SearcharxivSearch

arXiv subjects

Salvatore Guastella

Publications and source records attributed to Salvatore Guastella.

2 recordsLinked to original sources

Digital-Based Potentiostat and Mesoporous Microelectrode Co-Design for Non-Enzymatic Glucose Detection at 0.3V-VDD and 1.65nW-Power

This paper presents a proof-of-concept ultra-low voltage and ultra-low power chronoamperometric electrochemical sensor for non-enzymatic glucose readout integrated circuit (IC) in 130nm CMOS detection featuring a reconfigurable Digital-Based (DB) Potentiostat. The signal transfer and noise characteristics of the new digital-based architecture are analytically described in the frequency domain for the first time by an equivalent linearized model that is validated by simulations and experiments. Based on experiments, the proposed DB potentiostat enables the detection of a wide electrochemical current range, spanning from 600pA to 650nA, with R2=0.991 linearity and consumes only 1.65nW (53.5nW) at V dd = 300mV (V dd = 500mV). The proposed DB readout is tested in a proof of-concept platform for non-enzymatic glucose detection with nanostructured microelectrodes, demonstrating successful non enzymatic glucose detection at physiological levels at the lowest reported voltage and power, even in the presence of an interferent (ascorbic acid) and under aerobic conditions, thus revealing a strong potential for emerging Point of Care (PoC) diagnostics applications.

eess.SY

Ambipolar suppression of superconductivity by ionic gating in optimally-doped BaFe2(As,P)2 ultrathin films

Superconductivity (SC) in the Ba-122 family of iron-based compounds can be controlled by aliovalent or isovalent substitutions, applied external pressure, and strain, the combined effects of which are sometimes studied within the same sample. Most often, the result is limited to a shift of the SC dome to different doping values. In a few cases, the maximum SC transition at optimal doping can also be enhanced. In this work, we study the combination of charge doping together with isovalent P substitution and strain by performing ionic gating experiments on BaFe$_2$(As$_{0.8}$P$_{0.2}$)$_2$ ultrathin films. We show that the polarization of the ionic gate induces modulations to the normal-state transport properties that can be mainly ascribed to surface charge doping. We demonstrate that ionic gating can only shift the system away from the optimal conditions, as the SC transition temperature is suppressed by both electron and hole doping. We also observe a broadening of the resistive transition, which suggests that the SC order parameter is modulated nonhomogeneously across the film thickness, in contrast with earlier reports on charge-doped standard BCS superconductors and cuprates.

cond-mat.supr-con