arXiv subjects

Sebastiaan Krijt

Publications and source records attributed to Sebastiaan Krijt.

At least 37 records · Page 2Linked to original sources

arXiv2025

Class I/II Jets with JWST: Mass loss rates, Asymmetries, and Binary induced Wigglings

We present JWST NIRSpec spectro-imaging observations of jets from four edge-on protoplanetary disks that exhibit clear signatures of MHD disk winds. Bipolar jets are detected and spatially resolved in over 30 shock-excited forbidden lines, multiple Paschen and Brackett series lines of atomic hydrogen, and the high-energy excitation line of atomic helium (1.083 um). This helium line is the brightest jet-tracer towards HH 30 and FS TauB, which also exhibit asymmetric intensity between their red- and blue-shifted lobes in all tracers, including the [Fe II] and [He I] lines. Extinction maps reveal no significant differences across the lobes, suggesting an asymmetric jet-launching mechanism rather than environmental effects. Diagnostic line ratios yield consistent shock speeds of 50-60 km/s, jet ionization fractions of 0.1-0.2, and pre-shock electron densities of 1000 /cm^3. Combined with pixel-by-pixel electron density maps and [Fe II] line luminosities, we estimate jet mass-loss rates using three independent methods, averaging around a few 10^(-9) solar masses/yr. We estimate the accretion rates for these sources as 10 times the jet mass loss rates and find them to match well with the independently derived accretion estimates of other Class II sources in the Taurus star-forming region. Owing to JWST's high precision, we also investigate jet wiggling and find Tau 042021 to showcase the perfect case of mirror-symmetric wiggling, which can only be explained by the motion of the jet source around a stellar companion. Modeling this wiggling suggests Tau 042021 to host 0.33 and 0.07 solar masses binary at the center with binary separation of 1.35 au and an orbital period of 2.5 years.

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arXiv2025

Smuggling unnoticed: Towards a 2D view of water and dust delivery to the inner regions of protoplanetary discs

Infrared spectroscopy, e.g., with JWST, provides a glimpse into the chemical inventory of the innermost region of protoplanetary discs, where terrestrial planets eventually form. The chemical make-up of regions inside snowlines is connected to the material drifting from the outer regions, which can be modeled with dust evolution models. However, infrared observations are limited by the high dust extinction in the inner disc, and only probes the abundances of gaseous species in the disc surface layers. As a result, the bulk mass of delivered volatiles is not directly relatable to what is measured through infrared spectra. In this paper, we investigate how the delivery of dust and ice after prolonged pebble drift affects the observable reservoir of water vapor in the inner disc. We develop a 1+1D approach based on dust evolution models to determine the delivery and distribution of vapor compared to the height of the $τ= 1$ surface in the dust continuum. We find that the observable column density of water vapor at wavelengths probed by JWST spans many orders of magnitude over time, exhibiting different radial profiles depending on dust properties, drift rate, and local processing. In the presence of a traffic-jam effect inside the snowline, the observable vapor reservoir appears constant in time despite the ongoing delivery by pebble drift, such that water is effectively smuggled unnoticed. Differences in measured column densities then originate not only from variations in bulk vapor content, but also from differences in the properties and distribution of dust particles.

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arXiv2025

The CO-Fuelled Time Machine: Tracing Birth Conditions and Terrestrial Planet Formation Outcomes in HD 163296 through Pebble Drift-induced CO Enhancements

The architecture and composition of planetary systems are thought to be strongly influenced by the transport and delivery of dust and volatiles via ices on pebbles during the planet formation phase in protoplanetary discs. Understanding these transport mechanisms is crucial in building a comprehensive picture of planet formation, including material and chemical budget; constraining the birth properties of these discs is a key step in this process. We present a novel method of retrieving such properties by studying the transport of icy pebbles in the context of an observed gas-phase CO enhancement within the CO snowline in the protoplanetary disc around HD 163296. We combine Markov Chain Monte Carlo (MCMC) sampling with a fast model of radial drift to determine the birth gas mass and characteristic radius of the disc, and compare our results against observations and models in the literature; we find the birth-condition disc gas mass to be $\log_{10}(M_{\rm{disc}}/M_{\odot})=-0.64^{+0.19}_{-0.24}$ and the characteristic radius to be $\log_{10}(r_{\rm{c}}/\rm{AU})=2.30^{+0.45}_{-0.46}$. We additionally determine that dust grains must be `fragile' ($v_{f}=100~\mathrm{cms}^{-1}$) to retain enough dust to match current dust mass observations, with our lowest fragmentation velocity model providing a current-age dust mass of $\rm{M_{dust}}=662^{+518}_{-278} \rm{M_{\oplus}}$ based on the retrieved birth conditions. Using our retrieved birth conditions, we extend our simulations to mass of material reaching the water snowline in the inner disc, where terrestrial and super-Earth planets may be forming, and speculate on the nature of these exoplanets.

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arXiv2024

The First JWST View of a 30-Myr-old Protoplanetary Disk Reveals a Late-stage Carbon-rich Phase

We present a JWST MIRI/MRS spectrum of the inner disk of WISE J044634.16$-$262756.1B (hereafter J0446B), an old ($\sim$34 Myr) M4.5 star but with hints of ongoing accretion. The spectrum is molecule-rich and dominated by hydrocarbons. We detect 14 molecular species (H$_2$, CH$_3$, CH$_4$, C$_2$H$_2$, $^{13}$CCH$_2$, C$_2$H$_4$, C$_2$H$_6$, C$_3$H$_4$, C$_4$H$_2$, C$_6$H$_6$, HCN, HC$_3$N, CO$_2$ and $^{13}$CO$_2$) and 2 atomic lines ([Ne II] and [Ar II]), all observed for the first time in a disk at this age. The detection of spatially unresolved H$_2$ and Ne gas strongly supports that J0446B hosts a long-lived primordial disk, rather than a debris disk. The marginal H$_2$O detection and the high C$_2$H$_2$/CO$_2$ column density ratio indicate that the inner disk of J0446B has a very carbon-rich chemistry, with a gas-phase C/O ratio $\gtrsim$2, consistent with what have been found in most primordial disks around similarly low-mass stars. In the absence of significant outer disk dust substructures, inner disks are expected to first become water-rich due to the rapid inward drift of icy pebbles, and evolve into carbon-rich as outer disk gas flows inward on longer timescales. The faint millimeter emission in such low-mass star disks implies that they may have depleted their outer icy pebble reservoir early and already passed the water-rich phase. Models with pebble drift and volatile transport suggest that maintaining a carbon-rich chemistry for tens of Myr likely requires a slowly evolving disk with $α-$viscosity $\lesssim10^{-4}$. This study represents the first detailed characterization of disk gas at $\sim$30 Myr, strongly motivating further studies into the final stages of disk evolution.

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arXiv2024

Water in protoplanetary disks with JWST-MIRI: spectral excitation atlas and radial distribution from temperature diagnostic diagrams and Doppler mapping

This work aims at providing fundamental general tools for the analysis of water spectra as observed in protoplanetary disks with JWST-MIRI. We analyze 25 high-quality spectra from the JDISC Survey reduced with asteroid calibrators as presented in Pontoppidan et al. (2024). First, we present a spectral atlas to illustrate the clustering of H$_2$O transitions from different upper level energies ($E_u$) and identify single (un-blended) transitions that provide the most reliable measurements. With that, we demonstrate two important excitation effects: the opacity saturation of ortho-para line pairs that overlap, and the non-LTE excitation of $v=1-1$ lines scattered across the $v=0-0$ rotational band. Second, we define a shorter list of fundamental lines spanning $E_u=$ 1500-6000 K to develop simple line-ratio diagnostic diagrams for the radial temperature distribution of water in inner disks, which can be interpreted using discrete temperature components or a radial gradient. Third, we report the detection of disk-rotation Doppler broadening of molecular lines, which confirms the radial distribution of water emission including, for the first time, the radially-extended $\approx$ 170-220 K reservoir close to the snowline. The combination of measured line ratios and broadening suggests that drift-dominated disks have shallower temperature gradients with an extended cooler disk surface enriched by ice sublimation. We also report the first detection of a H$_2$O-rich inner disk wind from narrow blue-shifted absorption in the ro-vibrational lines. We summarize these findings and tools into a general recipe to make the study of water in planet-forming regions reliable, effective, and sustainable for samples of $> 100$ disks.

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arXiv2024

JWST/MIRI detection of a carbon-rich chemistry in a solar nebula analog

It has been proposed, and confirmed by multiple observations, that disks around low mass stars display a molecule-rich emission and carbon-rich disk chemistry as compared to their hotter, more massive solar counterparts. In this work, we present JWST Disk Infrared Spectral Chemistry Survey (JDISCS) MIRI-MRS observations of the solar-mass star DoAr 33, a low-accretion rate T Tauri star showing an exceptional carbon-rich inner disk. We report detections of H$_2$O, OH, and CO$_2$, as well as the more complex hydrocarbons, C$_2$H$_2$ and C$_4$H$_2$. Through the use of thermochemical models, we explore different spatial distributions of carbon and oxygen across the inner disk and compare the column densities and temperatures obtained from LTE slab model retrievals. We find a best match to the observed column densities with models that have carbon enrichment, and the retrieved emitting temperature and area of C$_2$H$_2$ with models that have C/O $=$ 2$-$4 inside the 500 K carbon-rich dust sublimation line. This suggests that the origin of the carbon-rich chemistry is likely due to the sublimation of carbon rich grains near the soot line. This would be consistent with the presence of dust processing as indicated by the detection of crystalline silicates. We propose that this long-lived hydrocarbon rich chemistry observed around a solar-mass star is a consequence of the unusually low M-star-like accretion rate of the central star, which lengthens the radial mixing timescale of the inner disk allowing the chemistry powered by carbon grain destruction to linger.

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arXiv2024

JWST/NIRSpec Reveals the Nested Morphology of Disk Winds from Young Stars

Radially extended disk winds could be the key to unlocking how protoplanetary disks accrete and how planets form and migrate. A distinctive characteristic is their nested morphology of velocity and chemistry. Here we report JWST/NIRSpec spectro-imaging of four young stars with edge-on disks in the Taurus star-forming region that demonstrate the ubiquity of this structure. In each source, a fast collimated jet traced by [Fe II] is nested inside a hollow cavity within wider lower-velocity H2 and, in one case, also CO ro-vibrational (v=1-0) emission. Furthermore, in one of our sources, ALMA CO(2-1) emission, paired with our NIRSpec images, reveals the nested wind structure extends further outward. This nested wind morphology strongly supports theoretical predictions for wind-driven accretion and underscores the need for theoretical work to assess the role of winds in the formation and evolution of planetary systems

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arXiv2024

A closer look at individual collisions of dust aggregates: Material mixing and exchange on microscopic scales

Collisions between aggregates with different histories and compositions are expected to be commonplace in dynamically active protoplanetary discs. Nonetheless, relatively little is known about how collisions themselves may contribute to the resulting mixing of material. Here we use state-of-the-art granular dynamics simulations to investigate mixing between target/projectile material in a variety of individual aggregate-aggregate collisions, and use the results to discuss the efficiency of collisional mixing in protoplanetary environments. We consider sticking collisions (up to 10-20 m/s for our set-up) and disruptive collisions (40 m/s) of BPCA and BCCA clusters, and quantify mixing in the resulting fragments on both individual fragment and sub-aggregate levels. We find that the mass fraction of material that can be considered to be `well-mixed' (i.e., locally made up of a mix of target and projectile material) to be limited, typically between 3-6% for compact BPCA precursors, and increasing to 20-30% for more porous BCCA clusters. The larger fragments produced in disruptive collisions are equally heterogeneous, suggesting aggregate-aggregate collisions are a relatively inefficient way of mixing material with different origins on small scales.

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arXiv2024

Retrieval of Thermally-Resolved Water Vapor Distributions in Disks Observed with JWST-MIRI

The mid-infrared water vapor emission spectrum provides a novel way to characterize the delivery of icy pebbles towards the innermost ($<5$ au) regions of planet-forming disks. Recently, JWST MIRI-MRS showed that compact disks exhibit an excess of low-energy water vapor emission relative to extended multi-gapped disks, suggesting that icy pebble drift is more efficient in the former. We carry out detailed emission line modeling to retrieve the excitation conditions of rotational water vapor emission in a sample of four compact and three extended disks within the JDISC Survey. We present two-temperature H$_2$O slab model retrievals and, for the first time, constrain the spatial distribution of water vapor by fitting parametric radial temperature and column density profiles. Such models statistically outperform the two-temperature slab fits. We find a correlation between the observable hot water vapor mass and stellar mass accretion rate, as well as an anti-correlation between cold water vapor mass and sub-mm dust disk radius, confirming previously reported water line flux trends. We find that the mid-IR spectrum traces H$_2$O with temperatures down to 180-300 K, but the coldest 150-170 K gas remains undetected. Furthermore the H$_2$O temperature profiles are generally steeper and cooler than the expected `super-heated' dust temperature in passive irradiated disks. The column density profiles are used to estimate icy pebble mass fluxes, which suggest that compact and extended disks may produce markedly distinct inner-disk exoplanet populations if local feeding mechanisms dominate their assembly.

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arXiv2023

Surviving the Heat: multi-wavelength analysis of V883 Ori reveals that dust aggregates survive the sublimation of their ice mantles

Investigating the response of icy dust aggregates to water ice sublimation is essential for understanding the formation and properties of planetesimals in protoplanetary discs. However, their fate remains unclear, as previous studies suggest aggregates could either survive or completely fall apart to (sub)μm-sized grains. Protoplanetary discs around stars undergoing accretion outbursts represent a unique laboratory to study the ice sublimation process, as the water snowline is pushed outward to regions accessible to current observatories. In this work, we aim to understand the aggregates' response to ice sublimation by focusing on V883 Ori, a system currently undergoing a powerful accretion outburst. We present new analysis of archival high resolution ALMA observations of the protoplanetary disc of V883 Ori at 0.88, 1.3, 2.0, and 3.1 mm, and derive new radial spectral index profiles, which we compare with predictions from one-dimensional dust evolution simulations. In the region of V883 Ori where water ice has sublimated, we find lower spectral indices than previously obtained, indicating the presence of cm-sized particles. Coupled with our dust evolution models, we find that the only way to explain their presence is to assume they formed before the outburst, and survived the sublimation process. The resilience of dust aggregates to such intense events leads us to speculate that it may extend to other environments with more gentle heating, such as pebbles drifting through the water snowline in quiescent protoplanetary discs. In that case, it may alter the formation pathway of dry planetesimals interior to the snowline.

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arXiv2023

Water-Rich Disks around Late M-stars Unveiled: Exploring the Remarkable Case of Sz114

We present an analysis of the JDISC JWST/MIRI-MRS spectrum of Sz~114, an accreting M5 star surrounded by a large dust disk with a shallow gap at $\sim 39$ au. The spectrum is molecular-rich: we report the detection of water, CO, CO$_2$, HCN, C$_2$H$_2$, and H$_2$. The only identified atomic/ionic transition is from [NeII] at 12.81 micron. A distinct feature of this spectrum is the forest of water lines with the 17.22 micron emission surpassing that of most mid-to-late M-star disks by an order of magnitude in flux and aligning instead with disks of earlier-type stars. Moreover, flux ratios of C$_2$H$_2$/H$_2$O and HCN/H$_2$O in Sz~114 also resemble those of earlier-type disks, with a slightly elevated CO$_2$/H$_2$O ratio. While accretional heating can boost all infrared lines, the unusual properties of Sz~114 could be explained by the young age of the source, its formation under unusual initial conditions (a large massive disk), and the presence of dust substructures. The latter delays the inward drift of icy pebbles and help preserve a lower C/O ratio over an extended period. In contrast, mid-to-late M-star disks--which are typically faint, small in size, and likely lack significant substructures--may have more quickly depleted the outer icy reservoir and already evolved out of a water-rich inner disk phase. Our findings underscore the unexpected diversity within mid-infrared spectra of mid-to-late M-star disks, highlighting the need to expand the observational sample for a comprehensive understanding of their variations and thoroughly test pebble drift and planet formation models.

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arXiv2023

JWST reveals excess cool water near the snowline in compact disks, consistent with pebble drift

Previous analyses of mid-infrared water spectra from young protoplanetary disks observed with the Spitzer-IRS found an anti-correlation between water luminosity and the millimeter dust disk radius observed with ALMA. This trend was suggested to be evidence for a fundamental process of inner disk water enrichment, used to explain properties of the Solar System 40 years ago, in which icy pebbles drift inward from the outer disk and sublimate after crossing the snowline. Previous analyses of IRS water spectra, however, were uncertain due to the low spectral resolution that blended lines together. We present new JWST-MIRI spectra of four disks, two compact and two large with multiple radial gaps, selected to test the scenario that water vapor inside the snowline is regulated by pebble drift. The higher spectral resolving power of MIRI-MRS now yields water spectra that separate individual lines, tracing upper level energies from 900 K to 10,000 K. These spectra clearly reveal excess emission in the low-energy lines in compact disks, compared to the large disks, demonstrating an enhanced cool component with $T \approx$ 170-400 K and equivalent emitting radius $R_{\rm{eq}}\approx$ 1-10 au. We interpret the cool water emission as ice sublimation and vapor diffusion near the snowline, suggesting that there is indeed a higher inwards mass flux of icy pebbles in compact disks. Observation of this process opens up multiple exciting prospects to study planet formation chemistry in inner disks with JWST.

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arXiv2023

Chemical footprints of giant planet formation. Role of planet accretion in shaping the C/O ratio of protoplanetary disks

Protoplanetary disks, the birthplaces of planets, commonly feature bright rings and dark gaps in both continuum and line emission maps. Accreting planets are interacting with the disk, not only through gravity, but also by changing the local irradiation and elemental abundances, which are essential ingredients for disk chemistry. We propose that giant planet accretion can leave chemical footprints in the gas local to the planet, which potentially leads to the spatial coincidence of molecular emissions with the planet in ALMA observation. Through 2D multi-fluid hydrodynamical simulations in Athena++ with built-in sublimation, we simulate the process of an accreting planet locally heating up its vicinity, opening a gas gap in the disk, and creating the conditions for C-photochemistry. An accreting planet located outside the methane snowline can render the surrounding gas hot enough to sublimate the C-rich organics off pebbles before they are accreted by the planet. This locally elevates the disk gas-phase C/O ratio, providing a potential explanation for the C$_2$H line-emission rings observed with ALMA. In particular, our findings provide an explanation for the MWC480 disk, where previous work has identified a statistically significant spatial coincidence of line-emission rings inside a continuum gap. Our findings present a novel view of linking the gas accretion of giant planets and their natal disks through the chemistry signals. This model demonstrates that giant planets can actively shape their forming chemical environment, moving beyond the traditional understanding of the direct mapping of primordial disk chemistry onto planets.

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arXiv2023

The Effect of Dust Evolution and Traps on Inner Disk Water Enrichment

Substructures in protoplanetary disks can act as dust traps that shape the radial distribution of pebbles. By blocking the passage of pebbles, the presence of gaps in disks may have a profound effect on pebble delivery into the inner disk, crucial for the formation of inner planets via pebble accretion. This process can also affect the delivery of volatiles (such as H$_2$O) and their abundance within the water snow line region (within a few au). In this study, we aim to understand what effect the presence of gaps in the outer gas disk may have on water vapor enrichment in the inner disk. Building on previous work, we employ a volatile-inclusive multi-Myr disk evolution model that considers an evolving ice-bearing drifting dust population, sensitive to dust-traps, which loses its icy content to sublimation upon reaching the snow line. We find that vapor abundance in the inner disk is strongly affected by fragmentation velocity (v$_{\rm f}$) and turbulence, which control how intense vapor enrichment from pebble delivery is, if present, and how long it may last. Generally, for disks with low to moderate turbulence ($α$ $\le$ 1 $\times$ 10$^{-3}$) and for a range of v$_{\rm f}$, radial location, and gap depth (especially that of the innermost gaps), can significantly alter enrichment. Shallow inner gaps may continuously leak material from beyond it, despite the presence of additional deep outer gaps. We finally find that the for realistic v$_{\rm f}$ ($\le$ 10 m s$^{-1}$), presence of gaps is more important than planetesimal formation beyond the snow line in regulating pebble and volatile delivery into the inner disk.

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arXiv2023

Collisional evolution of dust and water ice in protoplanetary discs during and after an accretion outburst

Most protoplanetary discs are thought to undergo violent and frequent accretion outbursts, during which the accretion rate and central luminosity are elevated for several decades. This temporarily increases the disc temperature, leading to the sublimation of ice species as snowlines move outwards. In this paper, we investigate how an FUor-type accretion outburst alters the growth and appearance of dust aggregates at different locations in protoplanetary discs. We develop a model based on the Monte Carlo approach to simulate locally the coagulation and fragmentation of icy dust particles and investigate different designs for their structure and response to sublimation. Our main finding is that the evolution of dust grains located between the quiescent and outburst water snowlines is driven by significant changes in composition and porosity. The time required for the dust population to recover from the outburst and return to a coagulation/fragmentation equilibrium depends on the complex interplay of coagulation physics and outburst properties, and can take up to 4500 yr at 5 au. Pebble-sized particles, the building blocks of planetesimals, are either deprecated in water ice or completely destroyed, respectively resulting in drier planetesimals or halting their formation altogether. When accretion outbursts are frequent events, the dust can be far from collisional equilibrium for a significant fraction of time, offering opportunities to track past outbursts in discs at millimetre wavelengths. Our results highlight the importance of including accretion outbursts in models of dust coagulation and planet formation.

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arXiv2022

Chemical evolution in planet-forming regions with growing grains

[Abridged] Planets and their atmospheres are built from gas and solid material in protoplanetary disks. This solid material grows from smaller, micron-sized grains to larger sizes in the disks, during the process of planet formation. Our goal is to model the compositional evolution of volatile ices on grains of different sizes, assuming both time-dependent grain growth and several constant grain sizes. The state-of-the-art Walsh chemical kinetics code is utilised for modeling chemical evolution. This code has been upgraded to account for the time-evolving sizes of solids. Chemical evolution is modelled locally at four different radii in a protoplanetary disk midplane for up to 10Myr. The evolution is modelled for five different constant grain sizes, and one model where the grain size changes with time according to a grain growth model appropriate for the disk midplane. Local grain growth, with conservation of total grain mass and the assumption of spherical grains, acts to reduced the total grain-surface area that is available for ice-phase reactions. This reduces these reactions efficiency compared to a chemical scenario with a conventional grain-size choice of 0.1$μ$m. The modelled chemical evolution with grain growth leads to increased abundances of H$_{2}$O ice. For carbon in the inner disk, grain growth leads CO gas to overtake CO$_{2}$ ice as dominant carrier, and in the outer disk, CH$_{4}$ ice to become the dominant carrier. Overall, a constant grain size adopted from a grain evolution model leads to almost identical chemical evolution, when compared with chemical evolution with evolving grain sizes. A constant grain size choice, albeit larger than 0.1$μ$m, may therefore be an appropriate simplification when approximating the impact of grain growth on chemical evolution.

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arXiv2022

Chemical Habitability: Supply and Retention of Life's Essential Elements During Planet Formation

Carbon, Hydrogen, Nitrogen, Oxygen, Phosphorus and Sulfur (CHNOPS) play key roles in the origin and proliferation of life on Earth. Given the universality of physics and chemistry, not least the ubiquity of water as a solvent and carbon as a backbone of complex molecules, CHNOPS are likely crucial to most habitable worlds. To help guide and inform the search for potentially habitable and ultimately inhabited environments, we begin by summarizing the CHNOPS budget of various reservoirs on Earth, their role in shaping our biosphere, and their origins in the Solar Nebula. We then synthesize our current understanding of how these elements behave and are distributed in diverse astrophysical settings, tracing their journeys from synthesis in dying stars to molecular clouds, protoplanetary settings, and ultimately temperate rocky planets around main sequence stars. We end by identifying key branching points during this journey, highlighting instances where a forming planets' distribution of CHNOPS can be altered dramatically, and speculating about the consequences for the chemical habitability of these worlds.

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arXiv2021

If you like C/O variations, you should have put a ring on it

The C/O-ratio as traced with C$_2$H emission in protoplanetary disks is fundamental for constraining the formation mechanisms of exoplanets and our understanding of volatile depletion in disks, but current C$_2$H observations show an apparent bimodal distribution which is not well understood, indicating that the C/O distribution is not described by a simple radial dependence. The transport of icy pebbles has been suggested to alter the local elemental abundances in protoplanetary disks, through settling, drift and trapping in pressure bumps resulting in a depletion of volatiles in the surface and an increase of the elemental C/O. We combine all disks with spatially resolved ALMA C$_2$H observations with high-resolution continuum images and constraints on the CO snowline to determine if the C$_2$H emission is indeed related to the location of the icy pebbles. We report a possible correlation between the presence of a significant CO-icy dust reservoir and high C$_2$H emission, which is only found in disks with dust rings outside the CO snowline. In contrast, compact dust disks (without pressure bumps) and warm transition disks (with their dust ring inside the CO snowline) are not detected in C$_2$H, suggesting that such disks may never have contained a significant CO ice reservoir. This correlation provides evidence for the regulation of the C/O profile by the complex interplay of CO snowline and pressure bump locations in the disk. These results demonstrate the importance of including dust transport in chemical disk models, for a proper interpretation of exoplanet atmospheric compositions, and a better understanding of volatile depletion in disks, in particular the use of CO isotopologues to determine gas surface densities.

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