk-like values, bridging the gap in the inferred dust evolution. Finally, we statistically confirm a significant correlation between beta and the mass of protostellar envelopes, previously suggested in the literature. Our findings indicate that the dust optical properties smoothly vary from the ISM, through envelopes and all the way down to disks. Multi-wavelength surveys are needed to further this study and make more general claims on dust evolution in its pathway from cloud to disks.

astro-ph.SR↗

arXiv2025

Investigating the chemical link between H$_2$CO and CH$_3$OH within the CMZ of NGC 253

Formaldehyde (H$_2$CO) and methanol (CH$_3$OH) have served as traditional tracers of the star formation process for decades. Studies of the environments which produce these species, though, have pointed to significant differences in the physical environments within which each molecule resides. In this paper we investigate the physical and chemical conditions which give rise to formaldehyde and methanol emission in the nearby starburst galaxy NGC 253. We employ high spatial (1.$''$6 or $\sim28$ pc) and spectral ($\sim10$ km/s) imaging of the NGC 253 central molecular zone (CMZ) from the ALCHEMI Large Program to constrain radiative transfer models of the dense gas volume density, and temperature, molecular species column density, and source filling factor within eight giant molecular clouds (GMCs). We also measure the relative abundances of the two nuclear spin isomers of CH$_3$OH to investigate its formation history. The physical and chemical conditions derived clearly indicate that H$_2$CO and CH$_3$OH originate from distinct physical environments. H$_2$CO traces low volume density and high kinetic temperatures, while CH$_3$OH traces high volume density and low kinetic temperatures. The H$_2$CO abundances are constant, though poorly constrained, within the eight NGC 253 GMCs analyzed, while the CH$_3$OH abundance shows a radial gradient from low to high values within the NGC 253 CMZ. Our findings highlight the complex chemical and physical differentiation of CH$_3$OH and H$_2$CO in the starburst environment of NGC 253. Methanol formation appears to be influenced by warm, dynamic processes rather than cold cloud chemistry, while formaldehyde primarily forms via gas-phase reactions. These results challenge the assumption of a direct chemical link between CH$_3$OH and H$_2$CO and underscores the impact of starburst-driven shocks, turbulence, and cosmic rays on molecular gas chemistry.

astro-ph.GA↗

arXiv2025

Decoding the molecular torus of NGC 1068: Insights into its structure and kinematics from high-resolution ALMA observations

We dissect the kinematics and morphology of the molecular gas within the near-nuclear region of NGC 1068 to understand the mechanisms in the central AGN that might be fueling it, and the impact of its energy output on the surrounding molecular gas. We present high angular and spectral resolution ALMA observations of the HCO$^+$4->3 and CO 3->2 molecular lines in the near-nuclear region of the prototype Seyfert 2 galaxy NGC 1068. The spatial resolution (1.1~pc) is almost two times better than that of previous works studying the same molecular lines at the same transitions and is the highest resolution achievable with ALMA at these frequencies. Our analysis focuses on moment maps, position-velocity (PV) diagrams, and spectra obtained at the position of the nuclear continuum source, along with a simple kinematic model developed using the 3DBarolo software. Our observations reveal significant asymmetry between the eastern and western sides of the nuclear disc in terms of morphology, velocity, and line intensity. The broad lines seen in the inner 2 pc could be accounted for by either beam smearing or highly turbulent gas in this region. Outside this radius the mean velocities drop to $\pm$30 km/s, which cannot be explained by asymmetric drift. We find low velocity connections extending to 13 pc suggesting interactions with larger scale structures. The CO/HCO$^+$ line ratio at the nucleus reported here are extremely low compared to values in the literature of the same galaxy at lower spatial resolutions.

astro-ph.GA↗

arXiv2025

Complex Organic Molecules towards the central molecular zone of NGC 253

Interstellar complex organic molecules (iCOMs) may have a link to prebiotic species, key building blocks for life. In Galactic star-forming (SF) regions, spatial variations of iCOMs emission could reflect the source physical structure or different chemical formation pathways. Investigating iCOMs in extragalactic SF regions may thus provide crucial information about these regions. As an active extragalactic SF region, the central molecular zone (CMZ) of the nearby galaxy NGC 253 provides an ideal template for studying iCOMs under more extreme conditions. We aim to investigate the emission of a few selected iCOMs and understand if a difference between the iCOMs could reflect on the source's chemical or physical structure. Using the high angular resolution ($\sim 27$ pc) observations from the ALCHEMI ALMA large program, we imaged the emission of selected iCOMs and precursors; CH$_3$CHO, C$_2$H$_5$OH, NH$_2$CHO, CH$_2$NH, and CH$_3$NH$_2$. We estimated the iCOMs gas temperatures and column densities using a rotational diagram analysis, and by performing a non-LTE analysis for CH$_2$NH.The iCOM emission concentrates mostly towards the inner part of the CMZ of NGC 253 and can be reproduced with two gas components. Different emission processes can explain iCOM emission towards the CMZ of NGC 253: at Giant Molecular Cloud (GMC) scales ($\sim 27$ pc), the iCOMs could trace large-scale shocks whilst at smaller scales (few pc), both shock and heating processes linked with ongoing star formation may be involved. Using column density correlation trends and known formation pathways, we find that more than one formation path could be involved to explain the iCOM emission. Finally, we found chemical differences between the GMCs, such as a decrease of abundance for the N-bearing species towards one of the GMCs or different excitation conditions for NH$_2$CHO and CH$_3$CHO towards two of the GMCs.

astro-ph.GA↗

arXiv2025

A multi-scale investigation into the diagnostic potential of the HCN/HCO$^+$ ratio for AGN and starburst activity in nearby galaxies

(Abridged) The identification of AGN and SB regions in galaxies is crucial for understanding the role of various physical processes in galaxy evolution. Molecular line ratios, such as the HCN/HCO+ ratio, have been proposed as potential tracers of these distinct environments. This paper aims to assess the reliability of the HCN/HCO+ ratio, from J = 1-0 to J = 4-3 transitions, as a diagnostic tool for differentiating AGN and SB activity across a diverse sample of nearby galaxies. We focus on evaluating the effect of spatial resolution on the robustness of these ratios and investigate the underlying physical conditions that drive observed variations. We compile observations of HCN and HCO+ lines across multiple J transitions from various sources, covering different galaxy types, including Seyferts, starbursts, and (ultra-)luminous infrared galaxies (U/LIRGs). The observations span spatial scales from cloud-sized regions to kiloparsec scales. We analyse the behaviour of these ratios at varying resolutions and employ non-LTE radiative transfer models to infer the physical conditions that drive the observed ratios. We find that the HCN/HCO+ ratio from higher J transitions can differentiate between AGN and SB activity when observed at high spatial resolution. This distinction occurs around unity. However, at lower resolutions, contamination from multiple emission sources and beam averaging effects destroy these distinctions. Modelling suggests that elevated HCN/HCO+ ratios in AGN-dominated regions are largely driven by an enhancement in HCN abundance relative to HCO+, likely due to high-temperature chemistry or increased excitation. Our study confirms that the HCN/HCO+ ratio, particularly of higher J transitions, can be a reliable tracer of AGN versus SB activity if observations are conducted at sufficiently high spatial resolution.

astro-ph.GA↗