SearcharxivSearch

arXiv subjects

Sanjay Govindjee

Publications and source records attributed to Sanjay Govindjee.

5 recordsLinked to original sources

Magnetic influence on ion transport in concentrated solid solutions: An analytic investigation

It is well established that magnetic fields have a significant effect on transport in certain classes of electronic conductors. Less reported, however, are similar effects in solid ionic conductors. Despite the rarity of Hall mobility measurements in ionic conductors, recent experimental work in batteries and other systems has demonstrated that an applied magnetic field can significantly and beneficially alter ionic transport and electrochemical processes in solid materials in a way that would not be predicted from na\"{\i}ve Hall coefficient estimates. In this work, the influence of a magnetic field on ion transport in solids is investigated analytically, and general multi-component transport equations accounting for magnetic effects are presented. Specific models are then derived for solid, isotropic binary and single ion conductors. Material property combinations for which magnetic field influence may become significant are then computed for certain systems subject to compositional constraints. Finally, it is demonstrated that the derived model for binary conductors in a magnetic field fits experimental magneto-resistance data well for the fluoride ion conducting solid Pb$_{0.66}$Cd$_{0.34}$F$_2$, provided an assumption of near degenerate multi-component transport.

cond-mat.mtrl-sci

Return point memory in knitted fabrics

The tunable mechanical response of knitted fabrics underpins applications ranging from soft robotics and artificial muscles to morphing electromagnetic field sensors. Elasticity in fabrics emerges from the bending of yarn in the knitted structure; however, properties beyond elasticity are relatively unexplored. Here, we demonstrate that knitted fabrics subjected to cyclic uniaxial stress exhibit significant hysteresis and the remarkable ability to "remember" their response to previous deformations -- reminiscent of classical return point memory in magnetic systems. The hysteretic behavior deviates from the two standard models of hysteresis that usually apply to solid-state materials, viscoelasticity and plasticity. Thus, we develop a phenomenological extension of the Preisach model of hysteresis which well replicates our data, and discuss implications of these results on the underlying mechanisms of memory in knitted fabrics.

cond-mat.soft

Anomalous tensorial properties of anisotropic 2D materials

Odd transport phenomena -- defined as a flux response orthogonal to an applied gradient -- have been recently observed in isotropic systems, with a multitude of proposed models and experiments to study these effects. Odd transport manifests in tensors that describe linear relations between fluxes and gradients that drive them, particularly when parity and time-reversal symmetries are broken. In this work, we identify such odd properties to be a subset of a broader class of major-symmetry-breaking behaviors, which we term ``anomalous." We develop a classification of anomalous properties described by $2^\mathrm{nd}$ and $4^\mathrm{th}$ order tensors in anisotropic 2D materials that maintain discrete rotational and reflection symmetries, characterized by the 17 wallpaper groups. To this end, we present representation theorems for these tensors, identifying which components are constrained for specific spatial symmetries and thereby allowing materials to be grouped into classes that exhibit anomalous responses or not. We focus our discussion on $2^\mathrm{nd}$ order tensors in the context of electrical resistivity and on $4^\mathrm{th}$ order tensors in the context of viscosity and elasticity. These findings are broadly applicable to the study of novel emergent material properties. To illustrate this, we discuss implications of our findings for two very different 2D materials that have recently garnered attention in condensed matter physics: knitted fabrics and twisted bilayer graphene.

cond-mat.soft

A variational approach to effective models for inelastic systems

Given a set of inelastic material models, a microstructure, a macroscopic structural geometry, and a set of boundary conditions, one can in principle always solve the governing equations to determine the system's mechanical response. However, for large systems this procedure can quickly become computationally overwhelming, especially in three-dimensions when the microstructure is locally complex. In such settings multi-scale modeling offers a route to a more efficient model by holding out the promise of a framework with fewer degrees of freedom, which at the same time faithfully represents, up to a certain scale, the behavior of the system. In this paper, we present a methodology that produces such models for inelastic systems upon the basis of a variational scheme. The essence of the scheme is the construction of a variational statement for the free energy as well as the dissipation potential for a coarse scale model in terms of the free energy and dissipation functions of the fine scale model. From the coarse scale energy and dissipation we can then generate coarse scale material models that are computationally far more efficient than either directly solving the fine scale model or by resorting to FE-square type modeling. Moreover, the coarse scale model preserves the essential mathematical structure of the fine scale model. An essential feature for such schemes is the proper definition of the coarse scale inelastic variables. By way of concrete examples, we illustrate the needed steps to generate successful models via application to problems in classical plasticity, included are comparisons to direct numerical simulations of the microstructure to illustrate the accuracy of the proposed methodology.

cs.CE

The exponentiated Hencky strain energy in modelling tire derived material for moderately large deformations

This work presents a hyper-viscoelastic model based on the Hencky-logarithmic strain tensor to model the response of a Tire Derived Material (TDM) undergoing moderately large deformations. TDM is a composite made by cold forging a mix of rubber fibers and grains, obtained by grinding scrap tires, and polyurethane binder. The mechanical properties are highly influenced by the presence of voids associated with the granular composition and low tensile strength due to the weak connection at the grain-matrix interface. For these reasons, TDM use is restricted to applications concerning a limited range of deformations. Experimental tests show that a central feature of the response is connected to highly nonlinear behavior of the material under volumetric deformation which conventional hyperelastic models fail in predicting. The strain energy function presented here is a variant of the exponentiated Hencky strain energy proposed by Neff et al., which for moderate strains is as good as the quadratic Hencky model and in the large strain region improves several important features from a mathematical point of view. The proposed form of the exponentiated Hencky energy possesses a set of parameters uniquely determined in the infinitesimal strain regime and an orthogonal set of parameters to determine the nonlinear response. The hyperelastic model is additionally incorporated in a finite deformation viscoelasticity framework that accounts for the two main dissipation mechanisms in TDMs, one at the microscale level and one at the macroscale level. The model is capable of predicting different deformation modes in a certain range of frequency and amplitude with a unique set of parameters with most of them having a clear physical meaning. Moreover, by comparing the predictions from the proposed constitutive model with experimental data we conclude that the new constitutive model gives accurate prediction.

math.CA