arXiv subjects

Satoshi Aya

Publications and source records attributed to Satoshi Aya.

16 recordsLinked to original sources

arXiv2026

Reactive polar mesogenic self-assembly approach enables domain-programmable polymer ferroelectrics

Ferroelectric polymers combine switchable polarization with the processability of soft materials, but their development has been dominated by poly(vinylidene fluoride) and related fluoropolymers, whose crystalline polar phases restrict mechanical compliance and domain design with spatial precision. Here we establish a generic design principle for creating intrinsically flexible ferroelectric liquid-crystal polymers through reactive polar mesogenic self-assembly. The approach creates polyfluoroalkyl-free polymer films in which robust ferroelectric order arises from liquid-crystalline molecular organization rather than crystalline phase formation. By transferring ferroelectric order from fluid mesogenic states into polymer networks, the resulting materials combine mechanical adaptability with programmable polar architectures. Especially, the photoalignment technology enables these polar states to be organized into pixelated domain architectures. This work establishes a design space towards soft ferroelectric polymers that integrate molecularly programmed polar order, mechanical tunability and environmentally conscious chemistry, expanding the design space of adaptive materials for flexible electronics, wearable systems and soft robotics.

cond-mat.soft↗

arXiv2025

Hybrid Topological Defects in Ferroelectric Nematic Fluids

We investigate the evolution of topological defects in polar fluids driven by discrete inversion symmetry-breaking acrossthe nematic-to-ferroelectric nematic phase transition. Using photopatterned surface alignment to prescribe well-defined initial defect configurations in the nematic phase, we track their metamorphosis upon entering the ferroelectric phase. Through systematic comparisons between experiments and numerical simulations, we demonstrate that the resulting polar structures are generically hybrid, intertwining topological configurations of different dimensionalities. Specifically, we identify three basic hybrid defects evolving from precursor disclinations of net charge 0 and +1 (via pairs), and +1 (via single defects): domain walls terminated by surface disclinations, monopole-decorated domain walls, and meron-mediated boojum and monopole complexes. We further demonstrate that these stable hybrid polar defects are ubiquitous in the ferroelectric nematic phase, providing the basic motifs needed to understand, predict, and engineer complex topological textures in polar fluids.

cond-mat.soft↗

arXiv2025

Polar solitons in a nonpolar chiral soft matter system

Polar solitons, i.e., solitonic waves accompanying asymmetry of geometry or phase, have garnered attention in polar systems, such as ferroelectric or magnetoelectric materials, where they play a critical role in topological transitions and nonreciprocal responses to external fields. A key question is whether such polar solitons can emerge in nonpolar systems, where intrinsic polarity is absent. Here, we demonstrate an unprecedented polar soliton with nematic order in a nonpolar and chiral liquid crystal system by applying an alternating electric field. The soliton is corn-kernel-shaped, displaying a pair of oppositely charged topological defects at its two ends. While head-to-head collision between the solitons leads to repulsion, head-to-tail collision attracts the solitons into a single polar soliton. A rich variety of solitonic kinetics, such as rectilinear translation and circulation motions, can be activated by controlling the voltage and frequency of an electric field. Simulations reveal that the formation of the polar solitons is achieved through balancing the electric and nematic elastic energies, while the flexoelectric effect drives their rotational behaviors. The discovery of polar solitons in nonpolar systems expands the understanding of topological solitons, opening new avenues for dynamic control in soft matter systems, with potential applications in nonreciprocal responsive materials and topological information storage.

physics.optics↗

arXiv2024

Double Splay Nematic Order in Confined Polar Fluids

In this study, we demonstrate that when a ferroelectric nematic is confined between two glass plates coated with ionic polymers, a modulated phase emerges in a narrow temperature range between the nematic and ferroelectric nematic phases. This modulated phase emerges from the nematic phase in a continuous manner and then transforms into the ferroelectric nematic phase via a first-order transition upon cooling. Using optical microscopy, we provide compelling evidence that this modulated phase corresponds to the theoretically predicted double splay nematic phase. In this phase, splay deformations alternate in two orthogonal directions oriented at 45{\deg} to the substrate surfaces, creating a modulation wavelength that is twice the thickness of the cell. Our experiments with different ionic coatings reveal that only polymeric cationic coatings effectively promote the formation of this phase, highlighting the critical role of electrical screening. These findings not only confirm the existence of the double splay nematic phase but also provide insights into the distinctive topological defects of this phase in confined geometries.

cond-mat.soft↗

arXiv2024

Mean-field theory of the uniaxial ferroelectric smectic A liquid crystal phase

Following the groundbreaking discovery of the ferroelectric nematic liquid crystal phase (NF), a series of closely-related new polar phases have also been found. An especially interesting one is the ferroelectric smectic A phase (SmAF) with spontaneous polarization along the layer normal observed in a few materials of the NF realm. Here, we present a mean-field molecular model that successfully captures the rich phase diagrams experimentally observed in the literature in terms of two parameters. Additionally, we carry out second harmonic generation, X-ray diffraction and birefringence measurements in a compound exhibiting the SmAF phase to determine the appropriate order parameters and compare with the model predictions.

cond-mat.soft↗

arXiv2024

Chiral {\pi} Domain Walls Composed of Twin Half-Integer Surface Disclinations in Ferroelectric Nematic Liquid Crystals

Ferroelectric nematic liquid crystals are polar fluids characterized by microscopic orientational ordering and macroscopic spontaneous polarizations. Within these fluids, walls that separate domains of different polarizations are ubiquitous. We demonstrate that the {\pi} walls in films of polar fluids consist of twin half-integer surface disclinations spaced horizontally, enclosing a subdomain where the polarization exhibits left- or right-handed {\pi} twists across the film. The degenerate geometric configurations of these twin disclinations give rise to kinks and antikinks, effectively partitioning subdomains of opposite chirality like Ising chains. The hierarchical topological structures dictate that field-driven polar switching entails a two-step annihilation process of the disclinations. These findings serve as a cornerstone for comprehending other walls in ferroelectric and ferromagnetic materials, thereby laying the base for domain engineering crucial for advancing their nonlinear and optoelectronic applications.

cond-mat.soft↗

arXiv2024

Half-integer Topological Defects Paired via String Micelles in Polar Liquids

Ferroelectric nematic (NF) liquid crystals present a compelling platform for exploring topological defects in polar fields, while their structural properties can be significantly altered by ionic doping. In this study, we demonstrate that doping the ferroelectric nematic material RM734 with cationic polymers enable the formation of polymeric micelles that connect pairs of half-integer topological defects. Polarizing optical microscopy reveals that these string defects exhibit butterfly textures, featured with a two-dimensional polarization field divided by N\'eel-type kink-walls into domains exhibiting either uniform polarization or negative splay and bend deformations. Through analysis of electrophoretic motion and direct measurements of polarization divergences, we show that the string micelles are positively charged and their side regions exhibit positive bound charges. To elucidate these observations, we propose a charge double layer model for the string defects: the positive charged cationic polymer chains and densely packed RM734 molecules form a Stern charge layer, while small anionic ions and positive bound charges constitute the charge diffusion layer. Notably, our experiments indicate that only cationic polymer doping effectively induces the formation of these unique string defects. These findings enhance our understanding of ionic doping effects and provide valuable insights for engineering polar topologies in liquid crystal systems.

cond-mat.soft↗

arXiv2024

Extended free-energy functionals for achiral and chiral ferroelectric nematic liquid crystals

Polar nematic liquid crystals are new classes of condensed-matter states where the inversion symmetry common to the traditional apolar nematics is broken. Establishing theoretical descriptions for the novel phase states is an urgent task. Here, we develop a Landau-type mean-field theory for both the achiral and chiral ferroelectric nematics. In the polar nematic states, the inversion symmetry breaking adds two new contributions: an additional odd elastic term (corresponding to the flexoelectricity in symmetry) to the standard Oseen-Frank free energy and an additional Landau term relating to the gradient of local polarisation. As a general necessity, the coupling between the scalar order parameter and polarisation order is further considered. In the chiral and polar nematic state, we reveal that the competition between the twist elasticity and polarity dictates effective compressive energy arising from the quasi-layer structure. The polarisation gradient is an essential term for describing the ferroelectric nature of the systems. The approaches provide theoretical foundations for testing and predicting polar structures in emerging polar liquid crystals.

cond-mat.soft↗

arXiv2023

Collective and non-collective molecular dynamics in a ferroelectric nematic liquid crystal studied by broadband dielectric spectroscopy

A great deal of effort has been recently devoted to the study of dielectric relaxation processes in ferroelectric nematic liquid crystals, yet their interpretation remains unclear. In this work, we present the results of broadband dielectric spectroscopy experiments of a prototypical ferroelectric nematogen in the frequency range 10 Hz-110 MHz at different electrode separations and under the application of DC bias fields. The results evidence a complex behavior in all phases due to the magnitude of polar correlations in these systems. The observed modes have been assigned to different relaxation mechanisms based on existing theoretical frameworks.

cond-mat.soft↗

arXiv2023

High-g-Factor Phase-Matched Circular Dichroism of Second Harmonic Generation in Chiral Polar Liquids

Circular dichroism is a technologically important phenomenon contrasting the absorption and resultant emission properties between left- and right-handed circularly polarized light. While the chiral handedness of systems mainly determines the mechanism of the circular dichroism in linear optics, the counterpart in the nonlinear optical regime is nontrivial. Here, in contrast to traditional nonlinear circular dichroism responses from structured surfaces, we report on an unprecedented bulk-material-induced circular dichroism of second harmonic generation with a massive g-factor up to 1.8.

physics.optics↗

arXiv2023

Polarization patterning in ferroelectric nematic liquids

The recently discovered ferroelectric nematic liquids incorporate to the functional combination of fluidity, processability and anisotropic optical properties of nematic liquids, an astonishing range of physical properties derived from the phase polarity. Among them, the remarkably large values of second order optical susceptibility encourage to exploit these new materials for non-linear photonic applications. Here we show that photopatterning of the alignment layer can be used to structure polarization patterns. To do so, we take advantage of the flexoelectric effect and design splay structures that geometrically define the polarization direction. We demonstrate the creation of periodic polarization structures and the possibility of guiding polarization by embedding splay structures in uniform backgrounds. The demonstrated capabilities of polarization patterning, open a promising new route for the design of ferroelectric nematic based photonic structures and their exploitation.

cond-mat.soft↗

arXiv2022

Spontaneous electric-polarization topology in confined ferroelectric nematics

Topological spin and polar textures have fascinated people in different areas of physics and technologies. However, the observations are limited in magnetic and solid-state ferroelectric systems. Ferroelectric nematic is the first liquid-state ferroelectric that would carry many possibilities of spatially distributed polarization fields. Contrary to traditional magnetic or crystalline systems, anisotropic liquid crystal interactions can compete with the polarization counterparts, thereby setting a challenge in understating their interplays and the resultant topologies. Here, we discover chiral polarization meron-like structures during the emergence and growth of quasi-2D ferroelectric nematic domains, which are visualized by fluorescence confocal polarizing microscopy and second harmonic generation microscopies. Such micrometre-scale polarization textures are the modified electric variants of the magnetic merons. Unlike the conventional liquid crystal textures driven solely by the elasticity, the polarization field puts additional topological constraints, e.g., head-to-tail asymmetry, to the systems and results in a variety of previously unidentified polar topological patterns. The chirality can emerge spontaneously in polar textures and can be additionally biased by introducing chiral dopants. An extended mean-field modelling for the ferroelectric nematics reveals that the polarization strength of systems plays a dedicated role in determining polarization topology, providing a guide for exploring diverse polar textures in strongly-polarized liquid crystals.

cond-mat.soft↗

arXiv2022

Running streams of a ferroelectric nematic liquid crystal on a lithium niobate surface

Sessile droplets of a ferroelectric nematic liquid crystalline material were exposed to surface electric fields produced by pyroelectric and photogalvanic (photovoltaic) effects in X-cut iron-doped lithium niobate crystals. The resulting dynamic processes were monitored by polarization optical (video)microscopy (POM). During heating/cooling cycles, at first, the droplets change their shape from spherical to extended ellipsoidal. Then they start to move rapidly along the surface electric field, i.e., along the crystal's polar axis (c-axis). During this motion, several droplets merge into running streams (tendrils) extending towards the edges of the top surface area. Finally, practically all liquid crystalline material is transported from the top surface to the side surfaces of the crystal. At stabilized temperature, laser illumination of the assembly causes dynamic processes that are localized to the illuminated area. Also, in this case, the LC droplets merge into several tendril-like formations that are preferentially oriented along the c-axis of the crystal. The pattern of tendrils fluctuates with time, but it persists as long as the illumination is present. In this case, the LC material is transported between the central and the edge region of the illuminated area.

cond-mat.soft↗

arXiv2021

Observation of Spontaneous Helielectric Nematic Fluids: Electric Analogy to Helimagnets

About a century ago, Born proposed a possible matter of state, ferroelectric fluid, might exist if the dipole moment is strong enough. The experimental realisation of such states needs magnifying molecular polar nature to macroscopic scales in liquids. Here, we report on the discovery of a novel chiral liquid matter state, dubbed chiral ferronematic, stabilized by the local ferroelectric ordering coupled to the chiral helicity. It carries the polar vector rotating helically, corresponding to a helieletric structure, analogous to the magnetic counterpart of helimagnet. The state can be retained down to room-temperature and demonstrates gigantic dielectric and nonlinear optical responses. The novel matter state opens a new chapter for exploring the material space of the diverse ferroelectric liquids.

cond-mat.soft↗

arXiv2020

Development of polar nematic fluids with giant-\k{appa} dielectric properties

Super-high-\k{appa} materials that exhibit exceptionally high dielectric permittivity are recognized as potential candidates for a wide range of next-generation photonic and electronic devices. Generally, the high dielectricity for achieving a high-\k{appa} state requires a low symmetry of materials so that most of the discovered high-\k{appa} materials are symmetry-broken crystals. There are scarce reports on fluidic high-\k{appa} dielectrics. Here we demonstrate a rational molecular design, supported by machine-learning analyses, that introduces high polarity to asymmetric molecules, successfully realizing super-high-\k{appa} fluid materials (dielectric permittivity, {\epsilon} > 104) and strong second harmonic generation with macroscopic spontaneous polar ordering. The polar structures are confirmed to be identical for all the synthesized materials. Our experiments and computational calculation reveal the unique orientational structures coupled with the emerging polarity. Furthermore, adopting this strategy to high-molecular-weight systems additionally extends the novel material category from monomer to polar polymer materials, creating polar soft matters with spontaneous symmetry breaking.

cond-mat.mtrl-sci↗

arXiv2019

Kinetics of motile solitons in fluid nematics

Solitary waves, dubbed "solitons", are special types of waves that propagate for an infinite distance under ideal conditions. These waves are ubiquitously found in nature such as typhoon or neuron signals. Yet, their artificial generation and the control of their propagation remain outstanding challenges in materials science owing to an insufficient understanding of the experimental conditions and theoretical aspects. Herein, a generic strategy for forming particle-like solitons and controlling their kinetics in nematic fluid media is reported. The key to the realisation of the generation of solitons and the control of their kinetics is the coupling between the fluid elasticity and the background flow flux, as evidenced by experimental observations and theoretical approaches. The findings of this study enable the exploration of solitons in a wide range of materials and have technological ramifications for the lossless transport of energy or structures.

cond-mat.soft↗