arXiv subjects

S. Y. Larsen

Publications and source records attributed to S. Y. Larsen.

6 recordsLinked to original sources

arXiv2010

Third Bose Fugacity Coefficient in One Dimension, as a Function of Asymptotic Quantities

In one of the very few exact quantum mechanical calculations of fugacity coefficients, Dodd and Gibbs (\textit{J. Math.Phys}.,\textbf{15}, 41 (1974)) obtained $b_{2}$ and $b_{3}$ for a one dimensional Bose gas, subject to repulsive delta-function interactions, by direct integration of the wave functions. For $b_{2}$, we have shown (\textit{Mol. Phys}.,\textbf{103}, 1301 (2005)) that Dodd and Gibbs' result can be obtained from a phase shift formalism, if one also includes the contribution of oscillating terms, usually contributing only in 1 dimension. Now, we develop an exact expression for $b_{3}-b_{3}^{0}$ (where $b_{3}^{0}$ is the free particle fugacity coefficient) in terms of sums and differences of 3-body eigenphase shifts. Further, we show that if we obtain these eigenphase shifts in a distorted-Born approximation, then, to first order, we reproduce the leading low temperature behaviour, obtained from an expansion of the two-fold integral of Dodd and Gibbs. The contributions of the oscillating terms cancel. The formalism that we propose is not limited to one dimension, but seeks to provide a general method to obtain virial coefficients, fugacity coefficients, in terms of asymptotic quantities. The exact one dimensional results allow us to confirm the validity of our approach in this domain.

physics.chem-ph↗

arXiv2008

Using mixed data in the inverse scattering problem

Consider the fixed-$\ell$ inverse scattering problem. We show that the zeros of the regular solution of the Schrödinger equation, $r_{n}(E)$, which are monotonic functions of the energy, determine a unique potential when the domain of the energy is such that the $r_{n}(E)$ range from zero to infinity. This suggests that the use of the mixed data of phase-shifts $\{δ(\ell_0,k), k \geq k_0 \} \cup \{δ(\ell,k_0), \ell \geq \ell_0 \}$, for which the zeros of the regular solution are monotonic in both domains, and range from zero to infinity, offers the possibility of determining the potential in a unique way.

math-ph↗

arXiv2008

Construction of potentials using mixed scattering data

The long-standing problem of constructing a potential from mixed scattering data is discussed. We first consider the fixed-$\ell$ inverse scattering problem. We show that the zeros of the regular solution of the Schrödinger equation, $r_{n}(E)$ which are monotonic functions of the energy, determine a unique potential when the domain of energy is such that the $r_{n}(E)$'s range from zero to infinity. The latter method is applied to the domain $\{E \geq E_0, \ell=\ell_0 \} \cup \{E=E_0, \ell \geq \ell_0 \}$ for which the zeros of the regular solution are monotonic in both parts of the domain and still range from zero to infinity. Our analysis suggests that a unique potential can be obtained from the mixed scattering data $\{δ(\ell_0,k), k \geq k_0 \} \cup \{δ(\ell,k_0), \ell \geq \ell_0 \}$ provided that certain integrability conditions required for the fixed $\ell$-problem, are fulfilled. The uniqueness is demonstrated using the JWKB approximation.

math-ph↗

arXiv2004

Integral representation of one dimensional three particle scattering for delta function interactions

The Schrödinger equation, in hyperspherical coordinates, is solved in closed form for a system of three particles on a line, interacting via pair delta functions. This is for the case of equal masses and potential strengths. The interactions are replaced by appropriate boundary conditions. This leads then to requiring the solution of a free-particle Schrödinger equation subject to these boundary conditions. A generalized Kontorovich - Lebedev transformation is used to write this solution as an integral involving a product of Bessel functions and pseudo-Sturmian functions. The coefficient of the product is obtained from a three-term recurrence relation, derived from the boundary condition. The contours of the Kontorovich-Lebedev representation are fixed by the asymptotic conditions. The scattering matrix is then derived from the exact solution of the recurrence relation. The wavefunctions that are obtained are shown to be equivalent to those derived by McGuire. The method can clearly be applied to a larger number of particles and hopefully might be useful for unequal masses and potentials.

math-ph↗

arXiv2004

Second virial coefficient in one dimension, as a function of asymptotic quantities

A result from Dodd and Gibbs[1] for the second virial coefficient of particles in 1 dimension, subject to delta-function interactions, has been obtained by direct integration of the wave functions. It is shown that this result can be obtained from a phase shift formalism, if one includes the contribution of oscillating terms. The result is important in work to follow, for the third virial coefficient, for which a similar formalism is being developed. We examine a number of fine points in the quantum mechanical formalisms.

physics.chem-ph↗

arXiv2001

S-matrix poles and the second virial coefficient

For cutoff potentials, a condition which is not a limitation for the calculation of physical systems, the S-matrix is meromorphic. We can express it in terms of its poles, and then calculate the quantum mechanical second virial coefficient of a neutral gas. Here, we take another look at this approach, and discuss the feasibility, attraction and problems of the method. Among concerns are the rate of convergence of the 'pole' expansion and the physical significance of the 'higher' poles.

physics.chem-ph↗