arXiv subjects

Sarah M. Hörst

Publications and source records attributed to Sarah M. Hörst.

At least 19 recordsLinked to original sources

arXiv2026

Optical Constants of Photochemical Haze Analogs in N2-CH4-CO Atmospheres from 0.4 to 28.6 μm

Photochemical hazes play an important role in shaping the spectra and radiative balance of N2-dominated planetary atmospheres. We present newly acquired FTIR and retrieved optical constants (N=n+ik) of laboratory-generated haze analogs from N2/CH4 and N2/CH4/CO gas mixtures under plasma discharge conditions. The retrievals use particle densities newly measured for the CH4-series and previously published particle densities for the CO-series. The experiments systematically explored CH4 concentrations from 0.5% to 10% and CO concentrations from 0% to 5% with fixed 5% CH4. Using measured particle densities together with the Beer-Lambert law and subtractive Kramers-Kronig (SKK) relation, we derived optical constants over the 350-25000 cm-1 (0.4-28.6 μm) spectral range, with the 0.4-25 μm results presented in the main text. The infrared spectra reveal prominent absorption features associated with hydrocarbon-, nitrogen-, and oxygen-bearing functional groups. Increasing CH4 abundance enhances aliphatic hydrocarbon features and corresponds to decreasing particle density, whereas increasing CO abundance promotes oxygen incorporation, broader mid-infrared absorptions, and higher particle density. The derived k spectra exhibit strong absorptions near ~3 μm, ~4.6 μm, and ~6-10 μm, while the real refractive index n generally ranges from ~1.2 to 1.7. The controlled CH4- and CO-series establish composition-dependent variations in haze optical properties. A benchmark comparison among Titan-, Pluto-, and Triton-like haze analogs then uses these experimentally identified trends to interpret the optical differences among N2-dominated planetary haze compositions. The density and optical constants provide laboratory constraints for atmospheric radiative transfer models and for interpreting planetary and exoplanetary spectra from spacecraft and telescopes.

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arXiv2026

Ultraviolet Radiation Effects on the Optical Properties of Water-Dominated Exoplanet Hazes

Temperate sub-Neptune and terrestrial exoplanets could contain large inventories of water in various phases, such as water-dominated atmospheres or even oceans. Observations have shown that many exoplanets, including water worlds, likely contain photochemically-generated hazes. Haze particles are a key source of organic matter and may impact the evolution or origin of life; their optical properties are imperative for interpreting observations through theoretical atmospheric modeling. Modelers have thus far assumed haze optical properties that may not represent hazes under sub-Neptune and terrestrial atmospheric conditions. Often orbiting close to M-dwarf stars, these planets receive large amounts of radiation, especially during flaring events, which may accelerate atmospheric escape and affect atmospheric compositions. Here, we present optical constants of experimentally-generated sub-Neptune haze analogs before and after UV irradiation across a broad wavelength range (0.5 to 8 μm). We find that UV-irradiation alters haze optical constants which become generally more absorbing in this wavelength range, which we hypothesize is due to our sample containing more oxygen-rich absorbing bands post irradiation. We use Virga and PICASO to simulate transmission spectra of potentially hazy water-dominated planets GJ 1214b and LHS 1140b, accounting for irradiated haze layers in their atmospheres. For our GJ 1214b CH4-rich haze modeled case, we see a difference in the N-H feature at 2.6 μm in the resulting transmission spectrum between irradiated and unaltered haze that should be observable within current JWST capabilities. Broadly, we demonstrate the importance of using more representative optical constants, as they have an impact on current and future atmospheric composition interpretations.

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arXiv2026

Hydrolyzed Hazes on Water-rich Exoplanets: Optical Constants and Detectability

Observations of temperate sub-Neptunes suggest active chemical environments, finding evidence of both water vapor and photochemical hazes in their atmospheres. Hazes formed in water-rich atmospheres are chemically complex, containing molecules relevant to prebiotic chemistry, and their strong optical opacity obscures sought-after gaseous molecular absorption features. While many studies have investigated haze formation and properties across diverse atmospheric conditions, little is known about the evolution of these hazes in their environment once formed. In particular, interactions with water can drive hydrolysis reactions that alter haze composition and optical behavior, affecting our interpretations of habitability and observational spectroscopy. Here, we perform hydrolysis experiments on haze analogs of temperate water-rich exoplanets and measure their optical properties. Transmittance measurements from 0.4 to 28.5 $μ$m reveal changes in key functional groups after hydrolysis, along with an overall increase in sample absorbance. We report the derived optical constants for use in observational and modeling studies. Through synthetic atmospheric spectra, we demonstrate the need for physically informed haze optical properties in models, consistent with expected planetary conditions. The increased absorptivity and high imaginary refractive index of hydrolyzed hazes almost completely flatten features in model spectra, presenting critical consequences for atmospheric characterization of water-rich sub-Neptunes.

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arXiv2025

JWST-TST DREAMS: The Nightside Emission and Chemistry of WASP-17b

Theoretical studies have suggested using planetary infrared excess (PIE) to detect and characterize the thermal emission of transiting and non-transiting exoplanets, however the PIE technique requires empirical validation. Here we apply the PIE technique to a combination of JWST NIRSpec G395H transit and eclipse measurements of WASP-17b, a hot Jupiter orbiting an F-type star, obtained consecutively (0.5 phase or 1.8 days apart) as part of the JWST-TST program to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS). Using the in-eclipse measured stellar spectrum to circumvent the need for ultra-precise stellar models, we extract the first JWST nightside emission spectrum of WASP-17b using only transit and eclipse data thereby performing a controlled test of the PIE technique. From the WASP-17b nightside spectrum, we measure a nightside equilibrium temperature of $1005 \pm 256$ K and find tentative evidence for nightside SO2 absorption ($\ln B = 1.45$, $2.3σ$). In context with the dayside, the temperature of the nightside is consistent with (1) previous eclipse mapping findings that suggest relatively inefficient day-night heat transport, and (2) a non-zero bond albedo of $0.42^{+0.06}_{-0.10}$. SO2 on the nightside, if confirmed, would represent the first direct evidence for transport-induced chemistry, matching previous model predictions, and opening a new door into the 3D nature of giant exoplanets. Our results suggest that PIE is feasible with JWST/NIRSpec for two epochs separated in time by significantly less than the rotation period of the host star.

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arXiv2025

The impact of organic hazes and graphite on the observation of CO2-rich sub-Neptune atmospheres

Many sub-Neptune and super-Earth exoplanets are expected to develop metal-enriched atmospheres due to atmospheric loss processes such as photoevaporation or core-powered mass loss. Thermochemical equilibrium calculations predict that at high metallicity and a temperature range of 300-700 K, CO2 becomes the dominant carbon species, and graphite may be the thermodynamically favored condensate under low-pressure conditions. Building on prior laboratory findings that such environments yield organic haze rather than graphite, we measured the transmittance spectra of organic haze analogues and graphite samples, and computed their optical constants across the measured wavelength range from 0.4 to 25 μm. The organic haze exhibits strong vibrational absorption bands, notably at 3.0, 4.5, and 6.0 μm, while graphite shows featureless broadband absorption. The derived optical constants of haze and graphite provide the first dataset for organic haze analogues formed in CO2-rich atmospheres and offer improved applicability over prior graphite data derived from bulk reflectance or ellipsometry. We implemented these optical constants into the Virga and PICASO cloud and radiative transfer models to simulate transit spectra for GJ 1214b. The synthetic spectra with organic hazes reproduce the muted spectral features in the NIR observed by Hubble and general trends observed by JWST for GJ 1214b, while graphite models yield flat spectra across the observed wavelengths. This suggests haze features may serve as observational markers of carbon-rich atmospheres, whereas graphite's opacity could lead to radius overestimation, offering a possible explanation for super-puff exoplanets. Our work supplies essential optical to infrared data for interpreting observations of CO2-rich exoplanet atmospheres.

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arXiv2025

Formation of organic hazes in CO$_2$-rich sub-Neptune atmospheres within the graphite-stability regime

Super-Earths and sub-Neptunes are the most common exoplanets, with a "radius valley" suggesting that super-Earths may form by shedding sub-Neptunes' gaseous envelopes. Exoplanets that lie closer to the super-Earth side of the valley are more likely to have lost a significant fraction of their original H/He envelopes and become enriched in heavier elements with CO$_2$ gaining in abundance. It remains unclear which types of haze would form in such atmospheres, potentially significantly affecting spectroscopic observations. To investigate this, we performed laboratory simulations of two CO$_2$-rich gas mixtures (with 2000 times solar metallicity at 300 K and 500 K). We found that under plasma irradiation, organic hazes were produced at both temperatures with higher haze production rate at 300 K probably because condensation occurs more readily at lower temperature. Gas-phase analysis demonstrates the formation of various hydrocarbons, oxygen- and nitrogen-containing species, including reactive gas precursors like C$_2$H$_4$, CH$_2$O, and HCN, for haze formation. The compositional analysis of the haze particles reveals various functional groups and molecular formulas in both samples. The 500 K haze sample has larger average molecular sizes, higher degree of unsaturation with more double or triple bonds presence, and higher nitrogen content incorporated as N-H, C=N bonds, indicating different haze formation pathways. These findings not only improve the haze formation theories in CO$_2$-rich exoplanet atmospheres but also offer important implications for the interpretation of future observational data.

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arXiv2025

Effects of Ultraviolet Radiation on Sub-Neptune Exoplanet Hazes Through Laboratory Experiments

Temperate sub-Neptune exoplanets could contain large inventories of water in various phases, such as water-worlds with water-rich atmospheres or even oceans. Both space-based and ground-based observations have shown that many exoplanets likely also contain photochemically-generated hazes. Haze particles are a key source of organic matter and may impact the evolution or origin of life. In addition, haze layers could provide a mechanism for lower-atmospheric shielding and ultimately atmospheric retention. Often orbiting close to M-dwarf stars, these planets receive large amounts of radiation, especially during flaring events, which may strip away their atmospheres. M-dwarf stars are known to have higher stellar activity than other types of stars, and stellar flares have the potential to accelerate atmospheric escape. In this work, we present results on laboratory investigations of UV radiation effects simulating two different stellar flare energies on laboratory-produced exoplanet hazes made under conditions analogous to water-world atmospheres. We find that both simulated flares altered the overall transmittance and reflectance of the hazes, and higher energy "flares" make those alterations more pronounced. On a larger scale, these laboratory-made hazes show potential signs of degradation over the simulated flaring period. Our results provide insight into the effects that stellar flaring events have on potential exoplanet haze composition and the ability for water-world-like exoplanets to retain their atmospheres.

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arXiv2024

Comparing NASA Discovery and New Frontiers Class Mission Concepts for the Io Volcano Observer (IVO)

Jupiter's moon Io is a highly compelling target for future exploration that offers critical insight into tidal dissipation processes and the geology of high heat flux worlds, including primitive planetary bodies, such as the early Earth, that are shaped by enhanced rates of volcanism. Io is also important for understanding the development of volcanogenic atmospheres and mass-exchange within the Jupiter System. However, fundamental questions remain about the state of Io's interior, surface, and atmosphere, as well as its role in the evolution of the Galilean satellites. The Io Volcano Observer (IVO) would address these questions by achieving the following three key goals: (A) Determine how and where tidal heat is generated inside Io; (B) Understand how tidal heat is transported to the surface of Io; and (C) Understand how Io is evolving. IVO was selected for Phase A study through the NASA Discovery program in 2020 and, in anticipation of a New Frontiers 5 opportunity, an enhanced IVO-NF mission concept was advanced that would increase the Baseline mission from 10 flybys to 20, with an improved radiation design; employ a Ka-band communications to double IVO's total data downlink; add a wide angle camera for color and stereo mapping; add a dust mass spectrometer; and lower the altitude of later flybys to enable new science. This study compares and contrasts the mission architecture, instrument suite, and science objectives for Discovery (IVO) and New Frontiers (IVO-NF) missions to Io, and advocates for continued prioritization of Io as an exploration target for New Frontiers.

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arXiv2024

Towards Prebiotic Chemistry on Titan: Impact experiments on organic haze particles

Impacts are critical to producing the aqueous environments necessary to stimulate prebiotic chemistry on Titan's surface. Furthermore, organic hazes resting on the surface are a likely feedstock of biomolecules. In this work, we conduct impact experiments on laboratory-produced organic haze particles and haze/sand mixtures and analyze these samples for life's building blocks. Samples of unshocked haze and sand particles are also analyzed to determine the change in biomolecule concentrations and distributions from shocking. Across all samples, we detect seven nucleobases, nine proteinogenic amino acids, and five other biomolecules (e.g., urea) using a blank subtraction procedure to eliminate signals due to contamination. We find that shock pressures of 13 GPa variably degrade nucleobases, amino acids, and a few other organics in haze particles and haze/sand mixtures; however, certain individual biomolecules become enriched or are even produced from these events. Xanthine, threonine, and aspartic acid are enriched or produced in impact experiments containing sand, suggesting these minerals may catalyze the production of these biomolecules. On the other hand, thymine and isoleucine/norleucine are enriched or produced in haze samples containing no sand, suggesting catalytic grains are not necessary for all impact shock syntheses. Uracil, glycine, proline, cysteine, and tyrosine are the most unstable to impact-related processing. These experiments suggest that impacts alter biomolecule distributions on Titan's surface, and that organic hazes co-occurring with fine-grained material on the surface may provide an initial source for further prebiotic chemistry on Titan.

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arXiv2022

Saturn's atmospheric response to the large influx of ring material inferred from Cassini INMS measurements

During the Grand Finale stage of the Cassini mission, organic-rich ring material was discovered to be flowing into Saturn's equatorial upper atmosphere at a surprisingly large rate. Through a series of photochemical models, we have examined the consequences of this ring material on the chemistry of Saturn's neutral and ionized atmosphere. We find that if a substantial fraction of this material enters the atmosphere as vapor or becomes vaporized as the solid ring particles ablate upon atmospheric entry, then the ring-derived vapor would strongly affect the composition of Saturn's ionosphere and neutral stratosphere. Our surveys of Cassini infrared and ultraviolet remote-sensing data from the final few years of the mission, however, reveal none of these predicted chemical consequences. We therefore conclude that either (1) the inferred ring influx represents an anomalous, transient situation that was triggered by some recent dynamical event in the ring system that occurred a few months to a few tens of years before the 2017 end of the Cassini mission, or (2) a large fraction of the incoming material must have been entering the atmosphere as small dust particles less than ~100 nm in radius, rather than as vapor or as large particles that are likely to ablate. Future observations or upper limits for stratospheric neutral species such as HC$_3$N, HCN, and CO$_2$ at infrared wavelengths could shed light on the origin, timing, magnitude, and nature of a possible vapor-rich ring-inflow event.

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arXiv2022

An experimental and theoretical investigation of HCN production in the Hadean Earth atmosphere

A critical early stage for the origin of life on Earth may have involved the production of hydrogen cyanide (HCN) in a reducing, predominantly H$_2$ atmosphere. HCN is crucial for the origin of life as it is a possible precursor to several biomolecules that make up RNA and proteins including nucleobases, nucleotides, amino acids, and ribose. In this work, we perform an in depth experimental and theoretical investigation of HCN production in reducing atmospheric conditions (89-95% H$_2$) possibly representing the earliest stages of the Hadean eon, ~4.5-4.3 billion years ago. We make use of cold plasma discharges - a laboratory analog to shortwave UV radiation - to simulate HCN production in the upper layers of the atmosphere for CH$_4$ abundances ranging from 0.1-6.5%. We then combine experimental mass spectrum measurements with our theoretical plasma models to estimate the HCN concentrations produced in our experiments. We find that upper atmospheric HCN production scales linearly with CH$_4$ abundance with the relation [HCN] = 0.13 $\pm$ 0.01[CH$_4$]. Concentrations of HCN near the surface of the Hadean Earth are expected to be about 2-3 orders of magnitude lower. The addition of 1% water to our experiments results in a ~50% reduction in HCN production. We find that four reactions are primarily responsible for HCN production in our experiments: (i) $^4$N + CH$_3$ -> H$_2$CN + H -> HCN + H$_2$, (ii) $^4$N + CH -> CN + H followed by CN + CH$_4$ -> HCN + CH$_3$, (iii) C$_2$H$_4$ + $^4$N -> HCN + CH$_3$, and (iv) $^4$N + $^3$CH$_2$ -> HCN + H. The most prebiotically favorable Hadean atmosphere would have been very rich in CH$_4$ (> 5%), and as a result of greenhouse effects the surface would be likely very hot. In such a prebiotic scenario, it may have been important to incorporate HCN into organic hazes that could later release biomolecules and precursors into the first ponds.

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arXiv2021

Triton Haze Analogues: the Role of Carbon Monoxide in Haze Formation

Triton is the largest moon of the Neptune system and possesses a thin nitrogen atmosphere with trace amounts of carbon monoxide and methane, making it of similar composition to that of the dwarf planet Pluto. Like Pluto and Saturn's moon Titan, Triton has a haze layer thought to be composed of organics formed through photochemistry. Here, we perform atmospheric chamber experiments of 0.5% carbon monoxide and 0.2% methane in molecular nitrogen at 90 K and 1 mbar to generate Triton haze analogues. We then characterize the physical and chemical properties of these particles. We measure their production rate, their bulk composition with combustion analysis, their molecular composition with very high resolution mass spectrometry, and their transmission and reflectance from the optical to the near-infrared (0.4 to 5 microns) with Fourier Transform Infrared (FTIR) spectroscopy. We compare these properties to existing measurements of Triton's tenuous atmosphere and its surface, as well as contextualize these results in view of all the small, hazy nitrogen-rich worlds of our solar system. We find that carbon monoxide present at greater mixing ratios than methane in the atmosphere can lead to significantly oxygen- and nitrogen-rich haze materials. These Triton haze analogues have clear observable signatures in their near-infrared spectra, which may help us differentiate the mechanisms behind haze formation processes across diverse solar system bodies.

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arXiv2021

Haze Evolution in Temperate Exoplanet Atmospheres Through Surface Energy Measurements

Photochemical hazes are important opacity sources in temperate exoplanet atmospheres, hindering current observations from characterizing exoplanet atmospheric compositions. The haziness of an atmosphere is determined by the balance between haze production and removal. However, the material-dependent removal physics of the haze particles is currently unknown under exoplanetary conditions. Here we provide experimentally-measured surface energies for a grid of temperate exoplanet hazes to characterize haze removal in exoplanetary atmospheres. We found large variations of surface energies for hazes produced under different energy sources, atmospheric compositions, and temperatures. The surface energies of the hazes were found to be the lowest around 400 K for the cold plasma samples, leading to the lowest removal rates. We show a suggestive correlation between haze surface energy and atmospheric haziness with planetary equilibrium temperature. We hypothesize that habitable zone exoplanets could be less hazy, as they would possess high-surface-energy hazes which can be removed efficiently.

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arXiv2020

Chemistry of Temperate Super-Earth and Mini-Neptune Atmospheric Hazes from Laboratory Experiments

Very little experimental work has been done to explore the properties of photochemical hazes formed in atmospheres with very different compositions or temperatures than that of the outer solar system or of early Earth. With extrasolar planet discoveries now numbering thousands, this untapped phase space merits exploration. This study presents measured chemical properties of haze particles produced in laboratory analogues of exoplanet atmospheres. We used very high resolution mass spectrometry to measure the chemical components of solid particles produced in atmospheric chamber experiments. Many complex molecular species with general chemical formulas C$_w$H$_x$N$_y$O$_z$ were detected. We detect molecular formulas of prebiotic interest in the data, including those for the monosaccharide glyceraldehyde, a variety of amino acids and nucleotide bases, and several sugar derivatives. Additionally, the experimental exoplanetary haze analogues exhibit diverse solubility characteristics, which provide insight into the possibility of further chemical or physical alteration of photochemical hazes in super-Earth and mini-Neptune atmospheres. These exoplanet analogue particles can help us better understand chemical atmospheric processes and suggest a possible source of in situ atmospheric prebiotic chemistry on distant worlds.

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arXiv2019

Transmission Spectroscopy of WASP-79b from 0.6 to 5.0 $μ$m

As part of the PanCET program, we have conducted a spectroscopic study of WASP-79b, an inflated hot Jupiter orbiting an F-type star in Eridanus with a period of 3.66 days. Building on the original WASP and TRAPPIST photometry of Smalley et al (2012), we examine HST/WFC3 (1.125 - 1.650 $μ$m), Magellan/LDSS-3C (0.6 - 1 $μ$m) data, and Spitzer data (3.6 and 4.5 $μ$m). Using data from all three instruments, we constrain the water abundance to be --2.20 $\leq$ log(H$_2$O) $\leq$ --1.55. We present these results along with the results of an atmospheric retrieval analysis, which favor inclusion of FeH and H$^-$ in the atmospheric model. We also provide an updated ephemeris based on the Smalley, HST/WFC3, LDSS-3C, Spitzer, and TESS transit times. With the detectable water feature and its occupation of the clear/cloudy transition region of the temperature/gravity phase space, WASP-79b is a target of interest for the approved JWST Director's Discretionary Early Release Science (DD ERS) program, with ERS observations planned to be the first to execute in Cycle 1. Transiting exoplanets have been approved for 78.1 hours of data collection, and with the delay in the JWST launch, WASP-79b is now a target for the Panchromatic Transmission program. This program will observe WASP-79b for 42 hours in 4 different instrument modes, providing substantially more data by which to investigate this hot Jupiter.

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arXiv2019

k-Means Aperture Optimization Applied to Kepler K2 Time Series Photometry of Titan

Motivated by the Kepler K2 time series of Titan, we present an aperture optimization technique for extracting photometry of saturated moving targets with high temporally- and spatially-varying backgrounds. Our approach uses $k$-means clustering to identify interleaved families of images with similar Point-Spread Function and saturation properties, optimizes apertures for each family independently, then merges the time series through a normalization procedure. By applying $k$-means aperture optimization to the K2 Titan data, we achieve $\leq$0.33% photometric scatter in spite of background levels varying from 15% to 60% of the target's flux. We find no compelling evidence for signals attributable to atmospheric variation on the timescales sampled by these observations. We explore other potential applications of the $k$-means aperture optimization technique, including testing its performance on a saturated K2 eclipsing binary star. We conclude with a discussion of the potential for future continuous high-precision photometry campaigns for revealing the dynamical properties of Titan's atmosphere.

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arXiv2018

Gas Phase Chemistry of Cool Exoplanet Atmospheres: Insight from Laboratory Simulations

Photochemistry induced by stellar UV flux should produce haze particles in exoplanet atmospheres. Recent observations indicate that haze and/or cloud layers exist in the atmospheres of exoplanets. However, photochemical processes in exoplanetary atmospheres remain largely unknown. We performed laboratory experiments with the PHAZER chamber to simulate haze formation in a range of exoplanet atmospheres (hydrogen-rich, water-rich, and carbon dioxide-rich at 300, 400, and 600 K), and observed the gas phase compositional change (the destruction of the initial gas and the formation of new gas species) during these experiments with mass spectrometer. The mass spectra reveal that distinct chemical processes happen in the experiments as a function of different initial gas mixture and different energy sources (plasma or UV photons). We find that organic gas products and O2 are photochemically generated in the experiments, demonstrating that photochemical production is one of the abiotic sources for these potential biosignatures. Multiple simulated atmospheres produce organics and O2 simultaneously, which suggests that even the co-presence of organics and O2 could be false positive biosignature. From the gas phase composition changes, we identify potential precursors (C2H2, HCN, CH2NH, HCHO, etc.) for haze formation, among which complex reactions can take place and produce larger molecules. Our laboratory results indicate that complex atmospheric photochemistry can happen in diverse exoplanet atmospheres and lead to the formation of new gas products and haze particles, including compounds (O2 and organics) that could be falsely identified as biosignatures.

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arXiv2018

Perspectives on Astrophysics Based on Atomic, Molecular, and Optical (AMO) Techniques

About two generations ago, a large part of AMO science was dominated by experimental high energy collision studies and perturbative theoretical methods. Since then, AMO science has undergone a transition and is now dominated by quantum, ultracold, and ultrafast studies. But in the process, the field has passed over the complexity that lies between these two extremes. Most of the Universe resides in this intermediate region. We put forward that the next frontier for AMO science is to explore the AMO complexity that describes most of the Cosmos.

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