arXiv subjects

Sarah E. Moran

Publications and source records attributed to Sarah E. Moran.

At least 19 recordsLinked to original sources

arXiv2026

The Nancy Grace Roman Space Telescope Coronagraph Community Participation Program

In preparation for the operational phase of the Nancy Grace Roman Space Telescope, NASA has created the Coronagraph Community Participation Program (CPP) to prepare for and execute Coronagraph Instrument technology demonstration observations. The CPP is composed of 7 small, US-based teams, selected competitively via the Nancy Grace Roman Space Telescope Research and Support Participation Opportunity, members of the Roman Project Team, and international partner teams from ESA, JAXA, CNES, and the Max Planck Institute for Astronomy. The primary goals of the CPP are to prepare simulation tools, target databases, and data reduction software for the execution of the Coronagraph Instrument observation phase. Here, we present the current status of the CPP and its working groups, along with plans for future CPP activities up through Roman's launch. We also discuss plans to potentially enable future commissioning of currently-unsupported modes.

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arXiv2026

No Helium Detected in LHS 1140 b from Four JWST NIRISS/SOSS Transits

In the effort to determine which low-mass exoplanets have atmospheres, LHS 1140 b remains one of the most favorable targets. Its large size (5.6 $\rm M_{\oplus}$ and 1.7 $\rm R_{\oplus}$) and relatively long orbital period (24.7 days) imply an atmosphere may be likely, and notably, recent interior models favor either a hydrogen-dominated "mini-Neptune" or a "water world" over a true terrestrial planet. Another possibility is that it has a helium-rich atmosphere. This hypothesis is supported by recent ground-based observations that detected the metastable helium triplet during transit. These observations indicated there may be current helium escape from the planet's upper atmosphere, yet the signal was not detected during a subsequent observation, suggesting time-variable escape. Here we present four observations of LHS 1140 b with JWST NIRISS/SOSS, which covers the metastable helium triplet, obtained between 2023 and 2026. These observations span the epoch of the ground-based measurements, and although none were contemporaneous with the ground-based transits, all four are sensitive to helium absorption at the previously reported level. However, we detect no helium absorption in any visit. We reject the best-fit ground-based model at $>3σ$ in each visit, and find no clear trend in mass-loss with time. Our results suggest the reported ground-based detection may be spurious, although variability cannot be excluded if detectable helium absorption occurs in $\lesssim50\%$ of transits. The nature of LHS 1140 b thus remains a mystery until future transmission and emission analyses are complete.

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arXiv2026

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems VIII: patchy forsterite and enstatite clouds in the atmosphere of VHS 1256 b, retrieval lessons learned and outlook to the future

JWST defines a new era for the data-driven approach of retrieval modelling, which has become a cornerstone tool for the statistical inference of exoplanetary and brown dwarf properties. The Early Release Science program #1386 observations of VHS 1256 b represent a huge jump in data quality, data quantity and spectral coverage for such objects. VHS 1256 b is a young, planetary mass and extremely variable companion that populates the enigmatic L/T cohort of substellar atmospheres. In this first retrieval analysis of the full 1 - 18 micron dataset, we apply the Brewster retrieval framework to the NIRSpec and MIRI spectroscopic observations of VHS 1256 b, exploring a variety of cloud species and structures. Using Delta(BIC) we find that the data is best described by a forsterite (Mg$_{2}$SiO$_{4}$) and enstatite (MgSiO$_{3}$) cloud combination. Our analysis shows a strong preference for patchy silicate cloud coverage, which aligns with VHS 1256 b's extensive and well documented spectral variability. Our retrieval is able to place constraints on the abundances of H$_{2}$O, CO, CO$_{2}$, CH$_{4}$ as well as NH$_{3}$. We also show that the retrieved parameters are sensitive to the data used and the relative signal-to-noise ratios between data from different instruments. We conclude with the next steps for the wider retrieval community to better understand young and cloudy exoplanetary atmospheres.

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arXiv2026

Ultraviolet Radiation Effects on the Optical Properties of Water-Dominated Exoplanet Hazes

Temperate sub-Neptune and terrestrial exoplanets could contain large inventories of water in various phases, such as water-dominated atmospheres or even oceans. Observations have shown that many exoplanets, including water worlds, likely contain photochemically-generated hazes. Haze particles are a key source of organic matter and may impact the evolution or origin of life; their optical properties are imperative for interpreting observations through theoretical atmospheric modeling. Modelers have thus far assumed haze optical properties that may not represent hazes under sub-Neptune and terrestrial atmospheric conditions. Often orbiting close to M-dwarf stars, these planets receive large amounts of radiation, especially during flaring events, which may accelerate atmospheric escape and affect atmospheric compositions. Here, we present optical constants of experimentally-generated sub-Neptune haze analogs before and after UV irradiation across a broad wavelength range (0.5 to 8 μm). We find that UV-irradiation alters haze optical constants which become generally more absorbing in this wavelength range, which we hypothesize is due to our sample containing more oxygen-rich absorbing bands post irradiation. We use Virga and PICASO to simulate transmission spectra of potentially hazy water-dominated planets GJ 1214b and LHS 1140b, accounting for irradiated haze layers in their atmospheres. For our GJ 1214b CH4-rich haze modeled case, we see a difference in the N-H feature at 2.6 μm in the resulting transmission spectrum between irradiated and unaltered haze that should be observable within current JWST capabilities. Broadly, we demonstrate the importance of using more representative optical constants, as they have an impact on current and future atmospheric composition interpretations.

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arXiv2026

Magnesium Silicate Clouds in the Atmosphere of HD 209458b from a Rule-Based Tree-Structured Data Reduction

HD 209458b is the canonical hot Jupiter: the first to have its atmosphere measured and the first to hint at the role of aerosols in exoplanet atmospheres through the muting of Na absorption signatures in the optical. Here we present JWST MIRI/LRS transmission observations of HD 209458b from 5-12 microns, directly measuring the absorption signatures of its clouds for the first time. The observations indicate the presence of magnesium silicates, most likely Mg2SiO4 or a mixture of Mg2SiO4 and MgSiO3. We also present a new methodology to reduce observational data, whereby the analysis is formulated as a rule-based model with a tree structure, enabling key decisions to be identified and uncertain decisions to be incorporated into subsequent modeling. With this data reduction, and using a combination of ARCiS free retrievals and PICASO+Virga self consistent forward models, we are able to show that amorphous Mg2SiO4 clouds explain the LRS data to high significance over either a clear (Delta ln(Z)=16.63) or gray cloud atmosphere (Delta ln(Z)=22.26). By combining the LRS dataset with archival JWST NIRCam and HST optical and near-infrared observations, we are able to more robustly constrain the properties of the magnesium silicate condensates, finding particle sizes of approximately 0.1 microns and atmospheric pressures of the clouds of roughly 1-10 millibar. Our results add to the growing detections of silicate clouds as a dominant atmospheric component of hot Jupiters, with the exact silicate species contextualizing the atmospheric chemistry and potentially formation conditions of these planets.

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arXiv2026

JWST COMPASS Program: The 3--5$μ$m transmission spectrum of LTT 1445 A b

The search for an atmosphere on the closest rocky M dwarf planet, LTT 1445 A b, has been the subject of intense investigation from both the ground and space. Here, we present the first JWST transmission spectrum of LTT 1445 A b using a single visit spanning 3-5~$μ$m using NIRSpec/G395H. We conduct two independent reductions of the data using both the Eureka! and ExoTiC-JEDI pipelines. Overall, we measure the NRS1 transit depths to a median precision of $\sim23$~ppm in 41 spectroscopic channels with uniform widths of 30 pixels ($\sim$ 0.02 $μ$m), and the NRS2 transit depths to $\sim36$~ppm precision in 65 spectroscopic channels, also with uniform widths of 30 pixels. We rule out any statistically significant spectral features at this precision and place limits on atmospheric metallicity using a grid of chemical equilibrium models with grey opaque clouds. Using NIRSpec/G395H alone, we can place limits on the atmospheric metallicity of $\gtrsim350~\times$ Solar when the opaque pressure level is greater than 0.01~bars. We also conduct a combined analysis of JWST/NIRSpec and HST/WFC3 transmission data and find our atmospheric limits can be extended $\gtrsim500~\times$ Solar when considering both datasets. Future analyses both in transit and emission will uncover whether there are detectable atmospheric features.

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arXiv2026

Seasonal Variability of Pluto's Haze Formation Revealed by Laboratory Simulations

Pluto possesses a thin atmosphere primarily composed of N2, with minor constituents including CO and CH4. Photochemical processes generate distinct haze layers as observed by the New Horizons spacecraft. However, the mechanisms governing haze formation, as well as the composition and physical properties of the hazes, remain poorly constrained. Due to Pluto's highly eccentric orbit and obliquity, its surface temperature and atmospheric composition undergo substantial seasonal variations, but it is unclear how such seasonal variations impact the chemical pathways and efficiency of haze formation in Pluto's atmosphere. To address this, we conducted a laboratory simulation of Pluto's atmospheric photochemistry, in which N2/CH4/CO gas mixtures with CH4 concentrations varying from 0.1% to 5% were exposed to a glow discharge to initiate photochemical reactions. Gas-phase composition was monitored in situ using a residual gas analyzer (RGA), while the solid-phase products were characterized by atomic force microscopy (AFM), a gas pycnometer, infrared spectroscopy (IR), and very high-resolution mass spectrometry (VHRMS) to determine particle sizes, density, and composition, respectively. Our results show that increasing the CH4 mixing ratio significantly enhances the yield of gas and solid products. Under low CH4 conditions, nitrogen is primarily incorporated into solids as cyanide groups; whereas CH4-rich conditions favor the formation of amino groups, greatly promoting nitrogen incorporation into organic solids. These findings not only shed light on how seasonal variations into Pluto's atmosphere composition influence haze formation pathways, but also provide critical parameters to interpret observational data and to improve photochemical and microphysical models of planetary hazes.

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arXiv2026

Hydrolyzed Hazes on Water-rich Exoplanets: Optical Constants and Detectability

Observations of temperate sub-Neptunes suggest active chemical environments, finding evidence of both water vapor and photochemical hazes in their atmospheres. Hazes formed in water-rich atmospheres are chemically complex, containing molecules relevant to prebiotic chemistry, and their strong optical opacity obscures sought-after gaseous molecular absorption features. While many studies have investigated haze formation and properties across diverse atmospheric conditions, little is known about the evolution of these hazes in their environment once formed. In particular, interactions with water can drive hydrolysis reactions that alter haze composition and optical behavior, affecting our interpretations of habitability and observational spectroscopy. Here, we perform hydrolysis experiments on haze analogs of temperate water-rich exoplanets and measure their optical properties. Transmittance measurements from 0.4 to 28.5 $μ$m reveal changes in key functional groups after hydrolysis, along with an overall increase in sample absorbance. We report the derived optical constants for use in observational and modeling studies. Through synthetic atmospheric spectra, we demonstrate the need for physically informed haze optical properties in models, consistent with expected planetary conditions. The increased absorptivity and high imaginary refractive index of hydrolyzed hazes almost completely flatten features in model spectra, presenting critical consequences for atmospheric characterization of water-rich sub-Neptunes.

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arXiv2026

Influence of CO versus CH$_4$ on organic haze formation in atmospheres of diverse terrestrial exoplanets

Context. Terrestrial exoplanets are expected to host secondary, high-metallicity atmospheres derived from outgassing of volatiles such as N2, CO2, H2O, CH4, and CO. Photochemical organic hazes are likely to form in such environments, significantly affecting atmospheric observations and planetary habitability. Aims. We investigate haze formation in representative terrestrial exoplanet atmospheres and assess how CH4 versus CO as the primary carbon source affects haze production rates, particle properties, and chemical complexity. Methods. We performed six laboratory simulations by exposing gas mixtures at a few mbar to glow discharge at 300 K. Each atmosphere contained 75% N2, CO2, or H2O, 10% of each of the other two gases, and 5% CH4 or CO. Gas-phase products were analyzed with a residual gas analyzer, and solid products were characterized by production rate, particle density, atomic force microscopy, Fourier-transform infrared spectroscopy, and very high-resolution mass spectrometry. Results. CH4 experiments produced more diverse gas-phase species and much higher haze yields than the corresponding CO experiments. CO-derived hazes showed a narrow particle size range of 10-80 nm, whereas CH4-derived hazes were denser and chemically more complex. The identified molecular formulas suggest growth pathways linked to gaseous precursors such as HCN, CH2O, and C2H4. Conclusions. The atmospheric redox state critically controls haze formation in simulated terrestrial exoplanet atmospheres. CH4 is significantly more effective than CO in initiating organic growth, leading to higher haze production rates and greater chemical complexity. These results provide useful constraints for exoplanet atmospheric modeling and spectral interpretation, and further support the possibility that reducing atmospheres may facilitate prebiotic organic chemistry relevant to the emergence of life.

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arXiv2026

High Tide or Riptide on the Cosmic Shoreline? A Water-Rich Atmosphere or Stellar Contamination for the Warm Super-Earth GJ~486b from JWST Observations

Planets orbiting M-dwarf stars are prime targets in the search for rocky exoplanet atmospheres. The small size of M dwarfs renders their planets exceptional targets for transmission spectroscopy, facilitating atmospheric characterization. However, it remains unknown whether their host stars' highly variable extreme-UV radiation environments allow atmospheres to persist. With JWST, we have begun to determine whether or not the most favorable rocky worlds orbiting M dwarfs have detectable atmospheres. Here, we present a 2.8-5.2 micron JWST NIRSpec/G395H transmission spectrum of the warm (700 K, 40.3x Earth's insolation) super-Earth GJ 486b (1.3 R$_{\oplus}$ and 3.0 M$_{\oplus}$). The measured spectrum from our two transits of GJ 486b deviates from a flat line at 2.2 - 3.3 $σ$, based on three independent reductions. Through a combination of forward and retrieval models, we determine that GJ 486b either has a water-rich atmosphere (with the most stringent constraint on the retrieved water abundance of H2O > 10% to 2$σ$) or the transmission spectrum is contaminated by water present in cool unocculted starspots. We also find that the measured stellar spectrum is best fit by a stellar model with cool starspots and hot faculae. While both retrieval scenarios provide equal quality fits ($χ^2_ν$ = 1.0) to our NIRSpec/G395H observations, shorter wavelength observations can break this degeneracy and reveal if GJ 486b sustains a water-rich atmosphere.

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arXiv2026

JWST COMPASS: NIRSpec/G395H Transmission Observations of the Sub-Neptune HD 15337 c

We present the 3-5 $μ$m transmission spectrum of HD 15337 c (TOI-402.02), a sub-Neptune (2.526 R$_{\oplus}$, 6.792 M$_{\oplus}$, T$_{\rm eq}$$\sim$656 K) around a K1V star observed as part of the JWST COMPASS program. We reduce these observations with two pipelines and find consistent transmission spectra. The resulting median precisions in 30 pixel spectroscopic bins for visit 1 are $\sim$40 ppm and $\sim$70 ppm and for visit 2 are $\sim$30 ppm and $\sim$54 ppm for NRS1 and NRS2, respectively. We attribute the differing precisions to the lack of adequate pre-transit baseline in visit 1 from an early transit arrival caused by previously undetected transit timing variations (TTVs), hinting at a potential exterior companion. Our median JWST timing precision is 10 seconds, revealing TTVs $>$20 minutes when combined with previous TESS and CHEOPS data, highlighting JWST's TTV measurement capabilities. The transmission spectrum of HD 15337 c is featureless and can best be described by a step function with an offset between the NRS1 and NRS2 detectors, likely caused by instrumental systematics. From thermochemical equilibrium retrievals we find that, to $>$3$σ$, the data can rule out atmospheres with metallicities $<$600 or $<$310 $\times$ solar, depending on the reduction, for opaque pressures greater than a few millibars. HD 15337 c joins other sub-Neptunes with similar masses, radii, and temperatures in possessing a featureless transmission spectrum indicative of high metallicity and/or high-altitude aerosols and adds support to recent studies showing that aerosol opacity reaches a maximum for planets with equilibrium temperatures of 500-700 K.

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arXiv2026

JWST COMPASS: A NIRSpec G395H Transmission Spectrum of Radius Valley-Dweller TOI-260 b

We present a JWST/NIRSpec G395H transmission spectrum of TOI-260 b, a $T_\mathrm{eq}\sim 490$ K, $R_\mathrm{p} = 1.76\,R_\oplus$ planet. The transmission spectrum is derived by combining two transit observations, collected as part of the JWST COMPASS program. We achieved the same median transit depth precision of 37 ppm in both visits, and a median precision of 26 ppm when combining the spectroscopic light curves from the two visits. Implementing a 30-pixel-wide ($R\sim 200$) spectroscopic binning scheme, we find that the transmission spectrum is mostly featureless, with a possible feature around 3.17 $μ$m. We assess the significance of any features in the transmission spectrum with a suite of non-parametric models, which confirm the presence of a potential feature in the NRS1 bandpass and an offset between the NRS1 and NRS2 detectors. To investigate the atmospheric composition of TOI-260 b, we run a series of PLATON retrievals. We do not detect any clear molecular signatures, but the combined data from the two visits are sufficient to constrain the atmospheric metallicity to greater than $200\times$ solar, assuming no opaque deck $\lesssim2.5$ mbar. We also investigate causes of the potential feature near 3.17 $μ$m; while we find some compatible gaseous species and cannot fully discard an astrophysical origin, we suspect a systematics origin due to the variance in strength and position of the feature. Overall, this look at TOI-260 b adds to the small sample of radius-valley planets, which already seem to show a diversity in their atmospheric compositions. Determining the true nature of these enigmatic planets will require a larger telescope time investment.

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arXiv2025

Fractal Aggregate Aerosols in the Virga Cloud Code II: Exploring the Effects of Key Cloud Parameters in Warm Neptune, Hot Jupiter and Brown Dwarf Atmospheres

Aerosols and clouds are expected to be ubiquitous in exoplanet and brown dwarf atmospheres, where they can have a significant impact on transmission and emission spectra. The cloud code Virga is capable of quickly modeling cloud particle sizes as a function of altitude, and has recently been updated to include functionality for aggregates (ranging from very fluffy chains to compact fractals). We analyze the effect that these aggregates have on transmission spectra for typical warm Neptune and hot Jupiter environments, as well as their effect on emission spectra for an L-type brown dwarf, over the wavelength range 0.3 - 15 um. We find significant, measurable differences in spectra when particle shape is changed (particularly the shortest wavelengths where particle morphology strongly affects the scattering slope). We provide some intuitive rules for how non-absorbing aggregates impact spectra: when particle sizes are small compared to the wavelength of light, the most elongated and chain-like particles have the highest opacities. When particles are large, the inverse is true (the most compact shapes have the highest opacities). We present an explanation for these effects in terms of the dynamics of how the particles form and move through the atmosphere, as well as in terms of fundamental optics theory. Given the significant impact that particle shape can have on spectra, we strongly encourage the community to include shape as a free parameter in future case studies, atmospheric models, and retrievals.

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arXiv2025

Fractal Aggregate Aerosols in the Virga Cloud Code I: Model Description and Application to a Benchmark Cloudy Exoplanet

We introduce new functionality to treat fractal aggregate aerosol particles within the Virga cloud modeling framework. Previously, the open source cloud modeling code Virga (Batalha et al. 2025), the Python version of EddySed (Ackerman & Marley, 2001), assumed spherical particles to compute particle mass and size distributions throughout the atmosphere. The initial release of Virga also assumed spherical particles to compute Mie scattering properties, which include the single scattering albedo, asymmetry parameter, and optical depth as a function of particle radius and composition. However, extensive evidence from Solar system aerosols, astrophysical disks and dust, and Earth climate studies suggests that non-spherical aggregate particles are common compared to idealized compact spherical particles. Following recent advances in microphysical and opacity modeling, we implement a simple parametrization for dynamical and optical (modified mean field theory) effects of fractal aggregate particles into Virga. We then use this new functionality to perform a case study using basic planetary parameters similar to the well-characterized, aerosol-laden mini-Neptune GJ 1214 b, using KCl clouds made of aggregate particles. We choose KCl to most directly explore comparisons to previous studies. We demonstrate 1) how our method compares to previous fractal aggregate particle treatments and 2) how our new fractal treatment affects theoretical spectra of cloudy atmospheres. Overall, our model is faster and more flexible for a wider range of parameter space than previous studies. We explore the limitations of our modeling set-up and offer guidance for future investigations using our framework.

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arXiv2025

Condensation Clouds in Substellar Atmospheres with Virga

Here we present an open-source cloud model for substellar atmospheres, called Virga. The Virga-v0 series has already been widely adopted in the literature. It is written in Python and has heritage from the Ackerman & Marley (2001) model (often referred to as eddysed), used to study clouds on both exoplanets and brown dwarfs. In the development of the official Virga-v1 we have retained all the original functionality of eddysed and updated/expanded several components including the back-end optical constants data, calculations of the Mie properties, available condensate species, saturation vapor pressure curves and formalism for fall speeds calculations. Here we benchmark Virga by reproducing key results in the literature, including the SiO2 cloud detection in WASP-17 b and the brown dwarf Diamondback-Sonora model series. Development of Virga is ongoing, with future versions already planned and ready for release. We encourage community feedback and collaborations within the GitHub code repository.

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arXiv2025

Additional JWST/NIRSpec Transits of the Rocky M Dwarf Exoplanet GJ 1132 b Reveal a Featureless Spectrum

As an archetypal M-dwarf rocky exoplanet, GJ 1132 b has a varied history of atmospheric measurements. At 1.13 $\rm R_{\oplus}$, 1.66 $\rm M_{\oplus}$, and 580 K, it orbits a bright, slowly rotating M dwarf in a 1.6-day period, making it a prime target for characterization. In this study, we combine two JWST NIRSpec/G395H transits previously reported by May and MacDonald et al. 2023 with two new NIRSpec/G395M transits to constrain the presence of an atmosphere. This marks the first time the G395H and G395M modes have been combined for a single target, and we report no difference in the quality of data between the two modes. For rocky M-dwarf studies, G395H may still be preferred if stacking transits to utilize the high-resolution flux-calibrated stellar spectra and assess evolving stellar heterogeneity. GJ 1132 b's co-added transmission spectrum is best-fit with a flat line. A thin steam atmosphere is also consistent with the data, but this interpretation is driven almost entirely by the first transit, which suggests an increase in cool spot coverage-fraction derived from the flux-calibrated stellar spectra. This demonstrates the importance of always considering stellar heterogeneity evolution in multi-visit transits, and also the importance of a "leave-one-transit-out" approach in modeling efforts of co-added transits. We combine these results with MIRI/LRS emission data (Xue et al. 2024) to show that together, transmission and emission are consistent with only the thinnest of atmospheres. Given GJ 1132 b's age and distance from the star, a thin atmosphere is not likely stable. Therefore, the simplest explanation is that GJ 1132 b is indeed a bare rock.

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arXiv2025

The impact of organic hazes and graphite on the observation of CO2-rich sub-Neptune atmospheres

Many sub-Neptune and super-Earth exoplanets are expected to develop metal-enriched atmospheres due to atmospheric loss processes such as photoevaporation or core-powered mass loss. Thermochemical equilibrium calculations predict that at high metallicity and a temperature range of 300-700 K, CO2 becomes the dominant carbon species, and graphite may be the thermodynamically favored condensate under low-pressure conditions. Building on prior laboratory findings that such environments yield organic haze rather than graphite, we measured the transmittance spectra of organic haze analogues and graphite samples, and computed their optical constants across the measured wavelength range from 0.4 to 25 μm. The organic haze exhibits strong vibrational absorption bands, notably at 3.0, 4.5, and 6.0 μm, while graphite shows featureless broadband absorption. The derived optical constants of haze and graphite provide the first dataset for organic haze analogues formed in CO2-rich atmospheres and offer improved applicability over prior graphite data derived from bulk reflectance or ellipsometry. We implemented these optical constants into the Virga and PICASO cloud and radiative transfer models to simulate transit spectra for GJ 1214b. The synthetic spectra with organic hazes reproduce the muted spectral features in the NIR observed by Hubble and general trends observed by JWST for GJ 1214b, while graphite models yield flat spectra across the observed wavelengths. This suggests haze features may serve as observational markers of carbon-rich atmospheres, whereas graphite's opacity could lead to radius overestimation, offering a possible explanation for super-puff exoplanets. Our work supplies essential optical to infrared data for interpreting observations of CO2-rich exoplanet atmospheres.

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arXiv2025

Formation of organic hazes in CO$_2$-rich sub-Neptune atmospheres within the graphite-stability regime

Super-Earths and sub-Neptunes are the most common exoplanets, with a "radius valley" suggesting that super-Earths may form by shedding sub-Neptunes' gaseous envelopes. Exoplanets that lie closer to the super-Earth side of the valley are more likely to have lost a significant fraction of their original H/He envelopes and become enriched in heavier elements with CO$_2$ gaining in abundance. It remains unclear which types of haze would form in such atmospheres, potentially significantly affecting spectroscopic observations. To investigate this, we performed laboratory simulations of two CO$_2$-rich gas mixtures (with 2000 times solar metallicity at 300 K and 500 K). We found that under plasma irradiation, organic hazes were produced at both temperatures with higher haze production rate at 300 K probably because condensation occurs more readily at lower temperature. Gas-phase analysis demonstrates the formation of various hydrocarbons, oxygen- and nitrogen-containing species, including reactive gas precursors like C$_2$H$_4$, CH$_2$O, and HCN, for haze formation. The compositional analysis of the haze particles reveals various functional groups and molecular formulas in both samples. The 500 K haze sample has larger average molecular sizes, higher degree of unsaturation with more double or triple bonds presence, and higher nitrogen content incorporated as N-H, C=N bonds, indicating different haze formation pathways. These findings not only improve the haze formation theories in CO$_2$-rich exoplanet atmospheres but also offer important implications for the interpretation of future observational data.

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