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Savvas Constantinou

Publications and source records attributed to Savvas Constantinou.

18 recordsLinked to original sources

Ground-based Atmospheric Characterization of Super-Earth L 98-59 d at High Spectral Resolution

Atmospheric characterization of exoplanets using ground-based high-resolution transmission spectroscopy has traditionally focussed on large and close-in planets, such as hot Jupiters. In this work, we aim to extend this technique to smaller and more temperate planets by studying the atmospheric composition of the temperate super-Earth planet L 98-59 d ($\sim$$1.5\,\mathrm{R_{\oplus}}$; $\sim$$1.9\,\mathrm{M_{\oplus}}$). Using high-resolution transmission spectra obtained using IGRINS on the Gemini-South telescope, we demonstrate the feasibility for atmospheric characterization of super-Earths using ground-based facilities, and confirm the previous tentative JWST inference of hydrogen sulfide (H2S) in the atmosphere of L 98-59 d at $\lesssim$3.9$\,\sigma$ ($B\sim390$). This is the first ground-based inference of a molecular species in the atmosphere of a super-Earth planet, and reveals the sensitivity of spectrographs on 8m-class telescopes to the atmospheric characterization of such planets. By exploring a grid of atmospheric models, we find that the data favors a cloud-free atmosphere with an abundance of H2S corresponding to $\sim$1-10$\times$ solar metallicity. We additionally place constraints on the atmospheric abundances of other molecular species. Assuming cloud-free models, super-solar abundances for CH4 and NH3 are ruled out at 3.6$\sigma$ and $4.6\sigma$, respectively. Our results are consistent with previous suggestions that L 98-59 d is a super-Earth with possible disequilibrium production of H2S driven by volcanic outgassing from the surface. Future studies combining multiple observations with different facilities may be able to further constrain the atmospheric composition of this planet. This work underscores the promise of atmospheric characterization of super-Earth exoplanets using high-resolution spectroscopy with ground-based facilities.

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The atmospheric composition of TOI-270 d

The first explorations of temperate sub-Neptune exoplanets have been the hallmark of early JWST observations. The bulk properties of such planets are consistent with a range of possible internal structures, which can be distinguished through their interactions with the observable atmospheres. JWST observations of TOI-270 d, a temperate sub-Neptune, have previously led to contrasting conclusions: either a Hycean world, possessing a liquid water ocean, or a mixed-envelope sub-Neptune, where high temperatures prevent a liquid ocean and lead to a high mean molecular weight atmosphere. In order to resolve this uncertainty, we present a comprehensive retrieval analysis of TOI-270 d using recent NIRISS and NIRSpec transit spectroscopy across $\sim$1-5 $\mu$m. We find that prior inferences of a mixed envelope were affected by specific modelling choices leading to a high terminator temperature and high mean-molecular weight in the atmosphere. We confirm an H$_2$-rich atmosphere in TOI-270 d and present revised constraints on the molecular log-mixing ratios and maximal detection significances of CH$_4$ at $-1.86^{+0.30}_{-0.29}$ (6.4 $\sigma$), CO$_2$ at $-1.71^{+0.38}_{-0.66}$ (3.9 $\sigma$), H$_2$O at $-1.88^{+0.78}_{-4.13}$ (2.1 $\sigma$) and CS$_2$ at $-4.74^{+0.65}_{-1.10}$ (2.0 $\sigma$), with a terminator temperature of $323^{+58}_{-52}$ K at 10 mbar. We also find tentative evidence for more complex methyl-bearing species such as C$_2$H$_6$ and/or DMS at a 2.1-2.5 $\sigma$ level. The present constraints are consistent with TOI-270 d being a Hycean or dark Hycean world, with planet-wide or nightside liquid water oceans. However, more observations are required to verify the present findings and robustly constrain the atmospheric conditions and internal structure of TOI-270 d.

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Exploring the Sub-Neptune Frontier with JWST

Sub-Neptune planets, with sizes and masses between those of Earth and Neptune, dominate the exoplanet population. Sub-Neptunes are expected to be the most diverse family of the exoplanet population, potentially including rocky gas dwarfs, water worlds, and mini-Neptunes, with a wide range of atmospheric, surface and interior conditions. With no analogue in the solar system, these planets open fundamental questions in planetary processes, origins, and habitability, and present new avenues in the search for life elsewhere. Atmospheric observations with the James Webb Space Telescope (JWST) are enabling unprecedented characterization of sub-Neptunes, starting with the first detections of carbon-bearing molecules in the habitable zone sub-Neptune K2-18 b. We survey the present landscape of JWST observations and atmospheric inferences of sub-Neptunes, which in turn provide key insights into their atmospheric processes, internal structures, surface conditions, formation pathways and potential habitability. The atmospheric abundance constraints reveal evidence of chemical disequilibria, and insights into the planetary mass-metallicity relation in the sub-Neptune regime. Similarly, for sub-Neptunes with H$_2$O-rich interiors, increasing atmospheric H$_2$O abundances with the equilibrium temperature may indicate the existence of a critical temperature for transition from H$_2$ dominated atmospheres with tropospheric cold traps to those with steamy atmospheres. The chemical abundances also provide initial evidence for diverse planet types, from potentially habitable hycean worlds to steam worlds with super critical water layers. These planet types serve as benchmarks for an emerging taxonomy of volatile-rich sub-Neptunes as a function of their equilibrium temperature and atmospheric extent, heralding a new era of chemical classification of low-mass exoplanets with JWST.

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A water-rich interior in the temperate sub-Neptune K2-18 b revealed by JWST

Temperate sub-Neptunes are compelling targets for detecting liquid-water oceans beyond the Solar System. If water-rich and lacking massive hydrogen-helium envelopes, these planets could sustain liquid layers beneath their atmospheres despite sizes larger than Earth. Previous observations of the temperate sub-Neptune K2-18 b revealed an H2-dominated atmosphere rich in CH4, with moderate evidence for CO2 and tentative signs of dimethyl sulfide (DMS). Here we present four new JWST/NIRSpec transit observations of K2-18 b. The resulting high-precision transmission spectrum robustly detects both CH4 and CO2, precisely measuring their abundances and firmly establishing the planet's water-rich nature: either a thick envelope with >10% H2O by volume or a thin atmosphere above a liquid-water ocean. The spectrum reveals no detectable H2O, NH3, or CO. The absence of atmospheric water vapor suggests an efficient cold trap, while the nondetections of NH3 and CO support the scenario of a small H2-rich atmosphere overlying a liquid reservoir. However, alternative models that include these gases can also reproduce the spectrum within uncertainties, highlighting the need for deeper observations. The spectrum only contains marginal signals of DMS, methyl mercaptan (CH3SH), and nitrous oxide (N2O), with none exceeding 3 sigma in model preference and all falling below ~2 sigma without imposing a strong super-Rayleigh haze. Meanwhile, our self-consistent photochemical models show that DMS and CH3SH may form abiotically in massive H2-rich atmospheres of high metallicity, making it important to consider additional indicators for their potential use as biosignatures. K2-18 b, a cool, water-rich world, stands out as one of the most promising temperate sub-Neptunes for exploring the emergence of liquid-water environments in non-Earth-like planets, motivating further characterization of its atmosphere and interior.

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A Systematic Search for Trace Molecules in the Atmosphere of Exoplanet K2-18 b

The first transmission spectrum of the habitable-zone sub-Neptune K2-18 b with JWST has opened a new avenue for atmospheric characterisation of temperate low-mass exoplanets. The observations led to inferences of methane and carbon dioxide, as well as of dimethyl sulfide (DMS) and/or dimethyl disulfide (DMDS), both potential biosignatures. In the present work we conduct a broad and agnostic search for other chemical species in the atmosphere of K2-18 b. Our exploration includes 661 molecules, spanning a wide range of trace gases, including biotic, abiotic, and anthropogenic gases on Earth. We investigate possible preference for any of these gases, compared to a model only including the previously-detected CH$_4$ and CO$_2$, using three metrics: (a) preference in the JWST mid-infrared (MIR) spectrum, (b) preference in the JWST near-infrared spectrum, for species preferred in MIR and (c) plausible sources of production. We find that only DMS consistently results in Bayes factors $\ln B \geq 2.0$ across the datasets considered independently, though in the near-infrared this depends on detector offsets, as previously reported. The threshold of $\ln B \geq 2.0$ is motivated by the conventional threshold of $\ln B \geq 2.5$ for moderate preference, allowing for an empirical uncertainty of 0.5. A few other gases also provide comparable fits to a subset of the data or only with some of the retrieval codes used, but with limited known plausible sources. Our study highlights the need for further observations to distinguish between possible trace gases in the atmosphere of K2-18 b and theoretical work to establish their plausible sources.

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New Constraints on DMS and DMDS in the Atmosphere of K2-18 b from JWST MIRI

The sub-Neptune frontier has opened a new window into the rich diversity of planetary environments beyond the solar system. The possibility of hycean worlds, with planet-wide oceans and H$_2$-rich atmospheres, significantly expands and accelerates the search for habitable environments elsewhere. Recent JWST transmission spectroscopy of the candidate hycean world K2-18 b in the near-infrared led to the first detections of carbon-bearing molecules CH$_4$ and CO$_2$ in its atmosphere, with a composition consistent with predictions for hycean conditions. The observations also provided a tentative hint of dimethyl sulfide (DMS), a possible biosignature gas, but the inference was of low statistical significance. We report a mid-infrared transmission spectrum of K2-18 b obtained using the JWST MIRI LRS instrument in the ~6-12 $μ$m range. The spectrum shows distinct features and is inconsistent with a featureless spectrum at 3.4-$σ$ significance compared to our canonical model. We find that the spectrum cannot be explained by most molecules predicted for K2-18 b with the exception of DMS and dimethyl disulfide (DMDS), also a potential biosignature gas. We report new independent evidence for DMS and/or DMDS in the atmosphere at 3-$σ$ significance, with high abundance ($\gtrsim$10 ppmv) of at least one of the two molecules. More observations are needed to increase the robustness of the findings and resolve the degeneracy between DMS and DMDS. The results also highlight the need for additional experimental and theoretical work to determine accurate cross sections of important biosignature gases and identify potential abiotic sources. We discuss the implications of the present findings for the possibility of biological activity on K2-18 b.

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Towards a self-consistent evaluation of gas dwarf scenarios for temperate sub-Neptunes

The recent JWST detections of carbon-bearing molecules in a habitable-zone sub-Neptune have opened a new era in the study of low-mass exoplanets. The sub-Neptune regime spans a wide diversity of planetary interiors and atmospheres not witnessed in the solar system, including mini-Neptunes, super-Earths, and water worlds. Recent works have investigated the possibility of gas dwarfs, with rocky interiors and thick H$_2$-rich atmospheres, to explain aspects of the sub-Neptune population, including the radius valley. Interactions between the H$_2$-rich envelope and a potential magma ocean may lead to observable atmospheric signatures. We report a coupled interior-atmosphere modelling framework for gas dwarfs to investigate the plausibility of magma oceans on such planets and their observable diagnostics. We find that the surface-atmosphere interactions and atmospheric composition are sensitive to a wide range of parameters, including the atmospheric and internal structure, mineral composition, volatile solubility and atmospheric chemistry. While magma oceans are typically associated with high-temperature rocky planets, we assess if such conditions may be admissible and observable for temperate sub-Neptunes. We find that a holistic modelling approach is required for this purpose and to avoid unphysical model solutions. We find using our model framework and considering the habitable-zone sub-Neptune K2-18 b as a case study that its observed atmospheric composition is incompatible with a magma ocean scenario. We identify key atmospheric molecular and elemental diagnostics, including the abundances of CO$_2$, CO, NH$_3$ and, potentially, S-bearing species. Our study also underscores the need for fundamental material properties for accurate modelling of such planets.

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Exoplanet Transit Spectroscopy with JWST NIRSpec: Diagnostics and Homogeneous Case Study of WASP-39 b

The JWST has ushered in a new era of exoplanet transit spectroscopy. Among the JWST instruments, the Near-Infrared Spectrograph (NIRSpec) has the most extensive set of configurations for exoplanet time series observations. The NIRSpec Prism and G395H grating represent two extremes in NIRSpec instrument modes, with the Prism spanning a wider spectral range (0.6-5.3 $μ$m at lower resolution (R$\sim$100) compared to G395H (2.87-5.14 $μ$m; R$\sim$2700). In this work, we develop a new data reduction framework, JexoPipe, to conduct a homogeneous assessment of the two NIRSpec modes for exoplanet spectroscopy. We use observations of the hot Saturn WASP-39 b obtained as part of the JWST Transiting Exoplanets ERS program to assess the spectral quality and stability between the two instrument modes at different epochs. We explore the noise sources, effect of saturation, and offsets in transmission spectra between the different instrument modes and also between the two G395H NRS detectors. We find an inter-detector offset in G395H of $\sim$ 40-50 ppm, consistent with recent studies. We find evidence for correlated noise in the Prism white light curve. We find the G395H spectrum to be of higher precision compared to the Prism at the same resolution. We also compare the JexoPipe spectra with those reported from other pipelines. Our work underscores the need for robust assessment of instrument performance and identification of optimal practices for JWST data reduction and analyses.

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High-resolution Spectroscopic Reconnaissance of a Temperate Sub-Neptune

The study of temperate sub-Neptunes is the new frontier in exoplanetary science. A major development in the past year has been the first detection of carbon-bearing molecules in the atmosphere of a temperate sub-Neptune, K2-18 b, a possible Hycean world, with the James Webb Space Telescope (JWST). The JWST is poised to characterise the atmospheres of several other such planets with important implications for planetary processes in the temperate regime. Meanwhile, ground-based high-resolution spectroscopy has been highly successful in detecting chemical signatures of giant exoplanets, though low-mass planets have remained elusive. In the present work, we report the atmospheric reconnaissance of a temperate sub-Neptune using ground-based high-resolution transmission spectroscopy. The long orbital period and the low systemic velocity results in a low planetary radial velocity during transit, making this system a valuable testbed for high-resolution spectroscopy of temperate sub-Neptunes. We observe high-resolution time-series spectroscopy in the H- and K-bands during the planetary transit with the IGRINS instrument (R$\sim$45,000) on Gemini-South. Using observations from a single transit we find marginal evidence (2.2$σ$) for the presence of methane (CH$_4$) in the atmosphere and no evidence for ammonia (NH$_3$) despite its strong detectability for a cloud-free H$_2$-rich atmosphere. We assess our findings using injection tests with different atmospheric scenarios, and find them to be consistent with a high CH$_4$/NH$_3$ ratio and/or the presence of high-altitude clouds. Our results demonstrate the capability of Gemini-S/IGRINS for atmospheric characterization of temperate sub-Neptunes, and the complementarity between space- and ground-based facilities in this planetary regime.

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VIRA: An Exoplanet Atmospheric Retrieval Framework for JWST Transmission Spectroscopy

JWST observations are leading to important new insights into exoplanetary atmospheres through transmission spectroscopy. In order to harness the full potential of the broad spectral range and high sensitivity of JWST, atmospheric retrievals of exoplanets require a high level of robustness and accuracy in the underlying models. We present the VIRA retrieval framework which implements a range of modelling and inference capabilities motivated by early JWST observations of exoplanet transmission spectra. This includes three complementary approaches to modelling atmospheric composition, three atmospheric aerosol models, including a physically-motivated Mie scattering approach, and consideration of correlated noise. VIRA enables a cascading retrieval architecture involving a sequence of retrievals with increasing sophistication. We demonstrate VIRA using a JWST transmission spectrum of the hot Saturn WASP-39 b in the $\sim$1-5 $μ$m range. In addition to confirming prior chemical inferences, we retrieve molecular abundances for H$_2$O, CO, CO$_2$, SO$_2$ and H$_2$S, resulting in super-solar elemental abundances of log(O/H)=$-2.0\pm0.2$, log(C/H)=$-2.1\pm0.2$ and log(S/H)=$-3.6\pm0.2$, along with C/O and S/O ratios of $0.83^{+0.05}_{-0.07}$ and $0.029^{+0.012}_{-0.009}$, respectively, in the free chemistry case. The abundances correspond to $20.1^{+10.5}_{-8.1}\times$, $28.2^{+16.3}_{-12.1}\times$ and $20.8^{+10.3}_{-7.5}\times$ solar values for O/H, C/H and S/H, respectively, compared to C/H $= 8.67\pm0.35 \times$ solar for Saturn. Our results demonstrate how JWST transmission spectroscopy combined with retrieval frameworks like VIRA can measure multi-elemental abundances for giant exoplanets and enable comparative characterisation with solar system planets.

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Carbon-bearing Molecules in a Possible Hycean Atmosphere

The search for habitable environments and biomarkers in exoplanetary atmospheres is the holy grail of exoplanet science. The detection of atmospheric signatures of habitable Earth-like exoplanets is challenging due to their small planet-star size contrast and thin atmospheres with high mean molecular weight. Recently, a new class of habitable exoplanets, called Hycean worlds, has been proposed, defined as temperate ocean-covered worlds with H2-rich atmospheres. Their large sizes and extended atmospheres, compared to rocky planets of the same mass, make Hycean worlds significantly more accessible to atmospheric spectroscopy with the JWST. Here we report a transmission spectrum of the candidate Hycean world, K2-18 b, observed with the JWST NIRISS and NIRSpec instruments in the 0.9-5.2 $μ$m range. The spectrum reveals strong detections of methane (CH4) and carbon dioxide (CO2) at 5$σ$ and 3$σ$ confidence, respectively, with high volume mixing ratios of ~1% each in a H2-rich atmosphere. The abundant CH4 and CO2 along with the non-detection of ammonia (NH3) are consistent with chemical predictions for an ocean under a temperate H2-rich atmosphere on K2-18 b. The spectrum also suggests potential signs of dimethyl sulfide (DMS), which has been predicted to be an observable biomarker in Hycean worlds, motivating considerations of possible biological activity on the planet. The detection of CH4 resolves the long-standing missing methane problem for temperate exoplanets and the degeneracy in the atmospheric composition of K2-18 b from previous observations. We discuss possible implications of the findings, open questions, and future observations to explore this new regime in the search for life elsewhere.

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A precise blue-optical transmission spectrum from the ground: Evidence for haze in the atmosphere of WASP-74b

We report transmission spectroscopy of the bloated hot Jupiter WASP-74b in the wavelength range from 4000 to 6200 Å. We observe two transit events with the Very Large Telescope FOcal Reducer and Spectrograph (VLT FORS2) and present a new method to measure the exoplanet transit depth as a function of wavelength. The new method removes the need for a reference star in correcting the spectroscopic light curves for the impact of atmospheric extinction. It also provides improved precision, compared to other techniques, reaching an average transit depth uncertainty of 211 ppm for a solar-type star of V=9.8 mag and over wavelength bins of 80 Å. The VLT transmission spectrum is analysed both individually and in combination with published data from Hubble Space Telescope (HST) and Spitzer. The spectrum is found to exhibit a mostly featureless slope and equilibrium chemistry retrievals with PLATON favour hazes in the upper atmosphere of the exoplanet. Free chemistry retrievals with AURA further support the presence of hazes. While additional constraints are possible depending on the choice of atmospheric model, they are not robust and may be influenced by residual systematics in the data sets. Our results demonstrate the utility of new techniques in the analysis of optical, ground-based spectroscopic data and can be highly complementary to follow-up observations in the infrared with JWST.

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Early Insights for Atmospheric Retrievals of Exoplanets using JWST Transit Spectroscopy

We have entered the era of the James Webb Space Telescope (JWST). We use the first JWST transmission spectrum of the hot Saturn-mass exoplanet, WASP-39 b, obtained with the NIRSpec instrument in the 3-5 $μ$m range to investigate (a) what atmospheric constraints are possible with JWST-quality data in this spectral range, (b) requirements for atmospheric models used in retrievals, (c) effect of differences between data reduction pipelines on retrieved atmospheric properties, and (d) complementarity between JWST data in the 3-5 $μ$m range and HST observations at shorter wavelengths. JWST spectra in the 3-5 $μ$m range provide a promising avenue for chemical detections while encompassing a window in cloud opacity for several prominent aerosols. We confirm recent inferences of CO$_2$, SO$_2$, H$_2$O, and CO in WASP-39 b, report tentative evidence for H$_2$S, and retrieve elemental abundances consistent with Saturn's metallicity. We retrieve molecular abundances with $\sim$0.3-0.6 dex precision with this relatively limited spectral range. When considering the 3-5 $μ$m data alone, reported differences in spectra with different reduction pipelines can affect abundance estimates by up to $\sim$1 dex and the detectability of less prominent species. Complementing with data at shorter wavelengths, e.g. with other JWST instruments or HST WFC3 ($\sim$0.8-1.7 $μ$m), can significantly improve the accuracy and precision of the abundance estimates. The high data quality enables constraints on aerosol properties, including their composition, modal size and extent, motivating their consideration in retrievals. Our results highlight the promise of JWST exoplanet spectroscopy, while underscoring the importance of robust data reduction and atmospheric retrieval approaches in the JWST era.

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Characterising Atmospheres of Cloudy Temperate Mini-Neptunes with JWST

The upcoming James Webb Space Telescope (JWST) promises a generational shift in the study of temperate mini-Neptune atmospheres using transit spectroscopy. High-altitude clouds however threaten to impede their atmospheric characterisation by muting spectral features. In this study, we systematically investigate JWST instrument configurations for characterising cloudy mini-Neptune atmospheres, assessing the importance of instrument choice and wavelength coverage, focusing on NIRISS and NIRSpec. We consider two temperate mini-Neptunes orbiting nearby M dwarfs, K2-18 b and TOI-732 c, with equilibrium temperatures below 400 K, as case studies and assess observations using different instrument configurations with one transit per instrument. We find that their JWST transmission spectra with modest observing time and adequate wavelength coverage can provide precise abundance constraints of key molecules H2O, CH4, and NH3 even in the presence of clouds at significantly high altitudes. The best constraints are obtained by combining all three high-resolution NIRSpec gratings (G140H+G235H+G395H) that together span the ~1-5 $μ$m range. Single-transit observations with this three-instrument configuration allow precise abundance constraints for cloud-top pressures as low as 3 mbar and 0.1 mbar for K2-18 b and TOI-732 c, respectively, assuming a nominal 10x solar metallicity. The constraints vary with instrument combinations. We find that NIRSpec G235H+G395H is the optimal two-instrument configuration, while NIRISS or NIRSpec G235H is optimal for single-instrument observations. Absent high-altitude clouds, even single-instrument observations can provide good abundance constraints for these planets. Our findings underscore the promise of JWST transmission spectroscopy for characterising temperate mini-Neptunes orbiting nearby M dwarfs.

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Habitability and Biosignatures of Hycean Worlds

We investigate a new class of habitable planets composed of water-rich interiors with massive oceans underlying H2-rich atmospheres, referred to here as Hycean worlds. With densities between those of rocky super-Earths and more extended mini-Neptunes, Hycean planets can be optimal candidates in the search for exoplanetary habitability and may be abundant in the exoplanet population. We investigate the bulk properties (masses, radii, and temperatures), potential for habitability, and observable biosignatures of Hycean planets. We show that Hycean planets can be significantly larger compared to previous considerations for habitable planets, with radii as large as 2.6 Earth radii (2.3 Earth radii) for a mass of 10 Earth masses (5 Earth masses). We construct the Hycean habitable zone (HZ), considering stellar hosts from late M to sun-like stars, and find it to be significantly wider than the terrestrial-like HZ. While the inner boundary of the Hycean HZ corresponds to equilibrium temperatures as high as ~500 K for late M dwarfs, the outer boundary is unrestricted to arbitrarily large orbital separations. Our investigations include tidally locked `Dark Hycean' worlds that permit habitable conditions only on their permanent nightsides and `Cold Hycean' worlds that see negligible irradiation. Finally, we investigate the observability of possible biosignatures in Hycean atmospheres. We find that a number of trace terrestrial biomarkers which may be expected to be present in Hycean atmospheres would be readily detectable using modest observing time with the James Webb Space Telescope (JWST). We identify a sizable sample of nearby potential Hycean planets that can be ideal targets for such observations in search of exoplanetary biosignatures.

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Transmission spectroscopy with VLT FORS2: a featureless spectrum for the low-density transiting exoplanet WASP-88b

We present ground-based optical transmission spectroscopy of the low-density hot Jupiter WASP-88b covering the wavelength range 4413-8333 Å with the FORS2 spectrograph on the Very Large Telescope. The FORS2 white light curves exhibit a significant time-correlated noise which we model using a Gaussian Process and remove as a wavelength-independent component from the spectroscopic light curves. We analyse complementary photometric observations from the Transiting Exoplanet Survey Satellite and refine the system properties and ephemeris. We find a featureless transmission spectrum with increased absorption towards shorter wavelengths. We perform an atmospheric retrieval analysis with the AURA code, finding tentative evidence for haze in the upper atmospheric layers and a lower likelihood for a dense cloud deck. Whilst our retrieval analysis results point toward clouds and hazes, further evidence is needed to definitively reject a clear-sky scenario.

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Ground-Based Transmission Spectroscopy with VLT FORS2: Evidence for faculae and clouds in the optical spectrum of the warm Saturn WASP-110b

We present a ground-based optical transmission spectrum for the warm Saturn-mass exoplanet WASP-110b from two transit observations made with the FOcal Reducer and Spectrograph (FORS2) on the Very Large Telescope (VLT). The spectrum covers the wavelength range from 4000 to 8333Å, which is binned in 46 transit depths measured to an averaged precision of 220 parts per million (ppm) over an averaged 80Å~bin for a Vmag=12.8 star. The measured transit depths are unaffected by a dilution from a close A-type field dwarf, which was fully resolved. The overall main characteristic of the transmission spectrum is an increasing radius with wavelength and a lack of the theoretically predicted pressure-broadened sodium and potassium absorption features for a cloud-free atmosphere. We analyze archival high-resolution optical spectroscopy and find evidence for low to moderate activity of the host star, which we take into account in the atmospheric retrieval analysis. Using the AURA retrieval code, we find that the observed transmission spectrum can be best explained by a combination of unocculted stellar faculae and a cloud deck. Transmission spectra of cloud-free and hazy atmospheres are rejected at a high confidence. With a possible cloud deck at its terminator, WASP-110b joins the increasing population of irradiated hot-Jupiter exoplanets with cloudy atmospheres observed in transmission.

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Neutral Cr and V in the atmosphere of ultra hot jupiter WASP-121 b

Ultra hot jupiters (UHJs), giant exoplanets with equilibrium temperatures above 2000 K, are ideal laboratories for studying metal compositions of planetary atmospheres. At these temperatures the thermal dissociation of metal-rich molecules into their constituent elements makes these atmospheres conducive for elemental characterisation. Several elements, mostly ionized metals, have been detected in UHJs recently using high resolution transit spectroscopy. Even though a number of neutral transition metals (e.g., Fe, Ti, V, Cr) are expected to be strong sources of optical/NUV opacity and, hence, influence radiative processes in the lower atmospheres of UHJs, only Fe I has been detected to date. We conduct a systematic search for atomic species in the UHJ WASP-121 b. Using theoretical models we present a metric to predict the atomic species likely to be detectable in such planets with high resolution transmission spectroscopy. We search for the predicted species in observations of WASP-121 b and report the first detections of neutral transition metals Cr I and V I in an exoplanet at 3.6 $σ$ and 4.5 $σ$, respectively. We confirm previous detections of Fe I and Fe II. Whereas Fe II was detected previously in the NUV, we detect it in the optical. We infer that the neutral elements Fe I, V I, and Cr I are present in the lower atmosphere, as predicted by thermochemical equilibrium, while Fe II is a result of photoionisation in the upper atmosphere. Our study highlights the rich chemical diversity of UHJs.

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