arXiv subjects

Sangsoo Kim

Publications and source records attributed to Sangsoo Kim.

17 recordsLinked to original sources

arXiv2026

Cumulative X-ray Damage in Bismuth Selenide Examined by Simultaneous TXM and XRD

Bismuth selenide (Bi2Se3) is a topological insulator with potential applications in thermoelectrics, spintronics, and optoelectronics. However, its response to radiation remains poorly understood. We investigate cumulative X-ray damage in Bi2Se3 using simultane- ous transmission X-ray microscopy (TXM) and X-ray diffraction (XRD) at the Pohang Accelerator Laboratory X-Ray Free Electron Laser (PAL-XFEL) over 27,000 successive pulses. We observe distinct damage mechanisms: rapid hole formation via vaporization within 100 pulses, followed by slower grain refinement and material sputtering over thousands of thermal cycles. Williamson-Hall analysis reveals a progressive transformation from single-crystal to nanocrystalline structure, with grain sizes decreasing from mi- cron to nanometer scale. Finite-element modeling confirms that X-rays penetrate 13.47 {\mu}m, driving local temperatures above 1600 K with subsequent cooling between pulses. Scanning electron microscopy identifies three characteristic morphologies correspond- ing to different thermal histories: sputter streaks, prismatic crystals, and disordered microcrystals. Our results demonstrate that grain-boundary formation creates a feedback mechanism that accelerates damage in later pulses. This work establishes a method- ology for studying radiation damage across multiple length scales and provides insight into topological insulator stability under extreme conditions

cond-mat.mtrl-sci↗

arXiv2026

Strain patterning of flexomagnetism

Flexomagnetism, the coupling of magnetic ordering to strain gradients, provides access to novel symmetry-broken magnetic phases that cannot be accessed via uniform strain. However, flexomagnetism is hard to understand because it is extremely difficult to control a spatially varying strain. Here, we develop a top-down strategy to pattern transverse strain gradients using helium ion implantation through a lithographically defined mask. Using epitaxial films of the antiferromagnetic nodal line semimetal GdAuGe, we demonstrate that transverse strain gradients $\partial \varepsilon_{zz}/\partial x$ induce near-room-temperature ferromagnetic response, compared to the retained para or antiferromagnetism for homogeneously strained GdAuGe. We spatially correlate the magnetic response with the regions of largest strain gradient, via magnetic force microscopy and nanobeam x-ray diffraction, respectively, to confirm the flexomagnetic response. Our approach opens new avenues for the precise control of magnetic phases in thin films of quantum materials via a patterned strain gradient.

cond-mat.mtrl-sci↗

arXiv2025

Nanosculpting lateral weak link junctions in superconducting Fe(Te,Se)/Bi2Te3 with focused Si++ ions and implications on vortex pinning

Superconductor-normal-superconductor (SC-N-SC) weak links enable Cooper-pair tunneling and serve as Josephson junctions (JJs) used in modern superconducting qubits. Conventional JJs rely on vertically stacked Al-AlOx-Al trilayers that are difficult to fabricate and are sensitive to ambient exposure. Here, we demonstrate an all-in-plane alternative by "nanosculpting" ~100 nm-wide channels into thin films of FeTe0.75Se0.25/Bi2Te3 (FTS/BT), a candidate topological superconductor, with a Si++ focusses ion beam (FIB). Systematic irradiation shows that increasing the ion dose, while keeping the beam energy constant, progressively suppresses both the critical temperature (Tc) and critical current (Ic), confirming the creation of a controllable weak link even though a Fraunhofer interference pattern is not observed. Kelvin prove force microscopy , atomic force microscopy and scanning electron microscopy corroborate the structural and electronic modification of the irradiated region. Ic (B) measurements reveal a slower field-induced decay of Ic at higher doses, indicating that irradiation-induced defects act as vortex-pinning centers that mitigate vortex motion and associated dissipation, By tuning beam energy and dose, the process shifts from SC-N-SC regime toward a superconductor-insulator-superconductor (SC-I-SC) geometry, offering a simple scalable pathway to JJ fabrication. These results established FIB pattering as a versatile platform for engineering robust, scalable fault-tolerant qubits.

cond-mat.supr-con↗

arXiv2025

Programmable phase selection between altermagnetic and non-centrosymmetric polymorphs of MnTe on InP via molecular beam epitaxy

Phase selecting nearly degenerate crystalline polymorphs during epitaxial growth can be challenging yet is critical to targeting physical properties for specific applications. Here, we establish how phase selectivity of altermagnetic and non-centrosymmetric polymorphs of MnTe with high structural quality and phase purity can be programmed by subtle changes to the surface of lattice-matched InP substrates in molecular beam epitaxial (MBE) growth. Bulk altermagnetic MnTe is thermodynamically stable in the hexagonal NiAs-structure and is synthesized here on the (111)A surface (In-terminated) of InP, while the non-centrosymmetric, cubic ZnS-structure with wide band gap (> 3eV) is stabilized on the (111)B surface (P-terminated). Here we use electron microscopy, photoemission spectroscopy, and reflection high-energy electron diffraction, which together indicate that the phase selection is triggered at the interface and proceeds along the growing surface. First principles calculations suggest that interfacial termination and strain have a significant effect on the interfacial energy; stabilizing the NiAs polymorph on the In-terminated surface and the ZnS structure on the P-terminated surface. Selectively grown, high-quality films of MnTe polymorphs are key platforms that will enable our understanding of the novel properties of these materials, thereby facilitating their use in new applications ranging from spintronics to microelectronic devices.

cond-mat.mtrl-sci↗

arXiv2025

Nucleation and Antiphase Twin Control in Bi$_2$Se$_3$ via Step-Terminated Al$_2$O$_3$ Substrates

The epitaxial synthesis of high-quality 2D layered materials is an essential driver of both fundamental physics studies and technological applications. Bi$_2$Se$_3$, a prototypical 2D layered topological insulator, is sensitive to defects imparted during the growth, either thermodynamically or due to the film-substrate interaction. In this study, it is shown that step-terminated Al$_2$O$_3$ substrates with a high miscut angle (3{\deg}) can effectively suppress a particular hard-to-mitigate defect, the antiphase twin. Systematic investigations across a range of growth temperatures and substrate miscut angles confirm that atomic step edges act as preferential nucleation sites, stabilizing a single twin domain. First-principles calculations suggest that there is a significant energy barrier for twin boundary formation at step edges, supporting the experimental observations. Detailed structural characterization indicates that this twin-selectivity is lost through the mechanism of the 2D layers overgrowing the step edges, leading to higher twin density as the thickness increases. These findings highlight the complex energy landscape unique to 2D materials that is driven by the interplay between substrate properties, nucleation dynamics, and defect formation, and overcoming and controlling these are critical to improve material quality for quantum and electronic applications.

cond-mat.mtrl-sci↗

arXiv2024

Hidden dormant phase mediating the glass transition in disordered matter

Metallic glass is a frozen liquid with structural disorder that retains degenerate free energy without spontaneous symmetry breaking to become a solid. For over half a century, this puzzling structure has raised fundamental questions about how structural disorder impacts glass-liquid phase transition kinetics, which remain elusive without direct evidence. In this study, through single-pulse, time-resolved imaging using X-ray free-electron lasers, we visualized the glass-to-liquid transition, revealing a previously hidden dormant phase that does not involve any macroscopic volume change within the crossover regime between the two phases. Although macroscopically inactive, nanoscale redistribution occurs, forming channeld low-density bands within this dormant phase that drives the glass transition. By providing direct microscopic evidence, this work presents a new perspective on the phase transition process in disordered materials, which can be extended to various liquid and solid phases in other complex systems.

cond-mat.dis-nn↗

arXiv2024

Photoinduced surface plasmon control of ultrafast melting modes in Au nanorods

Photoinduced ultrafast phenomena in materials exhibiting nonequilibrium behavior can lead to the emergence of exotic phases beyond the limits of thermodynamics, presenting opportunities for femtosecond photoexcitation. Despite extensive research, the ability to actively control quantum materials remains elusive owing to the lack of clear evidence demonstrating the explicit control of phase-changing kinetics through light-matter interactions. To address this drawback, we leveraged single-pulse time-resolved X-ray imaging of Au nanorods undergoing photoinduced melting to showcase control over the solid-to-liquid transition process through the use of localized surface plasmons. Our study uncovers transverse or longitudinal melting processes accompanied by characteristic oscillatory distortions at different laser intensities. Numerical simulations confirm that the localized surface plasmons, excited by polarized laser fields, dictate the melting modes through anharmonic lattice deformations. These results provide direct evidence of photoinduced surface plasmon-mediated ultrafast control of matter, establishing a foundation for the customization of material kinetics using femtosecond laser fields.

cond-mat.mes-hall↗

arXiv2024

Deep-learning real-time phase retrieval of imperfect diffraction patterns from X-ray free-electron lasers

Machine learning is attracting surging interest across nearly all scientific areas by enabling the analysis of large datasets and the extraction of scientific information from incomplete data. Data-driven science is rapidly growing, especially in X-ray methodologies, where advanced light sources and detection technologies accumulate vast amounts of data that exceed meticulous human inspection capabilities. Despite the increasing demands, the full application of machine learning has been hindered by the need for data-specific optimizations. In this study, we introduce a new deep-learning-based phase retrieval method for imperfect diffraction data. This method provides robust phase retrieval for simulated data and performs well on weak-signal single-pulse diffraction data from X-ray free-electron lasers. Moreover, the method significantly reduces data processing time, facilitating real-time image reconstructions that are crucial for high-repetition-rate data acquisition. Thus, this approach offers a reliable solution to the phase problem and is expected to be widely adopted across various research areas.

physics.app-ph↗

arXiv2023

Infrared-induced ultrafast melting of nanostructured platinum films probed by an X-ray free-electron laser

Understanding melting in metals is a hot topic of present research. This may be accomplished by pumping the system with infrared (IR) laser radiation, and probing it with hard X-rays produced by an X-ray Free-Electron Laser (XFEL). In this work we studied nanostructured polycrystalline thin films of platinum that were illuminated by IR radiation of increasing fluences. We characterized the structural response as well as the nucleation and propagation of the liquid phase as a function of time delay between the IR pump and X-ray probe. We observed partial melting of the samples for IR fluences higher than 200 mJ$\cdot$cm$^{-2}$. To fit the contribution of the liquid phase to the scattering pattern in platinum we applied a model of liquid metal. The two-temperature model simulations were performed to understand the solid-state fraction of the sample heating process as a function of time delay and fluence.

cond-mat.mtrl-sci↗

arXiv2022

Simultaneous Bright- and Dark-Field X-ray Microscopy at X-ray Free Electron Lasers

The structures, strain fields, and defect distributions in solid materials underlie the mechanical and physical properties across numerous applications. Many modern microstructural microscopy tools characterize crystal grains, domains and defects required to map lattice distortions or deformation, but are limited to studies of the (near) surface. Generally speaking, such tools cannot probe the structural dynamics in a way that is representative of bulk behavior. Synchrotron X-ray diffraction based imaging has long mapped the deeply embedded structural elements, and with enhanced resolution, Dark Field X-ray Microscopy (DFXM) can now map those features with the requisite nm-resolution. However, these techniques still suffer from the required integration times due to limitations from the source and optics. This work extends DFXM to X-ray free electron lasers, showing how the $10^{12}$ photons per pulse available at these sources offer structural characterization down to 100 fs resolution (orders of magnitude faster than current synchrotron images). We introduce the XFEL DFXM setup with simultaneous bright field microscopy to probe density changes within the same volume. This work presents a comprehensive guide to the multi-modal ultrafast high-resolution X-ray microscope that we constructed and tested at two XFELs, and shows initial data demonstrating two timing strategies to study associated reversible or irreversible lattice dynamics.

cond-mat.mtrl-sci↗

arXiv2022

Large Magnetic Anisotropy and Magnetostriction in Thin Films of CoV$_2$O$_4$

Spinel Cobalt Vanadate CoV$_2$O$_4$ has been grown on (001) SrTiO$_3$ substrates. Using torque magnetometry experiments, we find that the previously observed temperature induced anisotropy change, where the easy axis changes from the out of plane [001] direction to a biaxial anisotropy with planar <100> easy axes, occurs in a gradual second-order structural phase transition. This work characterizes this transition and the magnetic anisotropies in the (001), (100), and (-110) rotation planes, and explores their field dependence up to 30~T. Below 80~K, hysteretic features appear around the hard axes, i.e., the out-of-plane direction in (-110) and (010) rotations and the planar <110> directions in (001) rotations. This is due to a Zeeman Energy that originates from the lag of the magnetization with respect to the applied magnetic field as the sample is rotated. The appearance of the hysteresis, which persist up to very high fields, shows that the anisotropy at low temperature is rather strong. Additionally, field dependent distortions to the symmetry of the torque response in increasing applied fields shows that magnetostriction plays a large role in determining the direction and magnitude of the anisotropy.

cond-mat.mtrl-sci↗

arXiv2022

An Online Dynamic Amplitude-Correcting Gradient Estimation Technique to Align X-ray Focusing Optics

High-brightness X-ray pulses, as generated at synchrotrons and X-ray free electron lasers (XFEL), are used in a variety of scientific experiments. Many experimental testbeds require optical equipment, e.g Compound Refractive Lenses (CRLs), to be precisely aligned and focused. The lateral alignment of CRLs to a beamline requires precise positioning along four axes: two translational, and the two rotational. At a synchrotron, alignment is often accomplished manually. However, XFEL beamlines present a beam brightness that fluctuates in time, making manual alignment a time-consuming endeavor. Automation using classic stochastic methods often fail, given the errant gradient estimates. We present an online correction based on the combination of a generalized finite difference stencil and a time-dependent sampling pattern. Error expectation is analyzed, and efficacy is demonstrated. We provide a proof of concept by laterally aligning optics on a simulated XFEL beamline.

physics.ins-det↗

arXiv2022

Statistical analysis of hard X-ray radiation at PAL-XFEL facility performed by Hanbury Brown and Twiss interferometry

Hanbury Brown and Twiss interferometry experiment based on second-order correlations was performed at PAL-XFEL facility. The statistical properties of the X-ray radiation were studied within this experiment. Measurements were performed at NCI beamline at 10 keV photon energy in various operation conditions: Self-Amplified Spontaneous Emission (SASE), SASE with a monochromator, and self-seeding regimes at 120 pC, 180 pC, and 200 pC electron bunch charge, respectively. Statistical analysis showed short average pulse duration from 6 fs to 9 fs depending on operation conditions. A high spatial degree of coherence of about 70-80% was determined in spatial domain for the SASE beams with the monochromator and self-seeding regime of operation. The obtained values describe the statistical properties of the beams generated at PAL-XFEL facility.

physics.acc-ph↗

arXiv2020

High-throughput ensemble characterization of individual core-shell nanoparticles with quantitative 3D density from XFEL single-particle imaging

The structures, as building-blocks for designing functional nanomaterials, have fueled the development of versatile nanoprobes to understand local structures of noncrystalline specimens. Progresses in analyzing structures of individual specimens with atomic scale accuracy have been notable recently. In most cases, however, only a limited number of specimens are inspected lacking statistics to represent the systems with structural inhomogeneity. Here, by employing single-particle imaging with X-ray free electron lasers and new algorithm for multiple-model 3D imaging, we succeeded in investigating several thousand specimens in a couple of hours, and identified intrinsic heterogeneities with 3D structures. Quantitative analysis has unveiled 3D morphology, facet indices and elastic strains. The 3D elastic energy distribution is further corroborated by molecular dynamics simulations to gain mechanical insight at atomic level. This work establishes a new route to high-throughput characterization of individual specimens in large ensembles, hence overcoming statistical deficiency while providing quantitative information at the nanoscale.

cond-mat.mtrl-sci↗

arXiv2017

Single-Shot 3D Diffractive Imaging of Core-Shell Nanoparticles with Elemental Specificity

We report 3D coherent diffractive imaging of Au/Pd core-shell nanoparticles with 6 nm resolution on 5-6 femtosecond timescales. We measured single-shot diffraction patterns of core-shell nanoparticles using very intense and short x-ray free electron laser pulses. By taking advantage of the curvature of the Ewald sphere and the symmetry of the nanoparticle, we reconstructed the 3D electron density of 34 core-shell structures from single-shot diffraction patterns. We determined the size of the Au core and the thickness of the Pd shell to be 65.0 +/- 1.0 nm and 4.0 +/- 0.5 nm, respectively, and identified the 3D elemental distribution inside the nanoparticles with an accuracy better than 2%. We anticipate this method can be used for quantitative 3D imaging of symmetrical nanostructures and virus particles.

physics.ins-det↗

arXiv2013

Single-shot 3D structure determination of nanocrystals with femtosecond X-ray free electron laser pulses

Coherent diffraction imaging (CDI) using synchrotron radiation, X-ray free electron lasers (X-FELs), high harmonic generation, soft X-ray lasers, and optical lasers has found broad applications across several disciplines. An active research direction in CDI is to determine the structure of single particles with intense, femtosecond X-FEL pulses based on diffraction-before-destruction scheme. However, single-shot 3D structure determination has not been experimentally realized yet. Here we report the first experimental demonstration of single-shot 3D structure determination of individual nanocrystals using ~10 femtosecond X-FEL pulses. Coherent diffraction patterns are collected from high-index-faceted nanocrystals, each struck by a single X-FEL pulse. Taking advantage of the symmetry of the nanocrystal, we reconstruct the 3D structure of each nanocrystal from a single-shot diffraction pattern at ~5.5 nm resolution. As symmetry exists in many nanocrystals and virus particles, this method can be applied to 3D structure studies of such particles at nanometer resolution on femtosecond time scales.

physics.optics↗

arXiv2010

Mapping cellular magnesium using X-ray microfluorescence and atomic force microscopy

Magnesium is the most abundant intracellular divalent cation. We present an innovative experimental approach to localizing intracellular magnesium that combines elemental and morphological information from individual cells with high-resolution spatial information. Integration of information from scanning fluorescence X-ray microscopy with information from atomic force microscopy was used to generate a magnesium concentration map and to determine the X-ray linear absorption coefficient map within a whole dehydrated mammary epithelial cell.

q-bio.CB↗