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Sebastian Zieba

Publications and source records attributed to Sebastian Zieba.

At least 19 recordsLinked to original sources

The dark and featureless surface of rocky exoplanet LHS 3844 b from JWST mid-infrared spectroscopy

JWST has opened a new era in the study of rocky exoplanets, enabling direct characterization of their surfaces with mid-infrared spectroscopy. Different types of rock have distinct spectral features that are diagnostic of the chemical composition and other physical properties like surface texture. Measurements of these features can provide valuable clues about a planet's geologic history and interior processes. Here we report a JWST 5-12 micron thermal emission spectrum for the rocky exoplanet LHS 3844 b. It is best matched by a dark, low-silica surface, such as basalt or other olivine-rich materials. The spectrum rules out fresh powder surfaces; however, space weathering can darken the powders and make them more consistent with the data. The data also disfavor trace concentrations of CO$_2$ or SO$_2$ gas (with 5-sigma and 3-sigma upper limits of 100 mbar and 10 microbar, respectively). Taken together, these results are well fit by an old, space-weathered surface with no evidence of accumulated volcanic gases.

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Sensitivity of Dry Lava Planet Atmospheric Emission Spectra to Changes in Lava Compositions

The atmospheres of hot rocky exoplanets are among the first primary targets of the JWST. Interpreting their atmospheric spectra requires understanding the link between silicate lava compositions and overlying atmospheres. We investigate the sensitivity of simulated emission spectra of dry lava planets to variations in oxide abundances in silicate melt. Our goal is to determine which molten surface features could be distinguishable with future observations. We combine our vaporisation code with gas chemical equilibrium and radiative transfer codes to self-consistently compute atmospheric chemistry and thermal structure. Alongside varying lava compositions, we assess the impact of host star spectral type on emission spectra. TiO2 melt abundance dictates atmospheric TiO, which strongly influences surface temperature and emission spectra due to its short-wave opacity. This creates a degeneracy with heat redistribution efficiency, potentially broken by observing the optical TiO emission feature. Atmospheric SiO and SiO2 abundances depend on melt SiO2 content, with stronger SiO and SiO2 emission features at higher melt abundances. For the currently best observable HREs, changes in TiO2 and SiO2 abundance of about an order of magnitude with respect to BSE, could potentially be observable with 12 JWST eclipse observations.

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An Ancient Brown Dwarf Transiting a Metal-Poor Thick Disk Star

We report the discovery of TOI-7019b, the first transiting brown dwarf (BD) known to orbit a star that is part of the Milky Way's ancient thick disk, as defined chemically ([Fe/H] $= -0.79 \pm 0.05$ dex, [$\alpha$/Fe] $= +0.26 \pm 0.05$ dex, [M/H] $= -0.59 \pm 0.06$ dex) and kinematically ($v_{\perp} \approx 150 \pm 1$ km s$^{-1}$). We estimate a system age $\tau = 12 \pm 2$ Gyr by fitting the host star's spectrum and spectral energy distribution to alpha-enhanced isochrones, and independently using the age-metallicity relation of the thick disk. This makes TOI-7019 by far the most metal-poor and ancient BD host known to date. We measure a BD mass of $61.3 \pm 2.1$ $M_{\rm J}$ and radius of $0.82 \pm 0.02$ $R_{\rm J}$ from a joint analysis of transit photometry and radial velocity measurements, along with an orbital period of $48.2592 \pm 0.0001$ days and an orbital eccentricity of $0.403 \pm 0.002$. The measured radius appears $12.3\% \pm 2.8\%$ larger than predicted relative to standard evolutionary models for old, metal-poor brown dwarfs, hinting at missing physics like the magnetic inhibition of convection. TOI-7019b lowers the probed metallicity regime for transiting BDs by over a factor of two, making it a benchmark system to test evolutionary models in the low-metallicity regime. Future measurements of TOI-7019b's atmosphere will test whether a brown dwarf's atmospheric composition tracks its host star's abundances, as expected for binary-like co-formation.

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First JWST thermal phase curves of temperate terrestrial exoplanets reveal no thick atmosphere around TRAPPIST-1 b and c

We report JWST/MIRI 15 $\mu$m phase curves of TRAPPIST-1 b and c, revealing thermal emission consistent with their irradiation levels, assuming no efficient heat redistribution. We find that TRAPPIST-1 b shows a high dayside brightness temperature (490 $\pm$ 17 K), no significantly detectable nightside emission ($F_{\rm b, Night, max}$ = $39_{-27}^{+55}$ ppm), and no phase offset -- features consistent with a low-albedo, airless ultramafic rocky surface. TRAPPIST-1 c exhibits a lower dayside brightness temperature (369 $\pm$ 23 K), and a nightside flux statistically indistinguishable from that of TRAPPIST-1 b ($F_{\rm c, Night, max}$ = $62_{-43}^{+60}$ ppm). Atmosphere models with surface pressures $\geq$1 bar and efficient greenhouse effects are strongly disfavoured for both planets. TRAPPIST-1 b is unlikely to possess any substantial atmosphere, while TRAPPIST-1 c may retain a tenuous, greenhouse-poor O$_2$-dominated atmosphere or be similarly airless with a more reflective surface. These results suggest divergent evolutionary pathways or atmospheric loss processes, despite similar compositions. These measurements tightly constrain atmosphere retention in the inner TRAPPIST-1 system.

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Characterising the Atmosphere of 55 Cancri e: 1D Forward Model Grid for Current and Future JWST Observations

Recent JWST observations with NIRCam and MIRI of the ultra-short-period super-Earth 55 Cancri e indicate a possible volatile atmosphere surrounding the planet. Previous analysis of the NIRCam spectra suggested potential absorption features from CO2 or CO and significant sub-weekly variability. The MIRI low-resolution spectrum does not contain substantial features but was found to be consistent with effective heat redistribution models. In this work, we computed a grid of over 25000 self-consistent 1D forward models incorporating H-N-O-C-S-P-Si-Ti equilibrium chemistry and assessed plausible atmospheric compositions based on the current JWST data. Despite exhaustive analysis, the composition and properties of the atmosphere remain elusive. While our results statistically favour a global, hydrogen-free, nitrogen-dominated atmosphere enriched in PO and CO2, various alternative compositions, including H2O-,CO-, PH3-, or Si-bearing remain viable explanations. Unconstrained heat redistribution efficiency and absolute NIRCam flux are among the largest sources of uncertainty in our analysis. We also find that the heat redistribution factor and surface pressure are highly degenerate with atmospheric composition, and that these parameters cannot be independently constrained using current JWST observations. Furthermore, we show that the observed variability may arise from dynamic interactions between the atmosphere and an underlying magma ocean, driving rapid shifts in atmospheric chemistry and thermal emission. Our results highlight the importance of using self-consistent forward models when analysing novel JWST spectra with limited signal-to-noise ratios -- such as those of 55 Cancri e -- as it allows for a more comprehensive evaluation of potential atmospheric scenarios while also being less sensitive to subtle spectral differences than retrievals...

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JWST sighting of decameter main-belt asteroids and view on meteorite sources

Asteroid discoveries are essential for planetary-defense efforts aiming to prevent impacts with Earth, including the more frequent megaton explosions from decameter impactors. While large asteroids ($\geq$100 km) have remained in the main belt since their formation, small asteroids are commonly transported to the near-Earth object (NEO) population. However, due to the lack of direct observational constraints, their size-frequency distribution--which informs our understanding of the NEOs and the delivery of meteorite samples to Earth--varies significantly among models. Here, we report 138 detections of the smallest asteroids ($\gtrapprox $10 m) ever observed in the main belt, which were enabled by JWST's infrared capabilities covering the asteroids' emission peaks and synthetic tracking techniques. Despite small orbital arcs, we constrain the objects' distances and phase angles using known asteroids as proxies, allowing us to derive sizes via radiometric techniques. Their size-frequency distribution exhibits a break at ${\sim}100$ m (debiased cumulative slopes of $q = -2.66\pm0.60$ and $-0.97\pm0.14$ for diameters smaller and larger than $\sim $100 m, respectively), suggestive of a population driven by collisional cascade. These asteroids were sampled from multiple asteroid families--most likely Nysa, Polana and Massalia--according to the geometry of pointings considered here. Through additional long-stare infrared observations, JWST is poised to serendipitously detect thousands of decameter-scale asteroids across the sky, probing individual asteroid families and the source regions of meteorites "in-situ".

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The $β$ Pictoris b Hill sphere transit campaign. Paper II: Searching for the signatures of the $β$ Pictoris exoplanets through time delay analysis of the $δ$ Scuti pulsations

The $β$ Pictoris system is the closest known stellar system with directly detected gas giant planets, an edge-on circumstellar disc, and evidence of falling sublimating bodies and transiting exocomets. The inner planet, $β$ Pictoris c, has also been indirectly detected with radial velocity (RV) measurements. The star is a known $δ$ Scuti pulsator, and the long-term stability of these pulsations opens up the possibility of indirectly detecting the gas giant planets through time delays of the pulsations due to a varying light travel time. We search for phase shifts in the $δ$ Scuti pulsations consistent with the known planets $β$ Pictoris b and c and carry out an analysis of the stellar pulsations of $β$ Pictoris over a multi-year timescale. We used photometric data collected by the BRITE-Constellation, bRing, ASTEP, and TESS to derive a list of the strongest and most significant $δ$ Scuti pulsations. We carried out an analysis with the open-source python package maelstrom to study the stability of the pulsation modes of $β$ Pictoris in order to determine the long-term trends in the observed pulsations. We did not detect the expected signal for $β$ Pictoris b or $β$ Pictoris c. The expected time delay is 6 seconds for $β$ Pictoris c and 24 seconds for $β$ Pictoris b. With simulations, we determined that the photometric noise in all the combined data sets cannot reach the sensitivity needed to detect the expected timing drifts. An analysis of the pulsational modes of $β$ Pictoris using maelstrom showed that the modes themselves drift on the timescale of a year, fundamentally limiting our ability to detect exoplanets around $β$ Pictoris via pulsation timing.

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Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

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Characterization of K2-167 b and CALM, a new stellar activity mitigation method

We report precise radial velocity (RV) observations of HD 212657 (= K2-167), a star shown by K2 to host a transiting sub-Neptune-sized planet in a 10 day orbit. Using Transiting Exoplanet Survey Satellite (TESS) photometry, we refined the planet parameters, especially the orbital period. We collected 74 precise RVs with the HARPS-N spectrograph between August 2015 and October 2016. Although this planet was first found to transit in 2015 and validated in 2018, excess RV scatter originally limited mass measurements. Here, we measure a mass by taking advantage of reductions in scatter from updates to the HARPS-N Data Reduction System (2.3.5) and our new activity mitigation method called CCF Activity Linear Model (CALM), which uses activity-induced line shape changes in the spectra without requiring timing information. Using the CALM framework, we performed a joint fit with RVs and transits using EXOFASTv2 and find $M_p = 6.3_{-1.4}^{+1.4}$ $M_{\oplus}$ and $R_p = 2.33^{+0.17}_{-0.15}$ $R_{\oplus}$, which places K2-167 b at the upper edge of the radius valley. We also find hints of a secondary companion at a $\sim$ 22 day period, but confirmation requires additional RVs. Although characterizing lower-mass planets like K2-167 b is often impeded by stellar variability, these systems especially help probe the formation physics (i.e. photoevaporation, core-powered mass loss) of the radius valley. In the future, CALM or similar techniques could be widely applied to FGK-type stars, help characterize a population of exoplanets surrounding the radius valley, and further our understanding of their formation.

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Potential Atmospheric Compositions of TRAPPIST-1 c constrained by JWST/MIRI Observations at 15 $μ$m

The first JWST observations of TRAPPIST-1 c showed a secondary eclipse depth of 421+/-94 ppm at 15 um, which is consistent with a bare rock surface or a thin, O2-dominated, low CO2 atmosphere (Zieba et al. 2023). Here, we further explore potential atmospheres for TRAPPIST-1 c by comparing the observed secondary eclipse depth to synthetic spectra of a broader range of plausible environments. To self-consistently incorporate the impact of photochemistry and atmospheric composition on atmospheric thermal structure and predicted eclipse depth, we use a two-column climate model coupled to a photochemical model, and simulate O2-dominated, Venus-like, and steam atmospheres. We find that a broader suite of plausible atmospheric compositions are also consistent with the data. For lower pressure atmospheres (0.1 bar), our O2-CO2 atmospheres produce eclipse depths within 1$σ$ of the data, consistent with the modeling results of Zieba et al. (2023). However, for higher-pressure atmospheres, our models produce different temperature-pressure profiles and are less pessimistic, with 1-10 bar O2, 100 ppm CO2 models within 2.0-2.2$σ$ of the measured secondary eclipse depth, and up to 0.5% CO2 within 2.9$σ$. Venus-like atmospheres are still unlikely. For thin O2 atmospheres of 0.1 bar with a low abundance of CO2 ($\sim$100 ppm), up to 10% water vapor can be present and still provide an eclipse depth within 1$σ$ of the data. We compared the TRAPPIST-1 c data to modeled steam atmospheres of $\leq$ 3 bar, which are 1.7-1.8$σ$ from the data and not conclusively ruled out. More data will be required to discriminate between possible atmospheres, or to more definitively support the bare rock hypothesis.

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No thick carbon dioxide atmosphere on the rocky exoplanet TRAPPIST-1 c

Seven rocky planets orbit the nearby dwarf star TRAPPIST-1, providing a unique opportunity to search for atmospheres on small planets outside the Solar System (Gillon et al., 2017). Thanks to the recent launch of JWST, possible atmospheric constituents such as carbon dioxide (CO2) are now detectable (Morley et al., 2017, Lincowski et al., 2018}. Recent JWST observations of the innermost planet TRAPPIST-1 b showed that it is most probably a bare rock without any CO2 in its atmosphere (Greene et al., 2023). Here we report the detection of thermal emission from the dayside of TRAPPIST-1 c with the Mid-Infrared Instrument (MIRI) on JWST at 15 micron. We measure a planet-to-star flux ratio of fp/fs = 421 +/- 94 parts per million (ppm) which corresponds to an inferred dayside brightness temperature of 380 +/- 31 K. This high dayside temperature disfavours a thick, CO2-rich atmosphere on the planet. The data rule out cloud-free O2/CO2 mixtures with surface pressures ranging from 10 bar (with 10 ppm CO2) to 0.1 bar (pure CO2). A Venus-analogue atmosphere with sulfuric acid clouds is also disfavoured at 2.6 sigma confidence. Thinner atmospheres or bare-rock surfaces are consistent with our measured planet-to-star flux ratio. The absence of a thick, CO2-rich atmosphere on TRAPPIST-1 c suggests a relatively volatile-poor formation history, with less than 9.5 +7.5 -2.3 Earth oceans of water. If all planets in the system formed in the same way, this would indicate a limited reservoir of volatiles for the potentially habitable planets in the system.

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Photochemical hazes dramatically alter temperature structure and atmospheric circulation in 3D simulations of hot Jupiters

Photochemical hazes are expected to form in hot Jupiter atmospheres and may explain the strong scattering slopes and muted spectral features observed in the transmission spectra of many hot Jupiters. Absorption and scattering by photochemical hazes have the potential to drastically alter temperature structure and atmospheric circulation of these planets but have previously been neglected in general circulation models (GCMs). We present GCM simulations of hot Jupiter HD 189733b that include photochemical hazes as a radiatively active tracer fully coupled to atmospheric dynamics. The influence of haze radiative feedback strongly depends on the assumed haze optical properties. For soot hazes, two distinct thermal inversions form, separated by a local temperature minimum around 10$^{-5}$ bar caused by upwelling on the dayside mixing air with low haze abundance upwards. The equatorial jet broadens and slows down. The horizontal distribution of hazes remains relatively similar to simulations with radiatively passive tracers. For Titan-type hazes, the equatorial jet accelerates and extends to much lower pressures, resulting in a dramatically different 3D distribution of hazes compared to radiatively passive or soot hazes. Further experimental and observational studies to constrain the optical properties of photochemical hazes will therefore be crucial for understanding the role of hazes in exoplanet atmospheres. In the dayside emission spectrum, for both types of hazes the amplitude of near-infrared features is reduced, while the emitted flux at longer wavelengths ($>$4 $μ$m) increases. Haze radiative feedback leads to increased phase curve amplitudes in many infrared wavelength regions, mostly due to stronger dayside emission.

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CHEOPS's hunt for exocomets: photometric observations of 5 Vul

The presence of minor bodies in exoplanetary systems is in most cases inferred through infra-red excesses, with the exception of exocomets. Even if over 35 years have passed since the first detection of exocomets around beta Pic, only ~ 25 systems are known to show evidence of evaporating bodies, and most of them have only been observed in spectroscopy. With the appearance of new high-precision photometric missions designed to search for exoplanets, such as CHEOPS, a new opportunity to detect exocomets is available. Combining data from CHEOPS and TESS we investigate the lightcurve of 5 Vul, an A-type star with detected variability in spectroscopy, to search for non periodic transits that could indicate the presence of dusty cometary tails in the system. While we did not find any evidence of minor bodies, the high precision of the data, along with the combination with previous spectroscopic results and models, allows for an estimation of the sizes and spatial distribution of the exocomets.

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A reflective, metal-rich atmosphere for GJ 1214b from its JWST phase curve

There are no planets intermediate in size between Earth and Neptune in our Solar System, yet these objects are found around a substantial fraction of other stars. Population statistics show that close-in planets in this size range bifurcate into two classes based on their radii. It is hypothesized that the group with larger radii (referred to as "sub-Neptunes") is distinguished by having hydrogen-dominated atmospheres that are a few percent of the total mass of the planets. GJ 1214b is an archetype sub-Neptune that has been observed extensively using transmission spectroscopy to test this hypothesis. However, the measured spectra are featureless, and thus inconclusive, due to the presence of high-altitude aerosols in the planet's atmosphere. Here we report a spectroscopic thermal phase curve of GJ 1214b obtained with JWST in the mid-infrared. The dayside and nightside spectra (average brightness temperatures of 553 $\pm$ 9 and 437 $\pm$ 19 K, respectively) each show >3$σ$ evidence of absorption features, with H$_2$O as the most likely cause in both. The measured global thermal emission implies that GJ 1214b's Bond albedo is 0.51 $\pm$ 0.06. Comparison between the spectroscopic phase curve data and three-dimensional models of GJ 1214b reveal a planet with a high metallicity atmosphere blanketed by a thick and highly reflective layer of clouds or haze.

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The transmission spectrum of the potentially rocky planet L 98-59 c

We present observations of the 1.35+/-0.07 Earth-radius planet L 98-59 c, collected using Wide Field Camera 3 on the Hubble Space Telescope. L 98-59 is a nearby (10.6 pc), bright (H=7.4 mag), M3V star that harbors three small, transiting planets. As one of the closest known transiting multi-planet systems, L 98-59 offers one of the best opportunities to probe and compare the atmospheres of rocky planets that formed in the same stellar environment. We measured the transmission spectrum of L 98-59 c and the extracted spectrum showed marginal evidence (2.1{\sigma}) for wavelength-dependent transit depth variations that could indicate the presence of an atmosphere. We forward-modeled possible atmospheric compositions of the planet based on the transmission spectrum. Although L 98-59 was previously thought to be a fairly quiet star, we have seen evidence for stellar activity, and therefore we assessed a scenario where the source of the signal originates with inhomogeneities on stellar surface. We also see a correlation between transits of L 98-59 c and L 98-59 b collected 12.5 hours apart, which is suggestive (but at <2{\sigma} confidence) of a contaminating component from the star impacting the exoplanet spectrum. While intriguing, our results are inconclusive and additional data is needed to verify any atmospheric signal. Fortunately, additional data has been collected from both HST and JWST. Should this result be confirmed with additional data, L 98-59 c would be the first planet smaller than two Earth-radii with a detected atmosphere.

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Eureka!: An End-to-End Pipeline for JWST Time-Series Observations

$\texttt{Eureka!}$ is a data reduction and analysis pipeline for exoplanet time-series observations, with a particular focus on JWST data. Over the next 1-2 decades, JWST will pursue four main science themes: Early Universe, Galaxies Over Time, Star Lifecycle, and Other Worlds. Our focus is on providing the astronomy community with an open source tool for the reduction and analysis of time-series observations of exoplanets in pursuit of the fourth of these themes, Other Worlds. The goal of $\texttt{Eureka!}$ is to provide an end-to-end pipeline that starts with uncalibrated FITS files and ultimately yields precise exoplanet spectra. The pipeline has a modular structure with six stages, and each stage uses a "Eureka! Control File" (ECF) to allow for easy control of the pipeline's behavior. Stage 5 also uses a "Eureka! Parameter File" (EPF) to control the fitted parameters. We provide template ECFs for the MIRI, NIRCam, NIRISS, and NIRSpec instruments on JWST and the WFC3 instrument on the Hubble Space Telescope (HST). These templates give users a good starting point for their analyses, but $\texttt{Eureka!}$ is not intended to be used as a black box tool, and users should expect to fine-tune some settings for each observation in order to achieve optimal results. At each stage, the pipeline creates intermediate figures and outputs that allow users to compare $\texttt{Eureka!}$'s performance using different parameter settings or to compare $\texttt{Eureka!}$ with an independent pipeline. The ECF used to run each stage is also copied into the output folder from each stage to enhance reproducibility. Finally, while $\texttt{Eureka!}$ has been optimized for exoplanet observations (especially the latter stages of the code), much of the core functionality could also be repurposed for JWST time-series observations in other research domains thanks to $\texttt{Eureka!}$'s modularity.

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PACMAN: A pipeline to reduce and analyze Hubble Wide Field Camera 3 IR Grism data

Here we present PACMAN, an end-to-end pipeline developed to reduce and analyze HST/WFC3 data. The pipeline includes both spectral extraction and light curve fitting. The foundation of PACMAN has been already used in numerous publications (e.g., Kreidberg et al., 2014; Kreidberg et al., 2018) and these papers have already accumulated hundreds of citations. The Hubble Space Telescope (HST) has become the preeminent workhorse facility for the characterization of extrasolar planets. HST currently has two of the most powerful space-based tools for characterizing exoplanets over a broad spectral range: The Space Telescope Imaging Spectrograph (STIS) in the UV and the Wide Field Camera 3 (WFC3) in the Near Infrared. With the introduction of a spatial scan mode on WFC3 where the star moves perpendicular to the dispersion direction during an exposure, WFC3 observations have become very efficient due to the reduction of overhead time and the possibility of longer exposures without saturation. For exoplanet characterization, WFC3 is used for transit and secondary eclipse spectroscopy, and phase curve observations. The instrument has two different grisms: G102 with a spectral range from 800 nm to up to 1150 nm and G141 encompassing 1075 nm to about 1700 nm. The spectral range of WFC3/G141 is primarily sensitive to molecular absorption from water at approximately 1.4 microns. This led to the successful detection of water in the atmosphere of over a dozen of exoplanets. The bluer part of WFC3, the G102 grism, is also sensitive to water and most notably led to the first detection of a helium exosphere.

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Early Release Science of the exoplanet WASP-39b with JWST NIRCam

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $μ$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $μ$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere.

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