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S. Wüster

Publications and source records attributed to S. Wüster.

At least 19 recordsLinked to original sources

A measure for adiabatic contributions to quantum transitions

We construct a measure for the adiabatic contribution to quantum transitions in an arbitrary basis, tackling the generic complex case where dynamics is only partially adiabatic, simultaneously populates several eigenstates and transitions between non-eigenstates are of key interest. Our measure is designed to distinguish transitions between basis states that occur due to the adiabatic change of the underlying populated eigenstates from transitions that occur due to beating between several such eigenstates. We demonstrate that the measure can be applied to material or molecular simulations using time-dependent density functional theory, allowing to quantify the relative importance of adiabaticity and thus nuclear motion, for example, in charge or energy transfer.

quant-ph

Excitons guided by polaritons

We show that an exciton on a discrete chain of sites can be guided by effective measurements induced by an ambient, non-equilibrium medium that is synchronised to the exciton transport. For experimental verification, we propose a hybrid cold atom platform, carrying the exciton as electronic excitation on a chain of atoms, which are surrounded by a slow light medium supporting polaritons. The chain is coupled to the medium through long-range Rydberg interactions. Despite the guiding mechanism being incoherent, the exciton pulse can be coherently transported with high fidelity. The implementation requires careful alignment of chain and medium but then no further time-dependent control. Our concept can be ported to other exciton and polariton carrying media or devices, and will enable switches and waveguides operating with the two quasi particles involved, as we demonstrate.

quant-ph

Solitary waves explore the quantum-to-classical transition

It is an open fundamental question how the classical appearance of our environment arises from the underlying quantum many-body theory. We propose that phenomena involved in the quantum-to-classical transition can be probed in collisions of bright solitary waves in Bose- Einstein condensates, where thousands of atoms form a large compound object at ultra cold temperatures. For the experimentally most relevant quasi-1D regime, where integrability is broken through effective three-body interactions, we find that ensembles of solitary waves exhibit complex interplay between phase coherence and entanglement generation in beyond mean-field simulations using the truncated Wigner method: An initial state of two solitons with a well defined relative phase looses that phase coherence in the ensemble, with its single particle two-mode density matrix exhibiting similar dynamics as a decohering two mode superposition. This apparent decoherence is a prerequisite for the formation of entangled superpositions of different atom numbers in a subsequent soliton collision. The necessity for the solitons to first decohere is explained based on the underlying phase-space of the quintic mean field equation. We show elsewhere that superpositions of different atom numbers later further evolve into spatially entangled solitons. Loss of ensemble phase coherence followed by system internal entanglement generation appear in an unusual order in this closed system, compared to a typical open quantum system.

quant-ph

Dynamics of atoms within atoms

Recent experiments with Bose-Einstein condensates have entered a regime in which thousands of ground-state condensate atoms fill the Rydberg-electron orbit. After the excitation of a single atom into a highly excited Rydberg state, scattering off the Rydberg electron sets ground-state atoms into motion, such that one can study the quantum-many-body dynamics of atoms moving within the Rydberg atom. Here we study this many-body dynamics using Gross-Pitaevskii and truncated Wigner theory. Our simulations focus in particular on the scenario of multiple sequential Rydberg excitations on the same Rubidium condensate which has become the standard tool to observe quantum impurity dynamics in Rydberg experiments. We investigate to what extent such experiments can be sensitive to details in the electron-atom interaction potential, such as the rapid radial modulation of the Rydberg molecular potential, or p-wave shape resonance. We demonstrate that both effects are crucial for the initial condensate response within the Rydberg orbit, but become less relevant for the density waves emerging outside the Rydberg excitation region at later times. Finally we explore the local dynamics of condensate heating. We find that it provides only minor corrections to the mean-field dynamics.

quant-ph

Imaging the interface of a qubit and its quantum-many-body environment

Decoherence affects all quantum systems, natural or artificial, and is the primary obstacle impeding quantum technologies. We show theoretically that for a Rydberg qubit in a Bose condensed environment, experiments can image the system-environment interface that is central for decoherence. High precision absorption images of the condensed environment will be able to capture transient signals that show the real time build up of a mesoscopic entangled state in the environment. This is possible before decoherence sources other than the condensate itself can kick in, since qubit decoherence time-scales can be tuned from the order of nanoseconds to microseconds by choice of the excited Rydberg principal quantum number ν. Imaging the interface will allow detailed explorations of open quantum system concepts and may offer guidance for coherence protection in challenging scenarios with non-Markovian environments.

quant-ph

Excitation Transport in Molecular Aggregates with thermal motion

Molecular aggregates can under certain conditions transport electronic excitation energy over large distances due to dipole-dipole interactions. Here, we explore to what extent thermal motion of entire monomers can guide or enhance this excitation transport. The motion induces changes of aggregate geometry and hence modifies exciton states. Under certain conditions, excitation energy can thus be transported by the aggregate adiabatically, following a certain exciton eigenstate. While such transport is always slower than direct migration through dipole-dipole interactions, we show that transport through motion can yield higher transport efficiencies in the presence of on-site energy disorder than the static counterpart. For this we consider two simple models of molecular motion: (i) longitudinal vibrations of the monomers along the aggregation direction within their inter-molecular binding potential and (ii) torsional motion of planar monomers in a plane orthogonal to the aggregation direction. The parameters and potential shapes used are relevant to dye-molecule aggregates. We employ a quantum-classical method, in which molecules move through simplified classical molecular dynamics, while the excitation transport is treated quantum mechanically using Schrödinger's equation. For both models we find parameter regimes in which the motion enhances excitation transport, however these are more realistic for the torsional scenario, due to the limited motional range in a typical Morse type inter-molecular potential. We finally show that the transport enhancement can be linked to adiabatic quantum dynamics. This transport enhancement through adiabatic motion appears a useful resource to combat exciton trapping by disorder.

physics.chem-ph

Tayloring Bose-Einstein condensate environments for a Rydberg impurity

Experiments have demonstrated that atoms excited to specific Rydberg states within Bose-Einstein condensates cause significant excitation of phonons. If the Rydberg atom is brought into an electronic superposition state, this coupling to phonons leads to decoherence. We provide the theoretical basis for the treatment of the latter. To this end, we evaluate Rydberg-phonon coupling coefficients using a combination of analytical and numerical techniques. From these coefficients, we calculate bath correlation functions, spectral densities and re-organisation energies. All these quantify the influence of the environment and form essential inputs for follow up open quantum system techniques. We find that the amplitude of bath correlations scales like the power law $ν^{-5}$ with the principal quantum number $ν$, while re-organisation energies scale like $ν^{-3}$, reflecting the extreme tunability of Rydberg atomic properties. Rydberg impurities in condensates thus constitute a non-trivial open-quantum system with exceptionally controlled system, coupling and environmental Hamiltonians.

cond-mat.quant-gas

Transport on flexible Rydberg aggregates using circular states

Assemblies of interacting Rydberg atoms show promise for the quantum simulation of transport phenomena, quantum chemistry and condensed matter systems. Such schemes are typically limited by the finite lifetime of Rydberg states. Circular Rydberg states have the longest lifetimes among Rydberg states but lack the energetic isolation in the spectrum characteristic of low angular momentum states. The latter is required to obtain simple transport models with few electronic states per atom. Simple models can however even be realized with circular states, by exploiting dipole-dipole selection rules or external fields. We show here that this approach can be particularly fruitful for scenarios where quantum transport is coupled to atomic motion, in adiabatic excitation transport or quantum simulations of electron-phonon coupling in light harvesting. Additionally, we explore practical limitations of flexible Rydberg aggregates with circular states and to which extent interactions among circular Rydberg atoms can be described using classical models.

physics.atom-ph

Rydberg Aggregates

We review Rydberg aggregates, assemblies of a few Rydberg atoms exhibiting energy transport through collective eigenstates, considering isolated atoms or assemblies embedded within clouds of cold ground-state atoms. We classify Rydberg aggregates, and provide an overview of their possible applications as quantum simulators for phenomena from chemical or biological physics. Our main focus is on flexible Rydberg aggregates, in which atomic motion is an essential feature. In these, simultaneous control over Rydberg-Rydberg interactions, external trapping and electronic energies, allows Born-Oppenheimer surfaces for the motion of the entire aggregate to be taylored as desired. This is illustrated with theory proposals towards the demonstration of joint motion and excitation transport, conical intersections and non-adiabatic effects. Additional flexibility for quantum simulations is enabled by the use of dressed dipole-dipole interactions or the embedding of the aggregate in a cold gas or BEC environment. Finally we provide some guidance regarding the parameter regimes that are most suitable for the realization of either static or flexible Rydberg aggregates based on Li or Rb atoms. The current status of experimental progress towards enabling Rydberg aggregates is also reviewed.

physics.atom-ph

Exciton induced directed motion of unconstrained atoms in an ultracold gas

We demonstrate that through localised Rydberg excitation in a three-dimensional cold atom cloud atomic motion can be rendered directed and nearly confined to a plane, without spatial constraints for the motion of individual atoms. This enables creation and observation of non-adiabatic electronic Rydberg dynamics in atoms accelerated by dipole-dipole interactions under natural conditions. Using the full $l=0,1$ $m=0,\pm1$ angular momentum state space, our simulations show that conical intersection crossings are clearly evident, both in atomic position information and excited state spectra of the Rydberg system. Hence, flexible Rydberg aggregates suggest themselves for probing quantum chemical effects in experiments on length scales much inflated as compared to a standard molecular situation.

physics.atom-ph

On-chip quantum tomography of mechanical nano-scale oscillators with guided Rydberg atoms

Nano-mechanical oscillators as well as Rydberg-atomic waveguides hosted on micro-fabricated chip surfaces hold promise to become pillars of future quantum technologies. In a hybrid platform with both, we show that beams of Rydberg atoms in waveguides can quantum-coherently interrogate and manipulate nanomechanical elements, allowing full quantum state tomography. Central to the tomography are quantum non-demolition measurements using the Rydberg atoms as probes. Quantum coherent displacement of the oscillator is also made possible, by driving the atoms with external fields while they interact with the oscillator. We numerically demonstrate the feasibility of this fully integrated on-chip control and read-out suite for quantum nano-mechanics, taking into account noise and error sources.

quant-ph

Quantum dynamics of long-range interacting systems using the positive-P and gauge-P representations

We provide the necessary framework for carrying out stochastic positive-P and gauge-P simulations of bosonic systems with long range interactions. In these approaches, the quantum evolution is sampled by trajectories in phase space, allowing calculation of correlations without truncation of the Hilbert space or other approximations to the quantum state. The main drawback is that the simulation time is limited by noise arising from interactions. We show that the long-range character of these interactions does not further increase the limitations of these methods, in contrast to the situation for alternatives such as the density matrix renormalisation group. Furthermore, stochastic gauge techniques can also successfully extend simulation times in the long-range-interaction case, by making using of parameters that affect the noise properties of trajectories, without affecting physical observables. We derive essential results that significantly aid the use of these methods: estimates of the available simulation time, optimized stochastic gauges, a general form of the characteristic stochastic variance and adaptations for very large systems. Testing the performance of particular drift and diffusion gauges for nonlocal interactions, we find that, for small to medium systems, drift gauges are beneficial, whereas for sufficiently large systems, it is optimal to use only a diffusion gauge. The methods are illustrated with direct numerical simulations of interaction quenches in extended Bose-Hubbard lattice systems and the excitation of Rydberg states in a Bose-Einstein condensate, also without the need for the typical frozen gas approximation. We demonstrate that gauges can indeed lengthen the useful simulation time.

quant-ph

Non-Hermitian matter wave mixing in Bose Einstein condensates: dissipation induced amplification

We investigate the nonlinear scattering dynamics in interacting atomic Bose-Einstein condensates under non-Hermitian dissipative conditions. We show that by carefully engineering a momentum-dependent atomic loss profile one can achieve matter-wave amplification through four wave mixing in a one-dimensional quasi free-space setup - a process that is forbidden in the counterpart Hermitian systems due to energy mismatch. Additionally, we show that similar effects lead to rich nonlinear dynamics in higher dimensions. Finally, we propose a physical realization for selectively tailoring the momentum-dependent atomic dissipation. Our strategy is based on a two step process: (i) exciting atoms to narrow Rydberg- or metastable excited states, and (ii) introducing loss through recoil; all while leaving the bulk condensate intact due to protection by quantum interference.

quant-ph

Non-Markovian Dynamics in Ultracold Rydberg Aggregates

We propose a setup of an open quantum system in which the environment can be tuned such that either Markovian or non-Markovian system dynamics can be achieved. The implementation uses ultracold Rydberg atoms, relying on their strong long-range interactions. Our suggestion extends the features available for quantum simulators of molecular systems employing Rydberg aggregates and presents a new test bench for fundamental studies of the classification of system-environment interactions and the resulting system dynamics in open quantum systems.

quant-ph

Orthogonal flexible Rydberg aggregates

We study the link between atomic motion and exciton transport in flexible Rydberg aggregates, assemblies of highly excited light alkali atoms, for which motion due to dipole-dipole interaction becomes relevant. In two one-dimensional atom chains crossing at a right angle adiabatic exciton transport is affected by a conical intersection of excitonic energy surfaces, which induces controllable non-adiabatic effects. A joint exciton/motion pulse that is initially governed by a single energy surface is coherently split into two modes after crossing the intersection. The modes induce strongly different atomic motion, leading to clear signatures of non-adiabatic effects in atomic density profiles. We have shown how this scenario can be exploited as an exciton switch, controlling direction and coherence properties of the joint pulse on the second of the chains [K.~Leonhardt {\it et al.}, Phys.~Rev.~Lett. {\bf 113} 223001 (2014)]. In this article we discuss the underlying complex dynamics in detail, characterise the switch and derive our isotropic interaction model from a realistic anisotropic one with the addition of a magnetic bias field.

physics.atom-ph

Coupling of a nano mechanical oscillator and an atomic three-level medium

We theoretically investigate the coupling of an ultracold three-level atomic gas and a nano-mechanical mirror via classical electromagnetic radiation. The radiation pressure on the mirror is modulated by absorption of a probe light field, caused by the atoms which are electromagnetically rendered nearly transparent, allowing the gas to affect the mirror. In turn, the mirror can affect the gas as its vibrations generate opto-mechanical sidebands in the control field. We show that the sidebands cause modulations of the probe intensity at the mirror frequency, which can be enhanced near atomic resonances. Through the radiation pressure from the probe beam onto the mirror, this results in resonant driving of the mirror. Controllable by the two photon detuning, the phase relation of the driving to the mirror motion decides upon amplification or damping of mirror vibrations. This permits direct phase locking of laser amplitude modulations to the motion of a nano-mechanical element opening a perspective for cavity-free cooling through coupling to an atomic gas.

quant-ph

Quantum simulation of energy transport with embedded Rydberg aggregates

We show that an array of ultracold Rydberg atoms embedded in a laser driven background gas can serve as an aggregate for simulating exciton dynamics and energy transport with a controlled environment. Spatial disorder and decoherence introduced by the interaction with the background gas atoms can be controlled by the laser parameters. This allows for an almost ideal realization of a Haken-Reineker-Strobl type model for energy transport. Physics can be monitored using the same mechanism that provides control over the environment. The degree of decoherence is traced back to information gained on the excitation location through the monitoring, turning the setup into an experimentally accessible model system for studying the effects of quantum measurements on the dynamics of a many-body quantum system.

physics.atom-ph

Correlated Exciton Transport in Rydberg-Dressed-Atom Spin Chains

We investigate the transport of excitations through a chain of atoms with non-local dissipation introduced through coupling to additional short-lived states. The system is described by an effective spin-1/2 model where the ratio of the exchange interaction strength to the reservoir coupling strength determines the type of transport, including coherent exciton motion, incoherent hopping and a regime in which an emergent length scale leads to a preferred hopping distance far beyond nearest neighbors. For multiple impurities, the dissipation gives rise to strong nearest-neighbor correlations and entanglement. These results highlight the importance of non-trivial dissipation, correlations and many-body effects in recent experiments on the dipole-mediated transport of Rydberg excitations.

physics.atom-ph